FI74028C - Process foer tillverkning av aromatiska polyestrar. - Google Patents

Process foer tillverkning av aromatiska polyestrar. Download PDF

Info

Publication number: FI74028C
Authority: FI; Finland
Prior art keywords: phosphite; polyester; prepolymer; acid; process according
Prior art date: 1982-06-08

Application number

FI831883A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI831883L (fi

FI74028B (fi

FI831883A0 (fi

Inventor

Steve Gust Cottis

Original Assignee

Dart Ind Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-06-08

Filing date

1983-05-26

Publication date

1987-12-10

1983-05-26 Application filed by Dart Ind Inc filed Critical Dart Ind Inc

1983-05-26 Publication of FI831883A0 publication Critical patent/FI831883A0/fi

1983-12-09 Publication of FI831883L publication Critical patent/FI831883L/fi

1987-08-31 Publication of FI74028B publication Critical patent/FI74028B/fi

1987-12-10 Application granted granted Critical

1987-12-10 Publication of FI74028C publication Critical patent/FI74028C/fi

Links

238000000034 method Methods 0.000 title claims description 31
229920000728 polyester Polymers 0.000 title claims description 28
125000003118 aryl group Chemical group 0.000 title claims description 9
238000004519 manufacturing process Methods 0.000 title description 2
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 21
-1 phosphite compound Chemical class 0.000 claims description 14
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 10
PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 claims description 6
238000006116 polymerization reaction Methods 0.000 claims description 6
FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 4
238000006243 chemical reaction Methods 0.000 claims description 3
238000009833 condensation Methods 0.000 claims description 3
230000005494 condensation Effects 0.000 claims description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
239000002253 acid Substances 0.000 claims description 2
150000008065 acid anhydrides Chemical class 0.000 claims description 2
230000010933 acylation Effects 0.000 claims description 2
238000005917 acylation reaction Methods 0.000 claims description 2
239000011541 reaction mixture Substances 0.000 claims description 2
239000002243 precursor Substances 0.000 claims 3
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims 2
229920002396 Polyurea Polymers 0.000 claims 1
230000002378 acidificating effect Effects 0.000 claims 1
VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims 1
IMHDGJOMLMDPJN-UHFFFAOYSA-N dihydroxybiphenyl Natural products OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 claims 1
238000005530 etching Methods 0.000 claims 1
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 21
229920000642 polymer Polymers 0.000 description 16
230000004580 weight loss Effects 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
229920005989 resin Polymers 0.000 description 10
239000011347 resin Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 9
239000000178 monomer Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000000654 additive Substances 0.000 description 5
238000002411 thermogravimetry Methods 0.000 description 5
238000000113 differential scanning calorimetry Methods 0.000 description 4
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
229920001634 Copolyester Polymers 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
238000012662 bulk polymerization Methods 0.000 description 3
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
230000000694 effects Effects 0.000 description 3
125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
229920001225 polyester resin Polymers 0.000 description 3
239000004645 polyester resin Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
229940090248 4-hydroxybenzoic acid Drugs 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
125000006267 biphenyl group Chemical group 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
238000000227 grinding Methods 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
239000000155 melt Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
239000000047 product Substances 0.000 description 2
238000010926 purge Methods 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
238000012216 screening Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
JTUIDPCUTRXCPW-UHFFFAOYSA-N (6-acetyloxynaphthalen-2-yl) acetate Chemical compound C1=C(OC(C)=O)C=CC2=CC(OC(=O)C)=CC=C21 JTUIDPCUTRXCPW-UHFFFAOYSA-N 0.000 description 1
