ES2135741T3 - Procedimiento y productos intermedios para la obtencion de metilamidas de acido alfa-metoxiiminocarboxilico. - Google Patents
Procedimiento y productos intermedios para la obtencion de metilamidas de acido alfa-metoxiiminocarboxilico.Info
- Publication number
- ES2135741T3 ES2135741T3 ES95921761T ES95921761T ES2135741T3 ES 2135741 T3 ES2135741 T3 ES 2135741T3 ES 95921761 T ES95921761 T ES 95921761T ES 95921761 T ES95921761 T ES 95921761T ES 2135741 T3 ES2135741 T3 ES 2135741T3
- Authority
- ES
- Spain
- Prior art keywords
- formula
- methylamides
- procedure
- obtaining
- intermediate products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 239000013067 intermediate product Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract 2
- 150000002923 oximes Chemical class 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical group O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- 238000003482 Pinner synthesis reaction Methods 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D249/12—Oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
- C07C235/70—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
- C07C235/72—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton with the carbon atoms of the carboxamide groups bound to acyclic carbon atoms
- C07C235/76—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton with the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of an unsaturated carbon skeleton
- C07C235/78—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton with the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of an unsaturated carbon skeleton the carbon skeleton containing rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/08—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reaction of hydroxylamines with carbonyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/12—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reactions not involving the formation of oxyimino groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
- C07C251/60—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/18—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group
- C07C67/22—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group from nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO Y PRODUCTOS INTERMEDIOS PARA LA OBTENCION DE METILAMIDAS DE ACIDOS {AL}-METOXIIMINOCARBOXILICOS DE FORMULA (I), ( X = NITRO, TRIFLUOROMETILO, HALOGENO, ALQUILO O ALCOXILO, N = 1, 2, 3 O 4; Y = UN RADICAL ORGANICO DE CARBONO) MEDIANTE LA REACCION DE PINNER DE UNA CIANOCETONA DE FORMULA (II) CON UN ALCOHOL Y A CONTINUACION REACCION DEL ESTER FORMADO EN LA REACCION DE PINNER DE FORMULA (IV) CON HIDROXILAMINA PARA DAR LA OXIMA DE FORMULA (V), METILACION DE V PARA DAR EL ETER DE LA OXIMA DE FORMULA (VI), Y A CONTINUACION REACCION DE (VI) CON METILAMINA.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4420416 | 1994-06-10 | ||
| DE4420416 | 1994-06-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2135741T3 true ES2135741T3 (es) | 1999-11-01 |
| ES2135741T5 ES2135741T5 (es) | 2008-02-16 |
Family
ID=6520340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95921761T Expired - Lifetime ES2135741T5 (es) | 1994-06-10 | 1995-05-26 | Metodo y productos intermedios para la preparacion de metilamidas de acido alfa-metoxiiminocarboxilico. |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US5856560A (es) |
| EP (1) | EP0765304B2 (es) |
| JP (1) | JP4114948B2 (es) |
| KR (2) | KR100374949B1 (es) |
| CN (1) | CN1082503C (es) |
| AT (1) | ATE183176T1 (es) |
| AU (1) | AU686821B2 (es) |
| BG (1) | BG63115B1 (es) |
| BR (1) | BR9507979A (es) |
| CA (1) | CA2192594C (es) |
| CZ (1) | CZ297235B6 (es) |
| DE (1) | DE59506598D1 (es) |
| DK (1) | DK0765304T4 (es) |
| ES (1) | ES2135741T5 (es) |
| FI (1) | FI120583B (es) |
| GE (1) | GEP20012438B (es) |
| GR (1) | GR3031313T3 (es) |
| HU (1) | HU219195B (es) |
| IL (1) | IL114038A (es) |
| MX (1) | MX9606276A (es) |
