ES2173046A1 - Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes. - Google Patents

Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes.

Info

Publication number
ES2173046A1
ES2173046A1 ES200100650A ES200100650A ES2173046A1 ES 2173046 A1 ES2173046 A1 ES 2173046A1 ES 200100650 A ES200100650 A ES 200100650A ES 200100650 A ES200100650 A ES 200100650A ES 2173046 A1 ES2173046 A1 ES 2173046A1
Authority
ES
Spain
Prior art keywords
compounds
oxides
dietil
piperidina
dimetil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200100650A
Other languages
English (en)
Other versions
ES2173046B1 (es
Inventor
Peter Nesvadba
Marie-Odile Zink
Andreas Kramer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2173046A1 publication Critical patent/ES2173046A1/es
Application granted granted Critical
Publication of ES2173046B1 publication Critical patent/ES2173046B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Compuestos de 2, 2, 6, 6-Dimetildietil-1-Alcoxi-Piperidina y sus 1-Oxidos correspondientes. Estos compuestos corresponden a las fórmulas Ia o IIa, en donde los radicales X e Y y los significados de los diferentes radicales R se corresponden con lo descrito en las reivindicaciones. La invención se refiere también a composiciones polimerizables que comprenden a) por los menos un monómero etilénicamente insaturado, y b) dichos derivados de piperidina. También se refiere a un procedimiento para la polimerización de monómeros etilénicamente insaturados. Los compuestos de la invención que están sustituidos en la posición 4 por un átomo de oxígeno o nitrógeno se usan para la polimerización de monómeros etilénicamente insaturados.
ES200100650A 2000-03-22 2001-03-21 Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes. Expired - Fee Related ES2173046B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22
EP00810246 2000-03-22

Publications (2)

Publication Number Publication Date
ES2173046A1 true ES2173046A1 (es) 2002-10-01
ES2173046B1 ES2173046B1 (es) 2004-06-16

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200100650A Expired - Fee Related ES2173046B1 (es) 2000-03-22 2001-03-21 Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes.

Country Status (16)

Country Link
US (3) US6624306B2 (es)
JP (1) JP2001316365A (es)
KR (1) KR100743975B1 (es)
CN (1) CN1319590A (es)
AU (1) AU784894B2 (es)
BE (1) BE1014058A5 (es)
BR (1) BR0101108A (es)
CA (1) CA2341791C (es)
DE (1) DE10113209A1 (es)
ES (1) ES2173046B1 (es)
FR (1) FR2806720B1 (es)
GB (1) GB2361235B (es)
IT (1) ITMI20010546A1 (es)
NL (1) NL1017635C2 (es)
NO (1) NO20011436L (es)
TW (1) TW541303B (es)

Families Citing this family (27)

