DD154995A5 - Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte - Google Patents

Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte Download PDF

Info

Publication number: DD154995A5
Authority: DD; German Democratic Republic
Prior art keywords: mercapto; functional; weight; inclusive; oxygen
Prior art date: 1979-12-03

Application number

DD80225688A

Other languages

German (de)

English (en)

Inventor

Gary R Homan

Chi-Long Lee

Original Assignee

Dow Corning

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-03

Filing date

1980-12-03

Publication date

1982-05-05

1980-12-03 Application filed by Dow Corning filed Critical Dow Corning

1982-05-05 Publication of DD154995A5 publication Critical patent/DD154995A5/de

Links

238000004519 manufacturing process Methods 0.000 title description 2
239000000203 mixture Substances 0.000 claims abstract description 89
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 61
239000003054 catalyst Substances 0.000 claims abstract description 57
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 37
239000001301 oxygen Substances 0.000 claims abstract description 36
229910052760 oxygen Inorganic materials 0.000 claims abstract description 36
239000000945 filler Substances 0.000 claims abstract description 24
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 21
229910052751 metal Inorganic materials 0.000 claims abstract description 20
239000002184 metal Substances 0.000 claims abstract description 20
125000005375 organosiloxane group Chemical group 0.000 claims abstract description 20
238000002156 mixing Methods 0.000 claims abstract description 9
239000011572 manganese Substances 0.000 claims abstract description 8
230000003197 catalytic effect Effects 0.000 claims abstract description 6
230000009471 action Effects 0.000 claims abstract description 5
ANHQLUBMNSSPBV-UHFFFAOYSA-N 4h-pyrido[3,2-b][1,4]oxazin-3-one Chemical group C1=CN=C2NC(=O)COC2=C1 ANHQLUBMNSSPBV-UHFFFAOYSA-N 0.000 claims abstract description 4
NBFCJULAAWWTBL-UHFFFAOYSA-N buta-1,3-diene;carbon monoxide;iron Chemical group [Fe].[O+]#[C-].[O+]#[C-].[O+]#[C-].C=CC=C NBFCJULAAWWTBL-UHFFFAOYSA-N 0.000 claims abstract description 4
230000007717 exclusion Effects 0.000 claims abstract description 3
-1 siloxane units Chemical group 0.000 claims description 90
238000000034 method Methods 0.000 claims description 28
238000002360 preparation method Methods 0.000 claims description 19
125000000217 alkyl group Chemical group 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 8
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
230000008569 process Effects 0.000 claims description 7
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
229910004298 SiO 2 Inorganic materials 0.000 claims description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
125000004429 atom Chemical group 0.000 claims description 2
239000000565 sealant Substances 0.000 abstract description 12
239000011347 resin Substances 0.000 abstract description 11
229920005989 resin Polymers 0.000 abstract description 11
125000001424 substituent group Chemical group 0.000 abstract description 9
239000000499 gel Substances 0.000 abstract description 7
238000000576 coating method Methods 0.000 abstract description 4
229940087654 iron carbonyl Drugs 0.000 abstract description 4
239000011248 coating agent Substances 0.000 abstract description 2
239000004615 ingredient Substances 0.000 abstract description 2
239000000047 product Substances 0.000 description 37
229920000642 polymer Polymers 0.000 description 26
125000003396 thiol group Chemical group [H]S* 0.000 description 26
239000000463 material Substances 0.000 description 19
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
238000009472 formulation Methods 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
235000013870 dimethyl polysiloxane Nutrition 0.000 description 14
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 14
125000004122 cyclic group Chemical group 0.000 description 13
229920001971 elastomer Polymers 0.000 description 13
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
239000000806 elastomer Substances 0.000 description 11
229910052742 iron Inorganic materials 0.000 description 11
230000000704 physical effect Effects 0.000 description 11
239000004205 dimethyl polysiloxane Substances 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 9
239000007788 liquid Substances 0.000 description 9
238000006116 polymerization reaction Methods 0.000 description 9
150000001875 compounds Chemical class 0.000 description 8
229920001577 copolymer Polymers 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
229910000019 calcium carbonate Inorganic materials 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
239000011159 matrix material Substances 0.000 description 6
229910021485 fumed silica Inorganic materials 0.000 description 5
230000007246 mechanism Effects 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
150000002894 organic compounds Chemical class 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
239000012763 reinforcing filler Substances 0.000 description 5
