JPH037667B2 - - Google Patents
Info
- Publication number
- JPH037667B2 JPH037667B2 JP59214463A JP21446384A JPH037667B2 JP H037667 B2 JPH037667 B2 JP H037667B2 JP 59214463 A JP59214463 A JP 59214463A JP 21446384 A JP21446384 A JP 21446384A JP H037667 B2 JPH037667 B2 JP H037667B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- polycarbonates
- potassium
- sodium
- hydroxyphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 125000005543 phthalimide group Chemical class 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 229960000583 acetic acid Drugs 0.000 claims description 5
- 239000012362 glacial acetic acid Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 description 46
- 239000004417 polycarbonate Substances 0.000 description 46
- -1 alkali metal salts Chemical class 0.000 description 18
- 229910052783 alkali metal Inorganic materials 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- 229910052708 sodium Inorganic materials 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
- 229910052700 potassium Inorganic materials 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- 125000003118 aryl group Chemical group 0.000 description 10
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 150000007524 organic acids Chemical class 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 150000007522 mineralic acids Chemical class 0.000 description 7
- 239000005871 repellent Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 229910003002 lithium salt Inorganic materials 0.000 description 4
- 159000000002 lithium salts Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229940093915 gynecological organic acid Drugs 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 159000000001 potassium salts Chemical class 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 3
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000005819 Potassium phosphonate Substances 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- DRXDBDATOLWSNZ-UHFFFAOYSA-L dilithium;dioxido-oxo-phenyl-$l^{5}-phosphane Chemical compound [Li+].[Li+].[O-]P([O-])(=O)C1=CC=CC=C1 DRXDBDATOLWSNZ-UHFFFAOYSA-L 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- YXXXKCDYKKSZHL-UHFFFAOYSA-M dipotassium;dioxido(oxo)phosphanium Chemical compound [K+].[K+].[O-][P+]([O-])=O YXXXKCDYKKSZHL-UHFFFAOYSA-M 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000011814 protection agent Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229940083542 sodium Drugs 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 1
- VPVTXVHUJHGOCM-UHFFFAOYSA-N 2,4-bis[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 VPVTXVHUJHGOCM-UHFFFAOYSA-N 0.000 description 1
- MAQOZOILPAMFSW-UHFFFAOYSA-N 2,6-bis[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=C(CC=3C(=CC=C(C)C=3)O)C=C(C)C=2)O)=C1 MAQOZOILPAMFSW-UHFFFAOYSA-N 0.000 description 1
