ES2155014B1 - Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. - Google Patents
Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion.Info
- Publication number
- ES2155014B1 ES2155014B1 ES009900470A ES9900470A ES2155014B1 ES 2155014 B1 ES2155014 B1 ES 2155014B1 ES 009900470 A ES009900470 A ES 009900470A ES 9900470 A ES9900470 A ES 9900470A ES 2155014 B1 ES2155014 B1 ES 2155014B1
- Authority
- ES
- Spain
- Prior art keywords
- sub
- derivatives
- polialquil
- piperidina
- alcoxi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000001404 mediated effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/74—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Hydrogenated Pyridines (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98810194 | 1998-03-09 | ||
| EP98810531 | 1998-06-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2155014A1 ES2155014A1 (es) | 2001-04-16 |
| ES2155014B1 true ES2155014B1 (es) | 2001-12-01 |
Family
ID=26151881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES009900470A Expired - Fee Related ES2155014B1 (es) | 1998-03-09 | 1999-03-08 | Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. |
Country Status (18)
| Country | Link |
|---|---|
| US (4) | US6353107B1 (2) |
| JP (1) | JP4651137B2 (2) |
| KR (1) | KR100581654B1 (2) |
| CN (1) | CN1171871C (2) |
| AT (1) | AT408655B (2) |
| AU (1) | AU754927B2 (2) |
| BE (1) | BE1012399A3 (2) |
| BR (1) | BR9900977B1 (2) |
| CA (1) | CA2264460A1 (2) |
| CH (1) | CH693416A5 (2) |
| CZ (1) | CZ78999A3 (2) |
| DE (1) | DE19909767B4 (2) |
| ES (1) | ES2155014B1 (2) |
| FR (1) | FR2777892B1 (2) |
| GB (1) | GB2335190B (2) |
| IT (1) | IT1309590B1 (2) |
| NL (1) | NL1011493C2 (2) |
| SG (1) | SG82601A1 (2) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG82601A1 (en) * | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
| DE69916455T2 (de) * | 1998-07-31 | 2004-09-09 | Ciba Specialty Chemicals Holding Inc. | Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler |
| WO2000020469A1 (fr) | 1998-10-06 | 2000-04-13 | Atofina | Procede de polymerisation ou copolymerisation radicalaire controlee de l'ethylene sous haute pression en presence d'un amorceur-controleur |
| TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
| ATE272610T1 (de) * | 1999-07-02 | 2004-08-15 | Ciba Sc Holding Ag | Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren |
| TW546311B (en) * | 1999-11-25 | 2003-08-11 | Ciba Sc Holding Ag | Composition and method for color improvement of nitroxyl containing polymers |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
| EP1655303B1 (en) * | 2000-05-19 | 2011-02-23 | Basf Se | Process for the Controlled Increase in Molecular Weight of Polyethylene or Polyethylene Blends |
| TW572896B (en) * | 2000-05-26 | 2004-01-21 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| TW574236B (en) * | 2000-09-25 | 2004-02-01 | Ciba Sc Holding Ag | Process for controlled radical polymerization in aqueous dispersion |
| TWI225492B (en) * | 2000-09-25 | 2004-12-21 | Ciba Sc Holding Ag | Composition and process for enhancing controlled free radical polymerization |
| TWI236482B (en) * | 2000-11-13 | 2005-07-21 | Ciba Sc Holding Ag | Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical |
| TWI274053B (en) * | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
| TW557305B (en) | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
| US6849679B2 (en) | 2001-05-21 | 2005-02-01 | Ciba Specialty Chemicals Corporation | Pigment compositions with modified block copolymer dispersants |
| JP4389247B2 (ja) * | 2001-06-13 | 2009-12-24 | チバ ホールディング インコーポレーテッド | 4−イミノ−n−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用 |
| US7868171B2 (en) * | 2001-11-12 | 2011-01-11 | Ciba Specialty Chemicals Corp. | N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators |
| TW200407307A (en) * | 2001-11-26 | 2004-05-16 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| US7297819B2 (en) * | 2002-03-05 | 2007-11-20 | Ciba Specialty Chemicals Corp. | Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization |
| DE10212831A1 (de) * | 2002-03-22 | 2003-10-02 | Tesa Ag | Verfahren zur Herstellung copolymerer Polyacrylat-Haftklebemassen, damit erhaltene Nitroxid-modifizierte Polyacrylate und Kamm-Blockpolymere |
