CS251096B2 - Method of carrier catalyst preparation for application during alpha-olefins' polymerization - Google Patents

Method of carrier catalyst preparation for application during alpha-olefins' polymerization Download PDF

Info

Publication number: CS251096B2
Authority: CS; Czechoslovakia
Prior art keywords: compound; carrier; vanadium; catalyst; organomagnesium
Prior art date: 1984-04-04

Application number

CS852319A

Other languages

Czech (cs)

English (en)

Inventor

Thomas E Nowlin

Original Assignee

Mobil Oil Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-04-04

Filing date

1985-03-29

Publication date

1987-06-11

1985-03-29 Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp

1987-06-11 Publication of CS251096B2 publication Critical patent/CS251096B2/cs

Links

239000003054 catalyst Substances 0.000 title claims abstract description 155
239000004711 α-olefin Substances 0.000 title claims abstract description 8
238000000034 method Methods 0.000 title claims description 44
238000006116 polymerization reaction Methods 0.000 title claims description 28
238000002360 preparation method Methods 0.000 title claims description 12
239000011777 magnesium Substances 0.000 claims abstract description 56
229910052749 magnesium Inorganic materials 0.000 claims abstract description 44
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 42
150000003682 vanadium compounds Chemical class 0.000 claims abstract description 40
229910052720 vanadium Inorganic materials 0.000 claims abstract description 38
239000010936 titanium Substances 0.000 claims abstract description 37
229910052719 titanium Inorganic materials 0.000 claims abstract description 32
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 31
125000002734 organomagnesium group Chemical group 0.000 claims abstract description 28
150000003609 titanium compounds Chemical class 0.000 claims abstract description 26
239000007788 liquid Substances 0.000 claims description 46
239000000126 substance Substances 0.000 claims description 32
-1 vanadium halide compound Chemical class 0.000 claims description 30
150000001875 compounds Chemical class 0.000 claims description 28
150000002901 organomagnesium compounds Chemical class 0.000 claims description 25
125000004432 carbon atom Chemical group C* 0.000 claims description 13
239000000843 powder Substances 0.000 claims description 13
239000007787 solid Substances 0.000 claims description 13
239000000463 material Substances 0.000 claims description 10
229910052736 halogen Inorganic materials 0.000 claims description 6
150000002367 halogens Chemical class 0.000 claims description 6
238000001704 evaporation Methods 0.000 claims description 3
230000008020 evaporation Effects 0.000 claims description 3
125000001183 hydrocarbyl group Chemical group 0.000 claims 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 28
239000000203 mixture Substances 0.000 abstract description 28
230000000379 polymerizing effect Effects 0.000 abstract 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 84
229920000642 polymer Polymers 0.000 description 50
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 48
239000000047 product Substances 0.000 description 44
239000007789 gas Substances 0.000 description 42
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 39
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 38
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WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 32
239000002245 particle Substances 0.000 description 30
VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 27
238000006243 chemical reaction Methods 0.000 description 24
229910052757 nitrogen Inorganic materials 0.000 description 24
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 23
239000012190 activator Substances 0.000 description 22
239000002904 solvent Substances 0.000 description 21
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 21
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 18
239000005977 Ethylene Substances 0.000 description 18
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 16
230000000052 comparative effect Effects 0.000 description 15
239000000377 silicon dioxide Substances 0.000 description 15
230000000694 effects Effects 0.000 description 13
YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 description 13
150000002681 magnesium compounds Chemical class 0.000 description 12
229920000573 polyethylene Polymers 0.000 description 11
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VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 11
238000010438 heat treatment Methods 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 10
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239000002879 Lewis base Substances 0.000 description 8
