IL107958A - Spherical catalyst components for the polymerization of olefins their preparation and catalysts comprising them - Google Patents

Spherical catalyst components for the polymerization of olefins their preparation and catalysts comprising them

Info

Publication number: IL107958A
Authority: IL; Israel
Prior art keywords: compound; alkyl; carbon atoms; polymerization; olefins
Prior art date: 1992-12-11

Application number

IL10795893A

Other languages

English (en)

Other versions

IL107958A0 (en

Original Assignee

Montell Technology Company Bv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-11

Filing date

1993-12-09

Publication date

1998-09-24

1993-12-09 Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv

1994-04-12 Publication of IL107958A0 publication Critical patent/IL107958A0/xx

1998-09-24 Publication of IL107958A publication Critical patent/IL107958A/en

Links

238000006116 polymerization reaction Methods 0.000 title claims abstract description 26
150000001336 alkenes Chemical class 0.000 title claims abstract description 15
239000003054 catalyst Substances 0.000 title claims description 42
238000002360 preparation method Methods 0.000 title claims description 13
150000001875 compounds Chemical class 0.000 claims abstract description 38
238000000034 method Methods 0.000 claims abstract description 36
-1 magnesium halide Chemical class 0.000 claims abstract description 25
239000010936 titanium Substances 0.000 claims abstract description 23
239000011148 porous material Substances 0.000 claims abstract description 19
239000011777 magnesium Substances 0.000 claims abstract description 18
150000003609 titanium compounds Chemical class 0.000 claims abstract description 16
229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
229910052736 halogen Inorganic materials 0.000 claims abstract description 10
238000004438 BET method Methods 0.000 claims abstract description 8
150000002367 halogens Chemical class 0.000 claims abstract description 5
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 30
125000004432 carbon atom Chemical group C* 0.000 claims description 24
229910001629 magnesium chloride Inorganic materials 0.000 claims description 15
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 12
229910052719 titanium Inorganic materials 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 11
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 11
229910003074 TiCl4 Inorganic materials 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 10
125000000753 cycloalkyl group Chemical group 0.000 claims description 10
150000005840 aryl radicals Chemical class 0.000 claims description 9
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
239000004215 Carbon black (E152) Substances 0.000 claims description 8
229930195733 hydrocarbon Natural products 0.000 claims description 8
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 8
229910052753 mercury Inorganic materials 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 7
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
150000004756 silanes Chemical class 0.000 claims description 3
150000007513 acids Chemical class 0.000 claims description 2
150000001993 dienes Chemical class 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
150000002430 hydrocarbons Chemical class 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims 4
150000007860 aryl ester derivatives Chemical class 0.000 claims 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
229910052760 oxygen Inorganic materials 0.000 claims 1
239000001301 oxygen Substances 0.000 claims 1
239000007787 solid Substances 0.000 abstract description 11
239000011949 solid catalyst Substances 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 24
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 21
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 20
239000005977 Ethylene Substances 0.000 description 20
229920000642 polymer Polymers 0.000 description 16
238000011282 treatment Methods 0.000 description 15
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
238000003756 stirring Methods 0.000 description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
230000000877 morphologic effect Effects 0.000 description 6
239000002245 particle Substances 0.000 description 5
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
238000005406 washing Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
229920001903 high density polyethylene Polymers 0.000 description 4
239000004700 high-density polyethylene Substances 0.000 description 4
229920000092 linear low density polyethylene Polymers 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
239000004711 α-olefin Substances 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
229920005606 polypropylene copolymer Polymers 0.000 description 2
238000004062 sedimentation Methods 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
238000007669 thermal treatment Methods 0.000 description 2
IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
108010007666 IMP cyclohydrolase Proteins 0.000 description 1
102100020796 Inosine 5'-monophosphate cyclohydrolase Human genes 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
241000786363 Rhampholeon spectrum Species 0.000 description 1
229910003910 SiCl4 Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
239000004708 Very-low-density polyethylene Substances 0.000 description 1
238000002083 X-ray spectrum Methods 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
150000008378 aryl ethers Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
229920001198 elastomeric copolymer Polymers 0.000 description 1
229920013728 elastomeric terpolymer Polymers 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
238000007429 general method Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000004707 linear low-density polyethylene Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000035939 shock Effects 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
238000012725 vapour phase polymerization Methods 0.000 description 1
229920001866 very low density polyethylene Polymers 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Emergency Medicine (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