HQTRGFZLVRBFPT-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-3-octadecylhenicosane-1,3-diol Chemical compound CCCCCCCCCCCCCCCCCCC(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC HQTRGFZLVRBFPT-UHFFFAOYSA-N 0.000 description 1
GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 1
DNUYOWCKBJFOGS-UHFFFAOYSA-N 2-[[10-(2,2-dicarboxyethyl)anthracen-9-yl]methyl]propanedioic acid Chemical compound C1=CC=C2C(CC(C(=O)O)C(O)=O)=C(C=CC=C3)C3=C(CC(C(O)=O)C(O)=O)C2=C1 DNUYOWCKBJFOGS-UHFFFAOYSA-N 0.000 description 1
NALNZSALNRPKIG-UHFFFAOYSA-N 2-methylpropyl 4-acetyloxybenzoate Chemical compound CC(C)COC(=O)C1=CC=C(OC(C)=O)C=C1 NALNZSALNRPKIG-UHFFFAOYSA-N 0.000 description 1
SDCYWERHEYVPHL-UHFFFAOYSA-N 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound O1CC2(COP(OC=3C=CC=CC=3)OC2)COP1OC1=CC=CC=C1 SDCYWERHEYVPHL-UHFFFAOYSA-N 0.000 description 1
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 description 1
150000005168 4-hydroxybenzoic acids Chemical class 0.000 description 1
SGPZSOQUJLFTMQ-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl benzene-1,4-dicarboxylate Chemical compound CCOC(=O)C1=CC=C(C(=O)OC)C=C1 SGPZSOQUJLFTMQ-UHFFFAOYSA-N 0.000 description 1
WDCVVRPXMOAZLY-UHFFFAOYSA-N 5-acetyloxynaphthalene-1-carboxylic acid Chemical compound C1=CC=C2C(OC(=O)C)=CC=CC2=C1C(O)=O WDCVVRPXMOAZLY-UHFFFAOYSA-N 0.000 description 1
JCJUKCIXTRWAQY-UHFFFAOYSA-N 6-hydroxynaphthalene-1-carboxylic acid Chemical compound OC1=CC=C2C(C(=O)O)=CC=CC2=C1 JCJUKCIXTRWAQY-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
AUPUWLXSWWBAAC-UHFFFAOYSA-N C(CCCCCCC(C)C)C(O)C(CO)(CO)CO Chemical compound C(CCCCCCC(C)C)C(O)C(CO)(CO)CO AUPUWLXSWWBAAC-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
RZUHBLGLDSYPOM-UHFFFAOYSA-N OP(O)(=O)OP(=O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC Chemical compound OP(O)(=O)OP(=O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC RZUHBLGLDSYPOM-UHFFFAOYSA-N 0.000 description 1
RLIPARRCKPWOIA-UHFFFAOYSA-N P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC Chemical compound P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC RLIPARRCKPWOIA-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
OHRVBDRGLIWLPA-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dihydrogen phosphate Chemical compound OCC(CO)(CO)COP(O)(O)=O OHRVBDRGLIWLPA-UHFFFAOYSA-N 0.000 description 1
VMNKHSPZIGIPLL-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dihydrogen phosphite Chemical compound OCC(CO)(CO)COP(O)O VMNKHSPZIGIPLL-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000002252 acyl group Chemical group 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229920003232 aliphatic polyester Polymers 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
238000007664 blowing Methods 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
239000013068 control sample Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
QBCOASQOMILNBN-UHFFFAOYSA-N didodecoxy(oxo)phosphanium Chemical compound CCCCCCCCCCCCO[P+](=O)OCCCCCCCCCCCC QBCOASQOMILNBN-UHFFFAOYSA-N 0.000 description 1
JLVWYWVLMFVCDI-UHFFFAOYSA-N diethyl benzene-1,3-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC(C(=O)OCC)=C1 JLVWYWVLMFVCDI-UHFFFAOYSA-N 0.000 description 1
HPGJOUYGWKFYQW-UHFFFAOYSA-N diphenyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 HPGJOUYGWKFYQW-UHFFFAOYSA-N 0.000 description 1
SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000011888 foil Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000005165 hydroxybenzoic acids Chemical class 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
IJFXRHURBJZNAO-UHFFFAOYSA-N meta--hydroxybenzoic acid Natural products OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
210000003097 mucus Anatomy 0.000 description 1
ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
PCILLCXFKWDRMK-UHFFFAOYSA-N naphthalene-1,4-diol Chemical compound C1=CC=C2C(O)=CC=C(O)C2=C1 PCILLCXFKWDRMK-UHFFFAOYSA-N 0.000 description 1
DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
GJLNWLVPAHNBQN-UHFFFAOYSA-N phenyl 4-hydroxybenzoate Chemical compound C1=CC(O)=CC=C1C(=O)OC1=CC=CC=C1 GJLNWLVPAHNBQN-UHFFFAOYSA-N 0.000 description 1
GUWYYXPNUUACGW-UHFFFAOYSA-N phenyl 5-hydroxynaphthalene-1-carboxylate Chemical compound C1=CC=C2C(O)=CC=CC2=C1C(=O)OC1=CC=CC=C1 GUWYYXPNUUACGW-UHFFFAOYSA-N 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
- C08G63/605—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds the hydroxy and carboxylic groups being bound to aromatic rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/87—Non-metals or inter-compounds thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyesters Or Polycarbonates (AREA)

