ES8306775A1 - "procedimiento de producir articulos termoplasticos conformados". - Google Patents
"procedimiento de producir articulos termoplasticos conformados".Info
- Publication number
- ES8306775A1 ES8306775A1 ES513190A ES513190A ES8306775A1 ES 8306775 A1 ES8306775 A1 ES 8306775A1 ES 513190 A ES513190 A ES 513190A ES 513190 A ES513190 A ES 513190A ES 8306775 A1 ES8306775 A1 ES 8306775A1
- Authority
- ES
- Spain
- Prior art keywords
- solvent
- conformed
- procedure
- producing
- gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001169 thermoplastic Polymers 0.000 title abstract 3
- 239000004416 thermosoftening plastic Substances 0.000 title abstract 2
- 239000002904 solvent Substances 0.000 abstract 4
- -1 POLYETHYLENE Polymers 0.000 abstract 3
- 239000004698 Polyethylene Substances 0.000 abstract 2
- 229920000573 polyethylene Polymers 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 229920001748 polybutylene Polymers 0.000 abstract 1
- 229920006324 polyoxymethylene Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
PROCEDIMIENTO DE PRODUCIR ARTICULOS TERMOPLASTICOS CONFORMADOS. CONSTA DE LAS SIGUIENTES ETAPAS: 1 ) FORMAR UNA DISOLUCION DE UN POLIMERO TERMOPLASTICO CRISTALINO A BASE DE POLIETILENO, POLIPROPILENO, POLIOXIMETILENO, POLIBUTENO-1, POLILFLUORURO DE VINILIDENO Y POLI (4-METILPENTENO-1). 2 ) EXTRUIR LA SOLUCION. 3 ) REFRIGERAR LA SOLUCION JUNTO A LA ABERTURA, FORMANDO UN GEL QUE CONTIENE UN PRIMER DISOLVENTE. 4 ) EXTRAER EL GEL CON UN SEGUNDO DISOLVENTE VOLATIL. 5 ) SECAR EL GEL OBTENIDO. 6 ) ESTIRAR POR LO MENOS UNO DE: A) EL GEL QUE CONTIENE EL PRIMER DISOLVENTE, B) EL GEL QUE CONTIENE EL SEGUNDO DISOLVENTE, C) EL XEROGEL. SE OBTIENE UNA FIBRA DE POLIETILENO CON UN PESO MOLECULAR MEDIO DE AL MENOS UN MILLON Y CON UN MODULO DE TRACCION DE AL MENOS 1.600 G/DENIER, UNA TEMPERATURA DE FUSION DE AL MENOS 147 C Y UNA ELONGACION NO SUPERIOR DE 5%.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25926681A | 1981-04-30 | 1981-04-30 | |
| US35902082A | 1982-03-19 | 1982-03-19 | |
| US06/359,019 US4413110A (en) | 1981-04-30 | 1982-03-19 | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8306775A1 true ES8306775A1 (es) | 1983-06-16 |
| ES513190A0 ES513190A0 (es) | 1983-06-16 |
Family
ID=27401217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES513190A Granted ES513190A0 (es) | 1981-04-30 | 1982-05-22 | "procedimiento de producir articulos termoplasticos conformados". |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0064167B1 (es) |
| JP (2) | JPS585228A (es) |
| KR (1) | KR860000202B1 (es) |
| AU (2) | AU549453B2 (es) |
| CA (1) | CA1174818A (es) |
| DE (1) | DE3267521D1 (es) |
| ES (1) | ES513190A0 (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862791A (zh) * | 2015-05-19 | 2015-08-26 | 上海化工研究院 | 一种用于超高分子量聚乙烯干法纺丝生产均质加料装置 |
Families Citing this family (82)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU549453B2 (en) * | 1981-04-30 | 1986-01-30 | Allied Corporation | High tenacity, high modulus, cyrstalline thermoplastic fibres |
