CN102597342A - Fluorescent fiber and its application and production method - Google Patents

Fluorescent fiber and its application and production method Download PDF

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Publication number
CN102597342A
CN102597342A CN2010800416125A CN201080041612A CN102597342A CN 102597342 A CN102597342 A CN 102597342A CN 2010800416125 A CN2010800416125 A CN 2010800416125A CN 201080041612 A CN201080041612 A CN 201080041612A CN 102597342 A CN102597342 A CN 102597342A
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China
Prior art keywords
fiber
regenerated celulose
celulose fibre
original liquid
resisdye
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CN2010800416125A
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Chinese (zh)
Inventor
G·埃姆林格
U·马特斯
A·格斯泰特纳
G·克罗纳
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Lenzing AG
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Lenzing AG
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath
    • D01F2/12—Addition of delustering agents to the spinning solution
    • D01F2/14—Addition of pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath
    • D01F2/16—Addition of dyes to the spinning solution
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0004—General aspects of dyeing
    • D06P1/0012—Effecting dyeing to obtain luminescent or phosphorescent dyeings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及一种含有原液着色颜料和套染荧光染料的再生纤维素纤维以及将其用于生产纱线和面料的用途和生产这些纤维的方法。所述纤维满足EN471标准关于亮度、色域和耐磨度的要求，并且具有高于5的耐光度(ISO 105-B02，方法2)。The present invention relates to a regenerated cellulose fiber containing a solution-dyed pigment and an overdyeing fluorescent dye, as well as the use of the fiber in producing yarns and fabrics and a method for producing the fiber. The fiber meets the requirements of the EN471 standard regarding brightness, color range, and abrasion resistance and has a light fastness greater than 5 (ISO 105-B02, method 2).

