CS229503B1 - Method for the producing hard polyurethanizokyanuratic foams - Google Patents

Method for the producing hard polyurethanizokyanuratic foams Download PDF

Info

Publication number: CS229503B1
Authority: CS; Czechoslovakia
Prior art keywords: foams; polyol; diisocyanate; pat; compounds
Prior art date: 1980-08-29

Application number

CS590480A

Other languages

Czech (cs)

English (en)

Slovak (sk)

Inventor

Jozef Ing Csc Stresinka

Eugen Ing Malcovsky

Jozef Ing Mokry

Vendelin Prof Ing Drsc Macho

Original Assignee

Stresinka Jozef

Eugen Ing Malcovsky

Jozef Ing Mokry

Macho Vendelin

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-08-29

Filing date

1980-08-29

Publication date

1984-06-18

1980-08-29 Application filed by Stresinka Jozef, Eugen Ing Malcovsky, Jozef Ing Mokry, Macho Vendelin filed Critical Stresinka Jozef

1980-08-29 Priority to CS590480A priority Critical patent/CS229503B1/cs

1981-07-30 Priority to SU817771974A priority patent/SU1291589A1/ru

1981-07-31 Priority to DD23238681A priority patent/DD230249A3/de

1981-08-06 Priority to DE19813131203 priority patent/DE3131203A1/de

1981-08-07 Priority to PL23253081A priority patent/PL132083B2/pl

1981-08-12 Priority to RO105083A priority patent/RO83485B/ro

1981-08-28 Priority to AT374281A priority patent/ATA374281A/de

1984-06-18 Publication of CS229503B1 publication Critical patent/CS229503B1/cs

Links

239000006260 foam Substances 0.000 title claims description 24
238000000034 method Methods 0.000 title claims description 12
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 16
229920005862 polyol Polymers 0.000 claims description 14
150000003077 polyols Chemical class 0.000 claims description 14
239000004814 polyurethane Substances 0.000 claims description 14
229920002635 polyurethane Polymers 0.000 claims description 14
239000003054 catalyst Substances 0.000 claims description 13
238000004519 manufacturing process Methods 0.000 claims description 11
229920005906 polyester polyol Polymers 0.000 claims description 11
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 8
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 8
239000003381 stabilizer Substances 0.000 claims description 7
229920001228 polyisocyanate Polymers 0.000 claims description 6
239000005056 polyisocyanate Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
238000004821 distillation Methods 0.000 claims description 5
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
238000005886 esterification reaction Methods 0.000 claims description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
230000032050 esterification Effects 0.000 claims description 2
239000000546 pharmaceutical excipient Substances 0.000 claims description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
150000001875 compounds Chemical class 0.000 description 13
239000000203 mixture Substances 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 10
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 10
239000012948 isocyanate Substances 0.000 description 8
150000002513 isocyanates Chemical class 0.000 description 8
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 8
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
238000005829 trimerization reaction Methods 0.000 description 6
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
239000004604 Blowing Agent Substances 0.000 description 5
239000004721 Polyphenylene oxide Substances 0.000 description 5
-1 matelnovine Chemical class 0.000 description 5
229920000570 polyether Polymers 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 4
125000005442 diisocyanate group Chemical group 0.000 description 4
PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 4
238000005187 foaming Methods 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
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235000011056 potassium acetate Nutrition 0.000 description 4
239000000047 product Substances 0.000 description 4
239000007858 starting material Substances 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
150000003512 tertiary amines Chemical class 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 3
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239000007983 Tris buffer Substances 0.000 description 3
238000009835 boiling Methods 0.000 description 3
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150000001991 dicarboxylic acids Chemical class 0.000 description 3
239000003995 emulsifying agent Substances 0.000 description 3
239000003063 flame retardant Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000012190 activator Substances 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
239000003513 alkali Substances 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
239000012975 dibutyltin dilaurate Substances 0.000 description 2
125000006222 dimethylaminomethyl group Chemical group [H]C([H])([H])N(C([H])([H])[H])C([H])([H])* 0.000 description 2
239000000945 filler Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
150000004010 onium ions Chemical class 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
235000013772 propylene glycol Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