FI831883A 1982-06-08 1983-05-26 Process foer tillverkning av aromatiska polyestrar. FI74028C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US38645282A	1982-06-08	1982-06-08
US38645282		1982-06-08

Publications (4)

Publication Number	Publication Date
FI831883A0 FI831883A0 (fi)	1983-05-26
FI831883L FI831883L (fi)	1983-12-09
FI74028B FI74028B (fi)	1987-08-31
FI74028C true FI74028C (fi)	1987-12-10

Family

ID=23525637

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI831883A FI74028C (fi)	1982-06-08	1983-05-26	Process foer tillverkning av aromatiska polyestrar.

Country Status (27)

Country	Link
JP (1)	JPH0721049B2 (de)
KR (1)	KR910007550B1 (de)
AU (1)	AU548153B2 (de)
BE (1)	BE896826A (de)
BR (1)	BR8303040A (de)
CA (1)	CA1220889A (de)
CH (1)	CH656885A5 (de)
DE (1)	DE3320188C2 (de)
DK (1)	DK258783A (de)
ES (1)	ES8500297A1 (de)
FI (1)	FI74028C (de)
FR (1)	FR2528053B1 (de)
GB (1)	GB2121422B (de)
GR (1)	GR78268B (de)
IE (1)	IE54907B1 (de)
IT (1)	IT1170147B (de)
LU (1)	LU84818A1 (de)
MA (1)	MA19806A1 (de)
MX (1)	MX162012A (de)
NL (1)	NL8302041A (de)
NO (1)	NO832044L (de)
NZ (1)	NZ204378A (de)
PH (1)	PH20492A (de)
PL (1)	PL242416A1 (de)
PT (1)	PT76833B (de)
SE (1)	SE8303210L (de)
ZA (1)	ZA833836B (de)

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FI842150L (fi) *	1983-11-30	1985-05-31	Dart Ind Inc	Foerfarande foer framstaellning av aromatiska polyestrar.
JPS60208325A (ja) *	1984-04-02	1985-10-19	Polyplastics Co	ポリエステルの製造方法
DE3542815A1 (de) *	1985-12-04	1987-06-11	Basf Ag	Vollaromatische polyester, deren herstellung und verwendung
DE3542832A1 (de) *	1985-12-04	1987-06-11	Basf Ag	Vollaromatische fluessigkristalline polykondensate, deren herstellung und verwendung
US4680371A (en) *	1986-02-25	1987-07-14	Celanese Corporation	Preparation of aromatic polyester with improved stability by addition of phosphite during preparation
JPS62241917A (ja) *	1986-04-01	1987-10-22	ヘキスト・セラニーズ・コーポレーション	芳香族ポリエステルへのホスフアイト系安定剤の配合方法
US4952663A (en) *	1988-06-17	1990-08-28	Amoco Corporation	Wholly aromatic polyesters with reduced char content
JPH02276819A (ja) *	1988-12-29	1990-11-13	Kawasaki Steel Corp	芳香族ポリエステルおよび芳香族ポリエステルアミドならびにそれらを用いた繊維、樹脂組成物
US5221705A (en) *	1990-06-21	1993-06-22	Toray Industries, Inc.	Flame-retardant thermotropic polyester composition and its shaped article
US20050215426A1 (en) *	2004-03-26	2005-09-29	Putzig Donald E	Esterification catalyst and process therewith