IL10795893A 1992-12-11 1993-12-09 Spherical catalyst components for the polymerization of olefins their preparation and catalysts comprising them IL107958A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ITMI922822A IT1256648B (it)	1992-12-11	1992-12-11	Componenti e catalizzatori per la polimerizzazione delle olefine

Publications (2)

Publication Number	Publication Date
IL107958A0 IL107958A0 (en)	1994-04-12
IL107958A true IL107958A (en)	1998-09-24

Family

ID=11364444

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL10795893A IL107958A (en)	1992-12-11	1993-12-09	Spherical catalyst components for the polymerization of olefins their preparation and catalysts comprising them

Country Status (18)

Country	Link
US (1)	US6388028B2 (de)
EP (1)	EP0601525B1 (de)
JP (1)	JP4023833B2 (de)
KR (1)	KR100289267B1 (de)
CN (2)	CN1034580C (de)
AT (1)	ATE176676T1 (de)
AU (1)	AU673551B2 (de)
BR (1)	BR9305019A (de)
CA (1)	CA2111308A1 (de)
DE (1)	DE69323478T2 (de)
ES (1)	ES2129063T3 (de)
FI (1)	FI112240B (de)
IL (1)	IL107958A (de)
IT (1)	IT1256648B (de)
MX (1)	MX9307843A (de)
NO (1)	NO302825B1 (de)
RU (1)	RU2126420C1 (de)
ZA (1)	ZA939210B (de)

Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1264679B1 (it)	1993-07-07	1996-10-04	Spherilene Srl	Catalizzatori per la (co)polimerizzazione di etilene
IT1275573B (it) *	1995-07-20	1997-08-07	Spherilene Spa	Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
AU744327B2 (en)	1998-03-05	2002-02-21	Montell Technology Company B.V.	Polybutene-1 (co)polymers and process for their preparation
SG73622A1 (en) *	1998-03-11	2000-06-20	Sumitomo Chemical Co	Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
KR100530978B1 (ko)	1998-05-06	2005-11-24	바셀 테크놀로지 캄파니 비이브이	올레핀 중합용 촉매 성분
TW475934B (en)	1998-06-27	2002-02-11	Basell Technology Co Bv	Process for the production of Α-olefin polymer
IT1301990B1 (it)	1998-08-03	2000-07-20	Licio Zambon	Catalizzatori per la polimerizzazione delle olefine.
KR20010033872A (ko)	1998-11-04	2001-04-25	간디 지오프레이 에이치.	올레핀의 중합을 위한 성분 및 촉매
CN1128822C (zh)	1999-02-26	2003-11-26	中国石油化工集团公司	一种烯烃聚合催化剂载体的制备方法
WO2000055215A1 (en)	1999-03-15	2000-09-21	Basell Technology Company B.V.	Components and catalysts for the polymerization of olefins
CA2334743C (en)	1999-04-15	2010-01-12	Basell Technology Company B.V.	Components and catalysts for the polymerization of olefins
BR0006832B1 (pt) *	1999-06-18	2009-08-11		componentes catalìticos para a polimerização de olefinas, processo para a preparação de componentes catalìticos e catalisadores resultantes.
US6716940B1 (en)	1999-09-10	2004-04-06	Basell Polyolefine Gmbh	Catalyst for the polymerization of olefins
GB0001914D0 (en)	2000-01-27	2000-03-22	Borealis Polymers Oy	Catalyst
WO2001057099A1 (en)	2000-02-02	2001-08-09	Basell Technology Company B.V.	Components and catalysts for the polymerization of olefins
US6878659B2 (en) *	2000-05-24	2005-04-12	Toho Titanium Co., Ltd.	Solid catalyst component for olefin polymerization and catalyst
PL355609A1 (en)	2000-10-13	2004-05-04	Basell Poliolefine Italia S.P.A.	Catalyst components for the polymerization of olefines
BR0108587B1 (pt) *	2000-12-22	2011-07-12		processo para a preparação de um suporte esférico compreendendo um haleto de magnésio.
WO2002074818A1 (en) *	2001-03-15	2002-09-26	Basell Poliolefine Italia S.P.A.	Process for the (co)polymerization of ethylene
ES2297014T3 (es)	2001-09-13	2008-05-01	Basell Poliolefine Italia S.R.L.	Componentes y catalizadores para la polimerizacion de olefinas.
MY136330A (en) *	2001-12-12	2008-09-30	Basell Poliolefine Spa	Process for the polymerization of olefins
DE60318403T2 (de)	2002-03-08	2009-01-08	Basell Poliolefine Italia S.R.L.	Verfahren zur polymerisation von olefinen
ES2272981T3 (es)	2002-05-29	2007-05-01	Basell Poliolefine Italia S.R.L.	(co9 polimeros de 1-buteno y procedimiento para su preparacion.
US7585924B2 (en) *	2002-07-11	2009-09-08	E. I. Du Pont De Nemours And Company	Pressurized high temperature polymerization process and polymerization system used therein
CN100436491C (zh)	2002-10-09	2008-11-26	巴塞尔聚烯烃意大利有限公司	烯烃的气相催化聚合
CN100491421C (zh)	2002-11-28	2009-05-27	巴塞尔聚烯烃意大利有限公司	1-丁烯共聚物及其制备方法
US7932206B2 (en) *	2002-12-18	2011-04-26	Basell Poliolefine Italia S.P.A.	Magnesium dichloride-based adducts and catalyst components obtained therefrom
US7942572B2 (en) *	2003-10-16	2011-05-17	Basell Poliolefine Italia S.R.L.	Process for the continuous production of emulsions
WO2005047351A1 (en)	2003-10-28	2005-05-26	Basell Poliolefine Italia S.R.L.	Components and catalysts for the polymerization of olefins
ATE519787T1 (de)	2004-04-02	2011-08-15	Basell Poliolefine Srl	Komponenten und katalysatoren für die polymerisation von olefinen
US7674741B2 (en)	2004-06-16	2010-03-09	Basell Poliolefine Italia S.R.L.	Components and catalysts for the polymerization of olefins
ATE463517T1 (de) *	2004-06-18	2010-04-15	Basell Poliolefine Srl	Verfahren zur herstellung von katalysatorkomponenten für die olefinpolymerisation
CN101039967B (zh)	2004-10-18	2010-06-09	巴塞尔聚烯烃意大利有限责任公司	低全同立构规整度丁烯-1均聚物或共聚物
DE602005026837D1 (de)	2004-10-21	2011-04-21	Basell Polyolefine Gmbh	1-buten-polymer und herstellungsverfahren dafür
US7816466B2 (en)	2005-02-03	2010-10-19	Basell Poliolefine Italia S.R.L.	Propylene polymer composition for injection molding
CN101175778B (zh)	2005-05-12	2011-12-07	巴塞尔聚烯烃意大利有限责任公司	丙烯-乙烯共聚物和它们的制备方法
CA2613188A1 (en)	2005-07-01	2007-01-11	Basell Poliolefine Italia S.R.L.	Propylene polymers having broad molecular weight distribution
JP2009516044A (ja) *	2005-11-15	2009-04-16	バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ	プロピレン−エチレンコポリマー及びその製造法
CN101522732B (zh) *	2006-08-08	2012-06-13	巴塞尔聚烯烃意大利有限责任公司	1-丁烯共聚物
US20100029869A1 (en) *	2006-12-20	2010-02-04	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins and catalysts therefrom obtained
WO2008077770A1 (en) *	2006-12-22	2008-07-03	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins and catalysts therefrom obtained
CN101583634B (zh) *	2006-12-22	2012-12-05	巴塞尔聚烯烃意大利有限责任公司	用于烯烃聚合的催化剂组分以及由其获得的催化剂
JP5377474B2 (ja)	2007-04-27	2013-12-25	バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ	ブテン−１ターポリマー及びその製造方法
JP5404646B2 (ja) *	2007-12-24	2014-02-05	バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ	ポリオレフィン繊維
BRPI0915155B1 (pt)	2008-06-13	2019-10-08	Basell Poliolefine Italia S.R.L.	Sistema de catalisador para a polimerização de olefinas e processo para a (co)polimerização de fase gasosa de etileno
EP2370477B1 (de) *	2008-12-29	2012-11-21	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten für die polymerisation von olefinen und daraus erhaltene katalysatoren
CN102333798B (zh) *	2009-02-27	2014-06-04	巴塞尔聚烯烃股份有限公司	乙烯聚合的多级方法
US8227563B2 (en)	2009-04-16	2012-07-24	Basell Poliolefine Italia S.R.L.	Process for the preparation of polymer of 1-butene
WO2011006776A1 (en)	2009-07-14	2011-01-20	Basell Poliolefine Italia S.R.L.	Process for the preparation of polymer of 1-butene
RU2567391C2 (ru)	2009-08-21	2015-11-10	Чайна Петролеум Энд Кемикал Корпорейшн	Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора
CN102781971B (zh)	2010-03-04	2015-03-11	巴塞尔聚烯烃意大利有限责任公司	用于烯烃聚合的催化剂组分
US8829126B2 (en)	2010-03-04	2014-09-09	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins
US20130102744A1 (en)	2010-06-24	2013-04-25	Basell Poliolefine Italia, s.r.l.	Catalyst Systems for the Polymerization of Olefins
WO2012017040A1 (en)	2010-08-05	2012-02-09	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins
BR112013002868A2 (pt)	2010-08-05	2016-06-14	Basell Poliolefine Srl	componentes de catalisador para polimerização de olefinas
BR112013009372A2 (pt)	2010-10-19	2016-07-26	Basell Poliolefine Srl	processo para a preparação de polímeros de propileno de alta pureza
BR112013008900A2 (pt)	2010-10-19	2016-06-28	Basell Poliolefine Srl	"sistema da catalisação para a polimerização de olefinas"
CN103154050B (zh)	2010-10-19	2016-11-16	巴塞尔聚烯烃意大利有限责任公司	烯烃聚合方法
BR112013009717B1 (pt)	2010-10-21	2020-03-31	Basell Poliolefine Italia S.R.L.	Estrutura da película de múltiplas camadas refechável fácil de descascar para aplicação de vedação por calor.
EP2583985A1 (de)	2011-10-19	2013-04-24	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten für die Polymerisation von Olefinen
EP2583983A1 (de)	2011-10-19	2013-04-24	Basell Poliolefine Italia S.r.l.	Katalysator-Komponente zur Olefinpolymerisation
EP2607384A1 (de)	2011-12-21	2013-06-26	Basell Poliolefine Italia S.r.l.	Katalysatorsystem zur Olefinpolymerisation
EP2636687A1 (de)	2012-03-07	2013-09-11	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten zur Olefinpolymerisation
EP2666792A1 (de)	2012-05-23	2013-11-27	Basell Poliolefine Italia S.r.l.	Katalysatorbestandteil zur Olefinpolymeriation
EP2671894A1 (de)	2012-06-08	2013-12-11	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten zur Polymerisation von Buten-1
EP2712874A1 (de)	2012-09-26	2014-04-02	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten für die Polymerisation von Olefinen
EP2712875A1 (de)	2012-09-28	2014-04-02	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten für die Polymerisation von Olefinen
EP2746299A1 (de)	2012-12-19	2014-06-25	Basell Poliolefine Italia S.r.l.	Mehrstufiges Verfahren zur Polymerisierung von Ethylen
EP2757114A1 (de)	2013-01-18	2014-07-23	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten zur Olefinpolymerisation
EP2787014A1 (de)	2013-04-05	2014-10-08	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten zur Olefinpolymerisation
EP2803678A1 (de)	2013-05-14	2014-11-19	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten für die Polymerisation von Olefinen
EP2803679A1 (de)	2013-05-17	2014-11-19	Basell Poliolefine Italia S.r.l.	Katalysatorkomponente zur Polymerisation von Olefinen
WO2016142335A1 (en)	2015-03-10	2016-09-15	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins
US10246532B2 (en)	2015-03-12	2019-04-02	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins
ES2720058T3 (es)	2015-04-01	2019-07-17	Basell Poliolefine Italia Srl	Componentes catalizadores para la polimerización de olefinas
CN107580607B (zh)	2015-05-19	2019-09-27	巴塞尔聚烯烃意大利有限公司	用于烯烃聚合的催化剂组分
TWI735673B (zh)	2016-10-03	2021-08-11	日商東邦鈦股份有限公司	烯烴類聚合用固體觸媒成分、烯烴類聚合用固體觸媒成分之製造方法、烯烴類聚合用觸媒、烯烴類聚合體之製造方法、丙烯系共聚合體之製造方法及丙烯系共聚合體
WO2018091375A1 (en)	2016-11-18	2018-05-24	Basell Poliolefine Italia S.R.L.	Catalyst components for the polymerization of olefins
RU2725609C1 (ru)	2017-05-18	2020-07-03	Базелл Полиолефин Италия С.Р.Л.	Компоненты катализатора для полимеризации олефинов
WO2020069847A1 (en)	2018-10-01	2020-04-09	Basell Poliolefine Italia S.R.L.	Precursors and catalyst components for the polymerization of olefins
US20220056174A1 (en)	2018-12-04	2022-02-24	Basell Poliolefine Italia S.R.L.	Process for the preparation of a colored polypropylene
EP3894448B1 (de)	2018-12-14	2023-01-18	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten zur polymerisierung von olefinen
BR112021017834A2 (pt)	2019-04-11	2021-11-30	Basell Poliolefine Italia Srl	Processo para a preparação de um polímero de propileno
JP7100775B2 (ja)	2019-07-03	2022-07-13	バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ	オレフィン重合のための触媒成分
CN114667303B (zh)	2019-12-04	2024-01-26	巴塞尔聚烯烃意大利有限公司	用于烯烃聚合的催化剂
US12415910B2 (en)	2022-09-15	2025-09-16	Basell Polyolefine Gmbh	Polyethylene composition for blow molding having an improved swell behavior
US12351706B2 (en) *	2022-09-15	2025-07-08	Basell Polyolefine Gmbh	Polyethylene composition for blow molding having an improved swell behavior
JP2026506029A (ja)	2023-03-17	2026-02-20	バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ	オレフィン重合用触媒成分
EP4713375A1 (de)	2023-05-15	2026-03-25	Basell Poliolefine Italia S.r.l.	Katalysatorkomponenten für die olefinpolymerisation