Description

Fluorescent fiber and application thereof and production method
The present invention relates to for example to be used for the warning clothing of EN 471 standard codes fluorescence arrangement regenerated celulose fibre, use it for yarn and the purposes of fabric and the method for producing these fibers of producing.
The state of the art
EN 471 standards only relate to caution effect, the especially warning clothing of individual protective equipment.Warning clothing is made up of a kind of fluorescence background material and a kind of reflectorized material usually.According to the definition of EN 471 standards, the material that the wavelength of the wavelength ratio absorption radiation of sending radiation is longer is as fluorescent material of the present invention; Below also use this notion of high-visibility material for this reason.The present invention relates to the fluorescence background material, but do not relate to reflectorized material.
Serve as that the basis produces the high-visibility fabric only up to now, but these fabrics have the shortcoming of snugness of fit and security aspect with synthetic fiber especially polyester.The shortcoming of this kind fabric is that especially the skin sense is uncomfortable, wears after the long period and can produce smell because of ventilative inadequate material behavior, and the danger of the common static of synthetic fiber.A kind of possibility for example is the complex textile structure described in the WO 2006/017709, and the high-visibility composition is contained in its outside, and inboard main by constituting in order to the cellulose fibre that improves snugness of fit.Known now mainly with viscose process and solvent method fiber as tModified Cellulose Fibers.The whole world all is used for the standard application in fabric and nonwoven fabric field at this fibrid of production, its filament fiber number is between 0.8～16dtex.
Although can use fluorescent dye regenerated celulose fibre to be dyeed with common dip bath processes; But the fiber of dyeing does not reach fastness rate and requires (ISO 105-B02 by this way; Method 2＞5), it seriously fades after the xenon lamp irradiation, and tone greatly for a change; And color depth greatly reduces, and for example shows as the coordinate offset of colour gamut.
Just having known since the many decades to adopt original liquid coloring pigment dyeing mode to the viscose permanent stain.Can on market, buy corresponding fiber, but also not meet the solution dyeing regenerated fiber of EN 471 standard-requireds up to now.
Task of the present invention
Compared with prior art, task of the present invention provides and a kind ofly can satisfy EN 471 standards for example to the requirement of security warning clothes, can make the snugness of fit of this clothes and the fiber that security is improved with the expense of economical rationality again.Therefore should be with a kind of like this fiber production safety protective clothing under the situation of not mixing other types of fibers.It is especially important that the fabric with these fiber production can satisfy the following requirement of 471 pairs of background materials of EN:
● minimum brightness coefficient (standard value is according to CIE Publikation Nr.15.2) and colour gamut
● the color after the xenon lamp irradiation: shine according to 3 pairs of samples of ISO 105-B02 method
● the abrasion resistance (ISO 105-A02) of doing, wet
Measured the fastness rate of fiber in addition according to ISO 105-B02 method 2.
Task of the present invention also is to provide a kind of production method that is suitable for these fibers.
Surprisingly, adopt the regenerated celulose fibre that contains original liquid coloring pigment and resisdye fluorescent dye, can solve this task.These fibers of the present invention also have the fastness rate (measuring according to ISO 105-B02 method 2) greater than 5 astoundingly except improving snugness of fit and having improved the security because of the basic structure of cellulose.Use known up to now cellulose fibre not reach this effect.
These fibers also meet other desired abrasion resistance value, perspiration resistance degree value, water-fast degree of washing value, the degree of anti-dry-cleaning value, the degree of anti-hypochlorite bleaching value and the degree of anti-flatiron value in EN 471 standards.
Can produce the original liquid coloring regenerated celulose fibre, but also can produce according to viscose process, improved viscose process (for example zinc free viscose method of high wet modulus method, use aluminum sulfate or the like) according to the solvent method that the organic solvent or the so-called ionic liquid of use fusion water-soluble amine oxides and so on are operated.Therefore can these fibers be called viscose, high-wet-modulus fibre or solvent method fiber.
Regenerated celulose fibre can contain other additive.According to a kind of special embodiment, also regenerated celulose fibre is carried out flame-proof treatment.
A kind of preferred implementation of producing fire resistance fibre is to add pigment shape fire retardant.Especially can be except other type with organic phosphorus compound as pigment shape fire retardant, known be suitable for for example having of viscose glue can be from 2,2 of the commodity of having bought on the market Exolit by name or Sandoflame '-oxygen two [5; 5-dimethyl-1; 3, the 2-dioxaphosphorinane] 2,2 ' disulphide.
According to another kind of preferred implementation, also regenerated celulose fibre is carried out antibiotic finish.The material that for this reason can use the professional person to be familiar with.
Utilize the dyestuff (for example chemically-reactive dyes, direct dyes, reducing dye or the like) that is suitable for cellulosic material to carry out the dyeing of high-visibility bath method then.
Can carry out resisdye, the dyeing of bath method just to the flock of original liquid coloring fiber, the fabric face that contains the yarn of original liquid coloring fiber or contain the original liquid coloring fiber.For this reason can the familiar in principle continuous and discontinuous decoration method of Application Major personage.
Through suitable selection original liquid coloring pigment and the high-visibility dyestuff that is used for the dyeing of bath method, also can realize still not having the attainable tone of single solution up to now.
The present invention also relates to the purposes that fiber of the present invention is used to produce yarn.In order to have the characteristic that is suitable for corresponding uses; This yarn of the present invention is except containing fiber of the present invention; The fiber that can also contain other source, the for example polyacrylonitrile fibre (PANOX
Figure BPA00001547302000033
