DD141429A5 - Lichtstabilisierung von metalleffektlacken - Google Patents

Lichtstabilisierung von metalleffektlacken Download PDF

Info

Publication number: DD141429A5
Authority: DD; German Democratic Republic
Prior art keywords: hydrogen; group; alkyl; formula; acid
Prior art date: 1977-12-30

Application number

DD78210287A

Other languages

German (de)

English (en)

Inventor

Godwin Berner

Original Assignee

Ciba Geigy Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-30

Filing date

1978-12-29

Publication date

1980-04-30

1978-12-29 Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag

1980-04-30 Publication of DD141429A5 publication Critical patent/DD141429A5/de

Links

230000000694 effects Effects 0.000 title claims description 37
230000006641 stabilisation Effects 0.000 title description 14
238000011105 stabilization Methods 0.000 title description 14
239000002966 varnish Substances 0.000 title description 4
-1 oxyl Chemical group 0.000 claims description 130
239000004611 light stabiliser Substances 0.000 claims description 53
229910052739 hydrogen Inorganic materials 0.000 claims description 43
239000001257 hydrogen Substances 0.000 claims description 43
125000000217 alkyl group Chemical group 0.000 claims description 40
150000001875 compounds Chemical class 0.000 claims description 31
239000003973 paint Substances 0.000 claims description 28
238000000576 coating method Methods 0.000 claims description 27
150000002431 hydrogen Chemical class 0.000 claims description 27
125000002947 alkylene group Chemical group 0.000 claims description 25
229920005989 resin Polymers 0.000 claims description 24
239000011347 resin Substances 0.000 claims description 24
239000002253 acid Substances 0.000 claims description 22
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 21
125000003118 aryl group Chemical group 0.000 claims description 20
229920000180 alkyd Polymers 0.000 claims description 19
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 19
239000004925 Acrylic resin Substances 0.000 claims description 18
229920000178 Acrylic resin Polymers 0.000 claims description 18
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
125000003710 aryl alkyl group Chemical group 0.000 claims description 17
125000001931 aliphatic group Chemical group 0.000 claims description 16
239000004922 lacquer Substances 0.000 claims description 16
125000003342 alkenyl group Chemical group 0.000 claims description 14
239000011230 binding agent Substances 0.000 claims description 14
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 14
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 14
125000001589 carboacyl group Chemical group 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 12
239000003381 stabilizer Substances 0.000 claims description 12
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 11
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
125000000753 cycloalkyl group Chemical group 0.000 claims description 10
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 9
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
125000000732 arylene group Chemical group 0.000 claims description 9
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 7
150000002736 metal compounds Chemical class 0.000 claims description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 6
229910052760 oxygen Inorganic materials 0.000 claims description 6
239000001301 oxygen Substances 0.000 claims description 6
229910052698 phosphorus Inorganic materials 0.000 claims description 6
239000011574 phosphorus Substances 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
125000000304 alkynyl group Chemical group 0.000 claims description 5
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 5
125000002993 cycloalkylene group Chemical group 0.000 claims description 5
125000004956 cyclohexylene group Chemical group 0.000 claims description 5
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
OLRJXMHANKMLTD-UHFFFAOYSA-N silyl Chemical compound [SiH3] OLRJXMHANKMLTD-UHFFFAOYSA-N 0.000 claims description 5
230000000087 stabilizing effect Effects 0.000 claims description 5
125000006839 xylylene group Chemical group 0.000 claims description 5
125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 4
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 4
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239000000654 additive Substances 0.000 claims description 3
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239000004952 Polyamide Substances 0.000 claims description 2
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150000003926 acrylamides Chemical class 0.000 claims description 2
239000002318 adhesion promoter Substances 0.000 claims description 2
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KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 2
239000002270 dispersing agent Substances 0.000 claims description 2
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229920000642 polymer Polymers 0.000 claims description 2
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239000004814 polyurethane Substances 0.000 claims description 2
