DD281814A5 - Verfahren zur herstellung von isomerisiertem pflanzlichem oel - Google Patents

Verfahren zur herstellung von isomerisiertem pflanzlichem oel Download PDF

Info

Publication number: DD281814A5
Authority: DD; German Democratic Republic
Prior art keywords: oil; catalyst; isomerization; suspension; reaction
Prior art date: 1987-07-16

Application number

DD31799088A

Other languages

German (de)

English (en)

Inventor

Jerzy Szafko

Kazimierz Kalucki

Jan Rodziewicz

Zbyslaw Kosinski

Andrzej Jarczak

Krzysztof Garbaruk

Tadeusz Wojnicz

Janusz Mazurczak

Piotr Biernacki

Original Assignee

Politechnika Szczecinska,Pl

Zaklady Chemiczne "Szcecin",Pl

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-07-16

Filing date

1988-07-15

Publication date

1990-08-22

1988-07-15 Application filed by Politechnika Szczecinska,Pl, Zaklady Chemiczne "Szcecin",Pl filed Critical Politechnika Szczecinska,Pl

1990-08-22 Publication of DD281814A5 publication Critical patent/DD281814A5/de

Links

238000000034 method Methods 0.000 title claims abstract description 33
238000004519 manufacturing process Methods 0.000 title description 3
239000003054 catalyst Substances 0.000 claims abstract description 33
238000006317 isomerization reaction Methods 0.000 claims abstract description 26
239000000725 suspension Substances 0.000 claims abstract description 17
239000002904 solvent Substances 0.000 claims abstract description 15
239000000010 aprotic solvent Substances 0.000 claims abstract description 12
239000003381 stabilizer Substances 0.000 claims abstract description 12
239000012429 reaction media Substances 0.000 claims abstract description 11
239000011575 calcium Substances 0.000 claims abstract description 9
229910052791 calcium Inorganic materials 0.000 claims abstract description 9
235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 9
239000008158 vegetable oil Substances 0.000 claims abstract description 9
239000011734 sodium Substances 0.000 claims abstract description 7
229910052708 sodium Inorganic materials 0.000 claims abstract description 7
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 5
-1 calcium halides Chemical class 0.000 claims abstract description 4
150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract description 4
238000002604 ultrasonography Methods 0.000 claims abstract description 4
239000011777 magnesium Substances 0.000 claims abstract description 3
229910052749 magnesium Inorganic materials 0.000 claims abstract description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract 2
239000003921 oil Substances 0.000 claims description 46
235000019198 oils Nutrition 0.000 claims description 46
230000007935 neutral effect Effects 0.000 claims description 6
229910052700 potassium Inorganic materials 0.000 claims description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
239000011591 potassium Substances 0.000 claims description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
150000004678 hydrides Chemical class 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
239000002253 acid Substances 0.000 abstract description 13
229910052500 inorganic mineral Inorganic materials 0.000 abstract description 7
239000011707 mineral Substances 0.000 abstract description 7
239000011541 reaction mixture Substances 0.000 abstract description 5
229910052751 metal Inorganic materials 0.000 abstract description 4
239000002184 metal Substances 0.000 abstract description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 4
150000004703 alkoxides Chemical class 0.000 abstract description 3
238000000926 separation method Methods 0.000 abstract description 3
239000003973 paint Substances 0.000 abstract description 2
229910000027 potassium carbonate Inorganic materials 0.000 abstract description 2
238000002360 preparation method Methods 0.000 abstract description 2
150000001805 chlorine compounds Chemical class 0.000 abstract 1
239000002244 precipitate Substances 0.000 abstract 1
239000002966 varnish Substances 0.000 abstract 1
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 25
238000006243 chemical reaction Methods 0.000 description 16
238000007086 side reaction Methods 0.000 description 9
235000019484 Rapeseed oil Nutrition 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
239000007789 gas Substances 0.000 description 5
235000010755 mineral Nutrition 0.000 description 5
239000000203 mixture Substances 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 3
230000021615 conjugation Effects 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000012467 final product Substances 0.000 description 3
230000007062 hydrolysis Effects 0.000 description 3
238000006460 hydrolysis reaction Methods 0.000 description 3
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
238000000576 coating method Methods 0.000 description 2
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
238000004821 distillation Methods 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
238000012423 maintenance Methods 0.000 description 2
ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
230000001603 reducing effect Effects 0.000 description 2
238000010992 reflux Methods 0.000 description 2
239000011877 solvent mixture Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
238000009210 therapy by ultrasound Methods 0.000 description 2
238000005406 washing Methods 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
SUAKHGWARZSWIH-UHFFFAOYSA-N N,N‐diethylformamide Chemical compound CCN(CC)C=O SUAKHGWARZSWIH-UHFFFAOYSA-N 0.000 description 1
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000005266 casting Methods 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000000835 fiber Substances 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000012994 industrial processing Methods 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
DNHVXYDGZKWYNU-UHFFFAOYSA-N lead;hydrate Chemical compound O.[Pb] DNHVXYDGZKWYNU-UHFFFAOYSA-N 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
235000019476 oil-water mixture Nutrition 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
238000010422 painting Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000000527 sonication Methods 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
230000008719 thickening Effects 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

DD31799088A 1987-07-16 1988-07-15 Verfahren zur herstellung von isomerisiertem pflanzlichem oel DD281814A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PL26690487A PL150101B1 (en)	1987-07-16	1987-07-16	Method of obtaining isomerized vegetable oil

Publications (1)

Publication Number	Publication Date
DD281814A5 true DD281814A5 (de)	1990-08-22

Family

ID=20037391

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD31799088A DD281814A5 (de)	1987-07-16	1988-07-15	Verfahren zur herstellung von isomerisiertem pflanzlichem oel

Country Status (2)

Country	Link
DD (1)	DD281814A5 (pl)
PL (1)	PL150101B1 (pl)

1987
- 1987-07-16 PL PL26690487A patent/PL150101B1/pl unknown
1988
- 1988-07-15 DD DD31799088A patent/DD281814A5/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
PL150101B1 (en)	1990-04-30
PL266904A1 (en)	1989-01-23

Legal Events

Date	Code	Title	Description
1996-11-07	ENJ	Ceased due to non-payment of renewal fee

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