CS199720B2 - Způsob výroby katalyzátoru pro oxidaci naftalenu - Google Patents

Způsob výroby katalyzátoru pro oxidaci naftalenu Download PDF

Info

Publication number: CS199720B2
Authority: CS; Czechoslovakia
Prior art keywords: carrier; catalyst; temperature; suspension; oxidation
Prior art date: 1977-03-11

Application number

CS152478A

Other languages

Czech (cs)

English (en)

Inventor

Maciej Dukielski

Irena Manikowska

Lech Stefaniak

Maria Wozniakiewicz-Baj

Leszek Grzelewski

Original Assignee

Inst Chemii Przemyslowej

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-03-11

Filing date

1978-03-10

Publication date

1980-07-31

1978-03-10 Application filed by Inst Chemii Przemyslowej filed Critical Inst Chemii Przemyslowej

1980-07-31 Publication of CS199720B2 publication Critical patent/CS199720B2/cs

Links

239000003054 catalyst Substances 0.000 title claims description 37
230000003647 oxidation Effects 0.000 title claims description 11
238000007254 oxidation reaction Methods 0.000 title claims description 11
238000004519 manufacturing process Methods 0.000 title claims description 4
238000000034 method Methods 0.000 claims description 25
239000000725 suspension Substances 0.000 claims description 19
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 15
239000002904 solvent Substances 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
239000013543 active substance Substances 0.000 claims description 9
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 6
238000000354 decomposition reaction Methods 0.000 claims description 4
229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
238000009835 boiling Methods 0.000 claims description 2
229910052593 corundum Inorganic materials 0.000 claims description 2
239000010431 corundum Substances 0.000 claims description 2
230000008021 deposition Effects 0.000 claims description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
239000000243 solution Substances 0.000 description 13
239000000203 mixture Substances 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 5
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
238000001704 evaporation Methods 0.000 description 5
239000002609 medium Substances 0.000 description 5
238000005507 spraying Methods 0.000 description 5
239000007858 starting material Substances 0.000 description 5
229910001935 vanadium oxide Inorganic materials 0.000 description 5
229910003206 NH4VO3 Inorganic materials 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
239000000306 component Substances 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
238000000151 deposition Methods 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
229910052720 vanadium Inorganic materials 0.000 description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000011149 active material Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
229910052939 potassium sulfate Inorganic materials 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
239000003039 volatile agent Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
-1 SbaCl3 Chemical compound 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000000463 material Substances 0.000 description 1
239000012533 medium component Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
230000009972 noncorrosive effect Effects 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000003891 oxalate salts Chemical class 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
239000002994 raw material Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000011973 solid acid Substances 0.000 description 1
238000000935 solvent evaporation Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
PHCBRBWANGJMHS-UHFFFAOYSA-J tetrasodium;disulfate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O PHCBRBWANGJMHS-UHFFFAOYSA-J 0.000 description 1
239000011135 tin Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
150000003681 vanadium Chemical class 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1

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Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CS152478A 1977-03-11 1978-03-10 Způsob výroby katalyzátoru pro oxidaci naftalenu CS199720B2 (cs)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PL19658977A PL106044B1 (pl)	1977-03-11	1977-03-11	Sposob wytwarzania katalizatorow wanadowych do utleniania naftalenu

Publications (1)

Publication Number	Publication Date
CS199720B2 true CS199720B2 (cs)	1980-07-31

Family

ID=19981375

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS152478A CS199720B2 (cs)	1977-03-11	1978-03-10	Způsob výroby katalyzátoru pro oxidaci naftalenu

Country Status (4)

Country	Link
CS (1)	CS199720B2 (pl)
HU (1)	HU177108B (pl)
PL (1)	PL106044B1 (pl)
YU (1)	YU55178A (pl)

1977
- 1977-03-11 PL PL19658977A patent/PL106044B1/pl not_active IP Right Cessation
1978
- 1978-03-09 YU YU55178A patent/YU55178A/xx unknown
- 1978-03-10 HU HUII000261 patent/HU177108B/hu unknown
- 1978-03-10 CS CS152478A patent/CS199720B2/cs unknown

Also Published As

Publication number	Publication date
PL196589A1 (pl)	1978-10-09
YU55178A (en)	1982-06-30
HU177108B (hu)	1981-07-28
PL106044B1 (pl)	1979-11-30

Publication	Publication Date	Title
RU2043784C1 (ru)	1995-09-20	Катализатор для получения фталевого ангидрида
US3464930A (en)	1969-09-02	Oxidation catalyst containing vanadium and titanium
KR100234874B1 (ko)	1999-12-15	불포화 알데히드 및 불포화 카르복실산 합성용 담지촉매와 그 제조방법
JPS598178B2 (ja)	1984-02-23	アクロレィンを酸化してアクリル酸を製造するための触媒
ES2214492T3 (es)	2004-09-16	Modificacion superficial y promocion de catalizadores de oxido de vanadio-antimonio.
HUT69294A (en)	1995-09-28	Process for the transformation of vanadium/posphorus mixed oxide catalyst precursors into active catalysts for the production of maleic- anhydride
JPH0515711B2 (pl)	1993-03-02
MXPA00007821A (es)	2002-04-24	Catalizadores de heteropoliacido/polioxometalato.
US4075231A (en)	1978-02-21	Process for preparing phthalic anhydride
JPH01201023A (ja)	1989-08-14	安定化された特性を有する酸化チタン
JPS6018212B2 (ja)	1985-05-09	メタクリル酸製造用触媒の再生法
CS199720B2 (cs)	1980-07-31	Způsob výroby katalyzátoru pro oxidaci naftalenu
JPH0243949A (ja)	1990-02-14	パラフィン類のアンモ酸化法およびそのための触媒系
US4110369A (en)	1978-08-29	Process for the preparation of unsaturated acids from unsaturated aldehydes
NL8003061A (nl)	1980-12-02	Slijtbestendige katalysatoren.
US4097501A (en)	1978-06-27	Use of coated catalysts in the preparation of maleic anhydride
JPH04182450A (ja)	1992-06-30	メタクリル酸の製造方法
JP2002503628A (ja)	2002-02-05	複合金属酸化物材料
CS209892B2 (en)	1981-12-31	Method of preparation of the maleinanhydrite
JPH0149133B2 (pl)	1989-10-23
SU682107A3 (ru)	1979-08-25	Способ приготовлени ванадий-молибденового катализатора дл окислени бензола
JP2000300986A (ja)	2000-10-31	アクリル酸製造用触媒、その調製方法およびアクリル酸の製造方法
JPH0525079A (ja)	1993-02-02	置換ベンズアルデヒドの製造方法
JPH0386242A (ja)	1991-04-11	メタクリル酸製造用触媒およびその製造方法
PL56431B1 (pl)	1968-10-25