CS34392A3 - Linear or branched block co-polymer and process for preparing thereof - Google Patents

Linear or branched block co-polymer and process for preparing thereof Download PDF

Info

Publication number: CS34392A3
Authority: CS; Czechoslovakia
Prior art keywords: copolymer; polymer; block; complete; diene
Prior art date: 1991-02-06

Application number

CS92343A

Other languages

Czech (cs)

English (en)

Inventor

Sergio Dr Custro

Gian Tommaso Dr Viola

Original Assignee

Enichem Elastomers

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-02-06

Filing date

1992-02-06

Publication date

1992-08-12

1992-02-06 Application filed by Enichem Elastomers filed Critical Enichem Elastomers

1992-08-12 Publication of CS34392A3 publication Critical patent/CS34392A3/cs

Links

229920001400 block copolymer Polymers 0.000 title claims description 48
238000004519 manufacturing process Methods 0.000 title claims description 5
229920000642 polymer Polymers 0.000 claims description 84
229920001577 copolymer Polymers 0.000 claims description 55
239000000178 monomer Substances 0.000 claims description 44
150000001993 dienes Chemical class 0.000 claims description 42
238000006243 chemical reaction Methods 0.000 claims description 40
239000000203 mixture Substances 0.000 claims description 32
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 28
238000000034 method Methods 0.000 claims description 25
238000005984 hydrogenation reaction Methods 0.000 claims description 24
238000006735 epoxidation reaction Methods 0.000 claims description 20
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 18
230000008569 process Effects 0.000 claims description 14
238000005859 coupling reaction Methods 0.000 claims description 13
238000002360 preparation method Methods 0.000 claims description 12
229920002554 vinyl polymer Polymers 0.000 claims description 12
239000003054 catalyst Substances 0.000 claims description 10
229920006216 polyvinyl aromatic Polymers 0.000 claims description 10
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 9
235000019253 formic acid Nutrition 0.000 claims description 9
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 8
239000011541 reaction mixture Substances 0.000 claims description 7
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
239000003153 chemical reaction reagent Substances 0.000 claims description 6
230000008878 coupling Effects 0.000 claims description 6
238000010168 coupling process Methods 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
239000002904 solvent Substances 0.000 claims description 6
239000004593 Epoxy Substances 0.000 claims description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 5
239000004793 Polystyrene Substances 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 5
229920005684 linear copolymer Polymers 0.000 claims description 5
238000006116 polymerization reaction Methods 0.000 claims description 5
230000000379 polymerizing effect Effects 0.000 claims description 5
150000007513 acids Chemical class 0.000 claims description 4
238000012661 block copolymerization Methods 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
125000003700 epoxy group Chemical group 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
229920002223 polystyrene Polymers 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 3
WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 claims description 3
239000007822 coupling agent Substances 0.000 claims description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
229910052710 silicon Inorganic materials 0.000 claims description 2
239000010703 silicon Substances 0.000 claims description 2
229910052718 tin Inorganic materials 0.000 claims description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
125000001931 aliphatic group Chemical group 0.000 claims 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 2
150000004945 aromatic hydrocarbons Chemical class 0.000 claims 2
102100025403 Epoxide hydrolase 1 Human genes 0.000 claims 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
239000005977 Ethylene Substances 0.000 claims 1
101100451963 Homo sapiens EPHX1 gene Proteins 0.000 claims 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
125000005234 alkyl aluminium group Chemical group 0.000 claims 1
150000001805 chlorine compounds Chemical class 0.000 claims 1
150000001869 cobalt compounds Chemical class 0.000 claims 1
229910052732 germanium Inorganic materials 0.000 claims 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
229910052736 halogen Inorganic materials 0.000 claims 1
150000002367 halogens Chemical class 0.000 claims 1
239000003960 organic solvent Substances 0.000 claims 1
150000004760 silicates Chemical class 0.000 claims 1
230000003319 supportive effect Effects 0.000 claims 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
239000000243 solution Substances 0.000 description 10