) of (fire-retardant) polyester, modified acrylic fibers, contraposition and meta-aramid, polyamidoimide (Kermel
Figure BPA00001547302000031
), (fire-retardant) wool, polybenzimidazoles (PBI), polyimides (P84
Figure BPA00001547302000032
), polyamide, (fire-retardant) polyamide, flame-retardant acrylic fibre fiber, melamine fiber, polyphenylene sulfide (PPS), polytetrafluoroethylene (PTFE), glass fibre, cotton, silk, carbon fiber, heat of oxidation stabilisation and the mixture of conductive fiber and these fibers.According to a kind of preferred implementation, blending ingredients can have the high-visibility arrangement equally.
The present invention equally also relates to the purposes that fiber of the present invention is used to produce fabric panel; This lining is except containing fiber of the present invention; Also can contain other fiber, for example the polyacrylonitrile fibre (PANOX ) of (fire-retardant) polyester, modified acrylic fibers, contraposition and meta-aramid, polyamidoimide (Kermel ), (fire-retardant) wool, polybenzimidazoles (PBI), polyimides (P84 ), polyamide, (fire-retardant) polyamide, flame-retardant acrylic fibre fiber, melamine fiber, polyphenylene sulfide (PPS), polytetrafluoroethylene (PTFE), glass fibre, cotton, silk, carbon fiber, heat of oxidation stabilisation and the mixture of conductive fiber and these fibers.According to a kind of preferred implementation, other fiber can have the high-visibility arrangement equally.
Fabric panel is suitably woven fabric, knit goods or crocheting fabric, but also can be nonwoven fabric in principle.If woven fabric or crocheting fabric; Then can be employed in the mode of mixing before the yarn of producing; Just so-calledly evenly mix, perhaps in tatting, knitting or crocheting process, use the simple yarn of different fiber types simultaneously, fiber of the present invention and other fiber mixing.
The present invention equally also relates to the purposes that fiber of the present invention is used to produce warning clothing or other caution article, and common above-mentioned yarn or fabric panel occur with intermediate forms in the weaving industrial chain.Other caution article of the present invention for example have other article of the eye-catching especially or interest of pennant, flag, checkmark field and warning tape or color.Therefore purposes of the present invention surmounts simple warning function category.If use above-described nonwoven fabric as lining, for example be used among pennant, flag, checkmark field and the warning tape, then need not the intermediate of yarn certainly.The professional person all understands the different embodiments of this type of clothing and other caution article, no longer gives unnecessary details at this.
The present invention equally also relates to a kind of method of producing fluorescence regenerated celulose fibre according to the invention, according to this method, makes coloring pigment get among the fiber with the original liquid coloring method, in processing step subsequently, uses fluorescent dye that these fibers are carried out resisdye.
Usually adopt the mode that coloring pigment is joined in the spinning solution to carry out original liquid coloring.The professional person all understands this type of adding method in principle, and viscose process is not only arranged, and high wet modulus method and solvent-spinning method are arranged.But needn't in another road step, use another kind of dyestuff that the original liquid coloring cellulose fibre is carried out resisdye subsequently usually; Because original liquid coloring is exactly a kind of very high-efficiency method usually, can it be used for realizing the fastness of very high abrasion resistance, fastness rate, water-fast degree of washing and perspiration resistance degree aspect.But the present invention with after resisdye step combination use then and satisfy the specific (special) requirements of warning clothing with cellulose fibre.
To the flock of original liquid coloring fiber, or yarn or the fabric face that contains the original liquid coloring fiber carried out resisdye, the dyeing of bath method just.Can the equally also familiar in principle continuous and discontinuous decoration method of Application Major personage.
To make an explanation to the present invention according to embodiment now, these embodiment are available embodiment of the present invention, but the present invention is not limited only to these embodiment.
Embodiment 1:
A kind of FRC of original liquid coloring, wherein with respect to the cellulose meter, the weight percentage of yellow uitramarine 3 (for example Aquarine Yellow 10G) is 1.25%; 2,2 '-oxygen two [5,5-dimethyl-1; 3; The 2-dioxaphosphorinane] weight percentage of 2,2 ' disulphide (Exolit 5060, Clariant company) is 22%.According to following prescription, use Remazol glassy yellow FL (DyStar company) that these fibers are carried out resisdye then:
Flock is joined among the dye bath that contains 2%Remazol glassy yellow FL (DyStar company) and 100g/l sodium sulphate, and bath raio is 1: 10, and initial temperature is 25 ℃, is heated to 50 ℃ with the 1 ℃/min rate of heat addition then.Under this temperature,, add 5g/l soda, after 30 minutes, add 1.2ml/l NaOH (50% solution) again through after 10 minutes.Through after 40 minutes, let dye bath cool down again, the flushing of all being familiar with according to the professional person subsequently-soap-wash-order of soaping is carried out post processing.
Then woven fabric is dried and processed to fiber.Table 1 is depicted as the result of the test of this fabric.Result of the test shows according to the fiber of processing according to the invention, yarn and fabric and is particularly suitable among the warning clothing, and can not fade.
Table 1: result of the test (to embodiment 1)
Figure BPA00001547302000051
Embodiment 2 (comparative example):
According to the method identical, the commercially available viscose (Lenzing FR) that equally also uses Exolit 5060 to carry out flame treatment and not contain original liquid coloring pigment is carried out resisdye with embodiment 1.But be to use 6% Remazol glassy yellow FL (DyStar company), rather than 2% among the embodiment 1.Table 2 is depicted as the result of the test of this fiber.
Table 2: result of the test (to embodiment 2)
Figure BPA00001547302000052
After irradiation, the color harmony color depth intensity of variation of the fiber of prior art is obviously greater than fiber of the present invention among the embodiment 1 among the embodiment 2, and this also can find out through bigger colour gamut coordinate offset is clear.After irradiation, the brightness of non-fiber according to the invention also is worse than fiber of the present invention greatly.The fastness rate of the fiber among the embodiment 2 is especially not as fiber of the present invention among the embodiment 1.