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SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
JP4389247B2 (ja) * 2001-06-13 2009-12-24 チバ ホールディング インコーポレーテッド ４−イミノ−ｎ−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
CA2467119C (en) * 2001-12-21 2012-02-07 Ciba Specialty Chemicals Holding Inc. Novel flame retarding compounds
US8013062B2 (en) * 2002-01-22 2011-09-06 Arkema France Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerization in the presence of nitroxides
US7297819B2 (en) * 2002-03-05 2007-11-20 Ciba Specialty Chemicals Corp. Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
WO2005032479A2 (en) * 2003-10-01 2005-04-14 Unviversity Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
EP1675629A1 (en) * 2003-10-07 2006-07-05 Coloplast A/S An adhesive composition and use of such composition
WO2005118651A1 (en) * 2004-05-27 2005-12-15 Ciba Specialty Chemicals Holding Inc. Alkoxyamines containing a radically polymerizable group
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
BRPI0807571A2 (pt) * 2007-02-22 2014-07-01 Othera Holding Inc Compostos de hidroxilamina e métodos de seu uso
KR20090127193A (ko) * 2007-04-05 2009-12-09 바스프 에스이 선택 공중합체를 포함하는 선스크린 및 개인 위생 조성물
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
WO2009156277A1 (en) 2008-06-23 2009-12-30 Basf Se Pigment dispersants with modified copolymers
CN102137889B (zh) * 2008-08-28 2013-11-13 巴斯夫欧洲公司 用于无生命有机材料的稳定剂
KR101524342B1 (ko) 2010-03-30 2015-07-06 바스프 에스이 말단-관능화 중합체
JP4821916B1 (ja) 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
WO2012000992A1 (en) 2010-06-29 2012-01-05 Basf Se Process for improving the flow properties of polymer melts
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
CN104125984B9 (zh) 2012-02-23 2017-09-22 巴斯夫欧洲公司 具有低动态表面张力的氟代丙烯酸酯嵌段共聚物
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
CN111278934B (zh) 2017-10-23 2022-04-12 巴斯夫欧洲公司 硅氧烷聚合物水乳液
EP4314155B1 (en) 2021-03-26 2025-04-09 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant
CN120271495B (zh) * 2025-06-12 2025-09-19 成都道合尔医药技术有限公司 一种(3r,4r)-n-pg-4-氨基-3-甲基哌啶的合成方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2333795A1 (fr) * 1975-05-28 1977-07-01 Ciba Geigy Ag Derives de la 4-aminopiperidine utilisables pour stabiliser des matieres polymeres
FR2777892A1 (fr) * 1998-03-09 1999-10-29 Ciba Sc Holding Ag Derive de 1-alcoxy-polyalkyl-piperidine, composition polymerisable le contenant et son utilisation
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd （メタ）アクリル酸ピペリジン−１−オキシルエステル誘導体からなる（メタ）アクリル酸エステル用重合防止剤およびその製造方法
WO2000014134A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
WO2001002345A2 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers

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JPS5848580B2 (ja) * 1975-05-28 1983-10-29 三共株式会社 ゴウセイコウブンシザイリヨウヨウアンテイザイ
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
US4141883A (en) * 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
DE3486145T2 (de) 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
DE69708896T2 (de) 1996-09-25 2002-06-20 Akzo Nobel N.V., Arnheim/Arnhem Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation
DE69829588T2 (de) 1997-01-10 2006-01-19 E.I. Du Pont De Nemours And Co., Wilmington Farblose wässrige Ammoniumsulfidlösung
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
WO1999003894A1 (en) 1997-07-15 1999-01-28 Ciba Specialty Chemicals Holding Inc. Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
TWI246519B (en) * 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2333795A1 (fr) * 1975-05-28 1977-07-01 Ciba Geigy Ag Derives de la 4-aminopiperidine utilisables pour stabiliser des matieres polymeres
FR2777892A1 (fr) * 1998-03-09 1999-10-29 Ciba Sc Holding Ag Derive de 1-alcoxy-polyalkyl-piperidine, composition polymerisable le contenant et son utilisation
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd （メタ）アクリル酸ピペリジン−１−オキシルエステル誘導体からなる（メタ）アクリル酸エステル用重合防止剤およびその製造方法
WO2000014134A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
WO2001002345A2 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers

Also Published As

Publication number Publication date
GB2361235B (en) 2002-06-12
KR100743975B1 (ko) 2007-07-30
AU784894B2 (en) 2006-07-20
CA2341791C (en) 2010-02-23
CA2341791A1 (en) 2001-09-22
CN1319590A (zh) 2001-10-31
US6891008B2 (en) 2005-05-10
FR2806720B1 (fr) 2006-12-08
BE1014058A5 (fr) 2003-03-04
KR20010092697A (ko) 2001-10-26
FR2806720A1 (fr) 2001-09-28
GB2361235A (en) 2001-10-17
GB0105678D0 (en) 2001-04-25
JP2001316365A (ja) 2001-11-13
US20050143539A1 (en) 2005-06-30
DE10113209A1 (de) 2001-09-27
NL1017635C2 (nl) 2001-09-25
BR0101108A (pt) 2001-11-06
US7160966B2 (en) 2007-01-09
US20030166939A1 (en) 2003-09-04
US20030065184A1 (en) 2003-04-03
TW541303B (en) 2003-07-11
NO20011436D0 (no) 2001-03-21
NO20011436L (no) 2001-09-24
ITMI20010546A1 (it) 2002-09-15
US6624306B2 (en) 2003-09-23
ES2173046B1 (es) 2004-06-16
AU2804901A (en) 2001-09-27

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