239000001257 hydrogen Substances 0.000 description 8
229910052739 hydrogen Inorganic materials 0.000 description 8
150000007527 lewis bases Chemical class 0.000 description 8
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 8
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238000005243 fluidization Methods 0.000 description 7
238000010992 reflux Methods 0.000 description 7
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239000002243 precursor Substances 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
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VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
239000012298 atmosphere Substances 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000000969 carrier Substances 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
229910052804 chromium Inorganic materials 0.000 description 4
239000004707 linear low-density polyethylene Substances 0.000 description 4
239000000178 monomer Substances 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
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238000001556 precipitation Methods 0.000 description 4
239000002002 slurry Substances 0.000 description 4
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VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 4
238000012546 transfer Methods 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
239000007818 Grignard reagent Substances 0.000 description 3
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
229910021550 Vanadium Chloride Inorganic materials 0.000 description 3
229910052786 argon Inorganic materials 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
229940117975 chromium trioxide Drugs 0.000 description 3
GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 3
238000010908 decantation Methods 0.000 description 3
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
238000004821 distillation Methods 0.000 description 3
150000002170 ethers Chemical class 0.000 description 3
238000001914 filtration Methods 0.000 description 3
150000002430 hydrocarbons Chemical group 0.000 description 3
238000000465 moulding Methods 0.000 description 3
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 3
230000000737 periodic effect Effects 0.000 description 3
239000002685 polymerization catalyst Substances 0.000 description 3
239000011148 porous material Substances 0.000 description 3
239000011949 solid catalyst Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
238000012360 testing method Methods 0.000 description 3
238000005406 washing Methods 0.000 description 3
150000003752 zinc compounds Chemical class 0.000 description 3
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
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229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
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150000001335 aliphatic alkanes Chemical class 0.000 description 2
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229910052782 aluminium Inorganic materials 0.000 description 2
239000002585 base Substances 0.000 description 2
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238000001816 cooling Methods 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
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238000002474 experimental method Methods 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
150000002222 fluorine compounds Chemical class 0.000 description 2
239000003517 fume Substances 0.000 description 2
238000012685 gas phase polymerization Methods 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
150000004678 hydrides Chemical class 0.000 description 2
238000011068 loading method Methods 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
238000003801 milling Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 description 2
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239000011541 reaction mixture Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000005059 solid analysis Methods 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
QQXSEZVCKAEYQJ-UHFFFAOYSA-N tetraethylgermanium Chemical compound CC[Ge](CC)(CC)CC QQXSEZVCKAEYQJ-UHFFFAOYSA-N 0.000 description 1
ZRLCXMPFXYVHGS-UHFFFAOYSA-N tetramethylgermane Chemical compound C[Ge](C)(C)C ZRLCXMPFXYVHGS-UHFFFAOYSA-N 0.000 description 1
UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
238000013022 venting Methods 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
238000004260 weight control Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CS852319A 1984-04-04 1985-03-29 Method of carrier catalyst preparation for application during alpha-olefins' polymerization CS251096B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/596,777 US4593009A (en)	1984-04-04	1984-04-04	Catalyst composition for polymerizing alpha-olefins