239000002562 thickening agent Substances 0.000 claims description 2
KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims description 2
239000003223 protective agent Substances 0.000 claims 3
125000006832 (C1-C10) alkylene group Chemical group 0.000 claims 1
125000002861 (C1-C4) alkanoyl group Chemical group 0.000 claims 1
125000004650 C1-C8 alkynyl group Chemical group 0.000 claims 1
PTLMIIUMLITBQT-NCOIDOBVSA-N CpC Chemical group O=C1N=C(N)C=CN1[C@H]1[C@H](O)[C@H](O)[C@@H](COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2CO)N2C(N=C(N)C=C2)=O)O)O1 PTLMIIUMLITBQT-NCOIDOBVSA-N 0.000 claims 1
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238000005336 cracking Methods 0.000 description 20
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229910052782 aluminium Inorganic materials 0.000 description 17
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239000011248 coating agent Substances 0.000 description 17
150000003254 radicals Chemical class 0.000 description 15
125000001424 substituent group Chemical group 0.000 description 13
239000006096 absorbing agent Substances 0.000 description 12
239000012964 benzotriazole Substances 0.000 description 12
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239000008096 xylene Substances 0.000 description 11
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238000012360 testing method Methods 0.000 description 10
ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 7
229920003264 Maprenal® Polymers 0.000 description 7
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
125000004825 2,2-dimethylpropylene group Chemical group [H]C([H])([H])C(C([H])([H])[H])(C([H])([H])[*:1])C([H])([H])[*:2] 0.000 description 6
229920000877 Melamine resin Polymers 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 6
239000000049 pigment Substances 0.000 description 6
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 5
125000006017 1-propenyl group Chemical group 0.000 description 5
125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 5
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 5
229940126062 Compound A Drugs 0.000 description 5
NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 5
125000005394 methallyl group Chemical group 0.000 description 5
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 4
125000006040 2-hexenyl group Chemical group 0.000 description 4
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DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
239000004202 carbamide Substances 0.000 description 4
235000013877 carbamide Nutrition 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
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238000010348 incorporation Methods 0.000 description 4
230000014759 maintenance of location Effects 0.000 description 4
125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
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230000000475 sunscreen effect Effects 0.000 description 4
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ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
VVUWYXJTOLSMFV-UHFFFAOYSA-N (2-hydroxy-4-octylphenyl)-phenylmethanone Chemical compound OC1=CC(CCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 VVUWYXJTOLSMFV-UHFFFAOYSA-N 0.000 description 3
MIOKJIDWWJEJDE-UHFFFAOYSA-N (4-dodecyl-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(CCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 MIOKJIDWWJEJDE-UHFFFAOYSA-N 0.000 description 3
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GXPHKUHSUJUWKP-UHFFFAOYSA-N troglitazone Chemical compound C1CC=2C(C)=C(O)C(C)=C(C)C=2OC1(C)COC(C=C1)=CC=C1CC1SC(=O)NC1=O GXPHKUHSUJUWKP-UHFFFAOYSA-N 0.000 description 3
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RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
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OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
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QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
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125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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JMUOXOJMXILBTE-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 JMUOXOJMXILBTE-UHFFFAOYSA-N 0.000 description 1
IWZSHWBGHQBIML-ZGGLMWTQSA-N (3S,8S,10R,13S,14S,17S)-17-isoquinolin-7-yl-N,N,10,13-tetramethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-amine Chemical compound CN(C)[C@H]1CC[C@]2(C)C3CC[C@@]4(C)[C@@H](CC[C@@H]4c4ccc5ccncc5c4)[C@@H]3CC=C2C1 IWZSHWBGHQBIML-ZGGLMWTQSA-N 0.000 description 1
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
SCRNZBFVSFJGCI-UHFFFAOYSA-N 1,2,2,6,6-pentamethylpiperidin-3-amine Chemical compound CN1C(C)(C)CCC(N)C1(C)C SCRNZBFVSFJGCI-UHFFFAOYSA-N 0.000 description 1
YLNHMDBXZAIRGL-UHFFFAOYSA-N 1-(2,2,6,6-tetramethyl-4-phenylmethoxypiperidin-1-yl)prop-2-en-1-one Chemical compound C1C(C)(C)N(C(=O)C=C)C(C)(C)CC1OCC1=CC=CC=C1 YLNHMDBXZAIRGL-UHFFFAOYSA-N 0.000 description 1
NPGMRAKLNOUHHI-UHFFFAOYSA-N 2,2,6,6-tetramethyl-1-[4-(2,2,6,6-tetramethylpiperidin-1-yl)but-2-enyl]piperidine Chemical compound CC1(C)CCCC(C)(C)N1CC=CCN1C(C)(C)CCCC1(C)C NPGMRAKLNOUHHI-UHFFFAOYSA-N 0.000 description 1
VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 1
YSZJTDBKDUARSQ-UHFFFAOYSA-N 2,2-dibenzylpropanedioic acid Chemical compound C=1C=CC=CC=1CC(C(O)=O)(C(=O)O)CC1=CC=CC=C1 YSZJTDBKDUARSQ-UHFFFAOYSA-N 0.000 description 1
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APKFLZGRWMXNNV-UHFFFAOYSA-N 6-(carboxyamino)hexylcarbamic acid Chemical compound OC(=O)NCCCCCCNC(O)=O APKFLZGRWMXNNV-UHFFFAOYSA-N 0.000 description 1
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GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
101710191332 Cytochrome P450 monooxygenase cloA Proteins 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
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239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000007514 bases Chemical class 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
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238000009835 boiling Methods 0.000 description 1
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230000015556 catabolic process Effects 0.000 description 1
FCEOGYWNOSBEPV-FDGPNNRMSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FCEOGYWNOSBEPV-FDGPNNRMSA-N 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
WTVNFKVGGUWHQC-UHFFFAOYSA-N decane-2,4-dione Chemical compound CCCCCCC(=O)CC(C)=O WTVNFKVGGUWHQC-UHFFFAOYSA-N 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
BOBNOXCLPCOMIK-UHFFFAOYSA-N dimethyl-bis[(2,2,6,6-tetramethylpiperidin-4-yl)oxy]silane Chemical compound C1C(C)(C)NC(C)(C)CC1O[Si](C)(C)OC1CC(C)(C)NC(C)(C)C1 BOBNOXCLPCOMIK-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
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238000011156 evaluation Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000011888 foil Substances 0.000 description 1
IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
238000009472 formulation Methods 0.000 description 1
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ARZLUCYKIWYSHR-UHFFFAOYSA-N hydroxymethoxymethanol Chemical compound OCOCO ARZLUCYKIWYSHR-UHFFFAOYSA-N 0.000 description 1
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238000009434 installation Methods 0.000 description 1
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229910052748 manganese Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
238000013508 migration Methods 0.000 description 1
230000005012 migration Effects 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
BRSZLVDOXIGUSH-UHFFFAOYSA-N n-(1-acetyl-2,2,6,6-tetramethylpiperidin-4-yl)-n-cyclohexylacetamide Chemical compound C1C(C)(C)N(C(C)=O)C(C)(C)CC1N(C(=O)C)C1CCCCC1 BRSZLVDOXIGUSH-UHFFFAOYSA-N 0.000 description 1
RBIACHJMECYJOI-UHFFFAOYSA-N n-[[4-(aminomethyl)phenyl]methyl]-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound C1C(C)(C)NC(C)(C)CC1NCC1=CC=C(CN)C=C1 RBIACHJMECYJOI-UHFFFAOYSA-N 0.000 description 1
OWSKGHZFUXNYJC-UHFFFAOYSA-N n-benzyl-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound C1C(C)(C)NC(C)(C)CC1NCC1=CC=CC=C1 OWSKGHZFUXNYJC-UHFFFAOYSA-N 0.000 description 1
150000002816 nickel compounds Chemical class 0.000 description 1
GAIQJSWQJOZOMI-UHFFFAOYSA-L nickel(2+);dibenzoate Chemical compound [Ni+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 GAIQJSWQJOZOMI-UHFFFAOYSA-L 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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150000002989 phenols Chemical class 0.000 description 1
NPLSRXKOUBVHTB-UHFFFAOYSA-N phenyl-tris[(2,2,6,6-tetramethylpiperidin-4-yl)oxy]silane Chemical compound C1C(C)(C)NC(C)(C)CC1O[Si](C=1C=CC=CC=1)(OC1CC(C)(C)NC(C)(C)C1)OC1CC(C)(C)NC(C)(C)C1 NPLSRXKOUBVHTB-UHFFFAOYSA-N 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
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XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
125000005767 propoxymethyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])[#8]C([H])([H])* 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000011814 protection agent Substances 0.000 description 1
CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellityc acid Natural products OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical group O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229960004889 salicylic acid Drugs 0.000 description 1
239000000523 sample Substances 0.000 description 1
DNJNZJPMEZJNKB-UHFFFAOYSA-N spiro[4.5]decane-2,4-dione Chemical compound C1C(=O)CC(=O)C21CCCCC2 DNJNZJPMEZJNKB-UHFFFAOYSA-N 0.000 description 1
239000007921 spray Substances 0.000 description 1
125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
150000000000 tetracarboxylic acids Chemical class 0.000 description 1
150000003628 tricarboxylic acids Chemical class 0.000 description 1
TZCXWPBSZLCVFR-UHFFFAOYSA-N tris(2,2,6,6-tetramethyl-1-propylpiperidin-4-yl) phosphate Chemical compound C1C(C)(C)N(CCC)C(C)(C)CC1OP(=O)(OC1CC(C)(C)N(CCC)C(C)(C)C1)OC1CC(C)(C)N(CCC)C(C)(C)C1 TZCXWPBSZLCVFR-UHFFFAOYSA-N 0.000 description 1
239000006097 ultraviolet radiation absorber Substances 0.000 description 1
150000003672 ureas Chemical group 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31688—Next to aldehyde or ketone condensation product