| NO (1) | NO307333B1 (es) |
| NZ (1) | NZ287862A (es) |
| PL (1) | PL179861B1 (es) |
| RU (1) | RU2146247C1 (es) |
| SK (1) | SK283068B6 (es) |
| UA (1) | UA42776C2 (es) |
| WO (1) | WO1995034526A1 (es) |
| ZA (1) | ZA954825B (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4305502A1 (de) * | 1993-02-23 | 1994-08-25 | Basf Ag | Ortho-substituierte 2-Methoxyiminophenylessigsäuremethylamide |
| EP0738260B2 (en) * | 1994-01-05 | 2006-12-13 | Bayer CropScience AG | Pesticides |
| JPH07238701A (ja) * | 1994-02-28 | 1995-09-12 | Koji Sakata | 立体駐車装置 |
| ES2145920T3 (es) * | 1994-09-06 | 2000-07-16 | Shionogi & Co | Procedimiento de produccion de derivado de alcoxiiminoacetamida. |
| DE19540361A1 (de) | 1995-10-30 | 1997-05-07 | Basf Ag | Phenylessigsäurederivate, Verfahren und Zwischenprodukte zu ihrer Herstellung und ihre Verwendung zur Bekämpfung von Schadpilzen und tierischen Schädlingen |
| ES2173330T5 (es) * | 1995-11-29 | 2007-03-16 | Bayer Cropscience Ag | Procedimiento para la preparacion de derivados de acido metoximinofenilglioxilico. |
| CN1238337C (zh) * | 1995-12-07 | 2006-01-25 | 拜尔公开股份有限公司 | 农药 |
| CN1111155C (zh) * | 1995-12-07 | 2003-06-11 | 拜尔公开股份有限公司 | 农药的制备方法 |
| DE59605241D1 (de) * | 1996-01-03 | 2000-06-21 | Novartis Ag | Verfahren zur Herstellung o-Chlor-Methyl-Phenylglyoxylsäure-Derivaten |
| FR2773155B1 (fr) * | 1997-12-29 | 2000-01-28 | Rhone Poulenc Agrochimie | Nouveaux composes fongicides |
| WO1999050231A1 (en) * | 1998-03-26 | 1999-10-07 | Shionogi & Co., Ltd. | Process for producing oxime compound |
| US6313344B1 (en) | 1998-05-27 | 2001-11-06 | Bayer Aktiengesellschaft | Organic compounds |
| WO2009037230A2 (en) * | 2007-09-17 | 2009-03-26 | Dsm Fine Chemicals Austria Nfg Gmbh & Co Kg | Improved process for preparing (e)-2-(2-chloromethylphenyl)-2-alkoximinoacetic esters |
| JP2012516868A (ja) | 2009-02-05 | 2012-07-26 | ビーエーエスエフ ソシエタス・ヨーロピア | 2−ハロゲノメチルフェニル酢酸誘導体の製造方法 |
| CN109912417A (zh) * | 2018-12-29 | 2019-06-21 | 京博农化科技有限公司 | 一种2-(2-甲基苯氧甲基)-苯甲酰甲酸甲酯的合成方法 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8617648D0 (en) † | 1986-07-18 | 1986-08-28 | Ici Plc | Fungicides |
| IL87020A (en) † | 1987-07-11 | 1996-09-12 | Schering Agrochemicals Ltd | Acrylic acid derivatives and their use as pesticides |
| DE3827361A1 (de) † | 1988-08-12 | 1990-03-01 | Basf Ag | Oximether, verfahren zu ihrer herstellung und diese verbindungen enthaltende fungizide |
| EP0370629B2 (en) * | 1988-11-21 | 1998-01-07 | Zeneca Limited | Fungicides |
| DE3843439A1 (de) † | 1988-12-23 | 1990-06-28 | Basf Ag | Schwefelhaltige oximether und diese enthaltende fungizide |
| DE69029334T2 (de) * | 1989-05-17 | 1997-04-30 | Shionogi Seiyaku Kk | Verfahren zur Herstellung von Alkoxyiminoacetamid-Derivaten und ein Zwischenproduckt dafür |
| DE3933891A1 (de) * | 1989-10-11 | 1991-04-18 | Basf Ag | Phenylessigsaeure-derivate und diese enthaltende fungizide |
| DE4009616A1 (de) * | 1990-03-26 | 1991-10-02 | Henkel Kgaa | Fluessige koerperreinigungsmittel |
| PH11991042549B1 (es) * | 1990-06-05 | 2000-12-04 | ||
| DE59109047D1 (de) * | 1990-06-27 | 1998-10-08 | Basf Ag | O-Benzyl-Oximether und diese Verbindungen enthaltende Pflanzenschutzmittel |
| DE4030038A1 (de) * | 1990-09-22 | 1992-03-26 | Basf Ag | Ortho-substituierte phenylessigsaeureamide |
| DE4042280A1 (de) * | 1990-12-31 | 1992-07-02 | Basf Ag | Verfahren zur herstellung von (alpha)-ketocarbonsaeureestern |
| EP0712833B1 (de) * | 1990-12-31 | 1997-09-03 | Basf Aktiengesellschaft | Verfahren zur Herstellung von 2-Phenoxymethylbenzoesäuren |
| DE4042271A1 (de) * | 1990-12-31 | 1992-07-02 | Basf Ag | Verfahren zur herstellung von arylglyoxylsaeureestern |
| DE4042273A1 (de) * | 1990-12-31 | 1992-07-02 | Basf Ag | Verfahren zur herstellung von (alpha)-ketocarbonsaeureestern |
| JPH06504538A (ja) * | 1991-01-30 | 1994-05-26 | ゼネカ・リミテッド | 殺菌剤 |
| GB9218541D0 (en) * | 1991-09-30 | 1992-10-14 | Ici Plc | Fungicides |
| GB9122098D0 (en) * | 1991-10-17 | 1991-11-27 | Ici Plc | Fungicides |
