ES2082191T3 - Monomeros polimerizables por aniones, sus polimeros y uso de tales polimeros en sustancias fotoprotectoras. - Google Patents
Monomeros polimerizables por aniones, sus polimeros y uso de tales polimeros en sustancias fotoprotectoras.Info
- Publication number
- ES2082191T3 ES2082191T3 ES91902819T ES91902819T ES2082191T3 ES 2082191 T3 ES2082191 T3 ES 2082191T3 ES 91902819 T ES91902819 T ES 91902819T ES 91902819 T ES91902819 T ES 91902819T ES 2082191 T3 ES2082191 T3 ES 2082191T3
- Authority
- ES
- Spain
- Prior art keywords
- polymers
- monomers
- image
- silicon
- photoprotecting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000178 monomer Substances 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title 2
- 150000001450 anions Chemical class 0.000 title 1
- 230000003711 photoprotective effect Effects 0.000 title 1
- 239000000126 substance Substances 0.000 title 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 125000006575 electron-withdrawing group Chemical group 0.000 abstract 2
- 238000003384 imaging method Methods 0.000 abstract 2
- 229920002120 photoresistant polymer Polymers 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- MCAGVWOAZVDCMI-UHFFFAOYSA-N 3-trimethylsilylpropyl 2-cyanoprop-2-enoate Chemical group C[Si](C)(C)CCCOC(=O)C(=C)C#N MCAGVWOAZVDCMI-UHFFFAOYSA-N 0.000 abstract 1
- 206010073306 Exposure to radiation Diseases 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000001393 microlithography Methods 0.000 abstract 1
- 229910052719 titanium Chemical group 0.000 abstract 1
- 238000007740 vapor deposition Methods 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/075—Silicon-containing compounds
- G03F7/0757—Macromolecular compounds containing Si-O, Si-C or Si-N bonds
- G03F7/0758—Macromolecular compounds containing Si-O, Si-C or Si-N bonds with silicon- containing groups in the side chains
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Polymerisation Methods In General (AREA)
- Dental Preparations (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Materials For Photolithography (AREA)
Abstract
MONOMEROS ANIONICAMENTE POLIMERIZABLES QUE CONTIENEN AL MENOS UN ATOMO DE SILICIO O DE TITANIO PARA SUSTANCIAS FOTOENDURECIBLES POLIMERICAS PARA UTILIZARLOS EN UNA MICROLITOGRAFIA. LOS MONOMEROS TIENEN LA FORMULA (I), EN DONDE A ES -H O -CH=CH SUB 2; X ES UN GRUPO FUERTE DE RETIRADA DE ELECTRONES; Y ES UN FUERTE GRUPO DE RETIRADA DE ELECTRONES QUE CONTIENE AL MENOS UN ATOMO DE SILICIO O DE TITANIO. Y ES PREFERENTEMENTE (II), EN DONDE N ES DE 1 A 5 Y R (AL CUADRADO) , R ELEVADO 3 Y R ELEVADO 4 SON ALQUILO C SUB 1 -C SUB 10. UN MONOMERO PARTICULARMENTE PREFERENTE ES 3-TRIMETILSILILPROPIL -2-CIANOACRILATO. SE DESCRIBEN LOS METODOS PARA APLICAR UN REVESTIMIENTO RESISTENTE MEDIANTE UNA DEPOSICION POR VAPOR DE ESTOS MONOMEROS Y LA EXPOSICION A UNA RADIACION. SE PUEDE PRODUCIR UNA IMAGEN DE TONO POSITIVO O NEGATIVO DEPENDIENDO DEL METODO DE FORMACION DE IMAGENES UTILIZADO. LA CAPA FORMADORA DE IMAGENES PUEDE SER APLICADA SOBRE UNA CAPA PLANIFICADORA PARA FORMAR UNA SUSTANCIA FOTOENDURECIBLE MULTICAPA.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IE371389 | 1989-11-21 | ||
| US54246490A | 1990-06-22 | 1990-06-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2082191T3 true ES2082191T3 (es) | 1996-03-16 |
Family
ID=26319352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91902819T Expired - Lifetime ES2082191T3 (es) | 1989-11-21 | 1990-11-20 | Monomeros polimerizables por aniones, sus polimeros y uso de tales polimeros en sustancias fotoprotectoras. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5359101A (es) |
| EP (1) | EP0502128B1 (es) |
| JP (1) | JPH05504366A (es) |
| AT (1) | ATE132510T1 (es) |
| CA (1) | CA2019669A1 (es) |
| DE (1) | DE69024661T2 (es) |
| ES (1) | ES2082191T3 (es) |
| HK (1) | HK1005457A1 (es) |
| WO (1) | WO1991007446A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5548055A (en) * | 1995-01-13 | 1996-08-20 | Sri International | Single-ion conducting solid polymer electrolytes |