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Compositions Of Macromolecular Compounds (AREA)
Hydrogenated Pyridines (AREA)

DD78210287A 1977-12-30 1978-12-29 Lichtstabilisierung von metalleffektlacken DD141429A5 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH1629777		1977-12-30
CH465178		1978-04-28

Publications (1)

Publication Number	Publication Date
DD141429A5 true DD141429A5 (de)	1980-04-30

Family

ID=25695992

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD78210287A DD141429A5 (de)	1977-12-30	1978-12-29	Lichtstabilisierung von metalleffektlacken

Country Status (7)

Country	Link
US (1)	US4426472A (pl)
KR (1)	KR820000386B1 (pl)
AT (1)	AT380267B (pl)
BR (1)	BR7808627A (pl)
DD (1)	DD141429A5 (pl)
DE (1)	DE2862332D1 (pl)
PL (1)	PL212385A1 (pl)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH662359A5 (de) *	1983-03-21	1987-09-30	Sandoz Ag	Fluessige zubereitung von uv-lichtstabilisatoren.
JPS60197775A (ja)	1984-03-21	1985-10-07	Adeka Argus Chem Co Ltd	熱硬化性合成樹脂塗料組成物
US5030670A (en) *	1984-04-13	1991-07-09	Sandoz Ltd.	Stable aqueous dispersions of tetraalkylpiperidines
IT1200103B (it) *	1984-08-14	1989-01-05	Sandoz Ag	Composti tetraalchilpiridinici n-sostituiti agenti come stabilizzanti agli effetti della luce per materiali polimerici
US4675353A (en) *	1985-01-29	1987-06-23	The Bfgoodrich Company	Hindered 2-keto-1,4-diazacycloalkane oligomers containing triazine rings and compositions stabilized thereby
US4619956A (en) *	1985-05-03	1986-10-28	American Cyanamid Co.	Stabilization of high solids coatings with synergistic combinations
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1978
- 1978-12-16 DE DE7878101720T patent/DE2862332D1/de not_active Expired
- 1978-12-28 AT AT932078A patent/AT380267B/de not_active IP Right Cessation
- 1978-12-29 DD DD78210287A patent/DD141429A5/de unknown
- 1978-12-29 BR BR7808627A patent/BR7808627A/pt unknown
- 1978-12-30 PL PL21238578A patent/PL212385A1/pl unknown
- 1978-12-30 KR KR7803998A patent/KR820000386B1/ko not_active Expired
1982
- 1982-05-06 US US06/375,416 patent/US4426472A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
KR820000386B1 (ko)	1982-03-26
DE2862332D1 (en)	1983-11-10
BR7808627A (pt)	1979-07-10
ATA932078A (de)	1985-09-15
PL212385A1 (pl)	1979-08-27
AT380267B (de)	1986-05-12
US4426472A (en)	1984-01-17