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DK133012C (da)	1968-11-21	1976-08-09	Montedison Spa	Katalysator til polymerisation af alkener
YU35844B (en)	1968-11-25	1981-08-31	Montedison Spa	Process for obtaining catalysts for the polymerization of olefines
US3953414A (en)	1972-09-13	1976-04-27	Montecatini Edison S.P.A.,	Catalysts for the polymerization of olefins to spherically shaped polymers
IT1096661B (it)	1978-06-13	1985-08-26	Montedison Spa	Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it)	1978-08-22	1985-09-07	Montedison Spa	Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS5767612A (en) *	1980-10-15	1982-04-24	Mitsui Petrochem Ind Ltd	Preparation of ethylene copolymer
IT1136627B (it)	1981-05-21	1986-09-03	Euteco Impianti Spa	Catalizzatore supportato per la polimerizzazione di etilene
IT1151627B (it) *	1982-06-10	1986-12-24	Anic Spa	Procedimento per la preparazione di copolimeri dell'etilene con basso valore delle densita'
IT1212698B (it) *	1983-02-10	1989-11-30	Sir Soc Italiana Resine Spa	In sospensione di etilene con procedimento di copolimerizzazione alfa-olefine lineari perl'ottenimento di copolimeri a bassa densita'.
FR2577558B1 (fr) *	1985-02-19	1987-03-06	Bp Chimie Sa	Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse
IT1190319B (it)	1986-04-17	1988-02-16	Enichem Polimeri	Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo
FI80055C (fi)	1986-06-09	1990-04-10	Neste Oy	Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1203330B (it)	1987-02-06	1989-02-15	Enichem Base Spa	Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
US4970280A (en) *	1987-04-01	1990-11-13	Chisso Corporation	Continuous process for producing high molten viscoelastic polypropylene or ethylene-propylene copolymer
IT1227259B (it) *	1988-09-30	1991-03-28	Himont Inc	Catalizzatori per la polimerizzazione di olefine.
IT1227258B (it) *	1988-09-30	1991-03-28	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine
IT1230134B (it) *	1989-04-28	1991-10-14	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine.
JP2879347B2 (ja)	1989-10-02	1999-04-05	チッソ株式会社	オレフィン重合用触媒の製法
IT1236509B (it) *	1989-10-06	1993-03-11	Francesco Masi	Procedimento per la preparazione di copolimeri etilene-butene-1 con densita' ultra-bassa.
IL95567A (en) *	1989-10-18	1994-02-27	Himont Inc	Polymetallic catalysts, their preparation and polymers produced thereby
IT1262935B (it) *	1992-01-31	1996-07-22	Montecatini Tecnologie Srl	Componenti e catalizzatori per la polimerizzazione di olefine
IT1262934B (it) *	1992-01-31	1996-07-22	Montecatini Tecnologie Srl	Componenti e catalizzatori per la polimerizzazione di olefine