| WO2003093330A1 (en) * | 2002-05-01 | 2003-11-13 | Ciba Specialty Chemicals Holding Inc. | Process for chain stopping of pvc polymerization |
| EP1375476A1 (en) * | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | A new process for the synthesis of alkoxyamines active in controlled radical polymerization |
| EP1375457A1 (en) | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | One-pot process for the preparation of functionalized alkoxyamines |
| CA2514167A1 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Comb copolymers with defined side chains and process for their manufacture |
| JP4107996B2 (ja) * | 2003-04-25 | 2008-06-25 | 大塚化学株式会社 | リビングラジカルポリマーの製造方法及びポリマー |
| JP4046678B2 (ja) * | 2003-10-15 | 2008-02-13 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ |
| JP4466650B2 (ja) | 2004-06-09 | 2010-05-26 | 日立化成工業株式会社 | フィルム状接着剤、フィルム状回路接続材、回路部材の接続方法及び半導体装置 |
| CN100577692C (zh) * | 2005-01-11 | 2010-01-06 | 西巴特殊化学品控股有限公司 | 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法 |
| JP4046734B2 (ja) | 2005-01-18 | 2008-02-13 | 横浜ゴム株式会社 | ポリマーの変性方法 |
| DE602006017187D1 (de) * | 2005-04-04 | 2010-11-11 | Basf Se | Verfahren zur herstellung von stern- und blockcopolymeren über epoxidfunktionelle alkoxyamine |
| ATE465183T1 (de) * | 2005-08-30 | 2010-05-15 | Basf Se | Aus nitroxylradikalpolymerisation gewonnene polymere |
| JP5425623B2 (ja) * | 2006-07-11 | 2014-02-26 | チバ ホールディング インコーポレーテッド | カラーフィルター組成物 |
| US20080087380A1 (en) * | 2006-10-13 | 2008-04-17 | Dow Global Technologies Inc. | Reactively-coupled articles and related methods |
| KR20090127193A (ko) * | 2007-04-05 | 2009-12-09 | 바스프 에스이 | 선택 공중합체를 포함하는 선스크린 및 개인 위생 조성물 |
| WO2008145595A1 (en) * | 2007-06-01 | 2008-12-04 | Basf Se | Modified printable surfaces |
| EP2235146B1 (en) * | 2007-12-18 | 2016-04-20 | Basf Se | Biodiesel cold flow improver |
| CN102015911B (zh) | 2008-01-17 | 2015-11-25 | 巴斯夫欧洲公司 | 聚合毛发染料 |
| US9062209B2 (en) * | 2009-12-01 | 2015-06-23 | Silberline Manufacturing Company, Inc. | Polymer encapsulated aluminum particulates |
| KR101524342B1 (ko) | 2010-03-30 | 2015-07-06 | 바스프 에스이 | 말단-관능화 중합체 |
| WO2012000992A1 (en) | 2010-06-29 | 2012-01-05 | Basf Se | Process for improving the flow properties of polymer melts |
| US8912252B2 (en) | 2010-07-20 | 2014-12-16 | Silberline Manufacturing Company, Inc. | Film-forming pigments and coating system including the same |
| US8815982B2 (en) | 2010-07-20 | 2014-08-26 | Silberline Manufacturing Company, Inc. | Colored system |
| WO2012010570A1 (en) | 2010-07-22 | 2012-01-26 | Basf Se | Additive combination for sealants applications |
| WO2013060708A1 (en) | 2011-10-25 | 2013-05-02 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| CN104125984B9 (zh) | 2012-02-23 | 2017-09-22 | 巴斯夫欧洲公司 | 具有低动态表面张力的氟代丙烯酸酯嵌段共聚物 |
| CN103073695B (zh) * | 2012-12-27 | 2015-03-11 | 中山大学 | 一种本征型室温自修复结晶性聚合物 |
| US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
| KR102335051B1 (ko) | 2013-07-08 | 2021-12-07 | 바스프 에스이 | 신규 광 안정화제 |
| KR101595087B1 (ko) * | 2015-09-23 | 2016-02-18 | 주식회사 엘림산업 | 피혁용 버핑머신 구동롤러 |
| KR101595084B1 (ko) * | 2015-09-23 | 2016-02-29 | 주식회사 엘림산업 | 피혁용 버핑머신 |
| KR101635582B1 (ko) * | 2015-10-02 | 2016-07-20 | (주)이미인 | 원단 유연화 장치 |
| CN111278934B (zh) | 2017-10-23 | 2022-04-12 | 巴斯夫欧洲公司 | 硅氧烷聚合物水乳液 |
| EP4251665B1 (en) | 2020-11-30 | 2025-01-08 | Basf Se | Process of producing polymer dispersions |
| EP4314155B1 (en) | 2021-03-26 | 2025-04-09 | Basf Se | Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3503982A (en) * | 1966-08-24 | 1970-03-31 | Sankyo Co | 2,2-dimethyl-6,6 disubstituted-4-substituted aminopiperidine-1-oxides |
| JPS4940557B1 (2) * | 1969-03-06 | 1974-11-02 | ||
| US3975357A (en) | 1973-04-19 | 1976-08-17 | Sankyo Company Limited | Stabilized synthetic polymer compositions |
| GB1492494A (en) * | 1975-05-28 | 1977-11-23 | Sankyo Co | Derivatives of 4-aminopiperidine |
| JPS5848580B2 (ja) * | 1975-05-28 | 1983-10-29 | 三共株式会社 | ゴウセイコウブンシザイリヨウヨウアンテイザイ |
| US4141883A (en) | 1975-05-28 | 1979-02-27 | Sankyo Company, Limited | Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives |
| GB1478261A (en) * | 1975-05-28 | 1977-06-29 | Ciba Geigy Ag | Derivatives of 4-oxopiperidines |
| GB1493996A (en) * | 1975-05-28 | 1977-12-07 | Sankyo Co | 4-siloxy derivatives of polyalkylated piperidines |
| GB1496844A (en) * | 1975-05-28 | 1978-01-05 | Ciba Geigy Ag | Stabilization of polymers |
| JPS6089452A (ja) * | 1983-07-11 | 1985-05-20 | コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン | 遊離基重合開始用化合物 |
| AU571240B2 (en) * | 1983-07-11 | 1988-04-14 | Commonwealth Scientific And Industrial Research Organisation | Alkoxy-amines, useful as initiators |
| DE3486145T2 (de) * | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
| EP0155912A3 (de) | 1984-03-20 | 1986-06-04 | Ciba-Geigy Ag | Strahlenstabilisierte polymere Zusammensetzungen |
| US5185448A (en) | 1991-05-07 | 1993-02-09 | Ciba-Geigy Corporation | Substituted 1-oxy-4-acyloxypiperidine and 1-oxy-4-acylaminopiperidine stabilizers |
| TW270131B (2) | 1993-07-13 | 1996-02-11 | Ciba Geigy | |
| EP0638617A1 (de) | 1993-08-13 | 1995-02-15 | Ciba-Geigy Ag | Pigmentsalze |
| US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
| TW358820B (en) | 1995-04-11 | 1999-05-21 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
| EP0792911A3 (en) | 1996-02-27 | 1998-01-14 | Fmc Corporation | Flame resistant polyolefin compositions |
| JP3673525B2 (ja) * | 1996-03-29 | 2005-07-20 | ダウ グローバル テクノロジーズ インコーポレーテッド | ビニル芳香族モノマーの重合中のその場でのブロックコポリマーの製造 |
| TW467931B (en) | 1996-08-22 | 2001-12-11 | Ciba Sc Holding Ag | Stabilizer mixtures |
| DE69708896T2 (de) | 1996-09-25 | 2002-06-20 | Akzo Nobel N.V., Arnheim/Arnhem | Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation |
| DE69829588T2 (de) | 1997-01-10 | 2006-01-19 | E.I. Du Pont De Nemours And Co., Wilmington | Farblose wässrige Ammoniumsulfidlösung |
| US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| WO1999003894A1 (en) * | 1997-07-15 | 1999-01-28 | Ciba Specialty Chemicals Holding Inc. | Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds |
| SG74700A1 (en) | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
| TW495515B (en) * | 1998-03-09 | 2002-07-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives, a polymerizable composition containing the same and a process for polymerization |
| SG82601A1 (en) * | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
| AU759408B2 (en) * | 1998-09-03 | 2003-04-17 | Ciba Specialty Chemicals Holding Inc. | Grafting of ethylenically unsaturated monomers onto polymers |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
-
1999
- 1999-03-02 SG SG9901047A patent/SG82601A1/en unknown
- 1999-03-02 CH CH00379/99A patent/CH693416A5/de not_active IP Right Cessation
- 1999-03-04 US US09/262,804 patent/US6353107B1/en not_active Expired - Lifetime
- 1999-03-04 BE BE9900152A patent/BE1012399A3/fr not_active IP Right Cessation
- 1999-03-05 CA CA002264460A patent/CA2264460A1/en not_active Abandoned
- 1999-03-05 CZ CZ99789A patent/CZ78999A3/cs unknown
- 1999-03-05 IT IT1999MI000453A patent/IT1309590B1/it active
- 1999-03-05 DE DE1999109767 patent/DE19909767B4/de not_active Expired - Lifetime
- 1999-03-08 ES ES009900470A patent/ES2155014B1/es not_active Expired - Fee Related
- 1999-03-08 AT AT0038799A patent/AT408655B/de not_active IP Right Cessation
- 1999-03-08 FR FR9902814A patent/FR2777892B1/fr not_active Expired - Lifetime
- 1999-03-08 CN CNB991020987A patent/CN1171871C/zh not_active Expired - Lifetime
- 1999-03-08 AU AU18636/99A patent/AU754927B2/en not_active Ceased
- 1999-03-08 JP JP06019899A patent/JP4651137B2/ja not_active Expired - Lifetime
- 1999-03-08 GB GB9905152A patent/GB2335190B/en not_active Expired - Lifetime
- 1999-03-09 KR KR1019990007738A patent/KR100581654B1/ko not_active Expired - Lifetime
- 1999-03-09 BR BRPI9900977-3B1A patent/BR9900977B1/pt active IP Right Grant
- 1999-03-09 NL NL1011493A patent/NL1011493C2/nl not_active IP Right Cessation
-
2001
- 2001-12-11 US US10/013,884 patent/US6683142B2/en not_active Expired - Lifetime
-
2003
- 2003-04-24 US US10/422,497 patent/US6927295B2/en not_active Expired - Lifetime
-
2005
- 2005-01-14 US US11/035,915 patent/US7402639B2/en not_active Expired - Fee Related
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