Claims (12)

1. the regenerated celulose fibre that contains original liquid coloring pigment and resisdye fluorescent dye.
2. regenerated celulose fibre according to claim 1, it has the fastness rate greater than 5, measures according to ISO 105-B02 method 2.
3. regenerated celulose fibre according to claim 1, it makes according to viscose process, high wet modulus method or solvent method.
4. regenerated celulose fibre according to claim 1, it also passes through flame-proof treatment.
5. regenerated celulose fibre according to claim 4, wherein antiflaming finishing agent is original liquid coloring organic phosphorus compound (preferred 2,2 '-two [5,5-dimethyl-1,3,2-dioxaphosphorinane] 2, the 2 ' disulphide of oxygen).
6. regenerated celulose fibre according to claim 1, it also passes through antibiotic finish.
7. the described fiber of claim 1～6 purposes that is used to produce yarn.
8. the described fiber of claim 1～6 purposes that is used to produce fabric panel.
9. the described fiber of claim 1～6 is used to produce the purposes of warning clothing or other caution article.
10. be used for the method for the said fluorescence regenerated celulose fibre of production claim 1～6, it is characterized in that, make coloring pigment get among the fiber, in processing step subsequently, use fluorescent dye that these fibers are carried out resisdye with the original liquid coloring method.
11. method according to claim 10 wherein adopts continuous or discontinuous processing step to carry out resisdye.
12., wherein yarn or the fabric panel of being processed by regenerated celulose fibre carried out resisdye according to claim 10 or 11 described methods.
CN2010800416125A 2009-09-17 2010-08-05 Fluorescent fiber and its application and production method Pending CN102597342A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ATA1471/2009 2009-09-17
AT0147109A AT508846B1 (en) 2009-09-17 2009-09-17 FLUORESCENT FIBERS, THEIR USE AND METHOD FOR THE PRODUCTION THEREOF
PCT/AT2010/000285 WO2011032191A1 (en) 2009-09-17 2010-08-05 Fluorescent fiber, use thereof, and method for the production thereof

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Publication Number Publication Date
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US (2) US20120244335A1 (en)
EP (1) EP2478138B1 (en)
CN (1) CN102597342A (en)
AT (1) AT508846B1 (en)
ES (1) ES2440939T3 (en)
IN (1) IN2012DN02222A (en)
RU (1) RU2541062C2 (en)
TW (1) TWI539046B (en)
WO (1) WO2011032191A1 (en)

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CN103437211A (en) * 2013-09-05 2013-12-11 苏州巨旺纺织有限公司 Fluorescent polyvinyl chloride fiber fabric
CN103437210A (en) * 2013-09-05 2013-12-11 苏州巨旺纺织有限公司 Fluorescent polypropylene fiber fabric
CN103437206A (en) * 2013-09-05 2013-12-11 苏州巨旺纺织有限公司 Fluorescent polyvinyl alcohol fiber fabric
CN106400235A (en) * 2016-12-07 2017-02-15 北京赛欧兰阻燃纤维有限公司 Blended yarn of organic silicon nitrogen system flame-retardant fiber and organophosphorus system flame-retardant fiber
CN108070951A (en) * 2016-11-14 2018-05-25 历德香港有限公司 Garment fabric manufacturing process, system and product thereof
CN108251908A (en) * 2017-12-01 2018-07-06 绍兴协力新材料科技有限公司 A kind of flame retardant polyester fiber

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DE102011102428A1 (en) 2011-05-24 2012-11-29 Glanzstoff Bohemia S.R.O. Luminescent cellulosic regenerated fiber and process for its preparation
AT511638B1 (en) * 2011-06-21 2016-06-15 Glanzstoff Bohemia Sro HIGHLY CELLULOSIC FILAMENT, ITS USE AND METHOD FOR THE PRODUCTION THEREOF
AT513426A1 (en) * 2012-09-17 2014-04-15 Chemiefaser Lenzing Ag Spun-dyed modal fiber, its use and process for its preparation
AT514469B1 (en) * 2013-01-11 2015-04-15 Chemiefaser Lenzing Ag Flame retardant fabric for protective clothing and upholstery fabrics applications and its use
EP2767180B1 (en) * 2013-02-18 2017-01-04 W.L. Gore & Associates GmbH Flame protective fabric structure
FR3008434A1 (en) * 2013-07-11 2015-01-16 Europrotect France Sa METHOD FOR COLORING A NON-FIRE TEXTILE SUPPORT IN HIGH VISIBILITY COLOR
CN104342779B (en) * 2014-11-11 2016-04-13 江苏江南高纤股份有限公司 Antiforge function polyester PET superbhort fiber, its application, preparation method and preparation system thereof
CN107557979A (en) * 2017-10-31 2018-01-09 东莞联兆纺织科技有限公司 A kind of bamboo fibre, vinegar green grass or young crops rib-loop looped fabric and its processing technology
TWI757669B (en) 2019-12-18 2022-03-11 財團法人紡織產業綜合研究所 Intrinsic fluorecent green fiber and preparing method thereof

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