EP0143634A3 - Verfahrenzur Herstellung von Butan-1,4-diol - Google Patents
Verfahrenzur Herstellung von Butan-1,4-diol Download PDFInfo
- Publication number
- EP0143634A3 EP0143634A3 EP19840308181 EP84308181A EP0143634A3 EP 0143634 A3 EP0143634 A3 EP 0143634A3 EP 19840308181 EP19840308181 EP 19840308181 EP 84308181 A EP84308181 A EP 84308181A EP 0143634 A3 EP0143634 A3 EP 0143634A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- butane
- diol
- ester
- bar
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract 5
- 150000002148 esters Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 abstract 1
- -1 diethyl maleate Natural products 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8331793A GB8331793D0 (en) | 1983-11-29 | 1983-11-29 | Process |
| GB8331793 | 1983-11-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0143634A2 EP0143634A2 (de) | 1985-06-05 |
| EP0143634A3 true EP0143634A3 (de) | 1985-10-30 |
Family
ID=10552507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19840308181 Ceased EP0143634A3 (de) | 1983-11-29 | 1984-11-26 | Verfahrenzur Herstellung von Butan-1,4-diol |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4584419A (de) |
| EP (1) | EP0143634A3 (de) |
| JP (1) | JPS6122035A (de) |
| KR (1) | KR910008935B1 (de) |
| CA (1) | CA1246616A (de) |
| ES (1) | ES8604844A1 (de) |
| GB (1) | GB8331793D0 (de) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3423447A1 (de) * | 1984-06-26 | 1986-01-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von 1,4-butandiol |
| WO1986003189A1 (en) * | 1984-11-21 | 1986-06-05 | Davy Mckee (London) Limited | Process for the production of butane-1,4-diol |
| GB8514002D0 (en) * | 1985-06-04 | 1985-07-10 | Davy Mckee Ltd | Process |
| US4652685A (en) * | 1985-11-15 | 1987-03-24 | General Electric Company | Hydrogenation of lactones to glycols |
| DE3776997D1 (de) * | 1986-07-23 | 1992-04-09 | Henkel Kgaa | Verfahren zur direkthydrierung von glyceridoelen. |
| GB8618892D0 (en) * | 1986-08-01 | 1986-09-10 | Davy Mckee Ltd | Process |
| JPH01500753A (ja) * | 1986-08-01 | 1989-03-16 | デイヴィ マッキー (ロンドン) リミテッド | ブタン‐1,4‐ジオールおよびガンマ‐ブチロラクトンの同時製造方法 |
| GB8618890D0 (en) * | 1986-08-01 | 1986-09-10 | Davy Mckee Ltd | Process |
| GB8618888D0 (en) * | 1986-08-01 | 1986-09-10 | Davy Mckee Ltd | Process |
| US4740272A (en) * | 1987-03-31 | 1988-04-26 | Davy Mckee (London) Limited | Separation of monoalkyl maleate from dialkyl maleate |
| DE3719790A1 (de) * | 1987-06-13 | 1988-12-22 | Henkel Kgaa | Herstellung von langkettigen polyolen aus nachwachsenden rohstoffen |
| GB8717993D0 (en) * | 1987-07-29 | 1987-09-03 | Davy Mckee Ltd | Process |
| GB8717989D0 (en) * | 1987-07-29 | 1987-09-03 | Davy Mckee Ltd | Catalyst |
| US4837368A (en) * | 1988-02-01 | 1989-06-06 | Eastman Kodak Company | Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor |
| US4837367A (en) * | 1987-08-03 | 1989-06-06 | Eastman Kodak Company | Low pressure catalytic hydrogenation of carbonyl-containing compounds |
| US4810807A (en) * | 1987-10-13 | 1989-03-07 | The Standard Oil Company | Hydrogenation of maleic anhydride to tetrahydrofuran |
| JP2596604B2 (ja) * | 1988-12-14 | 1997-04-02 | 東燃株式会社 | 1,4−ブタンジオールおよびテトラヒドロフランの製造方法 |
| DE3843956A1 (de) * | 1988-12-24 | 1990-06-28 | Huels Chemische Werke Ag | Verfahren zur herstellung von aliphatischen und cycloaliphatischen diolen durch katalytische hydrierung von dicarbonsaeureestern |
| GB8917864D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| GB8917862D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| JP2595358B2 (ja) * | 1989-12-07 | 1997-04-02 | 東燃株式会社 | 1,4―ブタンジオールおよびテトラヒドロフランの製造方法 |
| US5142067A (en) * | 1989-12-21 | 1992-08-25 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al-X catalysts |
| US5053380A (en) * | 1989-12-21 | 1991-10-01 | Union Carbide Chemicals And Plastics Technology Corporation | Cu-al catalyst for hydrogenation |