| US4501856A (en) † | 1982-03-19 | 1985-02-26 | Allied Corporation | Composite containing polyolefin fiber and polyolefin polymer matrix |
| US4543286A (en) * | 1982-03-19 | 1985-09-24 | Allied Corporation | Composite containing coated extended chain polyolefin fibers |
| US4584347A (en) * | 1982-09-30 | 1986-04-22 | Allied Corporation | Modified polyolefin fiber |
| US4599267A (en) * | 1982-09-30 | 1986-07-08 | Allied Corporation | High strength and modulus polyvinyl alcohol fibers and method of their preparation |
| US4455273A (en) * | 1982-09-30 | 1984-06-19 | Allied Corporation | Producing modified high performance polyolefin fiber |
| EP0115192B2 (en) * | 1982-12-28 | 1992-07-22 | Mitsui Petrochemical Industries, Ltd. | Process for producing stretched filaments of ultrahigh-molecular-weight polyethylene |
| JPS59187614A (ja) * | 1983-04-07 | 1984-10-24 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレン延伸物の製造法 |
| US5135804A (en) * | 1983-02-18 | 1992-08-04 | Allied-Signal Inc. | Network of polyethylene fibers |
| DE3480796D1 (de) * | 1983-02-18 | 1990-01-25 | Allied Signal Inc | Verfestigung von polyaethylenfasernetzwerken. |
| JPS59216912A (ja) * | 1983-05-20 | 1984-12-07 | Toyobo Co Ltd | 高強度・高弾性率ポリエチレン繊維の製造方法 |
| JPS59227420A (ja) * | 1983-06-10 | 1984-12-20 | Mitsui Petrochem Ind Ltd | 超高分子量ポリオレフイン二軸延伸フイルム及びその製造方法 |
| EP0139141B1 (en) * | 1983-08-15 | 1991-05-08 | Toyo Boseki Kabushiki Kaisha | Production of stretched polymeric material having high strength and high modulus |
| JPS6045630A (ja) * | 1983-08-23 | 1985-03-12 | 東洋紡績株式会社 | ゲルフアイバ−の延伸方法 |
| JPS6052613A (ja) * | 1983-08-30 | 1985-03-25 | Toyobo Co Ltd | 高強力、高弾性率ポリエチレン繊維 |
| JPS59216913A (ja) * | 1983-10-22 | 1984-12-07 | Toyobo Co Ltd | 高強度・高弾性率ポリエチレン繊維 |
| JPS59216914A (ja) * | 1983-10-22 | 1984-12-07 | Toyobo Co Ltd | 超高強力ポリエチレン繊維の製造方法 |
| NL8304263A (nl) * | 1983-12-10 | 1985-07-01 | Stamicarbon | Werkwijze voor het bereiden van polyacrylonitrilfilamenten met hoge treksterkte en modulus. |
| JPS60138507A (ja) * | 1983-12-27 | 1985-07-23 | Toyobo Co Ltd | ポリエチレン抗張力線 |
| JPS60164421A (ja) * | 1984-02-07 | 1985-08-27 | 東洋紡績株式会社 | 新規な釣糸 |
| JPS60173114A (ja) * | 1984-02-16 | 1985-09-06 | Toyobo Co Ltd | ゲル状成形体の処理方法 |
| JPS60189420A (ja) * | 1984-03-09 | 1985-09-26 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレンの延伸物の製造方法 |
| JPS60190330A (ja) * | 1984-03-12 | 1985-09-27 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレン延伸物の製造法 |
| JPS60210425A (ja) * | 1984-04-04 | 1985-10-22 | Mitsui Petrochem Ind Ltd | ポリエチレン延伸物の製造方法 |
| JPS60242035A (ja) * | 1984-04-27 | 1985-12-02 | Toa Nenryo Kogyo Kk | ポリエチレン微多孔膜の製造方法 |
| JPS60239509A (ja) * | 1984-05-04 | 1985-11-28 | Toray Ind Inc | 高強度高モジユラスポリオレフイン系繊維の製造方法 |
| JPH062841B2 (ja) * | 1984-05-31 | 1994-01-12 | 三菱化成株式会社 | 多孔化透過性ポリエチレンフイルム |
