IL208609A - Preparation and process for the destruction of pollutants containing phosphorus and / or sulfur - Google Patents

Preparation and process for the destruction of pollutants containing phosphorus and / or sulfur

Info

Publication number: IL208609A
Authority: IL; Israel
Prior art keywords: composition; acid; sodium; decontaminating; surfactant
Prior art date: 2008-04-30

Application number

IL208609A

Other languages

English (en)

Hebrew (he)

Other versions

IL208609A0 (en

Original Assignee

Arkema France

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2008-04-30

Filing date

2010-10-11

Publication date

2013-12-31

2010-10-11 Application filed by Arkema France filed Critical Arkema France

2010-12-30 Publication of IL208609A0 publication Critical patent/IL208609A0/en

2013-12-31 Publication of IL208609A publication Critical patent/IL208609A/en

Links

239000000203 mixture Substances 0.000 title claims abstract description 86
238000000034 method Methods 0.000 title claims description 18
239000003344 environmental pollutant Substances 0.000 title claims description 14
230000006378 damage Effects 0.000 title abstract description 7
231100000719 pollutant Toxicity 0.000 title description 7
CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 claims abstract description 22
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 claims abstract description 20
239000004094 surface-active agent Substances 0.000 claims abstract description 13
150000003839 salts Chemical class 0.000 claims abstract description 4
231100000167 toxic agent Toxicity 0.000 claims description 18
239000003440 toxic substance Substances 0.000 claims description 17
239000002610 basifying agent Substances 0.000 claims description 12
BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 9
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
239000000872 buffer Substances 0.000 claims description 8
IMPJIGYFRNDTFT-UHFFFAOYSA-N P1(=O)OC(CO)OP(O1)=O.[Na] Chemical group P1(=O)OC(CO)OP(O1)=O.[Na] IMPJIGYFRNDTFT-UHFFFAOYSA-N 0.000 claims description 5
231100001234 toxic pollutant Toxicity 0.000 claims description 5
-1 ammonium silicates Chemical class 0.000 claims description 4
150000001412 amines Chemical class 0.000 claims description 3
239000002736 nonionic surfactant Substances 0.000 claims description 3
235000011118 potassium hydroxide Nutrition 0.000 claims description 3
235000011121 sodium hydroxide Nutrition 0.000 claims description 3
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
239000004115 Sodium Silicate Substances 0.000 claims description 2
239000000908 ammonium hydroxide Substances 0.000 claims description 2
235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
NTBYNMBEYCCFPS-UHFFFAOYSA-N azane boric acid Chemical class N.N.N.OB(O)O NTBYNMBEYCCFPS-UHFFFAOYSA-N 0.000 claims description 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
235000019353 potassium silicate Nutrition 0.000 claims description 2
239000011734 sodium Substances 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
235000019351 sodium silicates Nutrition 0.000 claims description 2
235000010339 sodium tetraborate Nutrition 0.000 claims description 2
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical class [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims description 2
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical class [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 abstract description 9
231100000331 toxic Toxicity 0.000 abstract description 6
230000002588 toxic effect Effects 0.000 abstract description 6
KXXHZVHYFQSELL-UHFFFAOYSA-N 2-diethoxyphosphorylethanol Chemical compound CCOP(=O)(CCO)OCC KXXHZVHYFQSELL-UHFFFAOYSA-N 0.000 abstract 1
239000000463 material Substances 0.000 description 12
239000007864 aqueous solution Substances 0.000 description 10
238000005202 decontamination Methods 0.000 description 10
230000003588 decontaminative effect Effects 0.000 description 10
239000000243 solution Substances 0.000 description 10
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 9
150000001875 compounds Chemical class 0.000 description 9
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 8
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
238000009472 formulation Methods 0.000 description 8
150000004965 peroxy acids Chemical class 0.000 description 7
239000002253 acid Substances 0.000 description 6
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
239000002917 insecticide Substances 0.000 description 4
150000002898 organic sulfur compounds Chemical class 0.000 description 4
235000019260 propionic acid Nutrition 0.000 description 4
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
239000004327 boric acid Substances 0.000 description 3
239000002609 medium Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
150000002903 organophosphorus compounds Chemical class 0.000 description 3
WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 3
229960004623 paraoxon Drugs 0.000 description 3
229910000027 potassium carbonate Inorganic materials 0.000 description 3