239000000463 material Substances 0.000 description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
150000002924 oxiranes Chemical group 0.000 description 8
-1 aryl carbon Chemical compound 0.000 description 7
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
239000000758 substrate Substances 0.000 description 6
238000009472 formulation Methods 0.000 description 5
239000002243 precursor Substances 0.000 description 5
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
239000004952 Polyamide Substances 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
239000000499 gel Substances 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000011065 in-situ storage Methods 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
125000000466 oxiranyl group Chemical group 0.000 description 3
229920002647 polyamide Polymers 0.000 description 3
229920000728 polyester Polymers 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
239000013032 Hydrocarbon resin Substances 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical group OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 2
239000005062 Polybutadiene Substances 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000006096 absorbing agent Substances 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
239000013466 adhesive and sealant Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
229920005605 branched copolymer Polymers 0.000 description 2
OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
238000007306 functionalization reaction Methods 0.000 description 2
229920006270 hydrocarbon resin Polymers 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
UIEKYBOPAVTZKW-UHFFFAOYSA-L naphthalene-2-carboxylate;nickel(2+) Chemical compound [Ni+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 UIEKYBOPAVTZKW-UHFFFAOYSA-L 0.000 description 2
239000003921 oil Substances 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
150000004965 peroxy acids Chemical class 0.000 description 2
229920002857 polybutadiene Polymers 0.000 description 2
229920000515 polycarbonate Polymers 0.000 description 2
239000004417 polycarbonate Substances 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
239000000565 sealant Substances 0.000 description 2
238000004513 sizing Methods 0.000 description 2
239000010959 steel Substances 0.000 description 2
229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 2
SHWZFQPXYGHRKT-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;nickel Chemical compound [Ni].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O SHWZFQPXYGHRKT-FDGPNNRMSA-N 0.000 description 1
LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
NHQDETIJWKXCTC-UHFFFAOYSA-N 3-chloroperbenzoic acid Chemical compound OOC(=O)C1=CC=CC(Cl)=C1 NHQDETIJWKXCTC-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
229920000034 Plastomer Polymers 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
RJAKPNRTKDWPJZ-UHFFFAOYSA-N [NH4+].[NH4+].[NH4+].[NH4+].[Br-].[NH4+].[Br-].[Br-].[Br-].[Br-] Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[Br-].[NH4+].[Br-].[Br-].[Br-].[Br-] RJAKPNRTKDWPJZ-UHFFFAOYSA-N 0.000 description 1
QRSFFHRCBYCWBS-UHFFFAOYSA-N [O].[O] Chemical compound [O].[O] QRSFFHRCBYCWBS-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
238000010539 anionic addition polymerization reaction Methods 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000005452 bending Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
150000001804 chlorine Chemical class 0.000 description 1
SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 1
230000021615 conjugation Effects 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
230000007423 decrease Effects 0.000 description 1
ZMXDDKWLCZADIW-UHFFFAOYSA-N dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
JMNDBSWHIXOJLR-UHFFFAOYSA-N ethylbenzene;styrene Chemical compound CCC1=CC=CC=C1.C=CC1=CC=CC=C1 JMNDBSWHIXOJLR-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 1
230000003993 interaction Effects 0.000 description 1
230000016507 interphase Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
229920006030 multiblock copolymer Polymers 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000012285 osmium tetroxide Substances 0.000 description 1
229910000489 osmium tetroxide Inorganic materials 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
229920001707 polybutylene terephthalate Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920006380 polyphenylene oxide Polymers 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000009877 rendering Methods 0.000 description 1
239000005060 rubber Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
229920006163 vinyl copolymer Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/08—Epoxidation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Epoxy Resins (AREA)
Compositions Of Macromolecular Compounds (AREA)
Graft Or Block Polymers (AREA)