| JPS6147809A (ja) * | 1984-08-06 | 1986-03-08 | Toray Ind Inc | 高強度高モジユラスポリオレフイン系繊維の製造方法 |
| DE3577110D1 (de) * | 1984-09-28 | 1990-05-17 | Stamicarbon | Verfahren zur kontinuierlichen herstellung von homogenen loesungen von hochmolekularen polymeren. |
| NL8402964A (nl) * | 1984-09-28 | 1986-04-16 | Stamicarbon | Werkwijze voor het bereiden van polyalkeenfilms met hoge treksterkte en hoge modulus. |
| NL8402963A (nl) * | 1984-09-28 | 1986-04-16 | Stamicarbon | Werkwijze voor het bereiden van dunne films van hoogmolekulaire polyalkenen. |
| US4663101A (en) * | 1985-01-11 | 1987-05-05 | Allied Corporation | Shaped polyethylene articles of intermediate molecular weight and high modulus |
| US4623574A (en) * | 1985-01-14 | 1986-11-18 | Allied Corporation | Ballistic-resistant composite article |
| JPH06102847B2 (ja) * | 1985-05-31 | 1994-12-14 | 三井石油化学工業株式会社 | プラスチツクワイヤ−及びその製造方法 |
| DE3682241D1 (de) * | 1985-02-15 | 1991-12-05 | Toray Industries | Polyaethylen-multifilament-garn. |
| NL8500477A (nl) * | 1985-02-20 | 1986-09-16 | Stamicarbon | Werkwijze voor het bereiden van polyolefine gelvoorwerpen, alsmede voor het hieruit bereiden van voorwerpen met hoge treksterkte en modulus. |
| EP0193318B1 (en) * | 1985-02-25 | 1990-12-19 | Tonen Corporation | Microporous membrane of ultra-high molecular weight alpha-olefin polymer |
| JPS61215708A (ja) * | 1985-03-19 | 1986-09-25 | Toray Ind Inc | マルチフイラメントヤ−ンの製造方法 |
| JPH06102846B2 (ja) * | 1985-05-01 | 1994-12-14 | 三井石油化学工業株式会社 | 超高分子量ポリエチレン延伸物の製造方法 |
| EP0205960B1 (en) * | 1985-06-17 | 1990-10-24 | AlliedSignal Inc. | Very low creep, ultra high moduls, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber |
| JPS623728A (ja) * | 1985-07-01 | 1987-01-09 | 旭化成株式会社 | 釣糸 |
| EP0212133B2 (en) * | 1985-08-19 | 1999-09-22 | AlliedSignal Inc. | Method to prepare high strength ultrahigh molecular weight polyolefin articles by dissolving particles and shaping the solution |
| US5032338A (en) * | 1985-08-19 | 1991-07-16 | Allied-Signal Inc. | Method to prepare high strength ultrahigh molecular weight polyolefin articles by dissolving particles and shaping the solution |
| NL8502298A (nl) * | 1985-08-21 | 1987-03-16 | Stamicarbon | Werkwijze voor het vervaardigen van polyethyleenvoorwerpen met hoge treksterkte en modulus. |
| ATE65818T1 (de) * | 1985-11-07 | 1991-08-15 | Akzo Nv | Bewehrungselement aus kunststoff, verwendbar in armiertem beton, insbesondere in vorgespanntem beton, armierter beton versehen mit solchen bewehrungselementen und verfahren zur herstellung von bewehrungselementen und armiertem und vorgespanntem beton. |
| US4870136A (en) * | 1985-11-30 | 1989-09-26 | Mitsui Pertrochemical Industries, Ltd. | Molecular oriented, silane-crosslinked ultra-high-molecular-weight polyethylene molded article and process for preparation thereof |
| JPS62141110A (ja) * | 1985-12-11 | 1987-06-24 | Canon Inc | ゲル繊維の製造方法 |