235000011181 potassium carbonates Nutrition 0.000 description 3
239000000376 reactant Substances 0.000 description 3
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000010533 azeotropic distillation Methods 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000003093 cationic surfactant Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000002575 chemical warfare agent Substances 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000007598 dipping method Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000000269 nucleophilic effect Effects 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
239000003973 paint Substances 0.000 description 2
239000000575 pesticide Substances 0.000 description 2
125000001453 quaternary ammonium group Chemical group 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
238000005507 spraying Methods 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
IKJAVHKRVPYFOD-UHFFFAOYSA-N 2-hydroxyethylazanium;bromide Chemical compound Br.NCCO IKJAVHKRVPYFOD-UHFFFAOYSA-N 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
102000003914 Cholinesterases Human genes 0.000 description 1
108090000322 Cholinesterases Proteins 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
206010029350 Neurotoxicity Diseases 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
AXPZGGIIXCYPQK-UHFFFAOYSA-N OS(=O)P(O)(O)=O Chemical class OS(=O)P(O)(O)=O AXPZGGIIXCYPQK-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
DYAHQFWOVKZOOW-UHFFFAOYSA-N Sarin Chemical compound CC(C)OP(C)(F)=O DYAHQFWOVKZOOW-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
GRXKLBBBQUKJJZ-UHFFFAOYSA-N Soman Chemical compound CC(C)(C)C(C)OP(C)(F)=O GRXKLBBBQUKJJZ-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
206010044221 Toxic encephalopathy Diseases 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
PJVJTCIRVMBVIA-JTQLQIEISA-N [dimethylamino(ethoxy)phosphoryl]formonitrile Chemical compound CCO[P@@](=O)(C#N)N(C)C PJVJTCIRVMBVIA-JTQLQIEISA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 description 1
229960004373 acetylcholine Drugs 0.000 description 1
230000032683 aging Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
229910000148 ammonium phosphate Inorganic materials 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 description 1
QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
VZDYWEUILIUIDF-UHFFFAOYSA-J cerium(4+);disulfate Chemical compound [Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VZDYWEUILIUIDF-UHFFFAOYSA-J 0.000 description 1
229910000355 cerium(IV) sulfate Inorganic materials 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000008103 glucose Substances 0.000 description 1
229940075507 glyceryl monostearate Drugs 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
USSBDBZGEDUBHE-UHFFFAOYSA-L magnesium;2-oxidooxycarbonylbenzoate Chemical compound [Mg+2].[O-]OC(=O)C1=CC=CC=C1C([O-])=O USSBDBZGEDUBHE-UHFFFAOYSA-L 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
230000007135 neurotoxicity Effects 0.000 description 1
231100000228 neurotoxicity Toxicity 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
GIDDQKKGAYONOU-UHFFFAOYSA-N octylazanium;bromide Chemical compound Br.CCCCCCCCN GIDDQKKGAYONOU-UHFFFAOYSA-N 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
238000010422 painting Methods 0.000 description 1
LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
230000000865 phosphorylative effect Effects 0.000 description 1
238000000053 physical method Methods 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
229910000160 potassium phosphate Inorganic materials 0.000 description 1
235000011009 potassium phosphates Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229960004063 propylene glycol Drugs 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
239000011814 protection agent Substances 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229940079842 sodium cumenesulfonate Drugs 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
235000011008 sodium phosphates Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000001587 sorbitan monostearate Substances 0.000 description 1
229940035048 sorbitan monostearate Drugs 0.000 description 1
235000011076 sorbitan monostearate Nutrition 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/02—Chemical warfare substances, e.g. cholinesterase inhibitors
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/04—Pesticides, e.g. insecticides, herbicides, fungicides or nematocides
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/26—Organic substances containing nitrogen or phosphorus
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/28—Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen

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Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Toxicology (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Business, Economics & Management (AREA)
Emergency Management (AREA)
Detergent Compositions (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Fireproofing Substances (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