CS92343A 1991-02-06 1992-02-06 Linear or branched block co-polymer and process for preparing thereof CS34392A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ITMI910306A IT1244550B (it)	1991-02-06	1991-02-06	Copolimeri a blocchi idrogenati contenenti gruppi epossidici e loro metodo di preparazione

Publications (1)

Publication Number	Publication Date
CS34392A3 true CS34392A3 (en)	1992-08-12

Family

ID=11358459

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS92343A CS34392A3 (en)	1991-02-06	1992-02-06	Linear or branched block co-polymer and process for preparing thereof

Country Status (18)

Country	Link
US (2)	US5412040A (de)
EP (1)	EP0498426B1 (de)
JP (1)	JP3113049B2 (de)
AR (1)	AR246530A1 (de)
AT (1)	ATE147765T1 (de)
AU (1)	AU643594B2 (de)
BR (1)	BR9200409A (de)
CA (1)	CA2060692A1 (de)
CS (1)	CS34392A3 (de)
DE (1)	DE69216649T2 (de)
ES (1)	ES2097224T3 (de)
IE (1)	IE920377A1 (de)
IT (1)	IT1244550B (de)
MX (1)	MX9200503A (de)
PL (1)	PL293374A1 (de)
RU (3)	RU2083595C1 (de)
TR (1)	TR26417A (de)
ZA (1)	ZA92799B (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5399626A (en) *	1991-04-29	1995-03-21	Shell Oil Company	Viscous conjugated diene block copolymers
KR960700278A (ko) *	1993-01-04	1996-01-19	해리 제이. 그윈넬	에폭사이드화된 블록 공중합체(epoxidized block copolymers)
EP0658603A3 (de) *	1993-12-13	1997-11-19	Daicel Chemical Industries, Ltd.	Epoxidmodifiziertes Blockcopolymer enthaltende verträgliche Mischung, ein Verfahren eine thermoplastische Harzzusammensetzung und eine Asphaltzusammensetzung, die ein epoxidmodifiziertes Blockcopolymer enthält
US6255364B1 (en)	1994-06-21	2001-07-03	Shell Oil Company	Crosslinkable waterborne dispersions of epoxidized polydiene block copolymers and amino resins
EP0698638B1 (de) *	1994-07-18	1998-01-28	Shell Internationale Researchmaatschappij B.V.	Vernetzbare wässrige Dispersionen von hydroxyfunktionellen Dienpolymeren und Aminoharzen
US6576692B1 (en) *	1994-10-06	2003-06-10	Daicel Chemical Industries, Ltd.	Epoxidized block copolymer, its production, and its composition
KR100448562B1 (ko) *	1995-07-03	2004-11-16	다이셀 가가꾸 고교 가부시끼가이샤	에폭시화블록공중합체,그제법과조성물
JPH09324113A (ja) *	1996-06-07	1997-12-16	Polyplastics Co	熱可塑性ポリエステル樹脂組成物
EP0878505A4 (de) *	1996-11-22	2000-05-03	Daicel Chem	Heissschmelzzusammensetzungen und mehrschichtige gegenstände, die daraus hergestellte schichten enthalten
IT1295266B1 (it) *	1997-10-03	1999-05-04	Enichem Spa	Procedimento e catalizzatore per l'idrogenazione di composti olefinicamente insaturi
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1991
- 1991-02-06 IT ITMI910306A patent/IT1244550B/it active IP Right Grant
1992
- 1992-02-04 PL PL29337492A patent/PL293374A1/xx unknown
- 1992-02-04 ZA ZA92799A patent/ZA92799B/xx unknown
- 1992-02-05 CA CA002060692A patent/CA2060692A1/en not_active Abandoned
- 1992-02-05 RU SU925010856A patent/RU2083595C1/ru active
- 1992-02-05 US US07/831,444 patent/US5412040A/en not_active Expired - Lifetime
- 1992-02-05 AR AR92321742A patent/AR246530A1/es active
- 1992-02-05 IE IE037792A patent/IE920377A1/en unknown
- 1992-02-05 TR TR92/0129A patent/TR26417A/xx unknown
- 1992-02-05 RU RU93038868A patent/RU2126422C1/ru active
- 1992-02-06 DE DE69216649T patent/DE69216649T2/de not_active Expired - Lifetime
- 1992-02-06 AU AU10777/92A patent/AU643594B2/en not_active Ceased
- 1992-02-06 BR BR929200409A patent/BR9200409A/pt not_active IP Right Cessation
- 1992-02-06 ES ES92101997T patent/ES2097224T3/es not_active Expired - Lifetime
- 1992-02-06 EP EP92101997A patent/EP0498426B1/de not_active Expired - Lifetime
- 1992-02-06 CS CS92343A patent/CS34392A3/cs unknown
- 1992-02-06 JP JP04066587A patent/JP3113049B2/ja not_active Expired - Lifetime
- 1992-02-06 MX MX9200503A patent/MX9200503A/es unknown
- 1992-02-06 AT AT92101997T patent/ATE147765T1/de not_active IP Right Cessation
1993
- 1993-07-23 RU RU9393051530A patent/RU2079511C1/ru active
1995
- 1995-03-31 US US08/414,596 patent/US5491197A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
MX9200503A (es)	1992-08-31
RU2079511C1 (ru)	1997-05-20
RU2126422C1 (ru)	1999-02-20
AU1077792A (en)	1992-08-13
ITMI910306A0 (it)	1991-02-06
TR26417A (tr)	1995-03-15
CA2060692A1 (en)	1992-08-07
JPH06116321A (ja)	1994-04-26
DE69216649D1 (de)	1997-02-27
RU2083595C1 (ru)	1997-07-10
AU643594B2 (en)	1993-11-18
EP0498426A1 (de)	1992-08-12
BR9200409A (pt)	1992-10-13
IT1244550B (it)	1994-07-15
PL293374A1 (en)	1993-07-26
US5491197A (en)	1996-02-13
IE920377A1 (en)	1992-08-12
ITMI910306A1 (it)	1992-08-06
ATE147765T1 (de)	1997-02-15
JP3113049B2 (ja)	2000-11-27
EP0498426B1 (de)	1997-01-15
DE69216649T2 (de)	1997-07-10
US5412040A (en)	1995-05-02
AR246530A1 (es)	1994-08-31
ES2097224T3 (es)	1997-04-01
ZA92799B (en)	1993-02-24

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