| US5008235A (en) * | 1989-12-21 | 1991-04-16 | Union Carbide Chemicals And Plastics Technology Corporation | Catalysts of Cu-Al-third metal for hydrogenation |
| US5191091A (en) * | 1989-12-21 | 1993-03-02 | Union Carbide Chemicals & Plastics Technology Corporation | Hydrogenation with Cu-Al catalysts |
| DE4009029A1 (de) | 1990-03-21 | 1991-09-26 | Basf Ag | Verfahren zur herstellung von 1,4-butandiol |
| MY107920A (en) * | 1990-12-27 | 1996-06-29 | Kao Corp | Process for producing alcohol |
| US5134108A (en) * | 1991-05-22 | 1992-07-28 | Engelhard Corporation | Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof |
| GB9324786D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324752D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324823D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324753D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324783D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324785D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324784D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324782D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB2310206A (en) * | 1996-01-31 | 1997-08-20 | Procter & Gamble | Disulfated cleaning agent synthesis |
| ZA972614B (en) * | 1996-03-29 | 1997-12-22 | Kvaerner Process Tech Ltd | Process for the production of butane-1,4-diol. |
| ZA973972B (en) * | 1996-05-14 | 1998-03-23 | Kvaerner Process Tech Ltd | A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran. |
| ZA973971B (en) * | 1996-05-15 | 1998-03-23 | Kvaerner Process Tech Ltd | A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran. |
| GB9724004D0 (en) | 1997-11-13 | 1998-10-21 | Kvaerner Process Tech Ltd | Process |
| GB9724195D0 (en) | 1997-11-14 | 1998-01-14 | Kvaerner Process Tech Ltd | Process |
| BE1011698A6 (fr) | 1998-01-08 | 1999-12-07 | Pantochim Sa | Procede de production de tetrahydrofuranne, de gamma-butyrolactone et de butanediol. |
| ES2158645T3 (es) | 1998-03-23 | 2001-09-01 | Basf Ag | Procedimiento para la preparacion de 1,4-butanodiol, butirolactona y tetrahidrofurano. |
| BE1011870A6 (fr) * | 1998-04-09 | 2000-02-01 | Pantochim Sa | Procede de production de butanediol. |
| DE19842847A1 (de) * | 1998-09-18 | 2000-03-23 | Basf Ag | Verfahren zur Herstellung von Tetrahydrofuran |
| US6455742B1 (en) | 1999-09-02 | 2002-09-24 | Wisconsin Alumni Research Foundation | Method for catalytically reducing carboxylic acid groups to hydroxyl groups in hydroxycarboxylic acids |
| EP1108702A1 (de) * | 1999-12-13 | 2001-06-20 | Kvaerner Process Technology Limited | Verfahren zur Koproduktion von aliphatischen Diolen und cyclischen Ethern |
| GB0117090D0 (en) | 2001-07-12 | 2001-09-05 | Kvaerner Process Tech Ltd | Process |
| DE10225928A1 (de) * | 2002-06-11 | 2003-12-24 | Basf Ag | Zweistufiges Verfahren zur Herstellung von Butandiol in zwei Reaktoren |
| GB0325530D0 (en) * | 2003-10-31 | 2003-12-03 | Davy Process Techn Ltd | Process |
| GB0421928D0 (en) * | 2004-10-01 | 2004-11-03 | Davy Process Techn Ltd | Process |
| CN101307042B (zh) * | 2007-05-18 | 2011-04-20 | 中国石油化工股份有限公司 | 生产1,4-丁二醇并联产四氢呋喃、γ-丁内酯的方法 |
| GB0803663D0 (en) * | 2008-02-28 | 2008-04-09 | Davy Process Techn Ltd | Process |
| GB201115617D0 (en) | 2011-09-09 | 2011-10-26 | Davy Process Techn Ltd | Proacess |
| US9168509B2 (en) | 2011-11-09 | 2015-10-27 | China Petroleum & Chemical Corp. | Hydrogenation catalysts and the preparation processes thereof |
| EP2782893B1 (de) | 2011-11-25 | 2017-08-23 | Conser SPA | Verfahren zur herstellung von 1,4-butandiol, gamma-butyrolacton und tetrahydrofuran durch hydrierung von dialkylmaleat in einer gemischten flüssigkeits-/dampfphase |
| MX362055B (es) * | 2012-12-20 | 2019-01-07 | Archer Daniels Midland Co | Productos de hidrogenación obtenidos a partir de ésteres de ácidos carboxílicos derivados biológicamente. |
| GB201318175D0 (en) | 2013-10-14 | 2013-11-27 | Johnson Matthey Davy Technologies Ltd | Process |