IL208609A 2008-04-30 2010-10-11 Preparation and process for the destruction of pollutants containing phosphorus and / or sulfur IL208609A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR0852911A FR2930732B1 (fr)	2008-04-30	2008-04-30	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
PCT/FR2009/050779 WO2009141548A2 (fr)	2008-04-30	2009-04-28	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres

Publications (2)

Publication Number	Publication Date
IL208609A0 IL208609A0 (en)	2010-12-30
IL208609A true IL208609A (en)	2013-12-31

Family

ID=40288819

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL208609A IL208609A (en)	2008-04-30	2010-10-11	Preparation and process for the destruction of pollutants containing phosphorus and / or sulfur

Country Status (8)

Country	Link
EP (1)	EP2271410B1 (ja)
JP (1)	JP5437363B2 (ja)
CN (1)	CN102015035B (ja)
AT (1)	ATE528050T1 (ja)
ES (1)	ES2374703T3 (ja)
FR (1)	FR2930732B1 (ja)
IL (1)	IL208609A (ja)
WO (1)	WO2009141548A2 (ja)

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EP2271616B1 (en)	2008-03-28	2020-11-11	Ecolab USA Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US8809392B2 (en)	2008-03-28	2014-08-19	Ecolab Usa Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US12203056B2 (en)	2008-03-28	2025-01-21	Ecolab Usa Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US8871807B2 (en)	2008-03-28	2014-10-28	Ecolab Usa Inc.	Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids
US8809245B2 (en) *	2010-12-14	2014-08-19	Robert E. Hill	Remedial composition and treatment method
US9321664B2 (en)	2011-12-20	2016-04-26	Ecolab Usa Inc.	Stable percarboxylic acid compositions and uses thereof
BR112014020748B1 (pt)	2012-03-30	2021-02-23	Ecolab Usa Inc.	método de tratamento de águas, método de tratamento de uma fonte de água e composição aquosa de tratamento de água com atividade antimicrobiana
US8822719B1 (en)	2013-03-05	2014-09-02	Ecolab Usa Inc.	Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
US20140256811A1 (en)	2013-03-05	2014-09-11	Ecolab Usa Inc.	Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
US10165774B2 (en)	2013-03-05	2019-01-01	Ecolab Usa Inc.	Defoamer useful in a peracid composition with anionic surfactants
RU2669850C1 (ru) *	2017-08-28	2018-10-16	Федеральное Государственное бюджетное учреждение "27 Научный центр" Министерства обороны Российской Федерации	Пенное хлорактивное средство и способ его получения на основе фторорганического пенообразователя и n, n-дихлорарилсульфамидов
FR3072390B1 (fr) *	2017-10-18	2019-12-20	Quadrimex Chemical Sas	Composition extemporanee comprenant un melange de deux produits pour la destruction de polluants organophosphores et/ou organosoufres
BR112021002549A2 (pt)	2018-08-22	2021-05-04	Ecolab Usa Inc.	composição de ácido peroxicarboxílico estabilizada, e, método para reduzir uma população microbiana usando uma composição de ácido peroxicarboxílico estabilizada.
MX2021014340A (es)	2019-05-31	2022-01-06	Ecolab Usa Inc	Metodo de monitoreo de las concentraciones de peracidos mediante mediciones de conductividad y composiciones de peracidos.
US12096768B2 (en)	2019-08-07	2024-09-24	Ecolab Usa Inc.	Polymeric and solid-supported chelators for stabilization of peracid-containing compositions

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GB9004080D0 (en) *	1990-02-23	1990-04-18	Interox Chemicals Ltd	Solutions of peracids
FR2761080B1 (fr) *	1997-03-21	2002-07-19	Quadrimex	Composition a base de peracides pour le nettoyage, la desinfection et la decontamination de surfaces souillees par des agents toxiques
FR2766724B1 (fr) *	1997-07-31	1999-10-22	Irdec Sa	Compositions decontaminantes non agressives
FR2766725A1 (fr) *	1997-07-31	1999-02-05	Irdec Sa	Compositions decontaminantes stabilisees
FR2800291B1 (fr) *	1999-10-29	2004-07-09	Atofina	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
DE19960994A1 (de) *	1999-12-17	2001-06-21	Degussa	Verfahren zur Herstellung von Peroxycarbonsäurelösungen insbesondere Gleichgewichts-Peressigsäure und -Perpropionsäure
CN1513569A (zh) *	2003-07-28	2004-07-21	华南农业大学	去除有机磷及氨基甲酸酯农药残留的方法