| DE4203170A1 (de) * | 1992-02-05 | 1993-08-12 | Basf Ag | Verfahren zur herstellung von e-oximethern von phenylglyoxylsaeureestern |
| IL105191A (en) * | 1992-04-04 | 1998-08-16 | Basf Ag | Acids and aminooxymethylbenzoic acids and their preparation |
| DK0579124T3 (da) * | 1992-07-15 | 1996-11-18 | Basf Ag | Substituerede oximethere, fremgangsmåde til deres fremstilling og deres anvendelse til bekæmpelse af skadelige organismer og svampe |
| IL106473A0 (en) * | 1992-08-11 | 1993-11-15 | Basf Ag | Acetylene derivatives and crop protection agents containing them |
| ES2094432T3 (es) * | 1992-08-29 | 1997-01-16 | Basf Ag | N-metilamidas, procedimientos y productos intermedios para su obtencion asi como procedimiento para la lucha contra las pestes. |
| GB9221584D0 (en) * | 1992-10-14 | 1992-11-25 | Ici Plc | Chemical process |
| DE4238260A1 (de) * | 1992-11-12 | 1994-05-19 | Basf Ag | Substituierte ortho-Ethenylphenylessigsäurederivate |
| GB9226734D0 (en) * | 1992-12-22 | 1993-02-17 | Ici Plc | Fungicides |
| DE4305502A1 (de) * | 1993-02-23 | 1994-08-25 | Basf Ag | Ortho-substituierte 2-Methoxyiminophenylessigsäuremethylamide |
| US5506358A (en) * | 1993-03-16 | 1996-04-09 | Shionogi & Co., Ltd. | Process for producing alkoxyiminoacetamide compounds |
| ES2108897T3 (es) * | 1993-03-19 | 1998-01-01 | Ube Industries | Compuesto del tipo oxima eter, procesos para su preparacion y fungicida que contiene dicho compuesto. |
| DE4310143A1 (de) * | 1993-03-29 | 1994-10-06 | Basf Ag | Imino-substituierte Phenylessigsäureamide, ihre Herstellung und diese enthaltende Fungizide |
| JPH08319265A (ja) † | 1995-05-23 | 1996-12-03 | Mitsubishi Chem Corp | N−メチル−メトキシイミノ酢酸アミド誘導体の製造法およびその中間体 |
-
1995
- 1995-05-26 CN CN95194276A patent/CN1082503C/zh not_active Expired - Lifetime
- 1995-05-26 NZ NZ287862A patent/NZ287862A/xx not_active IP Right Cessation
- 1995-05-26 HU HU9603401A patent/HU219195B/hu not_active IP Right Cessation
- 1995-05-26 RU RU97100673A patent/RU2146247C1/ru not_active IP Right Cessation
- 1995-05-26 CZ CZ0357896A patent/CZ297235B6/cs not_active IP Right Cessation
- 1995-05-26 AU AU26710/95A patent/AU686821B2/en not_active Ceased
- 1995-05-26 ES ES95921761T patent/ES2135741T5/es not_active Expired - Lifetime
- 1995-05-26 BR BR9507979A patent/BR9507979A/pt not_active IP Right Cessation
- 1995-05-26 PL PL95317712A patent/PL179861B1/pl not_active IP Right Cessation
- 1995-05-26 JP JP50154296A patent/JP4114948B2/ja not_active Expired - Lifetime
- 1995-05-26 MX MX9606276A patent/MX9606276A/es unknown
- 1995-05-26 CA CA002192594A patent/CA2192594C/en not_active Expired - Fee Related
- 1995-05-26 GE GE2653A patent/GEP20012438B/en unknown
- 1995-05-26 KR KR1019960707049A patent/KR100374949B1/ko not_active Expired - Lifetime
- 1995-05-26 WO PCT/EP1995/002013 patent/WO1995034526A1/de not_active Ceased
- 1995-05-26 EP EP95921761A patent/EP0765304B2/de not_active Expired - Lifetime
- 1995-05-26 AT AT95921761T patent/ATE183176T1/de active
- 1995-05-26 DK DK95921761T patent/DK0765304T4/da active
- 1995-05-26 UA UA97010107A patent/UA42776C2/uk unknown
- 1995-05-26 SK SK1575-96A patent/SK283068B6/sk not_active IP Right Cessation
- 1995-05-26 DE DE59506598T patent/DE59506598D1/de not_active Expired - Lifetime
- 1995-06-07 IL IL11403895A patent/IL114038A/xx not_active IP Right Cessation
- 1995-06-12 ZA ZA954825A patent/ZA954825B/xx unknown
-
1996
- 1996-12-05 FI FI964901A patent/FI120583B/fi not_active IP Right Cessation
- 1996-12-09 NO NO965259A patent/NO307333B1/no not_active IP Right Cessation
- 1996-12-10 KR KR19967007049A patent/KR970703931A/ko active Granted
- 1996-12-10 US US08/750,822 patent/US5856560A/en not_active Expired - Lifetime
- 1996-12-28 BG BG101079A patent/BG63115B1/bg unknown
-
1999
- 1999-09-22 GR GR990402413T patent/GR3031313T3/el unknown
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| FG2A | Definitive protection |
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