- ZEKCYPANSOJWDH-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-1H-indol-2-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3NC2=O)C=2C=C(C)C(O)=CC=2)=C1 ZEKCYPANSOJWDH-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- XJGTVJRTDRARGO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)(C)C1=CC=C(O)C=C1 XJGTVJRTDRARGO-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- CIEGINNQDIULCT-UHFFFAOYSA-N 4-[4,6-bis(4-hydroxyphenyl)-4,6-dimethylheptan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)CC(C)(C=1C=CC(O)=CC=1)CC(C)(C)C1=CC=C(O)C=C1 CIEGINNQDIULCT-UHFFFAOYSA-N 0.000 description 1
- LIDWAYDGZUAJEG-UHFFFAOYSA-N 4-[bis(4-hydroxyphenyl)-phenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=CC=C1 LIDWAYDGZUAJEG-UHFFFAOYSA-N 0.000 description 1
- BOCLKUCIZOXUEY-UHFFFAOYSA-N 4-[tris(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 BOCLKUCIZOXUEY-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- ROXQQDABMSCAKU-UHFFFAOYSA-N C1(C=2C(C(=O)O1)=CC=CC2)=O.C2(C=1C(C(N2)=O)=CC=CC1)=O Chemical compound C1(C=2C(C(=O)O1)=CC=CC2)=O.C2(C=1C(C(N2)=O)=CC=CC1)=O ROXQQDABMSCAKU-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- GZGWZMBWGVIDKE-UHFFFAOYSA-N ClC1=CC=C(C=C1)[Na] Chemical compound ClC1=CC=C(C=C1)[Na] GZGWZMBWGVIDKE-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 235000009781 Myrtillocactus geometrizans Nutrition 0.000 description 1
- 240000009125 Myrtillocactus geometrizans Species 0.000 description 1
- YQYVVTQTIAMOLD-UHFFFAOYSA-N P(O)(O)=O.C[K] Chemical compound P(O)(O)=O.C[K] YQYVVTQTIAMOLD-UHFFFAOYSA-N 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- BJZIJOLEWHWTJO-UHFFFAOYSA-H dipotassium;hexafluorozirconium(2-) Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Zr+4] BJZIJOLEWHWTJO-UHFFFAOYSA-H 0.000 description 1
- RXCBCUJUGULOGC-UHFFFAOYSA-H dipotassium;tetrafluorotitanium;difluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Ti+4] RXCBCUJUGULOGC-UHFFFAOYSA-H 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- IOXPXHVBWFDRGS-UHFFFAOYSA-N hept-6-enal Chemical compound C=CCCCCC=O IOXPXHVBWFDRGS-UHFFFAOYSA-N 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical group C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- SJDACOMXKWHBOW-UHFFFAOYSA-N oxyphenisatine Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2NC1=O SJDACOMXKWHBOW-UHFFFAOYSA-N 0.000 description 1
- 229950003332 perflubutane Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 229940093916 potassium phosphate Drugs 0.000 description 1
- LVTHXRLARFLXNR-UHFFFAOYSA-M potassium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LVTHXRLARFLXNR-UHFFFAOYSA-M 0.000 description 1
- KIXKLKMUPZUMFB-UHFFFAOYSA-M potassium;2,3,4-trichlorobenzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=C(Cl)C(Cl)=C1Cl KIXKLKMUPZUMFB-UHFFFAOYSA-M 0.000 description 1
- IUTAHLUWHZYCKB-UHFFFAOYSA-M potassium;2,5-dichlorobenzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC(Cl)=CC=C1Cl IUTAHLUWHZYCKB-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 229960003339 sodium phosphate Drugs 0.000 description 1