Publications (1)

Publication Number	Publication Date
CS251096B2 true CS251096B2 (en)	1987-06-11

Family

ID=24388653

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS852319A CS251096B2 (en)	1984-04-04	1985-03-29	Method of carrier catalyst preparation for application during alpha-olefins' polymerization

Country Status (8)

Country	Link
US (1)	US4593009A (de)
EP (1)	EP0159839A3 (de)
JP (1)	JPS61204A (de)
AU (1)	AU582569B2 (de)
BR (1)	BR8501600A (de)
CA (1)	CA1236820A (de)
CS (1)	CS251096B2 (de)
ZA (1)	ZA852364B (de)

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US5783638A (en) *	1991-10-15	1998-07-21	The Dow Chemical Company	Elastic substantially linear ethylene polymers
US5525695A (en)	1991-10-15	1996-06-11	The Dow Chemical Company	Elastic linear interpolymers
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US5576263A (en) *	1993-12-28	1996-11-19	Phillips Petroleum Company	Chromium catalyst compositions and ethylene polymerization processes therewith
US5792534A (en)	1994-10-21	1998-08-11	The Dow Chemical Company	Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US6235105B1 (en)	1994-12-06	2001-05-22	General Atomics	Thin film pigmented optical coating compositions
US6153551A (en) *	1997-07-14	2000-11-28	Mobil Oil Corporation	Preparation of supported catalyst using trialkylaluminum-metallocene contact products
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1984
- 1984-04-04 US US06/596,777 patent/US4593009A/en not_active Expired - Fee Related
1985
- 1985-03-28 CA CA000477729A patent/CA1236820A/en not_active Expired
- 1985-03-28 AU AU40477/85A patent/AU582569B2/en not_active Ceased
- 1985-03-28 ZA ZA852364A patent/ZA852364B/xx unknown
- 1985-03-29 CS CS852319A patent/CS251096B2/cs unknown
- 1985-04-03 EP EP85302330A patent/EP0159839A3/de not_active Withdrawn
- 1985-04-03 BR BR8501600A patent/BR8501600A/pt unknown
- 1985-04-04 JP JP60071861A patent/JPS61204A/ja active Pending

Also Published As

Publication number	Publication date
JPS61204A (ja)	1986-01-06
ZA852364B (en)	1986-11-26
AU582569B2 (en)	1989-04-06
BR8501600A (pt)	1985-12-03
EP0159839A3 (de)	1987-03-04
EP0159839A2 (de)	1985-10-30
CA1236820A (en)	1988-05-17
AU4047785A (en)	1985-10-10
US4593009A (en)	1986-06-03

Publication	Publication Date	Title
CS251096B2 (en)	1987-06-11	Method of carrier catalyst preparation for application during alpha-olefins' polymerization
US4672096A (en)	1987-06-09	Catalyst composition for polymerizing alpha-olefins
US4481301A (en)	1984-11-06	Highly active catalyst composition for polymerizing alpha-olefins
US5079205A (en)	1992-01-07	Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization
CS264328B2 (en)	1989-07-12	Process for preparing carrier catalyst for the polymerization of alpha-olefines
CS232720B2 (en)	1985-02-14	Method of flow catalytic production of ethylene polymers
JP2004527633A (ja)	2004-09-09	オレフィン重合体の製造方法および選ばれた触媒
JPH01279906A (ja)	1989-11-10	分子量分布の制御された高密度または線状低密度オレフィンポリマーの製造用触媒組成物
AU723865B2 (en)	2000-09-07	Ziegler-natta catalyst for ethylene polymerization or copolymerization
JPH01247406A (ja)	1989-10-03	分子量分布の狭いアルファオレフィンポリマー重合用触媒組成物
SK279445B6 (sk)	1998-11-04	Katalyzátor typu ziegler-natta nanesený na nosičov
CS265241B2 (en)	1989-10-13	Process for catalytic polymerization of alphamonoolefines continuous method in gaseous phase in fluid bed
US4562169A (en)	1985-12-31	Alpha-olefins polymerization catalyst of high productivity
US5025072A (en)	1991-06-18	Highly active catalyst composition for polymerizing alpha-olefins
US4675369A (en)	1987-06-23	Catalyst composition for polymerizing alpha-olefins at low reactants partial pressures
US4448944A (en)	1984-05-15	Process for the preparation of a polyolefin, and a catalyst for this process
EP0081940B1 (de)	1986-09-17	Herstellung eines Katalysators und Verfahren zur Herstellung eines linearen Polyäthylens niederer Dichte
EP2350137A1 (de)	2011-08-03	Katalysator zur herstellung von linearem polyethylen niedriger dichte
US4634752A (en)	1987-01-06	Process for preparing alpha-olefin polymers
US4578440A (en)	1986-03-25	Polymerization catalyst and method
WO2018114347A1 (en)	2018-06-28	Ziegler-natta catalyst and preparation thereof
JPH04218506A (ja)	1992-08-10	担体付オレフィン重合触媒
US4568658A (en)	1986-02-04	Catalyst composition for polymerizing alpha-olefins at low reactants partial pressures
US4605638A (en)	1986-08-12	Highly active catalyst composition for polymerizing alpha-olefins
KR100251599B1 (ko)	2000-04-15	구상 촉매 성분의 제조방법