1992
- 1992-12-11 IT ITMI922822A patent/IT1256648B/it active IP Right Grant
1993
- 1993-12-06 DE DE69323478T patent/DE69323478T2/de not_active Expired - Lifetime
- 1993-12-06 AT AT93119646T patent/ATE176676T1/de not_active IP Right Cessation
- 1993-12-06 ES ES93119646T patent/ES2129063T3/es not_active Expired - Lifetime
- 1993-12-06 EP EP93119646A patent/EP0601525B1/de not_active Expired - Lifetime
- 1993-12-08 JP JP30802093A patent/JP4023833B2/ja not_active Expired - Fee Related
- 1993-12-08 ZA ZA939210A patent/ZA939210B/xx unknown
- 1993-12-08 RU RU93054528A patent/RU2126420C1/ru active
- 1993-12-08 AU AU52295/93A patent/AU673551B2/en not_active Ceased
- 1993-12-09 IL IL10795893A patent/IL107958A/en not_active IP Right Cessation
- 1993-12-09 KR KR1019930027080A patent/KR100289267B1/ko not_active Expired - Fee Related
- 1993-12-09 NO NO934496A patent/NO302825B1/no unknown
- 1993-12-10 FI FI935550A patent/FI112240B/fi not_active IP Right Cessation
- 1993-12-10 BR BR9305019A patent/BR9305019A/pt not_active IP Right Cessation
- 1993-12-10 MX MX9307843A patent/MX9307843A/es not_active IP Right Cessation
- 1993-12-11 CN CN93112859A patent/CN1034580C/zh not_active Expired - Fee Related
- 1993-12-13 CA CA002111308A patent/CA2111308A1/en not_active Abandoned
1995
- 1995-09-18 CN CN95115159A patent/CN1041525C/zh not_active Expired - Fee Related
1997
- 1997-06-19 US US08/878,681 patent/US6388028B2/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
RU2126420C1 (ru)	1999-02-20
NO302825B1 (no)	1998-04-27
CN1034580C (zh)	1997-04-16
IL107958A0 (en)	1994-04-12
CN1089622A (zh)	1994-07-20
JP4023833B2 (ja)	2007-12-19
CA2111308A1 (en)	1994-06-12
MX9307843A (es)	1994-07-29
JPH07300507A (ja)	1995-11-14
FI935550A0 (fi)	1993-12-10
ITMI922822A1 (it)	1994-06-11
EP0601525B1 (de)	1999-02-10
FI112240B (fi)	2003-11-14
KR940014457A (ko)	1994-07-18
NO934496L (no)	1994-06-13
DE69323478T2 (de)	1999-08-19
CN1041525C (zh)	1999-01-06
IT1256648B (it)	1995-12-12
ITMI922822A0 (it)	1992-12-11
DE69323478D1 (de)	1999-03-25
EP0601525A1 (de)	1994-06-15
ZA939210B (en)	1994-08-08
AU5229593A (en)	1994-06-23
US20010011060A1 (en)	2001-08-02
CN1127262A (zh)	1996-07-24
KR100289267B1 (ko)	2001-05-02
NO934496D0 (no)	1993-12-09
ES2129063T3 (es)	1999-06-01
BR9305019A (pt)	1994-07-05
FI935550L (fi)	1994-06-12
US6388028B2 (en)	2002-05-14
AU673551B2 (en)	1996-11-14
ATE176676T1 (de)	1999-02-15