- QBJDFZSOZNDVDE-UHFFFAOYSA-M sodium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F QBJDFZSOZNDVDE-UHFFFAOYSA-M 0.000 description 1
- OMVLAGBUFPUMGQ-UHFFFAOYSA-M sodium;2,4,5-trichlorobenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl OMVLAGBUFPUMGQ-UHFFFAOYSA-M 0.000 description 1
- XVIWIODPAIABBX-UHFFFAOYSA-M sodium;2,5-dichlorobenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(Cl)=CC=C1Cl XVIWIODPAIABBX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical class [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- ZIZQEDPMQXFXTE-UHFFFAOYSA-H tripotassium;hexafluoroaluminum(3-) Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[Al+3].[K+].[K+].[K+] ZIZQEDPMQXFXTE-UHFFFAOYSA-H 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Indole Compounds (AREA)
- Fireproofing Substances (AREA)
Description
æ¬çºæã¯äžè¬åŒïŒïŒ
åŒäžãã¯æ°ŽçŽ ãŸãã¯ïŒåãŸã§ã®ããã²ã³ã
瀺ããã㊠ïœã¯ïŒãŸãã¯ïŒã瀺ã ã®ãã¿ã«ã€ããååç©é¡ã«é¢ãããã®ã§ããã æ¬çºæã¯ãŸããåŒïŒïŒ åŒäžã ã¯åŒïŒïŒã®å Žåã«ç€ºãããŠããæå³ãæã
ã ã®ç¡æ°Žãã¿ã«é žãäžè¬åŒïŒïŒ åŒäžãïœã¯ïŒãŸãã¯ïŒã瀺ã ã®ã¢ãã³ãšå®è³ªçã«çã¢ã«éã§117âã«ãããŠã
溶åªãšããŠã®æ°·é ¢é žããã³æ°Žâæ æå€ãšããŠã®ã·
ã¯ããããµã³ã䜿çšããŠåå¿ããããåŒïŒïŒã®
ãã¿ã«ã€ããé¡ã®è£œé æ¹æ³ã«ãé¢ãããã®ã§ã
ãã åŒïŒïŒã®ã¢ãã³é¡ã¯æç®ããå ¬ç¥ã§ããã
ïŒäŸãã°ç±³åœç¹èš±æ现æž3753679åç §ïŒããŸãã¯ã
ãã«èšèŒãããŠããæ¹æ³ã«ããåŸãããã 溶åªã®äœ¿çšéã¯ïŒã¢ã«ã®äœ¿çšããã¢ãã³åœãã
çŽ2.5ã3.0ãªããã«ã§ãããæ°Žâæ æå€ã®éã¯ïŒ
ã¢ã«ã®ã¢ãã³åœããçŽ250â300mlã§ããã æ°èŠãªãã¿ã«ã€ããååç©é¡ã¯ãããªã«ãŒãã
ãŒãé¡çšã®å ¬ç¥ã®é²çå å·¥å€é¡ïŒflameproofing
agentsïŒãããªãã¡ææ©ãããã¯ç¡æ©é žé¡ã®ã¢ã«
ã«ãªéå±å¡©é¡ããšçµåããããšãããã²ã³ãå«ãŸ
ãªãããšããŒã«ç³»æåããã ã補é ãããç±å¯å¡
æ§è³éŠæããªã«ãŒãããŒãé¡ã®æ¥ççïŒflameâ
repellencyïŒãæ¹è¯ããã®ã«é©ããŠããçžä¹å€ãš
ãªãã åŸã€ãŠãæ¬çºæã¯ ïœ 0.1ãïŒéééšã®åŒïŒïŒã®ãã¿ã«ã€ããã
ããã³ ïœ 0.02ãïŒéééšã®ææ©ãããã¯ç¡æ©é žã®ã¢ã«
ã«ãªéå±å¡©ãç¹ã«ãããªãŠã ãã«ãªãŠã ãŸãã¯
ãªããŠã å¡©ã ãããªãé²çå å·¥å€çµæç©ã«ãé¢ãããã®ã§ã
ãã é²çå å·¥å€ãšããŠé©ããŠããææ©ãããã¯ç¡æ©
é žã®ã¢ã«ã«ãªéå±å¡©é¡ã¯äŸãã°ãã€ãå ¬éæ现æž
2703710ã2918882ããã³2918883äžã«èšãããŠã
ãã æ¬çºæãŸãã¯ãããã²ã³ãå«ãŸãªãããšããŒã«
ç³»æåé¡ã®ç±å¯å¡æ§åæéç¶è³éŠæããªã«ãŒãã
ãŒãã«ãããªã«ãŒãããŒããåºã«ããŠ0.1ãïŒé
éïŒ ã®éã®åŒïŒïŒã®ãã¿ã«ã€ãããããã³0.02
ãïŒééïŒ ã®ææ©ãããã¯ç¡æ©é žã®ã¢ã«ã«ãªéå±
å¡©ãåºã«ããæ¥çå å·¥ãæœãããã®æ¬çºæã«åŸã
é²çå å·¥å€ã®äœ¿çšã«ãé¢ãããã®ã§ããã æ¬çºæã¯ããã«ãé²çå å·¥å€ãæ··åãããã®åŸ
270â300âã®ã奜é©ã«ã¯270â280âã®ãç©è³ªæž©åºŠ
ã«ãããŠïŒâã¹ã¯ãªãŠãŒæŒåºåšãéããŠé¡ç²åã
ãããšãç¹åŸŽãšãããããã²ã³ãå«ãŸãªãããšã
ãŒã«åœ¢æåé¡ã®ç±å¯å¡æ§åæéç¶è³éŠæããªã«ãŒ
ãããŒãã«æ¥çå å·¥ãæœãæ¹æ³ã«ãé¢ãããã®ã§
ããã æé©ãªåŠçæ¡ä»¶ã¯ã40ã80å転ïŒåã®å転é床
ã«ãããŠãå®è³ªçã«18KgïŒæã®çç£éãåŸããã
ãããªãã®ã§ããã 䜿çšãããïŒâã¹ã¯ãªãŠãŒæŒåºåšã¯ãZSK53
ã®è¡šç€ºã®ã¯ãŒããŒã»ãŠã³ãã»ãã¬ã€ãã©ãŒè£œã®è£
眮ã§ããã æ¬çºæã¯ãŸããããã²ã³ãå«ãŸãªãããšããŒã«
ç³»æåé¡ã®ä»ã®æ·»å ç©é¡ãå«ãŸãªãç±å¯å¡æ§åæ
éç¶è³éŠæããªã«ãŒãããŒããåºã«ããŠ0.1ãïŒ
ééïŒ ã®éã®åŒïŒïŒã®ãã¿ã«ã€ããããã³0.02
ãïŒééïŒ ã®ææ©ãããã¯ç¡æ©é žã®ã¢ã«ã«ãªéå±
å¡©ãå«ãã§ããã該ããªã«ãŒãããŒããåºã«ãã
ç±å¯å¡æ§æåçšçµæç©é¡ã«ãé¢ãããã®ã§ããã ããã²ã³ãå«ãŸãªãããšããŒã«ç³»æåé¡ã®ç±å¯