229940029284 trichlorofluoromethane Drugs 0.000 description 2
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
ZXUJWPHOPHHZLR-UHFFFAOYSA-N 1,1,1-trichloro-2-fluoroethane Chemical compound FCC(Cl)(Cl)Cl ZXUJWPHOPHHZLR-UHFFFAOYSA-N 0.000 description 1
OIQOUHIUUREZOM-UHFFFAOYSA-N 1,1-dichloro-1,2-difluoroethane Chemical compound FCC(F)(Cl)Cl OIQOUHIUUREZOM-UHFFFAOYSA-N 0.000 description 1
FDYWJVHETVDSRA-UHFFFAOYSA-N 1,1-diisocyanatobutane Chemical compound CCCC(N=C=O)N=C=O FDYWJVHETVDSRA-UHFFFAOYSA-N 0.000 description 1
WOGVOIWHWZWYOZ-UHFFFAOYSA-N 1,1-diisocyanatoethane Chemical compound O=C=NC(C)N=C=O WOGVOIWHWZWYOZ-UHFFFAOYSA-N 0.000 description 1
ZGSXEIQCYGNTOH-UHFFFAOYSA-N 1,1-diisocyanatopropane Chemical compound O=C=NC(CC)N=C=O ZGSXEIQCYGNTOH-UHFFFAOYSA-N 0.000 description 1
WVWYODXLKONLEM-UHFFFAOYSA-N 1,2-diisocyanatobutane Chemical compound O=C=NC(CC)CN=C=O WVWYODXLKONLEM-UHFFFAOYSA-N 0.000 description 1
VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 1
LPCWDBCEHWHJGX-UHFFFAOYSA-N 1-ethyl-2-methylpiperidine Chemical compound CCN1CCCCC1C LPCWDBCEHWHJGX-UHFFFAOYSA-N 0.000 description 1
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
GELKGHVAFRCJNA-UHFFFAOYSA-N 2,2-Dimethyloxirane Chemical compound CC1(C)CO1 GELKGHVAFRCJNA-UHFFFAOYSA-N 0.000 description 1
WIIVKNLYINAMDA-UHFFFAOYSA-N 2,4,6-tris(diethylaminomethyl)phenol Chemical compound CCN(CC)CC1=CC(CN(CC)CC)=C(O)C(CN(CC)CC)=C1 WIIVKNLYINAMDA-UHFFFAOYSA-N 0.000 description 1
AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
FUIQBJHUESBZNU-UHFFFAOYSA-N 2-[(dimethylazaniumyl)methyl]phenolate Chemical compound CN(C)CC1=CC=CC=C1O FUIQBJHUESBZNU-UHFFFAOYSA-N 0.000 description 1
OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical class C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
WWOWSCHTOQOPOW-UHFFFAOYSA-N ClCCC(C)OP(O)(=O)OC(C)CCCl Chemical compound ClCCC(C)OP(O)(=O)OC(C)CCCl WWOWSCHTOQOPOW-UHFFFAOYSA-N 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
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229930195725 Mannitol Natural products 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
241001387976 Pera Species 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
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XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
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TUEIURIZJQRMQE-UHFFFAOYSA-N [2-(tert-butylsulfamoyl)phenyl]boronic acid Chemical compound CC(C)(C)NS(=O)(=O)C1=CC=CC=C1B(O)O TUEIURIZJQRMQE-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
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150000001447 alkali salts Chemical class 0.000 description 1
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150000001412 amines Chemical class 0.000 description 1
ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
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WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 description 1
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HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
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239000011651 chromium Substances 0.000 description 1
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239000010941 cobalt Substances 0.000 description 1
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239000007799 cork Substances 0.000 description 1
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125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
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150000002009 diols Chemical class 0.000 description 1
239000000975 dye Substances 0.000 description 1
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150000002148 esters Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
210000000497 foam cell Anatomy 0.000 description 1
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150000002334 glycols Chemical class 0.000 description 1
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238000010438 heat treatment Methods 0.000 description 1
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150000002430 hydrocarbons Chemical class 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
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WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical class [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
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230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
HVFSJXUIRWUHRG-UHFFFAOYSA-N oic acid Natural products C1CC2C3CC=C4CC(OC5C(C(O)C(O)C(CO)O5)O)CC(O)C4(C)C3CCC2(C)C1C(C)C(O)CC(C)=C(C)C(=O)OC1OC(COC(C)=O)C(O)C(O)C1OC(C(C1O)O)OC(COC(C)=O)C1OC1OC(CO)C(O)C(O)C1O HVFSJXUIRWUHRG-UHFFFAOYSA-N 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
150000001282 organosilanes Chemical class 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
150000004707 phenolate Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006149 polyester-amide block copolymer Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
ALRFTTOJSPMYSY-UHFFFAOYSA-N tin disulfide Chemical compound S=[Sn]=S ALRFTTOJSPMYSY-UHFFFAOYSA-N 0.000 description 1
YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Landscapes

Polyurethanes Or Polyureas (AREA)

