HRP990392A2 - Catalytic composition for the upgrading of hydrocarbons having boiling temperatures wizhin the naphta range - Google Patents

Catalytic composition for the upgrading of hydrocarbons having boiling temperatures wizhin the naphta range Download PDF

Info

Publication number: HRP990392A2
Authority: HR; Croatia
Prior art keywords: metal; group; zeolite; ers; catalytic preparation
Prior art date: 1998-12-22

Application number

HR990392A

Other languages

English (en)

Croatian (hr)

Inventor

Laura Zanibelli

Marco Ferrari

Luciano Cosimo Carluccio

Original Assignee

Agip Petroli

Enitecnologie Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-12-22

Filing date

1999-12-17

Publication date

2000-08-31

1999-12-17 Application filed by Agip Petroli, Enitecnologie Spa filed Critical Agip Petroli

2000-08-31 Publication of HRP990392A2 publication Critical patent/HRP990392A2/hr

Links

230000003197 catalytic effect Effects 0.000 title claims description 96
239000000203 mixture Substances 0.000 title claims description 47
229930195733 hydrocarbon Natural products 0.000 title claims description 24
150000002430 hydrocarbons Chemical class 0.000 title claims description 24
238000009835 boiling Methods 0.000 title claims description 18
229910052751 metal Inorganic materials 0.000 claims description 140
239000002184 metal Substances 0.000 claims description 140
239000010457 zeolite Substances 0.000 claims description 81
229910021536 Zeolite Inorganic materials 0.000 claims description 80
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 80
239000003054 catalyst Substances 0.000 claims description 73
238000000034 method Methods 0.000 claims description 66
238000002360 preparation method Methods 0.000 claims description 66
239000000243 solution Substances 0.000 claims description 49
150000003839 salts Chemical class 0.000 claims description 38
238000001035 drying Methods 0.000 claims description 27
238000001354 calcination Methods 0.000 claims description 25
239000006185 dispersion Substances 0.000 claims description 25
230000001476 alcoholic effect Effects 0.000 claims description 20
239000000463 material Substances 0.000 claims description 19
238000005470 impregnation Methods 0.000 claims description 18
150000002739 metals Chemical class 0.000 claims description 18
150000001336 alkenes Chemical class 0.000 claims description 16
238000006317 isomerization reaction Methods 0.000 claims description 16
239000004215 Carbon black (E152) Substances 0.000 claims description 15
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
229910052717 sulfur Inorganic materials 0.000 claims description 14
239000011593 sulfur Substances 0.000 claims description 14
239000007864 aqueous solution Substances 0.000 claims description 12
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 12
239000001257 hydrogen Substances 0.000 claims description 11
229910052739 hydrogen Inorganic materials 0.000 claims description 11
150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
230000032683 aging Effects 0.000 claims description 9
238000002156 mixing Methods 0.000 claims description 9
-1 hydrogen ions Chemical class 0.000 claims description 8
150000004703 alkoxides Chemical class 0.000 claims description 7
229910052782 aluminium Inorganic materials 0.000 claims description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
238000006477 desulfuration reaction Methods 0.000 claims description 7
230000023556 desulfurization Effects 0.000 claims description 7
150000002894 organic compounds Chemical class 0.000 claims description 7
229910052710 silicon Inorganic materials 0.000 claims description 7
239000010703 silicon Substances 0.000 claims description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
229910052719 titanium Inorganic materials 0.000 claims description 5
239000010936 titanium Substances 0.000 claims description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
150000001768 cations Chemical class 0.000 claims description 4
239000012266 salt solution Substances 0.000 claims description 4
229910052726 zirconium Inorganic materials 0.000 claims description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
229910002651 NO3 Inorganic materials 0.000 claims description 3
150000003863 ammonium salts Chemical class 0.000 claims description 3
229910052750 molybdenum Inorganic materials 0.000 claims description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
238000003825 pressing Methods 0.000 claims description 3
229910052814 silicon oxide Inorganic materials 0.000 claims description 3
239000011734 sodium Substances 0.000 claims description 3
229910052708 sodium Inorganic materials 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
229910017052 cobalt Inorganic materials 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
229910044991 metal oxide Inorganic materials 0.000 claims description 2
150000004706 metal oxides Chemical class 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
239000000969 carrier Substances 0.000 claims 1
150000002431 hydrogen Chemical class 0.000 claims 1
239000000725 suspension Substances 0.000 description 28
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 18
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 11
238000010438 heat treatment Methods 0.000 description 10
WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical compound [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 description 9
LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 8
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
238000003756 stirring Methods 0.000 description 7
MYWQGROTKMBNKN-UHFFFAOYSA-N tributoxyalumane Chemical compound [Al+3].CCCC[O-].CCCC[O-].CCCC[O-] MYWQGROTKMBNKN-UHFFFAOYSA-N 0.000 description 7
239000003153 chemical reaction reagent Substances 0.000 description 6
229910052593 corundum Inorganic materials 0.000 description 6
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 5
238000005984 hydrogenation reaction Methods 0.000 description 5
239000003921 oil Substances 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
239000010431 corundum Substances 0.000 description 4
239000003446 ligand Substances 0.000 description 4
239000002245 particle Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
230000004913 activation Effects 0.000 description 3
235000012239 silicon dioxide Nutrition 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
239000011148 porous material Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
229910001845 yogo sapphire Inorganic materials 0.000 description 2
229910019626 (NH4)6Mo7O24 Inorganic materials 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
229910016523 CuKa Inorganic materials 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
150000001925 cycloalkenes Chemical class 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
230000029087 digestion Effects 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
238000004231 fluid catalytic cracking Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
239000010742 number 1 fuel oil Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
238000005120 petroleum cracking Methods 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 1
ZGSOBQAJAUGRBK-UHFFFAOYSA-N propan-2-olate;zirconium(4+) Chemical compound [Zr+4].CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-] ZGSOBQAJAUGRBK-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000005987 sulfurization reaction Methods 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Inorganic materials [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/033—Using Hydrolysis
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