229910052710 silicon Inorganic materials 0.000 description 5
238000003756 stirring Methods 0.000 description 5
ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 5
IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
230000008859 change Effects 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000010703 silicon Substances 0.000 description 4
GXTPHRPCCNSDTM-UHFFFAOYSA-N 3-silyloxysilylpropane-1-thiol Chemical compound [SiH3]O[SiH2]CCCS GXTPHRPCCNSDTM-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
229910002012 Aerosil® Inorganic materials 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
239000005909 Kieselgur Substances 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
229920001002 functional polymer Polymers 0.000 description 3
239000010410 layer Substances 0.000 description 3
239000002480 mineral oil Substances 0.000 description 3
235000010446 mineral oil Nutrition 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
239000011253 protective coating Substances 0.000 description 3
239000003566 sealing material Substances 0.000 description 3
150000004756 silanes Chemical class 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
229910052814 silicon oxide Inorganic materials 0.000 description 3
238000003860 storage Methods 0.000 description 3
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
238000013459 approach Methods 0.000 description 2
230000008901 benefit Effects 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
150000001728 carbonyl compounds Chemical class 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
239000000470 constituent Substances 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
229920001684 low density polyethylene Polymers 0.000 description 2
239000004702 low-density polyethylene Substances 0.000 description 2
125000005358 mercaptoalkyl group Chemical group 0.000 description 2
150000002816 nickel compounds Chemical class 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
IALUUOKJPBOFJL-UHFFFAOYSA-N potassium oxidosilane Chemical compound [K+].[SiH3][O-] IALUUOKJPBOFJL-UHFFFAOYSA-N 0.000 description 2
238000010992 reflux Methods 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
GXQCGPVEDZFCGW-UHFFFAOYSA-N 2,3-dihydro-1h-pyrrolo[3,4-c]pyridine;dihydrochloride Chemical group Cl.Cl.N1=CC=C2CNCC2=C1 GXQCGPVEDZFCGW-UHFFFAOYSA-N 0.000 description 1
GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
101150065749 Churc1 gene Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
102100038239 Protein Churchill Human genes 0.000 description 1
241000158147 Sator Species 0.000 description 1
229910020175 SiOH Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
JOBBTVPTPXRUBP-UHFFFAOYSA-N [3-(3-sulfanylpropanoyloxy)-2,2-bis(3-sulfanylpropanoyloxymethyl)propyl] 3-sulfanylpropanoate Chemical compound SCCC(=O)OCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS JOBBTVPTPXRUBP-UHFFFAOYSA-N 0.000 description 1
LVAXPOVMRMFJSK-UHFFFAOYSA-N [Na].OS(=O)=O Chemical compound [Na].OS(=O)=O LVAXPOVMRMFJSK-UHFFFAOYSA-N 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
125000006267 biphenyl group Chemical group 0.000 description 1
235000008429 bread Nutrition 0.000 description 1
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
238000004040 coloring Methods 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
UCJHMXXKIKBHQP-UHFFFAOYSA-N dichloro-(3-chloropropyl)-methylsilane Chemical compound C[Si](Cl)(Cl)CCCCl UCJHMXXKIKBHQP-UHFFFAOYSA-N 0.000 description 1
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
239000008393 encapsulating agent Substances 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
210000003608 fece Anatomy 0.000 description 1
239000012765 fibrous filler Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
238000001879 gelation Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical class C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229940094933 n-dodecane Drugs 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
231100000344 non-irritating Toxicity 0.000 description 1
HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000011085 pressure filtration Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
238000007789 sealing Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000009423 ventilation Methods 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
125000002348 vinylic group Chemical group 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C5/00—Bracelets; Wrist-watch straps; Fastenings for bracelets or wrist-watch straps
- A44C5/18—Fasteners for straps, chains or the like
- A44C5/20—Fasteners for straps, chains or the like for open straps, chains or the like
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C5/00—Bracelets; Wrist-watch straps; Fastenings for bracelets or wrist-watch straps
- A44C5/18—Fasteners for straps, chains or the like
- A44C5/20—Fasteners for straps, chains or the like for open straps, chains or the like
- A44C5/2019—Hooks
- A44C5/2023—Sliding hooks
- A44C5/2028—Sliding hooks with spring closure means
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Silicon Polymers (AREA)
Adornments (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