å¡æ§åæéç¶è³éŠæããªã«ãŒãããŒãé¡ãšã¯ãã
ãªã«ãŒãããŒãé¡ã®è£œé çšã«äœ¿çšããããžããšã
ãŒã«é¡ãã¢ãããšããŒã«é¡ããã³ããªã¹ããšããŒ
ã«é¡ãããã©ããšããŒã«é¡ãŸãã¯ä»ã®åæéåå€
ãããã²ã³çœ®æåºãæããŠããªãããšãæå³ãã
ãšç解ãã¹ãã§ããããããã®ããªã«ãŒãããŒã
é¡ã¯ãã¡ãããäŸãã°ãã¹ã²ã³ã䜿çšããçžå¢ç
æ¹æ³ã«ãããããã補é ãããå Žåã«æ®åããŠã
ãå°ãªãppméã®å æ°Žå解ãããŠããªãå¡©çŽ ãäŸ
ç¶ãšããŠå«æããŠããããšãããã以äžã®ããã
ã²ã³ãå«ãŸãªããããªã«ãŒãããŒãé¡ã®å®çŸ©ã§
ã¯ããã®æ¹æ³ã§å æ°Žå解ã§ããããã²ã³ã®æ®æž£ã¯
èæ ®ã«ãããªããŠããã ãããã®æ°èŠãªé²çœå å·¥å€ã®äœ¿çšã«ãã
UL94VâïŒåé¡ã®é²çå å·¥ããªã«ãŒãããŒãé¡
ãåŸãããããã®ããã«ããŠæ¬çºæã«åŸãããã²
ã³ãå«ãŸãªããã¿ã«ã€ããé¡ãçšããããšã«ã
ãã1.6mmã®å£åãã§ïŒ¶âïŒã®C1ããã³Brâãå«
ãŸãªãé²çå å·¥ããªã«ãŒãããŒãé¡ãåŸãããã
âïŒã¯ããã²ã³å«æååç©ã䜿çšãããš0.8mm
ã®å£åãã§åŸããããããã«ãæ¬çºæã«åŸãåŒ
ïŒïŒã®ãã¿ã«ã€ããé¡ã¯éåžžã®ããªã«ãŒãããŒ
ãå å·¥æ¡ä»¶äžã«ãããäœæ®çºæ§ã«ãã€ãŠãç¹åŸŽã¥
ããããŠããã ãããã®ããªã«ãŒãããŒãæåçšçµæç©é¡ã¯ã
127Ã12.7Ã3.2mmïŒ1/8â³ïŒãŸãã¯127Ã12.7Ã1.6
mmïŒ1/16â³ïŒãŸãã¯127Ã12.7Ã0.8mmïŒ1/32â³ïŒã®
寞æ³ãæããè©Šéšçäžã§ã¢ã³ããŒã©ã€ã¿ãŒã¹ã»ã©
ãã©ããªã€ã¹ã»ã€ã³ã³ãŒãã¬ãŒããããããªãã³
94ã®ç©è³ªåé¡ã«é¢ããççŒè©ŠéšïŒä»¥äžã§ã¯UL94
ãšç§°ããïŒã«åŸãççŒåé¡ïŒ¶âïŒãããªãã¡æ»Žäž
ãããããå¹³åïŒç§ããçãåŸâççŒæéãæã
ãåé¡ããåŸãã ããªã«ãŒãããŒãã®æ¥çæ§ã¯ã¢ã«ã«ãªéå±å¡©é¡
ã®æ·»å ã«ããæ¹è¯ã§ããããšã¯ç¥ãããŠãããã
ãã§ããªã«ãŒãããŒãé¡ã¯ããã²ã³ãå«ãŸãªãã
ã®ã§ããŸãã¯ããã²ã³â眮æãããŠãããã®ã§ã
ãããïŒäŸãã°ãã€ãå ¬éæ现æž1930257ããã€ã
å ¬éæ现æž2049358ããã€ãå ¬éæ现æž2112987ã
ãã€ãå ¬éæ现æž2149311ããã€ãå ¬éæ现æž
2253072䞊ã³ã«ãã€ãå ¬éæ现æž2458968ã
2461063ã2461146ããã³2461077åç §ïŒã ããªã«ãŒãããŒãé¡ã®æ¥çæ§ã¯ææ©å¡©çŽ ååç©
é¡ãšããçš®ã®ç¡æ©å¡©é¡ãšã®æ··åç©ã®æ·»å ã«ããæ¹
è¯ã§ããããšãç¥ãããŠããïŒäŸãã°ãã€ãå ¬é
æ现æž2013496åç §ãç¹ã«ç¡æ°Žããã©ã¯ãããã¿
ã«é žãé©åœãªææ©å¡©çŽ ååç©ãšããŠæããããŠã
ããïŒ ããªã«ãŒãããŒãé¡ãèçŽ åããããã¿ã«ã€ã
ãé¡ãçšããŠæ¥çæ§ã«ããããšãç¥ãããŠãã
ïŒç±³åœç¹èš±3873587åç §ïŒã ãã¿ã«ã€ããååç©é¡ãã¢ã«ã«ãªéå±å¡©æ·»å ç©
é¡ãšçµã¿åãããŠäœ¿çšã§ããããšãç¥ãããŠã
ããããã²ã³åããããã¿ã«ã€ããé¡ã ãã䜿çš
ãããïŒãã€ãå ¬éæ现æž2707928ããã€ãå ¬é
æ现æž2740850ããã³ãã€ãå ¬éæ现æž2703710å
ç §ïŒã ããªã«ãŒãããŒãé¡ãåºã«ããéåäœé åç©é¡
ã«æ¥çæ§å å·¥ãäŸããããã«ãäŸãã°ããã²ã³å
ããããã¿ã«ã€ããé¡ã®åŠãææ©ããã²ã³ååç©
é¡ããã¢ã«ã«ãªéå±å¡©é¡ããã³ããªã«ãŒãããŒã
é¡ã®æ»ŽäžåŸåãæžããç©è³ªãšãçµã¿åãããŠäœ¿çš
ã§ããããšãç¥ãããŠããïŒãã€ãå ¬éæ现æž
2918882ããã³ãã€ãå ¬éæ现æž2918883åç §ïŒã åæéç¶è³éŠæããªã«ãŒãããŒãé¡ã®æåçšçµ
æç©é¡ã«ã¢ã«ã«ãªéå±å¡©é¡ããã³ããã²ã³åãã
ããã¿ã«ã€ããé¡ããã³ä»ã®èçŽ å«æç©ãšäžç·ã«
極端ãªç«çæ¡ä»¶çšã®æ¥çå å·¥å€ãäŸããããšãç¥
ãããŠããïŒãã€ãå ¬éæ现æž3203905åç §ïŒã ããããªãããæã ã®æèŠã§ã¯äžèšã®åèæç®
é¡ã¯ïŒïŒåŒã®ãã¿ã«ã€ããé¡ãŸãã¯ããã²ã³ã
å«ãŸãªãããªã«ãŒãããŒãé¡çšã®é²ççžä¹å€ãšã
ãŠã®ãããã®äœ¿çšãäºæž¬ãããã¯ç€ºåããŠã¯ããª
ãã ããã«ãå¡©çŽ ãå«ãŸãªãããã³èçŽ ãå«ãŸãªã
ãã¿ã«ã€ããããã®ããã«å°ãªãééã§æ··åãã
åŸã«ã1/8â³ããã³1/16â³ã®äžŠã³ã«ããã²ã³å«æç
æç©ã®äœ¿çšæã«ã¯1/32â³ã®å£åãã«ãããŠUL94ã«
åŸãççŒåé¡ïŒ¶âïŒã®ããªã«ãŒãããŒãæåçšçµ
æç©é¡ãäŸãããããªæ·»å ç©çµæç©é¡ã¯ãããŸã§
ã«é瀺ãããŠããªãã€ãã æ¬çºæã«åŸã€ãŠç¹èš±è«æ±ãããŠããäžè¬åŒ
ïŒïŒã®ãã¿ã«ã€ããé¡ã®æ··åç©ã¯éåžžã«ç±å®å®
æ§ã§ãããäœãæ®çºæ§ãæããå æ°Žå解ã«å¯ŸããŠ
å®å®ã§ãããããŠå®¹æã«ããªã«ãŒãããŒãäžã«æ··
åã§ããããããããã®çš®é¡ã®ç©è³ªé¡ã¯ç¹ã«æå©
ã§ããã æ¬çºæã®æŠå¿µã«ãããé©åœãªç¡æ©é žé¡ã®ã¢ã«ã«