CS590480A 1980-08-08 1980-08-29 Method for the producing hard polyurethanizokyanuratic foams CS229503B1 (en)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
CS590480A CS229503B1 (en)	1980-08-29	1980-08-29	Method for the producing hard polyurethanizokyanuratic foams
SU817771974A SU1291589A1 (ru)	1980-08-29	1981-07-30	Способ получени полиизоциануратуретановых пенопластов
DD23238681A DD230249A3 (de)	1980-08-29	1981-07-31	Verfahren zur herstellung von polyurethan-isozyanuraten
DE19813131203 DE3131203A1 (de)	1980-08-08	1981-08-06	Verfahren zur herstellung von polyurethanen und polyurethanisocyanuraten
PL23253081A PL132083B2 (en)	1980-08-29	1981-08-07	Method of manufacture of polyurethanes or polyurethaneisocyanurates
RO105083A RO83485B (ro)	1980-08-29	1981-08-12	Procedeu pentru obtinerea poliuretanilor si a poliuretanizocianuratilor
AT374281A ATA374281A (de)	1980-08-29	1981-08-28	Verfahren zur herstellung von polyurethanen oder polyurethanisozyanuraten und insbesondere von entsprechenden hartschaeumen

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CS590480A CS229503B1 (en)	1980-08-29	1980-08-29	Method for the producing hard polyurethanizokyanuratic foams

Publications (1)

Publication Number	Publication Date
CS229503B1 true CS229503B1 (en)	1984-06-18

Family

ID=5404878

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS590480A CS229503B1 (en)	1980-08-08	1980-08-29	Method for the producing hard polyurethanizokyanuratic foams

Country Status (3)

Country	Link
CS (1)	CS229503B1 (de)
DD (1)	DD230249A3 (de)
SU (1)	SU1291589A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2519938C2 (ru) *	2008-11-06	2014-06-20	Байер Матириальсайенс Аг	Способ получения сложных полиэфирполиолов с низким содержанием побочного диоксана

1980
- 1980-08-29 CS CS590480A patent/CS229503B1/cs unknown
1981
- 1981-07-30 SU SU817771974A patent/SU1291589A1/ru active
- 1981-07-31 DD DD23238681A patent/DD230249A3/de unknown

Also Published As

Publication number	Publication date
SU1291589A1 (ru)	1987-02-23
DD230249A3 (de)	1985-11-27

Publication	Publication Date	Title
AU592649B2 (en)	1990-01-18	A process for the production of oligoesters containing hydroxy groups and their use
US4469824A (en)	1984-09-04	Liquid terephthalic ester polyols and polyisocyanurate foams therefrom
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US4439549A (en)	1984-03-27	Novel aromatic polyester polyol mixtures made from polyethylene terephthalate residues and alkylene oxides
KR20000053019A (ko)	2000-08-25	경질 폴리우레탄 발포체
US5102919A (en)	1992-04-07	Reduced smoke generating polyurethane/polyisocyanurate foams
CZ301020B6 (cs)	2009-10-14	Zpusob výroby Mannichova polyolu
US5132040A (en)	1992-07-21	Chemical blowing agent
US4758607A (en)	1988-07-19	Distilled products of polyethylene terephthalate polymers and polycarboxylic acid-containing polyols and polymeric foams obtained therefrom
US4439546A (en)	1984-03-27	Scrap rim polyurethane modified extender polyols
EP0113172A1 (de)	1984-07-11	Aromatische Aminopolyole und daraus erhältliche starre Polyurethan- und Polyisocyanuratschäume
US4468483A (en)	1984-08-28	Aromatic polyester polycarbonates from polyols derived from recycled polyethylene terephthalate
US4760099A (en)	1988-07-26	Stabilizer-containing polyol compositions for polyurethane and polyisocyanurate foams
EP1112300B1 (de)	2003-11-26	Co-initiierte polyetherpolyolen und verfahren zu ihrer herstellung
US4046742A (en)	1977-09-06	Compositions containing hydroxyl groups and their use for the production of flameproof plastics
JPS63309511A (ja)	1988-12-16	ポリイソシアヌレート発泡体の製法
US5126305A (en)	1992-06-30	Catalyst composition
US4468481A (en)	1984-08-28	Flame retardant polyurethane modified polyisocyanurate
US3876568A (en)	1975-04-08	Low smoke output polyisocyanurate-urethane foams containing sulfur
US4753967A (en)	1988-06-28	Polyester polyols modified by polyols having 1 degree and 2 degree OH groups and cellular foams therefrom
US3988302A (en)	1976-10-26	Polyurethanes prepared by reaction of organic polyisocyanate with brominated ester-containing polyols
US4536522A (en)	1985-08-20	Manufacture of polyols and rigid polyurethane foam using thiodialkylene glycols
US5350780A (en)	1994-09-27	Process for the preparation of substantially closed-cell rigid foams containing urethane, urea, biuret, and isocyanurate groups and a method of use thereof
CS229503B1 (en)	1984-06-18	Method for the producing hard polyurethanizokyanuratic foams
US4468482A (en)	1984-08-28	Flame retarded polyisocyanurate foam made from polyol derived from halogen containing dicarboxylic acid anhydride