| GB201321627D0 (en) | 2013-12-06 | 2014-01-22 | Johnson Matthey Davy Technologies Ltd | Process |
| GB201321611D0 (en) | 2013-12-06 | 2014-01-22 | Johnson Matthey Davy Technologies Ltd | Process |
| GB201507234D0 (en) | 2015-04-28 | 2015-06-10 | Johnson Matthey Davy Technologies Ltd | Process |
| CN106187683B (zh) * | 2016-07-05 | 2018-07-24 | 中石化上海工程有限公司 | 1,4-丁二醇的生产方法 |
| CN106083523B (zh) * | 2016-07-05 | 2018-07-27 | 中石化上海工程有限公司 | 生产1,4-丁二醇的方法 |
| EP4188903B1 (de) | 2021-03-12 | 2024-01-03 | Conser S.P.A. | Verfahren zur gleichzeitigen herstellung von dialkylsuccinat und 1,4-butandiol durch hydrierung von dialkylmaleat in zwei stufen |
| CN114181038B (zh) | 2021-12-24 | 2022-10-11 | 常州瑞华化工工程技术股份有限公司 | 一种顺酐直接加氢生产1,4-丁二醇并联产丁二酸酐的方法 |
| GB202203264D0 (en) | 2022-03-09 | 2022-04-20 | Johnson Matthey Davy Technologies Ltd | Process for producing a refined 1,4-butanediol stream |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1276722A (fr) * | 1960-10-11 | 1961-11-24 | Eastman Kodak Co | Procédé de préparation d'un catalyseur en vue de la réduction des esters en alcools |
| US4032458A (en) * | 1975-08-08 | 1977-06-28 | Petro-Tex Chemical Corporation | Production of 1,4-butanediol |
| DE2719867A1 (de) * | 1977-05-04 | 1978-11-09 | Bayer Ag | Verfahren zur herstellung von butandiol-1,4 |
| US4172961A (en) * | 1975-08-08 | 1979-10-30 | Denka Chemical Corporation | Production of 1,4-butanediol |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB555240A (en) * | 1941-01-20 | 1943-08-12 | Du Pont | Improvements in and relating to the catalytic hydrogenation of organic compounds |
| US4112245A (en) * | 1976-08-18 | 1978-09-05 | Atlantic Richfield Company | Process for the preparation of ethylene glycol |
| BR8201302A (pt) * | 1981-03-12 | 1983-01-25 | Union Carbide Corp | Processo para a preparacao de etileno glicol |
-
1983
- 1983-11-29 GB GB8331793A patent/GB8331793D0/en active Pending
-
1984
- 1984-11-21 US US06/673,797 patent/US4584419A/en not_active Expired - Fee Related
- 1984-11-26 EP EP19840308181 patent/EP0143634A3/de not_active Ceased
- 1984-11-28 CA CA000468832A patent/CA1246616A/en not_active Expired
- 1984-11-28 KR KR1019840007459A patent/KR910008935B1/ko not_active Expired
- 1984-11-29 JP JP59253922A patent/JPS6122035A/ja active Pending
- 1984-11-29 ES ES538549A patent/ES8604844A1/es not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1276722A (fr) * | 1960-10-11 | 1961-11-24 | Eastman Kodak Co | Procédé de préparation d'un catalyseur en vue de la réduction des esters en alcools |
| US4032458A (en) * | 1975-08-08 | 1977-06-28 | Petro-Tex Chemical Corporation | Production of 1,4-butanediol |
| US4172961A (en) * | 1975-08-08 | 1979-10-30 | Denka Chemical Corporation | Production of 1,4-butanediol |
| DE2719867A1 (de) * | 1977-05-04 | 1978-11-09 | Bayer Ag | Verfahren zur herstellung von butandiol-1,4 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB8331793D0 (en) | 1984-01-04 |
| KR910008935B1 (ko) | 1991-10-26 |
| US4584419A (en) | 1986-04-22 |
| KR850004457A (ko) | 1985-07-15 |
| EP0143634A2 (de) | 1985-06-05 |
| ES538549A0 (es) | 1986-03-01 |
| CA1246616A (en) | 1988-12-13 |
| JPS6122035A (ja) | 1986-01-30 |
| ES8604844A1 (es) | 1986-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): DE FR GB IT NL |
|
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
| AK | Designated contracting states |
Designated state(s): DE FR GB IT NL |
|
| 17P | Request for examination filed |
Effective date: 19860404 |
|
| 17Q | First examination report despatched |
Effective date: 19861112 |
|
| 17Q | First examination report despatched |
Effective date: 19871210 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
| 18R | Application refused |
Effective date: 19900826 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: TURNER, KEITH Inventor name: SHARIF, MOHAMMAD |