HR990392A 1998-12-22 1999-12-17 Catalytic composition for the upgrading of hydrocarbons having boiling temperatures wizhin the naphta range HRP990392A2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT1998MI002773A IT1304792B1 (it)	1998-12-22	1998-12-22	Composizione catalitica per l'upgrading di idrocarburi aventi puntidi ebollizione nell'intervallo della nafta.

Publications (1)

Publication Number	Publication Date
HRP990392A2 true HRP990392A2 (en)	2000-08-31

Family

ID=11381304

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HR990392A HRP990392A2 (en)	1998-12-22	1999-12-17	Catalytic composition for the upgrading of hydrocarbons having boiling temperatures wizhin the naphta range

Country Status (16)

Country	Link
US (2)	US6416660B1 (it)
EP (1)	EP1013339A3 (it)
JP (1)	JP2000288398A (it)
CN (1)	CN1260375A (it)
AR (1)	AR022003A1 (it)
AU (1)	AU767598B2 (it)
BR (1)	BR9905940A (it)
CA (1)	CA2292950A1 (it)
HR (1)	HRP990392A2 (it)
HU (1)	HUP9904691A3 (it)
IT (1)	IT1304792B1 (it)
NO (1)	NO996371L (it)
NZ (1)	NZ501970A (it)
PL (1)	PL337358A1 (it)
RU (1)	RU2227066C2 (it)
SK (1)	SK183399A3 (it)

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JP3398273B2 (ja)	1995-11-14	2003-04-21	新日本石油株式会社	接触分解ガソリンの脱硫方法
EP0980908A1 (en) *	1998-08-15	2000-02-23	ENITECNOLOGIE S.p.a.	Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range
IT1304792B1 (it) *	1998-12-22	2001-03-29	Agip Petroli	Composizione catalitica per l'upgrading di idrocarburi aventi puntidi ebollizione nell'intervallo della nafta.
US6790803B2 (en)	2001-08-17	2004-09-14	Intevep, S.A.	Catalytic system for hydroconversion of naphtha
US6867341B1 (en) *	2002-09-17	2005-03-15	Uop Llc	Catalytic naphtha cracking catalyst and process
EP1403358A1 (en) *	2002-09-27	2004-03-31	ENI S.p.A.	Process and catalysts for deep desulphurization of fuels
US7288181B2 (en) *	2003-08-01	2007-10-30	Exxonmobil Research And Engineering Company	Producing low sulfur naphtha products through improved olefin isomerization
IT1392806B1 (it) *	2009-02-02	2012-03-23	Eni Spa	Processo integrato di cracking catalitico a letto fluido per ottenere miscele idrocarburiche con elevate qualita' come carburante
FI128142B (fi) *	2010-02-02	2019-10-31	Upm Kymmene Corp	Menetelmä ja laitteisto hiilivetyjen tuottamiseksi