ãªéå±å¡©é¡ã®äŸã¯ãç¡æ©ãããã³é žé¡ã®ãã®ã§ã
ããæ¬çºæã®æŠå¿µã«ãããç¡æ©ãããã³é žé¡ã¯ã¢
ã«ã«ãªéå±å¡©é¡ã圢æã§ããããã³ã¹ãããé žé¡
ïŒãããã³ã¹ãããé žé¡ããšããèªã«é¢ããŠã¯ãã€
ãŒã¶ãŒã»ã¢ã³ãã»ãã€ãŒã¶ãŒã®ãææ©ååŠãã
1965ã595é ãã€ã³ã¿ãŒãµã€ãšã³ã¹ã»ãããªãã·
ã€ãŒã¹ãããŠãŒãšãŒã¯ãç±³åœåç §ïŒãäŸãã°ã¡ã¿
ãŒããªã«ããŒãŸãã¯ãããŒçé žé¡ããã³ãã«ãªã
éå±é¯ååç©é¡ã®ãããã³é žé¡ãã§ããã æ¬çºæã®æŠå¿µã«ãããé©åœãªææ©é žé¡ã®ã¢ã«ã«
ãªéå±å¡©é¡ã¯ã¢ã«ã«ãªéå±å¡©é¡ã圢æã§ããççŽ
æ°ãå°ãªããšãïŒã®ææ©ããã³ã¹ãããé žé¡ã®ã
ã®ã§ããããã®ãããªä»»æã«çœ®æãããŠããŠãã
ãææ©é žé¡ã¯ãOHâãŸãã¯NHâé žååç©é¡ã
äŸãã°ã¹ã«ãã³é žé¡ããã¹ãã³é žé¡ãããªãã¹ã
ã³é žé¡ããã³NHâé žã¹ã«ãã³ã¢ããé¡ãŸãã¯ã¹
ã«ãã³ã€ããé¡ãã§ããããšãã§ããããããã¯
å°ãªããšãïŒåã®ïŒ£ååãæããŠããªããã°ãªã
ãããããŠå¥œé©ã«ã¯ïŒã30åã®éã®ïŒ£ååãæã
ãããšãã§ããã æ¬çºæã«åŸãé©åœãªã¢ã«ã«ãªéå±å¡©é¡ã¯å¥œé©ã«
ã¯ãå¡©é¡ã®ïŒééïŒ åŒ·åºŠæ°Žæº¶æ¶²ãŸãã¯æžæ¿æ¶²ã«å¯Ÿ
ããŠ20âã§æž¬å®ãããïŒãïŒã®éã®ãç¹ã«6.5ã
7.5ã®éã®ãPHå€ãæããã§ããã 奜é©ãªã¢ã«ã«ãªéå±é¡ã¯ã«ãªãŠã ããããªãŠã
ããã³ãªããŠã å¡©é¡ãç¹ã«ã«ãªãŠã å¡©é¡ãã§ã
ãã 奜é©ãªææ©é žé¡ã®ã¢ã«ã«ãªéå±å¡©é¡ã¯ã«ãªãŠ
ã ããããªãŠã ããã³ãªããŠã å¡©é¡ãç¹ã«ææ©ã¹
ã«ãã³é žé¡ããã³ãã¹ãã³é žé¡ã®ã«ãªãŠã å¡©é¡ã
ã§ãããããã®ææ©åºã¯ä»»æã«äŸãã°åŒçŽ ãå¡©çŽ
ãŸãã¯èçŽ ã®åŠãããã²ã³é¡ã«ãã眮æãããŠã
ãŠããããäŸãšããŠæãããããã®ã¯ããã«ãã«
ãªããã¿ã³ã¹ã«ãã³é žãããªãŠã ãããã¯ã«ãªãŠ
ã ããã«ãã«ãªãã¡ã¿ã³ã¹ã«ãã³é žãããªãŠã ã
ããã¯ã«ãªãŠã ãïŒïŒïŒâãžã¯ãããã³ãŒã³ã¹ã«
ãã³é žãããªãŠã ãããã¯ã«ãªãŠã ãïŒïŒïŒïŒïŒ
âããªã¯ãããã³ãŒã³ã¹ã«ãã³é žãããªãŠã ãã
ãã¯ã«ãªãŠã ãïŒïŒâã¯ããããšãã«ïŒâãã¹ãã³
é žãããªãŠã ãããã¯ã«ãªãŠã ãã¡ãã«âãã¹ã
ã³é žãããªãŠã ãããã¯ã«ãªãŠã ïŒïŒâããšãã«
ãšãã«ïŒâãã¹ãã³é žãããªãŠã ãããã¯ã«ãªãŠ
ã ãããã³ããšãã«âãã¹ãã³é žãªããŠã ã§ã
ãã 奜é©ãªç¡æ©é žé¡ã®ã¢ã«ã«ãªéå±å¡©é¡ã¯ã«ãªãŠ
ã ããããªãŠã ããã³ãªããŠã å¡©é¡ãç¹ã«äŸãã°
ãã«ãªãéå±ååç©é¡ã®åŠããããã³é žé¯äœé¡
ã®ãããã³ã¡ã¿ãŒããªã«ããŒãŸãã¯ãããŒçé žé¡
ã®ã«ãªãŠã å¡©é¡ãã§ããã äŸãšããŠæãããããã®ã¯ããããµãã«ãªãã¢
ã«ãã³é žäžãããªãŠã ãŸãã¯äžã«ãªãŠã ããããµ
ãã«ãªããã¿ã³é žäºãããªãŠã ãŸãã¯äºã«ãªãŠ
ã ããããµãã«ãªãçªé žäºãããªãŠã ãŸãã¯äºã«
ãªãŠã ããããµãã«ãªããžã«ã³ã³é žäºãããªãŠã
ãŸãã¯äºã«ãªãŠã ãããçé žãããªãŠã ãŸãã¯ã«
ãªãŠã ãã¡ã¿çé žãããªãŠã ãŸãã¯ã«ãªãŠã ãã
ãã©ãã«ãªãããŠé žãããªãŠã ãŸãã¯ã«ãªãŠã ã
ãããµãã«ãªãçé žãããªãŠã ãŸãã¯ã«ãªãŠã ã
ããã³çé žãããªãŠã ãã«ãªãŠã ãŸãã¯ãªããŠã
ã§ããã ç¹ã«é©ããŠããå¡©é¡ã¯ããã«ãã«ãªããã¿ã³ã¹
ã«ãã³é žã«ãªãŠã ãŸãã¯ãããªãŠã ãïŒïŒïŒâãž
ã¯ãããã³ãŒã³ã¹ã«ãã³é žã«ãªãŠã ãŸãã¯ãããª
ãŠã ãïŒïŒïŒïŒïŒâããªã¯ãããã³ãŒã³ã¹ã«ãã³
é žã«ãªãŠã ãŸãã¯ãããªãŠã ããããµãã«ãªãã¢
ã«ãã³é žã«ãªãŠã ãããçé žã«ãªãŠã ãã¡ãã«â
ãã¹ãã³é žã«ãªãŠã ããããµãã«ãªã¢ã«ãã³é žã
ããªãŠã ããã³ããšãã«âãã¹ãã³é žãªããŠã ã§
ããã 該塩é¡ã®çžäºæ··åç©é¡ãé©ããŠããã æ¬çºæã®æŠå¿µã§ã¯ããã²ã³ãå«ãŸãªãè³éŠæå
æéç¶ç±å¯å¡æ§ããªã«ãŒãããŒãé¡ãšã¯ãããã²
ã³ãå«ãŸãªããžããšããŒã«é¡ãç¹ã«ããããã·ãž
ã¢ãªãŒã«ã¢ã«ã«ã³é¡ãããã¹ã²ã³ãŸãã¯çé žã®ãž
ãšã¹ãã«é¡ãšåå¿ãããããšã«ããåŸãããéçž®
åç©é¡ã§ãããããã§ã¯æªçœ®æã®ãžããããã·ãž
ã¢ãªãŒã«ã¢ã«ã«ã³é¡ã®ä»ã«ãã¢ãªãŒã«åºãããã
ãã·åºã«é¢ããŠïœâããã³ïŒãŸãã¯ïœâäœçœ®ã«ã¢
ã«ãã«åºãæãããžããããã·ãžã¢ãªãŒã«ã¢ã«ã«
ã³é¡ãé©ããŠããããããã®éçž®åç©é¡ã¯ïŒäœ¿çš
ãããžããšããŒã«é¡ãåºã«ããŠïŒ0.05ã2.0ã¢ã«
ïŒ ã®éã®äžå®èœæ§ä»¥äžã®ååç©é¡ãäŸãã°äžå以
äžã®ããšããŒã«ç³»ããããã·ã«åºãæãããã®ã