Publication	Publication Date	Title
DD141429A5 (de)	1980-04-30	Lichtstabilisierung von metalleffektlacken
EP0006213B1 (de)	1982-09-01	Lichtstabilisierung von sauerkatalysierten Einbrennlacken
EP0016723B2 (de)	1987-09-16	Lichtstabilisierung von Zweischicht-Unilackierungen
EP0453396B1 (de)	1995-12-13	Lackzusammensetzungen
US5112890A (en)	1992-05-12	Stabilization of acid catalyzed thermoset resins
EP0309401B1 (en)	1994-10-26	Stabilization of coatings with N-hydroxy hindered amines
DE69229935T2 (de)	2000-03-16	Mischungen von hals-verbindungen
EP0293871A2 (de)	1988-12-07	Lichtstabilisierte, sternförmig polymerisierte Mikropartikel
DE3408948A1 (de)	1984-09-27	Neue 4-amino-polyalkylpiperidinverbindungen
EP0296391B1 (de)	1993-07-07	Lichtstabilisierte, epoxygruppenhaltige Polymermikropartikel
US5064883A (en)	1991-11-12	Stabilization of acid catalyzed thermoset resins with n-hydroxy hindered amines
EP0002753B1 (de)	1983-10-05	Stabilisierung von Metalleffekteinbrennlacken gegen die Einwirkung von Licht, Feuchtigkeit und Sauerstoff durch den Zusatz von Polyalkylpiperidinderivaten
EP0226538B1 (de)	1991-09-11	Lichtstabilisierte Polymermikropartikel
DE3027223A1 (de)	1982-02-11	Triazinylaminotriazine, ihre herstellung und verwendung
EP0052073A1 (de)	1982-05-19	Lichtstabilisierung von sauerkatalysierten Einbrennlacken
EP0006564B1 (de)	1981-12-30	2-(2-Hydroxy-3.5-disubstituiertes-phenyl)-2H-benzotriazol und damit stabilisierte Mischungen
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EP0015230B1 (de)	1983-02-23	Stabilisiertes organisches Polymer enthaltend als Lichtstabilisator ein 2-(2-Hydroxy-3,5-di-tert-octylphenyl)-2H-benzotriazol
DE3737398A1 (de)	1988-05-11	Heterocyclisch oder aromatisch substituierte oxalsaeurediamide und ihre verwendung als uv-stabilisatoren
DE3523679A1 (de)	1986-01-30	Neue polymethylpiperidinverbindungen
EP0323803A1 (de)	1989-07-12	Stabilisierung von Lacken mit N-formylierten gehinderten Aminen
CS227004B2 (cs)	1984-04-16	Způsob stabilizace jednovrstvových nebo dvouvrstvových vypalovacích laků
DE4010444A1 (de)	1990-10-11	Verwendung von hals-verbindungen in lacken
CH651832A5 (de)	1985-10-15	Pyrazolkomplexe.
CH652713A5 (de)	1985-11-29	4-aminomethyl-polymethylpiperidine.