| US5504252A (en) * | 1995-05-05 | 1996-04-02 | Loctite Corporation | Synthesis of cyanoacrylate esters by oxidation of aromatic selenyl cyanopropionates |
| US6673192B1 (en) | 1997-09-25 | 2004-01-06 | Loctite Corporation | Multi-amine compound primers for bonding of polyolefins with cyanoacrylate adhesives |
| KR100363642B1 (ko) * | 1999-11-11 | 2002-12-05 | 아남반도체 주식회사 | 반도체 소자의 접촉부 형성 방법 |
| US6245933B1 (en) | 1999-11-19 | 2001-06-12 | Closure Medical Corporation | Transesterification method for making cyanoacrylates |
| US7341716B2 (en) * | 2002-04-12 | 2008-03-11 | Boston Scientific Scimed, Inc. | Occlusive composition |
| WO2007046646A1 (en) * | 2005-10-20 | 2007-04-26 | Lg Chem, Ltd. | Novel organic silane compound |
| KR100840114B1 (ko) | 2005-10-20 | 2008-06-19 | 주식회사 엘지화학 | 점착제 조성물 |
| US7867688B2 (en) * | 2006-05-30 | 2011-01-11 | Eastman Kodak Company | Laser ablation resist |
| US7745101B2 (en) * | 2006-06-02 | 2010-06-29 | Eastman Kodak Company | Nanoparticle patterning process |
| US8686105B2 (en) * | 2007-10-24 | 2014-04-01 | Henkel IP & Holding GmbH | Adhesive systems using imines and salts thereof, precursors to electron deficient olefins and coreactants therefor |
| WO2009053484A2 (en) | 2007-10-24 | 2009-04-30 | Loctite (R & D) Limited | Electron deficient olefins and curable compositions prepared therefrom |
| US20100086735A1 (en) * | 2008-10-03 | 2010-04-08 | The United States Of America As Represented By The Secretary Of The Navy | Patterned Functionalization of Nanomechanical Resonators for Chemical Sensing |
| US10196471B1 (en) | 2008-10-24 | 2019-02-05 | Henkel IP & Holding GmbH | Curable composition having an electron deficient olefin |
| WO2015035066A1 (en) | 2013-09-04 | 2015-03-12 | President And Fellows Of Harvard College | Growing films via sequential liquid/vapor phases |
| EP3144072A1 (en) * | 2015-09-17 | 2017-03-22 | Henkel AG & Co. KGaA | Dispenser, kit and method for applying an activator for a curable cyanoacrylate-based component |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2391251A (en) * | 1941-08-08 | 1945-12-18 | Wingfoot Corp | Derivatives of fatty acids and method of preparing same |
| US2467926A (en) * | 1947-03-01 | 1949-04-19 | Goodrich Co B F | Preparation of monomeric alkyl alpha-cyano-acrylates |
| US2665299A (en) * | 1952-05-07 | 1954-01-05 | Goodrich Co B F | Stabilized compositions comprising monomeric 1, 1-dicyano ethylene |
| US2721858A (en) * | 1954-03-10 | 1955-10-25 | Eastman Kodak Co | Method of making alpha-cyanoacrylates |
| US2922807A (en) * | 1957-02-01 | 1960-01-26 | Dow Corning | Preparation of acryloxyalkylorganodisiloxanes |
| US2985682A (en) * | 1958-12-31 | 1961-05-23 | Monsanto Chemicals | Method of making cyanoacetic acid esters |
| US3142698A (en) * | 1960-10-03 | 1964-07-28 | Borden Co | Cyanoacrylate esters |
| US3254111A (en) * | 1960-12-09 | 1966-05-31 | Eastman Kodak Co | Esters of alpha-cyanoacrylic acid and process for the manufacture thereof |
| US3316227A (en) * | 1963-10-18 | 1967-04-25 | Lord Corp | Preparation of 1, 1-disubstituted diunsaturated compounds |
| GB1130638A (en) * | 1966-04-06 | 1968-10-16 | Ici Ltd | Preparation of -‡-cyanoacrylic esters |
| US3355482A (en) * | 1966-06-20 | 1967-11-28 | Eastman Kodak Co | Stabilized cyanoacrylate adhesives |
| CH540329A (de) * | 1967-11-10 | 1973-08-15 | Intercontinental Chem Co Ltd | Klebstoff |
| NL163797C (nl) * | 1969-10-10 | Loctite Ireland Ltd | Werkwijze voor het bereiden van hechtmiddelsamen- stellingen op basis van esters van alfa-cyaanacrylzuur, die een weekmaker bevatten. | |
| US3654340A (en) * | 1970-08-27 | 1972-04-04 | Minnesota Mining & Mfg | Cyanoacrylate monomer process |
| US4012402A (en) * | 1974-10-04 | 1977-03-15 | Johnson & Johnson | Modified cyanoacrylate monomers and methods for preparation |
| JPS5934296B2 (ja) * | 1976-06-16 | 1984-08-21 | 松下電器産業株式会社 | 電子ビ−ムレジストおよびその使用方法 |