ã®æ·»å ã«ããåæéåãããŠããã ãã®åã®ããªã«ãŒãããŒãé¡ããã³ãããã®è£œ
é ã¯äŸãã°ãã€ãå ¬éæ现æž1570533ã1595762ã
21116974ããã³2113347ãè±åœç¹èš±æ现æž
1079821ãç±³åœç¹èš±æ现æž3544514ããã³ãã€ãå ¬
éæ现æž2500092äžã«èšãããŠããã ããã²ã³ãå«ãŸãªãè³éŠæåæéç¶ç±å¯å¡æ§ã
ãªã«ãŒãããŒãé¡ã¯ãCH2Cl2äžã§ã®25âããã³
0.5ïœïŒ100mlã®æ¿åºŠã«ãããçžå¯Ÿçç²åºŠã®æž¬å®ã«
ããé©åœãªæ€åºŠåŸã«æž¬å®ããã15000ã100000ã®
éã®ã奜é©ã«ã¯20000ã80000ã®éã®ãééå¹³åå
åéMwãæããã é©åœãªããã²ã³ãå«ãŸãªããžããšãŒããŒã«é¡ã®
äŸã¯ãããããã·ãã¬ãœã«ã·ããŒã«ãïŒïŒ4â²âãž
ããããã·ãžããšãã«ããã¹âïŒããããã·ããš
ãã«ïŒâã¢ã«ã«ã³é¡ãäŸãã°C1âC8âã¢ã«ãã¬ã³
âãŸãã¯C2âC8âã¢ã«ããªãã³âãã¹ããšããŒ
ã«é¡ããã¹âïŒããããã·ããšãã«ïŒâã·ã¯ãã¢ã«
ã«ã³é¡ãäŸãã°C5âC15âã·ã¯ãã¢ã«ãã¬ã³âãŸ
ãã¯C5âC15âã·ã¯ãã¢ã«ããªãã³âãã¹ããšã
ãŒã«é¡ãããã³ãã¹ïŒããããã·ããšãã«ïŒã¹ã«
ãã€ãé¡ããšãŒãã«é¡ãã±ãã³é¡ãã¹ã«ããã·ã
é¡ãŸãã¯ã¹ã«ãã³é¡ã䞊ã³ã«Î±ïŒÎ±â²âãã¹âïŒã
ãããã·ããšãã«ïŒâãžã€ãœãããã«ãã³ãŒã³ã
ãã³å¯Ÿå¿ããæ žâã¢ã«ãã«åãããååç©é¡ã§ã
ããïŒïŒïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâ
ãããã³ïŒãã¹ããšããŒã«ïŒ¡ïŒãïŒïŒïŒâãã¹
ïŒïŒâããããã·âïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâ
ãããã³ïŒããã©ã¡ãã«ãã¹ããšããŒã«ïŒ¡ïŒãŸã
ã¯ïŒïŒïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâã·
ã¯ããããµã³ïŒãã¹ããšããŒã«ïŒºïŒãåºã«ããã
ãªã«ãŒãããŒãé¡äžŠã³ã«äžæ žæ§ãã¹ããšããŒã«
é¡ãäŸãã°Î±ïŒÎ±â²âãã¹âïŒïŒâããããã·ããš
ãã«ïŒâïœâãžã€ãœãããã«ãã³ãŒã³ããåºã«ã
ããã®ã奜é©ã§ããã ããªã«ãŒãããŒãé¡ã®è£œé çšã«é©ããŠããä»ã®
ããã²ã³ãå«ãŸãªããžããšããŒã«é¡ã¯ç±³åœç¹èš±æ
现æž3028365ããã³3275601äžã«èšãããŠããã äžå以äžã®ããšããŒã«ç³»ããããã·åºãæãã
䜿çšã§ããååç©é¡ã®ããã€ãã®äŸã¯ããããã°
ã«ã·ããŒã«ãïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒâã
ãªâïŒïŒâããããã·ããšãã«ïŒâãããâïŒâãš
ã³ïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒâããªâïŒïŒ
âããããã·ããšãã«ïŒâããã¿ã³ãïŒïŒïŒïŒïŒ
âããªâïŒïŒâããããã·ããšãã«ïŒâãã³ãŒã³ã
ïŒïŒïŒïŒïŒâããªâïŒïŒâããããã·ããšãã«ïŒâ
ãšã¿ã³ãããªâïŒïŒâããããã·ããšãã«ïŒâããš
ãã«ã¡ã¿ã³ãïŒïŒïŒâãã¹âïŒïŒïŒïŒâãã¹â
ïŒïŒâããããã·ããšãã«ïŒâã·ã¯ãããã·ã«ïŒã
ããã³ãïŒïŒïŒâãã¹âïŒïŒâããããã·ããšã
ã«âã€ãœãããã«ïŒããšããŒã«ãïŒïŒïŒâãã¹â
ïŒ2â²âããããã·â5â²âã¡ãã«âãã³ãžã«ïŒâïŒâ
ã¡ãã«ããšããŒã«ãïŒâïŒïŒâããããã·ããšã
ã«ïŒâïŒâïŒïŒïŒïŒâãžããããã·ããšãã«ïŒâã
ããã³ããããµâïŒïŒâïŒïŒâããããã·ããšãã«
âã€ãœãããã«ïŒâããšãã«ïŒâãªã«ãâãã¬ãã¿
ã«é žãšã¹ãã«ãããã©âïŒïŒâããããã·ããšã
ã«ïŒâã¡ã¿ã³ãããã©âïŒïŒâïŒïŒâããããã·ã
ãšãã«âã€ãœãããã«ïŒâããšããã·ïŒâã¡ã¿ã³ã
ãã³ïŒïŒïŒâãã¹âïŒïŒ4â²ïŒ4â³âãžããããã·ããª
ããšãã«ïŒâã¡ãã«ïŒâãã³ãŒã³ã§ãããä»ã®äžå®
èœæ§ååç©é¡ã¯ãïŒïŒïŒâãžããããã·å®æ¯éŠ
é žãããªã¡ã·ã³é žãå¡©åã·ã¢ãã«ãïŒïŒïŒâãã¹
âïŒïŒâããããã·ããšãã«ïŒâïŒâãªããœâïŒïŒ
ïŒâãžãããã€ã³ããŒã«ããã³ïŒïŒïŒâãã¹â
ïŒïŒâããããã·âïŒâã¡ãã«âããšãã«ïŒâïŒâ
ãªããœâïŒïŒïŒâãžãããã€ã³ããŒã«ã§ããã ååéçé·ã調æŽããããã®é©åœãªéåæ¢å€é¡
ã¯äŸãã°ãå ¬ç¥ã®éã§äœ¿çšãããå ¬ç¥ã®ããšããŒ
ã«ããã³ã¢ã«ãã«ããšããŒã«é¡ã§ããã è³éŠæåæéç¶ç±å¯å¡æ§ããªã«ãŒãããŒãé¡
ã¯ãäŸãã°çžå¢çæ¹æ³ã«ãããŸãã¯å質溶質溶液
äžã§ã®æ¹æ³ã®åŠãå ¬ç¥ã®æ¹æ³ã«ããã補é ãã
ããè³éŠæç±å¯å¡æ§ããªã«ãŒãããŒãé¡ã¯å ¬ç¥ã®
ãšã¹ãã«äº€ææ¹æ³ã«ãã€ãŠã補é ã§ããã æ¬çºæã®æŠå¿µã«ãããŠç¹ã«å¥œé©ãªããªã«ãŒãã
ãŒãé¡ã¯ãïŒã¢ã«ã®ãã¹ããšããŒã«ïŒ¡ãåºã«ããŠ
0.3ã1.0ã¢ã«ïŒ ã®åæéåå€ãæãããã¹ããšã
ãŒã«ïŒ¡ãåºã«ããåæéç¶ããªã«ãŒãããŒãé¡ã§
ããã åŒã®é©åœãªã¢ãã³ã¯ ã§ããã ãã®ååç©ã¯ç±³åœç¹èš±æ现æž3753679äžã«èšã