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US2437046A (en) *	1943-10-15	1948-03-02	Resinous Prod & Chemical Co	Stabilization of polyesters
US2728747A (en) *	1952-10-22	1955-12-27	Gen Mills Inc	Polyester resins
GB791283A (en) *	1955-01-21	1958-02-26	Ici Ltd	Process for the manufacture of highly polymeric polymethylene terephthalates
BE629270A (de) *	1962-03-07
FR1541000A (fr) *	1966-07-27	1968-10-04	Eastman Kodak Co	Nouveau procédé de préparation des polyesters
DE1953706C3 (de) *	1968-10-25	1978-10-26	Kanebo, Ltd., Tokio	Verfahren zur Herstellung von Polyestern
BE774721A (fr) *	1970-11-02	1972-02-14	Fiber Industries Inc	Polyesters thermo-stabilises et leur procede de fabrication
DE2259043C3 (de) *	1971-12-04	1980-04-24	Toray Industries, Inc., Tokio	Verwendung Lithium und Phosphor enthaltender Polyesterteilchen in faseru.iii- filmbildenden Polyestermassen
JPS5517786B2 (de) *	1972-06-23	1980-05-14
JPS4961244A (de) *	1972-10-18	1974-06-13
JPS5232914B2 (de) *	1974-05-11	1977-08-24
JPS602334B2 (ja) *	1976-01-26	1985-01-21	ユニチカ株式会社	芳香族ポリエステル共重合体の安定化方法
CH594006A5 (de) *	1976-02-02	1977-12-30	Ciba Geigy Ag
DE2965353D1 (en) *	1978-06-01	1983-06-16	Union Carbide Corp	Preparation of polyarylates
IE50008B1 (en) *	1979-09-10	1986-01-22	Dart Ind Inc	Improvements in or relating to plastics ovenware
DE2945729C2 (de) *	1979-11-13	1982-06-09	Chemische Werke Hüls AG, 4370 Marl	Verfahren zur Herstellung von hochmolekularen, linearen Polyestern

1983
- 1983-05-19 CA CA000428508A patent/CA1220889A/en not_active Expired
- 1983-05-24 IE IE1227/83A patent/IE54907B1/en unknown
- 1983-05-24 AU AU14925/83A patent/AU548153B2/en not_active Ceased
- 1983-05-25 LU LU84818A patent/LU84818A1/fr unknown
- 1983-05-25 BE BE0/210835A patent/BE896826A/fr not_active IP Right Cessation
- 1983-05-26 FI FI831883A patent/FI74028C/fi not_active IP Right Cessation
- 1983-05-26 ZA ZA833836A patent/ZA833836B/xx unknown
- 1983-05-27 NZ NZ204378A patent/NZ204378A/en unknown
- 1983-05-27 GR GR71485A patent/GR78268B/el unknown
- 1983-05-30 MA MA20028A patent/MA19806A1/fr unknown
- 1983-06-03 DE DE3320188A patent/DE3320188C2/de not_active Expired - Lifetime
- 1983-06-03 FR FR8309280A patent/FR2528053B1/fr not_active Expired
- 1983-06-04 KR KR1019830002503A patent/KR910007550B1/ko not_active Expired
- 1983-06-06 CH CH3105/83A patent/CH656885A5/de not_active IP Right Cessation
- 1983-06-06 NO NO832044A patent/NO832044L/no unknown
- 1983-06-07 ES ES523061A patent/ES8500297A1/es not_active Expired
- 1983-06-07 JP JP58100369A patent/JPH0721049B2/ja not_active Expired - Lifetime
- 1983-06-07 SE SE8303210A patent/SE8303210L/ not_active Application Discontinuation
- 1983-06-07 IT IT21506/83A patent/IT1170147B/it active
- 1983-06-07 PT PT76833A patent/PT76833B/pt unknown
- 1983-06-07 DK DK258783A patent/DK258783A/da not_active Application Discontinuation
- 1983-06-08 MX MX197577A patent/MX162012A/es unknown
- 1983-06-08 PH PH29028A patent/PH20492A/en unknown
- 1983-06-08 PL PL24241683A patent/PL242416A1/xx unknown
- 1983-06-08 NL NL8302041A patent/NL8302041A/nl not_active Application Discontinuation
- 1983-06-08 BR BR8303040A patent/BR8303040A/pt unknown
- 1983-06-08 GB GB08315764A patent/GB2121422B/en not_active Expired