| US4081276A (en) * | 1976-10-18 | 1978-03-28 | General Electric Company | Photographic method |
| US4153641A (en) * | 1977-07-25 | 1979-05-08 | Bausch & Lomb Incorporated | Polysiloxane composition and contact lens |
| DE3036615A1 (de) * | 1980-09-29 | 1982-05-13 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur herstellung von resiststrukturen |
| US4348473A (en) * | 1981-03-04 | 1982-09-07 | Xerox Corporation | Dry process for the production of microelectronic devices |
| US4425471A (en) * | 1981-04-23 | 1984-01-10 | Minnesota Mining & Manufacturing Company | Novel cyanoacrylate adhesive compositions and methods of bonding |
| EP0090089B1 (en) * | 1981-12-19 | 1988-10-05 | Daikin Kogyo Co., Ltd. | Resist material and process for forming fine resist pattern |
| JPS58108213A (ja) * | 1981-12-22 | 1983-06-28 | Toagosei Chem Ind Co Ltd | 2−シアノアクリル酸エステル重合体の製造方法 |
| JPS58123727A (ja) * | 1982-01-18 | 1983-07-23 | Fujitsu Ltd | 半導体装置の製造方法 |
| US4460436A (en) * | 1983-09-06 | 1984-07-17 | International Business Machines Corporation | Deposition of polymer films by means of ion beams |
| WO1985002030A1 (en) * | 1983-11-02 | 1985-05-09 | Hughes Aircraft Company | GRAFT POLYMERIZED SiO2 LITHOGRAPHIC MASKS |
| JPH0640233B2 (ja) * | 1984-04-13 | 1994-05-25 | 株式会社リコー | 電子写真装置 |
| JPS6160062A (ja) * | 1984-08-31 | 1986-03-27 | Nec Corp | リモ−ト中継フアクシミリ同報装置 |
| JPS61168607A (ja) * | 1985-01-21 | 1986-07-30 | Shin Etsu Chem Co Ltd | 一成分型室温硬化性組成物 |
| US4551418A (en) * | 1985-02-19 | 1985-11-05 | International Business Machines Corporation | Process for preparing negative relief images with cationic photopolymerization |
| JPH0680066B2 (ja) * | 1985-09-30 | 1994-10-12 | 日本合成ゴム株式会社 | α−シリルアクリル酸エステルの製造法 |
| US4675270A (en) * | 1986-02-10 | 1987-06-23 | Loctite (Ireland) Limited | Imaging method for vapor deposited photoresists of anionically polymerizable monomer |
| US4675273A (en) * | 1986-02-10 | 1987-06-23 | Loctite (Ireland) Limited | Resists formed by vapor deposition of anionically polymerizable monomer |
| JPS62215595A (ja) * | 1986-03-18 | 1987-09-22 | Shin Etsu Chem Co Ltd | 新規α−(シアノメチル)ビニルシラン化合物およびその製法 |
| JPS6395207A (ja) * | 1986-10-09 | 1988-04-26 | Daikin Ind Ltd | 気体分離膜 |
| JPS6456687A (en) * | 1987-08-28 | 1989-03-03 | Toshiba Corp | Alpha-chloroacrylate having silicon atom on ester side chain |
| JPH0730096B2 (ja) * | 1989-03-24 | 1995-04-05 | 信越化学工業株式会社 | α―トリフルオロメチルアクリル酸トリオルガノシリルメチルエステル |
| IE892044A1 (en) * | 1989-06-23 | 1991-01-02 | Loctite Ireland Ltd | Photoresists formed by polymerisation of di-unsaturated¹monomers |
| US5200238A (en) * | 1990-06-22 | 1993-04-06 | Loctite (Ireland) Limited | Liquid crystal display devices and method of manufacture |
| JPH0676420B2 (ja) * | 1990-11-30 | 1994-09-28 | 株式会社スリーボンド | 新規なα―シアノアクリレートおよび接着剤組成物 |
-
1990
- 1990-06-22 CA CA002019669A patent/CA2019669A1/en not_active Abandoned
- 1990-11-20 EP EP91902819A patent/EP0502128B1/en not_active Expired - Lifetime
- 1990-11-20 AT AT91902819T patent/ATE132510T1/de not_active IP Right Cessation
- 1990-11-20 HK HK98104514A patent/HK1005457A1/en not_active IP Right Cessation
- 1990-11-20 JP JP91503206A patent/JPH05504366A/ja active Pending
- 1990-11-20 WO PCT/US1990/006832 patent/WO1991007446A1/en not_active Ceased
- 1990-11-20 DE DE69024661T patent/DE69024661T2/de not_active Expired - Fee Related
- 1990-11-20 ES ES91902819T patent/ES2082191T3/es not_active Expired - Lifetime
-
1991
- 1991-10-01 US US07/769,511 patent/US5359101A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2019669A1 (en) | 1991-05-21 |
| JPH05504366A (ja) | 1993-07-08 |
| DE69024661D1 (de) | 1996-02-15 |
| WO1991007446A1 (en) | 1991-05-30 |
| HK1005457A1 (en) | 1999-01-08 |
| EP0502128A4 (en) | 1992-04-02 |
| US5359101A (en) | 1994-10-25 |
| DE69024661T2 (de) | 1996-08-01 |
| ATE132510T1 (de) | 1996-01-15 |
| EP0502128B1 (en) | 1996-01-03 |
| EP0502128A1 (en) | 1992-09-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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