ããŠããã åŒã®é©åœãªãã¿ã«ã€ããååç©é¡ã¯ã ããã³ ã§ããã ãããã®ååç©é¡ã¯å®æœäŸäžã®æ¹æ³ã«ããäžèš
ã®äžè¬çå·¥çšæ¡ä»¶äžã§è£œé ã§ããã æ¬çºæã«åŸãé²çœå å·¥å€é¡ã¯åã ã®æåé¡ãŸã
ã¯æ¿çž®ç©ãããªã«ãŒãããŒãäžã«æ··åããããšã«
ããäºã補é ããããšãã§ãããããŠäœ¿çšæãŸã§
貯èµããããšãã§ããã æ°èŠãªé²çœå å·¥å€çµæç©ã¯ããªã«ãŒãããŒãé¡
äžã«ãããã®åå¥æå圢ã§ãŸãã¯äžç·ã«ããŠãäŸ
ãã°æ··åããã®åŸ270â280âã«ãããŠïŒâã¹ã¯ãª
ãŠãŒæŒåºåšãéããŠç©è³ªãé¡ç²ã«ããããšã«ãã
å ããããšãã§ããã ããªã«ãŒãããŒããšé²çå å·¥å€çµæç©ãåºã«ã
ãæ¬çºæã«åŸãæåçšçµæç©é¡ã¯ãããªã«ãŒãã
ãŒãååŠã«ãããŠäžè¬çãªä»ã®æ·»å ç©é¡ãäŸãã°
é¡æãææãå å¡«æãå®å®å€ãŸãã¯åæãå€ãã
å«æã§ããã æ¬çºæã«åŸãæåçšçµæç©é¡ã¯æååé¡ãŸãã¯
ãã€ã«ã é¡ã«å å·¥ã§ããã æååé¡ã¯300â310âã®æž©åºŠã«ãããå°åºæå
æ¹æ³ã«ãã補é ãããã æ¬çºæã«åŸãæåçšçµæç©é¡ã¯äŸãã°é»æ°åé
ã«ãããŠã¹ã€ããã·ãŒã«ãããœã±ããããœã±ãã
ããã«ãã¹ã€ããããã¯ã¹çšãªã©ã«ã家å®çšåå
éã«ãããŠäœå® éšåçšã«ãã¢ã€ãã³ããã³ã³ãŒã
ãŒæ©æ¢°çšã«ã䞊ã³ã«å€ãã®é©çšåéã«ãããŠäŸã
ã°ã³ã³ããŠãŒã¿ãŒããŠãžã³ã°éšåçšã«äœ¿çšã§ã
ãã ççŒè©Šéšã®èšèŒ UL94è©ŠéšïŒã¢ã³ããŒã©ã€ã¿ãŒã¹ã»ã©ãã©ããª
ã€ã¹ã»ã€ã³ã³ãŒãã¬ãŒãããïŒã«åŸããããªã«ãŒ
ãããŒãè©Šæã127Ã12.7Ã3.2ïŒãŸãã¯1.6ãŸãã¯
0.8ïŒmm5.00Ã0.5Ã1/8ïŒãŸãã¯1/16ãŸãã¯1/3
ïŒïŒã€ã³ãã®å¯žæ³ãæããæ£ç¶ã«æåãããè©Š
éšçã®äžåŽãå 垯ç©è³ªçã®305mmäžã«ããããã«
æ£ãåçŽã«çœ®ãããåè©Šéšæ£ã10ç§éæç¶ããïŒ
åã®é£ç¶ççºç«æäœã«ããåã ã«çºç«ãããåçº
ç«æäœåŸã«ççŒç¹æ§ã芳å¯ãã次ã«è©Šæãè©äŸ¡ã
ãã3.73Ã104kJïŒm3ïŒ1.000BTUïŒå¹³æ¹ãã€ãŒ
ãïŒã®ç±å«æéãæãã10mmïŒ3/8ã€ã³ãïŒã®é«
ãã®å€©çã¬ã¹ã®éãçãçãããã³ãŒã³ã»ããŒã
ãŒãè©Šæã®çºç«çšã«äœ¿çšããã UL94VâïŒåé¡ã¯ãUL94ä»æ§ã«åŸãè©Šéšãã
ç©è³ªã®äžèšã®æ§è³ªã«é¢ãããã®ã§ããããã®åé¡
ã®ããªã«ãŒãããŒãã¯åè©Šéšçã®äœçšåŸã«10ç§ä»¥
äžçããè©Šæãå«ãã§ãããããããã¯äžçµã®è©Š
æã«å¯Ÿããäºåã®äœçšã«å¯ŸããŠã¯50ç§ä»¥äžã®åèš
ççŒæéã瀺ããããããã¯è©Šæã®äžç«¯ã«ä»ããŠ
ããæ¯æã¯ã©ã³ããŸã§å®å šã«ççŒããè©Šæãå«ã
ã§ãããããããã¯ççŒæ»ŽãŸãã¯ç²åã«ããè©Šæ
ã®äžã«çœ®ãããŠããã³ããã³ãŠãŒã«ãçºç«ããã
è©Šæãå«ãã§ãããããããã¯ãŸãè©Šéšçãé€ã
ãåŸã«30ç§ä»¥äžèµ€ç±ïŒglowïŒããŠããè©Šæãå«
ãã§ããªãã€ãã ä»ã®UL94åé¡ã¯ãããããæ¥çæ§ããã³èªå·±
æ¶ç«æ§ãå°ãããç滎ãŸãã¯ç²åãçããè©Šæã
è¡šãããŠããããããã®åé¡ã¯UL94VâïŒãã
ã³ïŒ¶âïŒãšè¡šç€ºãããã æ¬çºæã®ç¯å²å ã®ããªã«ãŒãããŒãé¡ã¯ç¹åŸŽç
ã«UL94VâïŒåé¡çšã«å¿ èŠãªæ§è³ªã瀺ããŠããã å®æœäŸ  åŒïŒïŒã®ãã¿ã«ã€ããé¡ã®è£œé  ïŒ ç¡æ°Žããã©ã¯ãããã¿ã«é žã䜿çšããäž
è¬åŒïŒïŒã®ãã¿ã«ã€ããã®è£œé æåã«1600mlã®æ°·é ¢é žãã枩床èšãæ¹æåšã
ãã³æ°Žåé¢åšãåããäžéŠãã©ã¹ã³äžã«å ãã
ãããŠ55âã«æããã次ã«171.6ïœïŒ0.6ã¢ã«ïŒ
ã®ç¡æ°Žããã©ã¯ãããã¿ã«é žããã³157.8ïœ
ïŒ0.6ã¢ã«ïŒã®ïŒâã¢ããâïŒâã¡ããã·âãžã
ãšãã«ã¹ã«ãã³ã®æ··åç©ãå ãããããŠæ··åç©
ãæ¿ããæ¹æãããåå¿æ··åç©ã118âã«ãã
ãŠéæµäžã§2.5æéä¿ã¡ã次ã«å·åŽããã150ml
ã®ã·ã¯ããããµã³ã®æ·»å åŸã«ãåå¿æ··åç©ãç°
æµäžã§ïŒæéä¿ã¡ããã®éã«åå¿æ°Žã¯æ°Žåé¢åš
äžã§é€å»ã§ããã çæããåºäœãç±æã«åžåŒæ¿Ÿå¥ããæ°·é ¢é žã§
æŽæµããç±ãã¢ã»ãã³äžã«æžæ¿ããããããŠä¹Ÿ
ç¥ããã ïŒ ïŒ® çè«å€ïŒ2.64ïŒ ïŒ ïŒ£ çè«å€ïŒ47.5ïŒ
ïŒ ïŒš çè«å€ïŒ2.1ïŒ ïŒ Cl çè«å€ïŒ26.7ã ïŒ ïŒ® å®æž¬å€ïŒ2.86ïŒ ïŒ ïŒ£ å®æž¬å€ïŒ47.5ïŒ
ïŒ ïŒš å®æž¬å€ïŒ2.05ïŒ ïŒ Cl å®æž¬å€ïŒ
26.5ã  ïŒ ç¡æ°Žãã¿ã«é žã䜿çšããäžè¬åŒïŒïŒã®
ãã¿ã«ã€ããã®è£œé ç¡æ°Žãã¿ã«é žã䜿çšããŠA1ã«åŸããã¿ã«ã€
ããã補é ããã ïŒ ïŒ® çè«å€ïŒ3.56ïŒ ïŒ ïŒ£ çè«å€ïŒ64.1ïŒ
ïŒ ïŒš çè«å€ïŒ3.82 ïŒ ïŒ® å®æž¬å€ïŒ3.54ïŒïŒ  å®æž¬å€ïŒ64.0ïŒ
