DD200326A1 - Verfahren zur selektiven butadien-polymerisation aus c tief 4-fraktionen - Google Patents

Verfahren zur selektiven butadien-polymerisation aus c tief 4-fraktionen Download PDF

Info

Publication number: DD200326A1
Authority: DD; German Democratic Republic
Prior art keywords: polymerization; butadiene; copolymers; fractions; fraction
Prior art date: 1981-08-21

Application number

DD23271481A

Other languages

German (de)

English (en)

Inventor

Elisabeth Anton

Volker Griehl

Dieter Stubenrauch

Peter Scholz

Hans-Otto Froehlich

Guenther Heublein

Original Assignee

Elisabeth Anton

Volker Griehl

Dieter Stubenrauch

Peter Scholz

Froehlich Hans Otto

Guenther Heublein

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-08-21

Filing date

1981-08-21

Publication date

1983-04-13

1981-08-21 Application filed by Elisabeth Anton, Volker Griehl, Dieter Stubenrauch, Peter Scholz, Froehlich Hans Otto, Guenther Heublein filed Critical Elisabeth Anton

1981-08-21 Priority to DD23271481A priority Critical patent/DD200326A1/de

1982-07-30 Priority to CS573482A priority patent/CS231023B1/cs

1983-04-13 Publication of DD200326A1 publication Critical patent/DD200326A1/de

Links

238000006116 polymerization reaction Methods 0.000 title claims abstract description 22
238000000034 method Methods 0.000 title claims abstract description 18
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 60
229920001577 copolymer Polymers 0.000 claims abstract description 14
239000000178 monomer Substances 0.000 claims abstract description 8
239000003999 initiator Substances 0.000 claims abstract description 7
239000000203 mixture Substances 0.000 claims abstract description 6
PNHIJJOZOUVMNU-UHFFFAOYSA-N prop-1-en-2-ylbenzene;sodium Chemical compound [Na].[Na].CC(=C)C1=CC=CC=C1 PNHIJJOZOUVMNU-UHFFFAOYSA-N 0.000 claims abstract description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 5
150000001340 alkali metals Chemical class 0.000 claims description 5
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
125000000524 functional group Chemical group 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 4
229920001400 block copolymer Polymers 0.000 claims description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
239000007791 liquid phase Substances 0.000 claims 1
239000012071 phase Substances 0.000 claims 1
229920005604 random copolymer Polymers 0.000 claims 1
239000002904 solvent Substances 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 12
229920002857 polybutadiene Polymers 0.000 abstract description 11
239000003208 petroleum Substances 0.000 abstract description 4
230000001588 bifunctional effect Effects 0.000 abstract description 3
238000000197 pyrolysis Methods 0.000 abstract description 3
239000003795 chemical substances by application Substances 0.000 abstract description 2
238000010348 incorporation Methods 0.000 abstract 1
238000000926 separation method Methods 0.000 abstract 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
239000003054 catalyst Substances 0.000 description 6
238000009826 distribution Methods 0.000 description 6
239000005062 Polybutadiene Substances 0.000 description 5
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
-1 lithium organo compound Chemical class 0.000 description 2
239000012454 non-polar solvent Substances 0.000 description 2
150000002900 organolithium compounds Chemical class 0.000 description 2
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
150000001241 acetals Chemical class 0.000 description 1
239000012190 activator Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000001273 butane Substances 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000002391 heterocyclic compounds Chemical class 0.000 description 1
VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
239000012456 homogeneous solution Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
238000002955 isolation Methods 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
125000001979 organolithium group Chemical group 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229920006250 telechelic polymer Polymers 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DD23271481A 1981-08-21 1981-08-21 Verfahren zur selektiven butadien-polymerisation aus c tief 4-fraktionen DD200326A1 (de)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
DD23271481A DD200326A1 (de)	1981-08-21	1981-08-21	Verfahren zur selektiven butadien-polymerisation aus c tief 4-fraktionen
CS573482A CS231023B1 (en)	1981-08-21	1982-07-30	Method of selective polymerization of butadiene from c4 fraction

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DD23271481A DD200326A1 (de)	1981-08-21	1981-08-21	Verfahren zur selektiven butadien-polymerisation aus c tief 4-fraktionen

Publications (1)

Publication Number	Publication Date
DD200326A1 true DD200326A1 (de)	1983-04-13

Family

ID=5533073

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD23271481A DD200326A1 (de)	1981-08-21	1981-08-21	Verfahren zur selektiven butadien-polymerisation aus c tief 4-fraktionen

Country Status (2)

Country	Link
CS (1)	CS231023B1 (cs)
DD (1)	DD200326A1 (cs)

1981
- 1981-08-21 DD DD23271481A patent/DD200326A1/de not_active IP Right Cessation
1982
- 1982-07-30 CS CS573482A patent/CS231023B1/cs unknown

Also Published As

Publication number	Publication date
CS231023B1 (en)	1984-09-17

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1996-02-01	ENJ	Ceased due to non-payment of renewal fee