2008
- 2008-04-30 FR FR0852911A patent/FR2930732B1/fr not_active Expired - Fee Related
2009
- 2009-04-28 ES ES09750029T patent/ES2374703T3/es active Active
- 2009-04-28 EP EP09750029A patent/EP2271410B1/fr not_active Not-in-force
- 2009-04-28 AT AT09750029T patent/ATE528050T1/de not_active IP Right Cessation
- 2009-04-28 WO PCT/FR2009/050779 patent/WO2009141548A2/fr not_active Ceased
- 2009-04-28 JP JP2011506755A patent/JP5437363B2/ja not_active Expired - Fee Related
- 2009-04-28 CN CN200980115146.8A patent/CN102015035B/zh not_active Expired - Fee Related
2010
- 2010-10-11 IL IL208609A patent/IL208609A/en not_active IP Right Cessation

Also Published As

Publication number	Publication date
CN102015035B (zh)	2013-02-13
IL208609A0 (en)	2010-12-30
ATE528050T1 (de)	2011-10-15
JP5437363B2 (ja)	2014-03-12
JP2011522066A (ja)	2011-07-28
CN102015035A (zh)	2011-04-13
FR2930732A1 (fr)	2009-11-06
FR2930732B1 (fr)	2010-05-14
EP2271410A2 (fr)	2011-01-12
ES2374703T3 (es)	2012-02-21
EP2271410B1 (fr)	2011-10-12
WO2009141548A3 (fr)	2010-03-25
WO2009141548A2 (fr)	2009-11-26

Legal Events

Date	Code	Title
2014-04-30	FF	Patent granted
2014-05-28	KB	Patent renewed
2015-03-31	KB	Patent renewed
2019-11-28	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
IL208609A (en)	2013-12-31	Preparation and process for the destruction of pollutants containing phosphorus and / or sulfur
Singh et al.	2010	Decontamination of chemical warfare agents
US7064241B2 (en)	2006-06-20	Chemical and biological warfare decontaminating solution using peracids and germinants in microemulsions, process and product thereof
US6245957B1 (en)	2001-06-12	Universal decontaminating solution for chemical warfare agents
KR100916328B1 (ko)	2009-09-11	화학적, 생물학적 및 산업적 독극물의 개선된 중화용 제제
US7390432B2 (en)	2008-06-24	Enhanced formulations for neutralization of chemical, biological and industrial toxants
AU635512B2 (en)	1993-03-25	Inhibition of mercaptan odor in organothiophosphate biocides
US6723891B1 (en)	2004-04-20	Molybdate/peroxide microemulsions useful for decontamination of chemical warfare agents
FR2766724A1 (fr)	1999-02-05	Compositions decontaminantes non agressives
EP2296764B1 (fr)	2016-08-10	Solution aqueuse decontaminante et moussante
RU2099115C1 (ru)	1997-12-20	Бифункциональная рецептура окислительно-нуклеофильного действия
US20100010285A1 (en)	2010-01-14	Decontamination system
EP0906773A1 (fr)	1999-04-07	Composition de décontamination
EP0894512A1 (fr)	1999-02-03	Utilisation de compositions décontaminantes stabilisées pour la décontamination d'agents toxiques et/ou polluants
US7910537B1 (en)	2011-03-22	Decontamination of chemical warfare agents using benign household chemicals
US6143088A (en)	2000-11-07	Peracid-based composition for decontamination of materials soiled by toxic agents
CA2389081C (fr)	2009-12-22	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
US7442677B1 (en)	2008-10-28	Activated peroxide solution with improved stability useful for the decontamination of chemical warfare agents
US20050085402A1 (en)	2005-04-21	Chemical and biological warfare agent decontaminating method using dioxirane-producing formulations
RU2484869C2 (ru)	2013-06-20	Деконтаминирующий и пенообразующий водный раствор
IL208608A (en)	2014-11-30	A propropionic acid preparation that will stabilize in a basic medium
UA115165U (xx)	2017-04-10	Деконтамінаційна композиція для утилізації фосфор- та сіркоорганічних токсичних речовин