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JPS5620087A (en) *	1979-07-30	1981-02-25	Mitsubishi Chem Ind Ltd	Conversion of hydrocarbon
JPS614786A (ja) *	1984-06-19	1986-01-10	Fuji Sekiyu Kk	炭化水素留分の改質法
US5013423A (en) *	1987-11-17	1991-05-07	Mobil Oil Corporation	Reforming and dehydrocyclization
DE69104247T2 (de)	1990-03-23	1995-03-09	Cosmo Oil Co Ltd	Verfahren zu deren Herstellung einer Katalysatorzusammensetzung für die hydrierende Entschwefelung von Kohlenwasserstofföl.
RU2026111C1 (ru) *	1991-06-27	1995-01-09	Всероссийский научно-исследовательский институт по переработке нефти	Способ приготовления катализатора для гидроочистки нефтяных фракций
US5326463A (en)	1991-08-15	1994-07-05	Mobil Oil Corporation	Gasoline upgrading process
AU658937B2 (en) *	1991-11-19	1995-05-04	Mobil Oil Corporation	Hydrocarbon upgrading process
US5397455A (en)	1993-08-11	1995-03-14	Mobil Oil Corporation	Gasoline upgrading process
US5770047A (en) *	1994-05-23	1998-06-23	Intevep, S.A.	Process for producing reformulated gasoline by reducing sulfur, nitrogen and olefin
US5576256A (en) *	1994-05-23	1996-11-19	Intevep, S.A.	Hydroprocessing scheme for production of premium isomerized light gasoline
TW470915B (en) *	1996-03-12	2002-01-01	Matsushita Electric Industrial Co Ltd	Optimization apparatus which removes transfer instructions by a global analysis of equivalence relations
IT1283284B1 (it) *	1996-03-21	1998-04-16	Eniricerche Spa	Zeolite ers-10 e procedimento per la sua preparazione
IT1299035B1 (it) *	1998-04-07	2000-02-07	Enichem Spa	Processo per la preparazione di composti aromatici monoalchilati
IT1304792B1 (it) *	1998-12-22	2001-03-29	Agip Petroli	Composizione catalitica per l'upgrading di idrocarburi aventi puntidi ebollizione nell'intervallo della nafta.

1998
- 1998-12-22 IT IT1998MI002773A patent/IT1304792B1/it active
1999
- 1999-12-17 CA CA002292950A patent/CA2292950A1/en not_active Abandoned
- 1999-12-17 HR HR990392A patent/HRP990392A2/hr not_active Application Discontinuation
- 1999-12-20 US US09/466,791 patent/US6416660B1/en not_active Expired - Fee Related
- 1999-12-20 RU RU99127286/04A patent/RU2227066C2/ru not_active IP Right Cessation
- 1999-12-20 EP EP99204430A patent/EP1013339A3/en not_active Withdrawn
- 1999-12-20 AU AU65323/99A patent/AU767598B2/en not_active Ceased
- 1999-12-21 HU HU9904691A patent/HUP9904691A3/hu unknown
- 1999-12-21 NO NO996371A patent/NO996371L/no not_active Application Discontinuation
- 1999-12-21 SK SK1833-99A patent/SK183399A3/sk unknown
- 1999-12-21 PL PL99337358A patent/PL337358A1/xx unknown
- 1999-12-21 NZ NZ501970A patent/NZ501970A/en unknown
- 1999-12-22 AR ARP990106706A patent/AR022003A1/es active IP Right Grant
- 1999-12-22 JP JP11365532A patent/JP2000288398A/ja active Pending
- 1999-12-22 BR BR9905940-1A patent/BR9905940A/pt not_active Application Discontinuation
- 1999-12-22 CN CN99127777A patent/CN1260375A/zh active Pending
2002
- 2002-02-14 US US10/073,977 patent/US6660676B2/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
SK183399A3 (en)	2001-01-18
EP1013339A3 (en)	2000-09-20
IT1304792B1 (it)	2001-03-29
EP1013339A2 (en)	2000-06-28
NO996371L (no)	2000-06-23
NO996371D0 (no)	1999-12-21
RU2227066C2 (ru)	2004-04-20
US6660676B2 (en)	2003-12-09
HUP9904691A3 (en)	2002-02-28
ITMI982773A1 (it)	2000-06-22
US20020108888A1 (en)	2002-08-15
AU6532399A (en)	2000-06-29
NZ501970A (en)	2001-04-27
AU767598B2 (en)	2003-11-20
CN1260375A (zh)	2000-07-19
HUP9904691A2 (hu)	2000-11-28
JP2000288398A (ja)	2000-10-17
US6416660B1 (en)	2002-07-09
HU9904691D0 (en)	2000-02-28
CA2292950A1 (en)	2000-06-22
PL337358A1 (en)	2000-07-03
BR9905940A (pt)	2000-08-08
AR022003A1 (es)	2002-09-04

Legal Events

Date	Code	Title	Description
2000-08-31	A1OB	Publication of a patent application
2001-01-03	ARAI	Request for the grant of a patent on the basis of the submitted results of a substantive examination of a patent application
2007-12-04	ODRP	Renewal fee for the maintenance of a patent	Payment date: 20071204 Year of fee payment: 9
2008-06-26	AIPI	Request for the grant of a patent on the basis of a substantive examination of a patent application
2009-01-16	ODBI	Application refused

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