Legal Events

Date	Code	Title
1999-01-26	FF	Patent granted
1999-07-14	KB	Patent renewed
2000-06-01	KB	Patent renewed
2004-02-08	KB	Patent renewed
2008-11-03	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
EP0601525B1 (de)	1999-02-10	Komponenten und Katalysatoren für Olefinpolymerisation
AU655526B2 (en)	1994-12-22	Components and catalysts for the polymerization of olefins
KR100268816B1 (ko)	2000-10-16	올레핀 중합용 성분 및 촉매
EP1032600B1 (de)	2002-10-09	Prepolymerisierte katalysatorkomponente für die polymerisierung von olefinen
US20090306316A1 (en)	2009-12-10	Catalyst components for the polymerization of olefins and catalysts therefrom obtained
US20030040427A1 (en)	2003-02-27	Pre-polymerized catalyst components for the polymerization of olefins
CN104334591A (zh)	2015-02-04	用于烯烃聚合的预聚合催化剂组分
EP0601524B1 (de)	1998-07-22	Verfahren zur Herstellung von (co)Polymeren von Ethylen mit breiter Molekulargewichtsverteilung
EP1232193B1 (de)	2007-02-07	Katalysator für die polymerisation von olefinen
WO2004005359A1 (en)	2004-01-15	Catalyst system for the polymerization of olefins
EP0604846B1 (de)	1997-10-29	Komponenten und Katalysatoren für die Olefinpolymerisation
MXPA00003277A (en)	2001-05-07	Pre-polymerized catalyst components for the polymerization of olefins