Also Published As

Publication number	Publication date
FI831883L (fi)	1983-12-09
IE831227L (en)	1984-01-08
GB2121422B (en)	1986-03-19
PT76833B (pt)	1986-01-15
SE8303210L (sv)	1983-12-09
MX162012A (es)	1991-03-20
CA1220889A (en)	1987-04-21
KR910007550B1 (ko)	1991-09-27
SE8303210D0 (sv)	1983-06-07
DK258783A (da)	1983-12-09
CH656885A5 (de)	1986-07-31
FI74028B (fi)	1987-08-31
NZ204378A (en)	1986-06-11
GB8315764D0 (en)	1983-07-13
KR840005166A (ko)	1984-11-05
DE3320188A1 (de)	1983-12-08
PT76833A (en)	1983-07-01
FR2528053A1 (fr)	1983-12-09
AU1492583A (en)	1983-12-15
PL242416A1 (en)	1984-07-02
ES523061A0 (es)	1984-10-01
FI831883A0 (fi)	1983-05-26
GB2121422A (en)	1983-12-21
DK258783D0 (da)	1983-06-07
LU84818A1 (fr)	1983-11-17
IT8321506A0 (it)	1983-06-07
IT1170147B (it)	1987-06-03
DE3320188C2 (de)	1999-07-01
JPS594622A (ja)	1984-01-11
BE896826A (fr)	1983-09-16
GR78268B (de)	1984-09-26
MA19806A1 (fr)	1983-12-31
ZA833836B (en)	1984-02-29
NO832044L (no)	1983-12-09
BR8303040A (pt)	1984-01-31
NL8302041A (nl)	1984-01-02
PH20492A (en)	1987-01-21
AU548153B2 (en)	1985-11-28
IE54907B1 (en)	1990-03-14
JPH0721049B2 (ja)	1995-03-08
ES8500297A1 (es)	1984-10-01
FR2528053B1 (fr)	1986-11-28

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: AMOCO CORPORATION

Publication	Publication Date	Title
US5886133A (en)	1999-03-23	Production of particular polyesters using a novel catalyst system
US3778410A (en)	1973-12-11	Process for preparing a final copolyester by reacting a starting polyester with an acyloxy aromatic carboxylic acid
US4639504A (en)	1987-01-27	Production of thermally stabilized aromatic polyesters
EP0314212B1 (de)	1993-06-30	Aus der Schmelze verarbeitbare, optisch anisotrope Polymere
EP0286444A2 (de)	1988-10-12	Verfahren zur Herstellung vom flussige Kristalle bildenden Polyester, aus einer Cyclohexandicarbonsäure und einem aromatischen Diol
JPS6096619A (ja)	1985-05-30	リン‐改質ポリエステルカーボネート樹脂
CA1220889A (en)	1987-04-21	Process for the production of aromatic polyesters
EP0252415B1 (de)	1994-06-08	Polyester-Polymere
EP0376380A1 (de)	1990-07-04	In der Schmelze verarbeitbares Polymer
NL8403066A (nl)	1985-06-17	Werkwijze voor de bereiding van aromatische polyesters.
JP3720858B2 (ja)	2005-11-30	２，６−ナフタレンジカルボン酸から高分子量ポリエステル樹脂を製造する方法
JPS581134B2 (ja)	1983-01-10	センジヨウネツソセイポリエステルノセイゾウホウホウ
US11708453B2 (en)	2023-07-25	Copolyester from terephthalic acid containing low diethylene glycol
JPS61143425A (ja)	1986-07-01	芳香族ポリエステル及びその製造法
JP2702323B2 (ja)	1998-01-21	結晶性全芳香族ポリエステル重合体の製造法
KR900007270B1 (ko)	1990-10-06	방향족 폴리에스테르 단량체의 제조방법
KR900007269B1 (ko)	1990-10-06	방향족 폴리에스테르 단량체의 제조방법.
JP2008500428A (ja)	2008-01-10	直接エステル化によって製造されたｐｅｔへのメチン紫外線吸収剤の添加方法
JPH01185324A (ja)	1989-07-24	新規共重合体とその製造方法
JPH01304123A (ja)	1989-12-07	ジ―ｓ―トリアジンのサーモトロピック液晶ポリマー類
JPH1129626A (ja)	1999-02-02	サーモトロピック液晶性ポリエステルの製造方法
JPH03255127A (ja)	1991-11-14	ポリエステルグラフト化ポリアミドおよびその製造法
JPH03121124A (ja)	1991-05-23	芳香族ポリエステルカーボネートの製造方法
Korshar et al.	1972	Some correlations in the formation of poly (amidearylates) from polycyclic bisphenols by low-temperature polycondensation
JPH03221521A (ja)	1991-09-30	全芳香族ポリエステル、そのフィルムおよび成形品