ES2129063T3 - Componentes y catalizadores para la polimerizacion de olefinas. - Google Patents

Componentes y catalizadores para la polimerizacion de olefinas.

Info

Publication number
ES2129063T3
ES2129063T3 ES93119646T ES93119646T ES2129063T3 ES 2129063 T3 ES2129063 T3 ES 2129063T3 ES 93119646 T ES93119646 T ES 93119646T ES 93119646 T ES93119646 T ES 93119646T ES 2129063 T3 ES2129063 T3 ES 2129063T3
Authority
ES
Spain
Prior art keywords
polymerization
measured according
components
olefins
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93119646T
Other languages
English (en)
Inventor
Mario Sacchetti
Illaro Cuffiani
Gianni Pennini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Application granted granted Critical
Publication of ES2129063T3 publication Critical patent/ES2129063T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A COMPONENTES CATALITICOS SOLIDOS ESFERICOS PARA LA POLIMERIZACION DE OLEFINAS, QUE CONTIENEN UN COMPUESTO DE TITANIO, SOPORTADO EN UN HALURO DE MAGNESIO, QUE CONTIENE MAS DE UN ENLACE TI-HALOGENO Y QUE OPCIONALMENTE CONTIENE GRUPOS DIFERENTES DEL HALOGENO EN UNA CANTIDAD INFERIOR A 0,5 MOLES POR MOL DE TI. LOS COMPUESTOS SOLIDOS ESFERICOS DE LA INVENCION SE CARACTERIZAN PORQUE TIENEN UN AREA SUPERFICIAL, MEDIDA SEGUN EL METODO BET, INFERIOR A 70 M2/G, UNA POROSIDAD TOTAL, MEDIDA SEGUN EL METODO DEL MERCURIO, SUPERIOR A 0,5 CM3/G Y UN RADIO DE LOS POROS TAL QUE AL MENOS EL 50% TENGA VALORES SUPERIORES A 800 ANGSTROMS.
ES93119646T 1992-12-11 1993-12-06 Componentes y catalizadores para la polimerizacion de olefinas. Expired - Lifetime ES2129063T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI922822A IT1256648B (it) 1992-12-11 1992-12-11 Componenti e catalizzatori per la polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
ES2129063T3 true ES2129063T3 (es) 1999-06-01

Family

ID=11364444

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93119646T Expired - Lifetime ES2129063T3 (es) 1992-12-11 1993-12-06 Componentes y catalizadores para la polimerizacion de olefinas.

Country Status (18)

Country Link
US (1) US6388028B2 (es)
EP (1) EP0601525B1 (es)
JP (1) JP4023833B2 (es)
KR (1) KR100289267B1 (es)
CN (2) CN1034580C (es)
AT (1) ATE176676T1 (es)
AU (1) AU673551B2 (es)
BR (1) BR9305019A (es)
CA (1) CA2111308A1 (es)
DE (1) DE69323478T2 (es)
ES (1) ES2129063T3 (es)
FI (1) FI112240B (es)
IL (1) IL107958A (es)
IT (1) IT1256648B (es)
MX (1) MX9307843A (es)
NO (1) NO302825B1 (es)
RU (1) RU2126420C1 (es)
ZA (1) ZA939210B (es)

Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1264679B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori per la (co)polimerizzazione di etilene
IT1275573B (it) * 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
DE69910511T2 (de) 1998-03-05 2004-06-17 Basell Poliolefine Italia S.P.A. Polybutene-1 (co)polymere und verfahren zu ihrer herstellung
SG73622A1 (en) * 1998-03-11 2000-06-20 Sumitomo Chemical Co Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
WO1999057160A1 (en) 1998-05-06 1999-11-11 Montell Technology Company B.V. Catalyst components for the polymerization of olefins
TW475934B (en) 1998-06-27 2002-02-11 Basell Technology Co Bv Process for the production of Α-olefin polymer
IT1301990B1 (it) 1998-08-03 2000-07-20 Licio Zambon Catalizzatori per la polimerizzazione delle olefine.
KR20010033872A (ko) 1998-11-04 2001-04-25 간디 지오프레이 에이치. 올레핀의 중합을 위한 성분 및 촉매
CN1128822C (zh) 1999-02-26 2003-11-26 中国石油化工集团公司 一种烯烃聚合催化剂载体的制备方法
JP4537587B2 (ja) 1999-03-15 2010-09-01 バセル テクノロジー カンパニー ビー．ブイ． オレフィンの重合用成分および触媒
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CA2510254A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom
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DE69323478T2 (de) 1999-08-19
NO934496L (no) 1994-06-13
AU673551B2 (en) 1996-11-14
IL107958A (en) 1998-09-24
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NO934496D0 (no) 1993-12-09
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AU5229593A (en) 1994-06-23
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BR9305019A (pt) 1994-07-05
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