| JPS62184110A (ja) * | 1986-02-06 | 1987-08-12 | Toray Ind Inc | 新規なポリエチレンフイラメント |
| JPS63175111A (ja) * | 1987-01-09 | 1988-07-19 | Toyobo Co Ltd | 架橋された高強力,高弾性率ポリエチレン繊維 |
| JPS63273651A (ja) * | 1987-04-30 | 1988-11-10 | Toa Nenryo Kogyo Kk | 超高分子量ポリエチレン微多孔膜の製造方法 |
| JPS63288264A (ja) * | 1987-05-18 | 1988-11-25 | 三井化学株式会社 | フイラメント等の処理槽 |
| JPH02251545A (ja) * | 1988-12-23 | 1990-10-09 | Nitto Denko Corp | 超高分子量ポリエチレン多孔質フィルムおよびその製造法 |
| DE3923139A1 (de) * | 1989-07-13 | 1991-01-17 | Akzo Gmbh | Verfahren zur herstellung von polyaethylenfaeden durch schnellspinnen von ultra-hochmolekularem polyaethylen |
| JPH06104736B2 (ja) * | 1989-08-03 | 1994-12-21 | 東燃株式会社 | ポリオレフィン微多孔膜 |
| GB9027601D0 (en) * | 1990-12-20 | 1991-02-13 | Thermalite Limited | Fibre-reinforced materials |
| JP3070694B2 (ja) * | 1991-06-11 | 2000-07-31 | 三井化学株式会社 | 超高分子量ポリプロピレン延伸成形体およびその製造方法 |
| US5230854A (en) * | 1991-12-09 | 1993-07-27 | Allied-Signal Inc. | Method for removal of spinning solvent from spun fiber |
| US5213745A (en) * | 1991-12-09 | 1993-05-25 | Allied-Signal Inc. | Method for removal of spinning solvent from spun fiber |
| JP3166858B2 (ja) * | 1991-12-09 | 2001-05-14 | アライド−シグナル・インコーポレーテッド | 紡出繊維から紡糸溶媒を除去する方法 |
| NL1010413C1 (nl) * | 1998-10-28 | 2000-05-01 | Dsm Nv | Hooggeoriënteerde polyolefinevezel. |
| US6723267B2 (en) | 1998-10-28 | 2004-04-20 | Dsm N.V. | Process of making highly oriented polyolefin fiber |
| US6448359B1 (en) * | 2000-03-27 | 2002-09-10 | Honeywell International Inc. | High tenacity, high modulus filament |
| NL1016356C2 (nl) * | 2000-10-09 | 2002-04-10 | Dsm Nv | Oven voor het op verhoogde temperatuur verstrekken van vezels. |
| WO2005066401A1 (en) * | 2004-01-01 | 2005-07-21 | Dsm Ip Assets B.V. | Process for making high-performance polyethylene multifilament yarn |
| EP1699953B1 (en) * | 2004-01-01 | 2012-06-20 | DSM IP Assets B.V. | Process for making high-performance polyethylene multifilament yarn |
| RU2334028C2 (ru) * | 2004-01-01 | 2008-09-20 | ДСМ Ай Пи ЭССЕТС Б.В. | Способ изготовления высококачественной полиэтиленовой многоволоконной пряжи |
| WO2008131925A1 (en) * | 2007-05-01 | 2008-11-06 | Dsm Ip Assets B.V. | Uhmwpe fiber and process for producing thereof |
| BRPI0702310A2 (pt) * | 2007-05-24 | 2009-01-13 | Braskem Sa | processo para a preparaÇço de fios polimÉricos a partir de homopolÍmeros ou copolÍmeros de ultra alto peso molecular, fios polimÉricos, artigos polimÉricos moldados, e, uso de fios polimÉricos |
| CN101122051B (zh) | 2007-09-24 | 2010-04-14 | 湖南中泰特种装备有限责任公司 | 低纤度、高强高模聚乙烯纤维的制备方法 |
| KR101522051B1 (ko) * | 2007-10-05 | 2015-05-20 | 디에스엠 아이피 어셋츠 비.브이. | Uhmwpe 섬유 및 이의 제조 방법 |
| EP2195477A2 (en) * | 2007-10-05 | 2010-06-16 | DSM IP Assets B.V. | Low creep, high strength uhmwpe fibres and process for producing thereof |
| CN101230501B (zh) | 2008-02-26 | 2010-06-02 | 山东爱地高分子材料有限公司 | 一种采用超高分子量聚乙烯与低密度聚乙烯共混熔融制备高强聚乙烯纤维的方法 |