DD80225688A 1979-12-03 1980-12-03 Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte DD154995A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/099,252 US4252932A (en)	1979-12-03	1979-12-03	Oxygen-curable mercaptoorganosiloxane compositions catalyzed by metal carbonyl compounds and method of forming higher molecular weight products therefrom

Publications (1)

Publication Number	Publication Date
DD154995A5 true DD154995A5 (de)	1982-05-05

Family

ID=22273918

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD80225688A DD154995A5 (de)	1979-12-03	1980-12-03	Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte

Country Status (10)

Country	Link
US (1)	US4252932A (mo)
EP (1)	EP0030155B1 (mo)
JP (2)	JPS604217B2 (mo)
BR (1)	BR8008945A (mo)
CA (1)	CA1155250A (mo)
DD (1)	DD154995A5 (mo)
DE (1)	DE3067047D1 (mo)
ES (1)	ES497367A0 (mo)
WO (1)	WO1981001565A1 (mo)
ZA (1)	ZA807548B (mo)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4526954A (en) *	1983-12-28	1985-07-02	Union Carbide Corporation	Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen
US5015717A (en) *	1986-12-22	1991-05-14	Wacker Silicones Corporation	Sulfur-containing organopolysiloxane waxes and a method for preparing the same
JPH01313565A (ja) *	1988-06-10	1989-12-19	Toray Dow Corning Silicone Co Ltd	硬化性オルガノポリシロキサン組成物
US5994456A (en) *	1998-04-09	1999-11-30	Dow Corning Corporation	Compositions comprising mercapto-functional organosilicon compounds
US6632674B1 (en)	1999-03-31	2003-10-14	Industrial Scientific Corporation	Method of testing gas detection instruments and associated apparatus
DE102012004132A1 (de) *	2012-02-29	2013-08-29	Friedrich-Schiller-Universität Jena	Kohlenstoffmonoxid freisetzende Materialien und deren Verwendung
JP7573232B2 (ja)	2020-07-06	2024-10-25	日本表面化学株式会社	化成処理用金属着色液及び金属着色処理方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3445419A (en) *	1966-01-21	1969-05-20	Dow Corning	Room temperature vulcanizable silicones
US4066603A (en) *	1976-03-03	1978-01-03	Dow Corning Corporation	Sulfur containing silicone elastomer and method of preparation
US4151156A (en) *	1976-07-22	1979-04-24	Shin-Etsu Chemical Co., Ltd.	Mercapto group-containing silicone rubber compositions
US4070328A (en) *	1977-01-03	1978-01-24	Dow Corning Corporation	Mercaptoorganopolysiloxanes cured to elastomers with peroxides and nitrogen compounds
US4070329A (en) *	1977-01-03	1978-01-24	Dow Corning Corporation	Siloxane elastomer prepared from mercaptoorg anopolysiloxanes
US4133939A (en) *	1977-12-16	1979-01-09	Dow Corning Corporation	Method for applying a silicone release coating and coated article therefrom

1979
- 1979-12-03 US US06/099,252 patent/US4252932A/en not_active Expired - Lifetime
1980
- 1980-11-21 CA CA000365275A patent/CA1155250A/en not_active Expired
- 1980-11-24 WO PCT/US1980/001598 patent/WO1981001565A1/en not_active Ceased
- 1980-11-24 JP JP81500346A patent/JPS604217B2/ja not_active Expired
- 1980-11-24 JP JP81500344A patent/JPS56501611A/ja active Granted
- 1980-11-24 BR BR8008945A patent/BR8008945A/pt unknown
- 1980-12-02 EP EP80304330A patent/EP0030155B1/en not_active Expired
- 1980-12-02 DE DE8080304330T patent/DE3067047D1/de not_active Expired
- 1980-12-02 ES ES497367A patent/ES497367A0/es active Granted
- 1980-12-03 ZA ZA00807548A patent/ZA807548B/xx unknown
- 1980-12-03 DD DD80225688A patent/DD154995A5/de unknown