| KR100959867B1 (ko) * | 2008-03-24 | 2010-05-27 | 김용건 | 초고강도 폴리에틸렌 섬유의 제조방법 및 이로부터 제조된초고강도 폴리에틸렌 섬유 |
| US20110238092A1 (en) * | 2008-06-20 | 2011-09-29 | Dsm Ip Assets B.V. | Ultrahigh molecular weight polyethylene yarn |
| MX366212B (es) | 2009-04-20 | 2019-07-02 | Barrday Inc | Materiales compuestos balisticos mejorados que tienen valor grande de denier por hilos de filamentos de alto rendimiento. |
| US8895138B2 (en) | 2009-11-17 | 2014-11-25 | E I Du Pont De Nemours And Company | Impact resistant composite article |
| US20110113534A1 (en) | 2009-11-17 | 2011-05-19 | E.I.Du Pont De Nemours And Company | Impact Resistant Composite Article |
| CN101775666B (zh) * | 2010-01-22 | 2011-07-27 | 东华大学 | 一种高强高模聚乙烯纤维的制备方法 |
| CN102002769B (zh) | 2010-11-08 | 2012-12-12 | 宁波大成新材料股份有限公司 | 超高分子量聚乙烯纤维制备方法 |
| AU2013366684A1 (en) * | 2012-12-20 | 2015-07-02 | Dsm Ip Assets B.V. | Polyolefin yarns and method for manufacturing |
| EP3957780B1 (en) * | 2013-10-29 | 2025-10-29 | Braskem, S.A. | Continuous system and method for producing at least one polymeric yarn |
| WO2025135019A1 (ja) * | 2023-12-20 | 2025-06-26 | 東洋紡エムシー株式会社 | ポリプロピレン繊維及びポリプロピレン繊維の製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE562603A (es) * | 1956-12-08 | |||
| NL177759B (nl) * | 1979-06-27 | 1985-06-17 | Stamicarbon | Werkwijze ter vervaardiging van een polyetheendraad, en de aldus verkregen polyetheendraad. |
| NL177840C (nl) * | 1979-02-08 | 1989-10-16 | Stamicarbon | Werkwijze voor het vervaardigen van een polyetheendraad. |
| AU549453B2 (en) * | 1981-04-30 | 1986-01-30 | Allied Corporation | High tenacity, high modulus, cyrstalline thermoplastic fibres |
-
1982
- 1982-04-01 AU AU82254/82A patent/AU549453B2/en not_active Ceased
- 1982-04-07 EP EP82102964A patent/EP0064167B1/en not_active Expired
- 1982-04-07 DE DE8282102964T patent/DE3267521D1/de not_active Expired
- 1982-04-22 CA CA000401450A patent/CA1174818A/en not_active Expired
- 1982-04-29 KR KR8201890A patent/KR860000202B1/ko not_active Expired
- 1982-04-30 JP JP57073297A patent/JPS585228A/ja active Pending
- 1982-05-22 ES ES513190A patent/ES513190A0/es active Granted
-
1985
- 1985-11-21 AU AU50242/85A patent/AU581702B2/en not_active Ceased
-
1992
- 1992-04-15 JP JP4095529A patent/JP2582985B2/ja not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862791A (zh) * | 2015-05-19 | 2015-08-26 | 上海化工研究院 | 一种用于超高分子量聚乙烯干法纺丝生产均质加料装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU8225482A (en) | 1982-11-04 |
| JP2582985B2 (ja) | 1997-02-19 |
| JPH05106107A (ja) | 1993-04-27 |
| CA1174818A (en) | 1984-09-25 |
| ES513190A0 (es) | 1983-06-16 |
| EP0064167A1 (en) | 1982-11-10 |
| EP0064167B1 (en) | 1985-11-21 |
| AU549453B2 (en) | 1986-01-30 |
| AU581702B2 (en) | 1989-03-02 |
| DE3267521D1 (en) | 1986-01-02 |
| KR860000202B1 (ko) | 1986-03-03 |
| KR830010224A (ko) | 1983-12-26 |
| AU5024285A (en) | 1986-06-12 |
| JPS585228A (ja) | 1983-01-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970505 |