Also Published As

Publication number	Publication date
ES8303477A1 (es)	1983-02-01
US4252932A (en)	1981-02-24
EP0030155B1 (en)	1984-03-14
JPS55501089A (mo)	1980-12-11
EP0030155A1 (en)	1981-06-10
BR8008945A (pt)	1981-10-20
JPS56501611A (mo)	1981-11-05
CA1155250A (en)	1983-10-11
WO1981001565A1 (en)	1981-06-11
JPS604217B2 (ja)	1985-02-02
ES497367A0 (es)	1983-02-01
ZA807548B (en)	1981-11-25
DE3067047D1 (en)	1984-04-19

Publication	Publication Date	Title
DE2809588C2 (de)	1982-12-23	Verwendung eines Gemischs aus einem Polysiloxan und einem Silan als Haftvermittler in einer Siliconelastomermasse
DE68904637T2 (de)	1993-06-03	Silikon-dichtungsmaterialien mit verminderter farbe.
DE2350369C2 (de)	1982-12-30	Verfahren zum Herstellen von Diorganopolysiloxanen
DE2702046C3 (de)	1980-07-17	Verfahren zur Hefstellung von Polysiloxanelastomeren
DE2754702C3 (de)	1980-06-04	Verfahren zur Herstellung von PoIysiloxanelastomeren bei Raumtemperatur
DE2702057C3 (de)	1980-06-19	Verfahren zur Herstellung von Polysiloxanelastomeren
DE2754703C3 (de)	1980-09-04	Verfahren zur Herstellung von Mercaptoorganopolysiloxanelastomeren
DE2631957C3 (de)	1981-02-05	Verfahren zur Herstellung eines Copolymeren
DE2437954A1 (de)	1975-02-20	Aus zwei teilen bestehende, bei raumtemperatur vulkanisierbare systeme
DD154993A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DE2702056A1 (de)	1977-09-08	Zu einem elastomer haertbare siloxanmasse
DD154995A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DE3028781C2 (de)	1985-08-14	Mercaptoorganosiloxanmasse und ihre Verwendung
DE69003615T2 (de)	1994-03-31	Reaktionsprodukte als Haftklebezusätze für UV-härtbare Zusammensetzungen und diese enthaltende Zusammensetzungen.
DD154997A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganopolysiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DD154991A5 (de)	1982-05-05	Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einem aliphatisch ungesaettigten polydorganosiloxan und einem metallsalz einer carbonsaeure
EP1104780A1 (de)	2001-06-06	Vernetzbare Organopolysiloxanmassen
DD154994A5 (de)	1982-05-05	Sauerstoffhaertbare masse auf basis mercaptofunktioneller organischer verbindungen und ihre verwendung zur herstellung hoehermolekularer produkte
DD155000A5 (de)	1982-05-05	Sauerstoffhaertbare masse auf basis mercaptofunktioneller organischer verbindungen und ihre verwendung zur herstellung hoehermolekularer produkte
DD154998A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganopolysiloxanmasse
EP0814120B1 (de)	1999-01-13	Unter Abspaltung von Alkoholen zu Elastomeren vernetzbare Organopolysiloxanmassen
DE3788247T2 (de)	1994-04-14	Polyorganosiloxan-Vernetzer für RTV-Abdichtungsmittel.
EP0218875A2 (de)	1987-04-22	Härtbare Silicon-Kautschukmassen
EP1108752A1 (de)	2001-06-20	Vernetzbare Organopolysiloxanmassen
DD154988A5 (de)	1982-05-05	Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan und einem zinn(iv)-salz einer carbonsaeure