ïŒ ïŒš å®æž¬å€ïŒ3.84ã  æ¥çæ§ã®åæéç¶ããªã«ãŒãããŒãé¡ ïŒCH2Cl2äžã§25âããã³0.5gïŒ100mlã®æ¿åºŠã«
ãããŠæž¬å®ãããïŒ1.31ã®æº¶æ¶²ç²åºŠãæãããã
ã¹ããšããŒã«ïŒ¡ã0.5ã¢ã«ïŒ ã®ïŒïŒïŒâãã¹âïŒïŒ
âããããã·âïŒâã¡ãã«ããšãã«ïŒâïŒâãªã
ãœâïŒïŒïŒâãžãããã€ã³ããŒã«ã3.0ã¢ã«ïŒ ã®
éåæ¢å€ãšããŠã®ããšããŒã«ãããã³ãã¹ã²ã³ã
åºã«ããåæéç¶ã®ããªã«ãŒãããŒãã0.1ïŒ ã®
ïœâãã«ãã«ãªããã¿ã³ã¹ã«ãã³é žã®ïŒ«å¡©ãšãŸã
ã¯æ¬çºæã«åŸããã¿ã«ã€ããé¡ãšæ··åããæ··åç©
ãæŒåºãããããŠããã®æ¥çæ§ã3.2mmã1.6mmã
ãã³0.8mmã®åãã«ãããŠUL94ã«åŸãè©Šéšããã äžè¡šã«çµæã瀺ãïŒ å®æœäŸïŒ
瀺ããã㊠ïœã¯ïŒãŸãã¯ïŒã瀺ã ã®ãã¿ã«ã€ããååç©é¡ã«é¢ãããã®ã§ããã æ¬çºæã¯ãŸããåŒïŒïŒ åŒäžã ã¯åŒïŒïŒã®å Žåã«ç€ºãããŠããæå³ãæã
ã ã®ç¡æ°Žãã¿ã«é žãäžè¬åŒïŒïŒ åŒäžãïœã¯ïŒãŸãã¯ïŒã瀺ã ã®ã¢ãã³ãšå®è³ªçã«çã¢ã«éã§117âã«ãããŠã
溶åªãšããŠã®æ°·é ¢é žããã³æ°Žâæ æå€ãšããŠã®ã·
ã¯ããããµã³ã䜿çšããŠåå¿ããããåŒïŒïŒã®
ãã¿ã«ã€ããé¡ã®è£œé æ¹æ³ã«ãé¢ãããã®ã§ã
ãã åŒïŒïŒã®ã¢ãã³é¡ã¯æç®ããå ¬ç¥ã§ããã
ïŒäŸãã°ç±³åœç¹èš±æ现æž3753679åç §ïŒããŸãã¯ã
ãã«èšèŒãããŠããæ¹æ³ã«ããåŸãããã 溶åªã®äœ¿çšéã¯ïŒã¢ã«ã®äœ¿çšããã¢ãã³åœãã
çŽ2.5ã3.0ãªããã«ã§ãããæ°Žâæ æå€ã®éã¯ïŒ
ã¢ã«ã®ã¢ãã³åœããçŽ250â300mlã§ããã æ°èŠãªãã¿ã«ã€ããååç©é¡ã¯ãããªã«ãŒãã
ãŒãé¡çšã®å ¬ç¥ã®é²çå å·¥å€é¡ïŒflameproofing
agentsïŒãããªãã¡ææ©ãããã¯ç¡æ©é žé¡ã®ã¢ã«
ã«ãªéå±å¡©é¡ããšçµåããããšãããã²ã³ãå«ãŸ
ãªãããšããŒã«ç³»æåããã ã補é ãããç±å¯å¡
æ§è³éŠæããªã«ãŒãããŒãé¡ã®æ¥ççïŒflameâ
repellencyïŒãæ¹è¯ããã®ã«é©ããŠããçžä¹å€ãš
ãªãã åŸã€ãŠãæ¬çºæã¯ ïœ 0.1ãïŒéééšã®åŒïŒïŒã®ãã¿ã«ã€ããã
ããã³ ïœ 0.02ãïŒéééšã®ææ©ãããã¯ç¡æ©é žã®ã¢ã«
ã«ãªéå±å¡©ãç¹ã«ãããªãŠã ãã«ãªãŠã ãŸãã¯
ãªããŠã å¡©ã ãããªãé²çå å·¥å€çµæç©ã«ãé¢ãããã®ã§ã
ãã é²çå å·¥å€ãšããŠé©ããŠããææ©ãããã¯ç¡æ©
é žã®ã¢ã«ã«ãªéå±å¡©é¡ã¯äŸãã°ãã€ãå ¬éæ现æž
2703710ã2918882ããã³2918883äžã«èšãããŠã
ãã æ¬çºæãŸãã¯ãããã²ã³ãå«ãŸãªãããšããŒã«
ç³»æåé¡ã®ç±å¯å¡æ§åæéç¶è³éŠæããªã«ãŒãã
ãŒãã«ãããªã«ãŒãããŒããåºã«ããŠ0.1ãïŒé
éïŒ ã®éã®åŒïŒïŒã®ãã¿ã«ã€ãããããã³0.02
ãïŒééïŒ ã®ææ©ãããã¯ç¡æ©é žã®ã¢ã«ã«ãªéå±
å¡©ãåºã«ããæ¥çå å·¥ãæœãããã®æ¬çºæã«åŸã
é²çå å·¥å€ã®äœ¿çšã«ãé¢ãããã®ã§ããã æ¬çºæã¯ããã«ãé²çå å·¥å€ãæ··åãããã®åŸ
270â300âã®ã奜é©ã«ã¯270â280âã®ãç©è³ªæž©åºŠ
ã«ãããŠïŒâã¹ã¯ãªãŠãŒæŒåºåšãéããŠé¡ç²åã
ãããšãç¹åŸŽãšãããããã²ã³ãå«ãŸãªãããšã
ãŒã«åœ¢æåé¡ã®ç±å¯å¡æ§åæéç¶è³éŠæããªã«ãŒ
ãããŒãã«æ¥çå å·¥ãæœãæ¹æ³ã«ãé¢ãããã®ã§
ããã æé©ãªåŠçæ¡ä»¶ã¯ã40ã80å転ïŒåã®å転é床
ã«ãããŠãå®è³ªçã«18KgïŒæã®çç£éãåŸããã
ãããªãã®ã§ããã 䜿çšãããïŒâã¹ã¯ãªãŠãŒæŒåºåšã¯ãZSK53
ã®è¡šç€ºã®ã¯ãŒããŒã»ãŠã³ãã»ãã¬ã€ãã©ãŒè£œã®è£
眮ã§ããã æ¬çºæã¯ãŸããããã²ã³ãå«ãŸãªãããšããŒã«
ç³»æåé¡ã®ä»ã®æ·»å ç©é¡ãå«ãŸãªãç±å¯å¡æ§åæ
éç¶è³éŠæããªã«ãŒãããŒããåºã«ããŠ0.1ãïŒ
ééïŒ ã®éã®åŒïŒïŒã®ãã¿ã«ã€ããããã³0.02
ãïŒééïŒ ã®ææ©ãããã¯ç¡æ©é žã®ã¢ã«ã«ãªéå±
å¡©ãå«ãã§ããã該ããªã«ãŒãããŒããåºã«ãã
ç±å¯å¡æ§æåçšçµæç©é¡ã«ãé¢ãããã®ã§ããã ããã²ã³ãå«ãŸãªãããšããŒã«ç³»æåé¡ã®ç±å¯
å¡æ§åæéç¶è³éŠæããªã«ãŒãããŒãé¡ãšã¯ãã
ãªã«ãŒãããŒãé¡ã®è£œé çšã«äœ¿çšããããžããšã
ãŒã«é¡ãã¢ãããšããŒã«é¡ããã³ããªã¹ããšããŒ
ã«é¡ãããã©ããšããŒã«é¡ãŸãã¯ä»ã®åæéåå€
ãããã²ã³çœ®æåºãæããŠããªãããšãæå³ãã
ãšç解ãã¹ãã§ããããããã®ããªã«ãŒãããŒã
é¡ã¯ãã¡ãããäŸãã°ãã¹ã²ã³ã䜿çšããçžå¢ç
æ¹æ³ã«ãããããã補é ãããå Žåã«æ®åããŠã
ãå°ãªãppméã®å æ°Žå解ãããŠããªãå¡©çŽ ãäŸ
ç¶ãšããŠå«æããŠããããšãããã以äžã®ããã
ã²ã³ãå«ãŸãªããããªã«ãŒãããŒãé¡ã®å®çŸ©ã§
ã¯ããã®æ¹æ³ã§å æ°Žå解ã§ããããã²ã³ã®æ®æž£ã¯
èæ ®ã«ãããªããŠããã ãããã®æ°èŠãªé²çœå å·¥å€ã®äœ¿çšã«ãã
UL94VâïŒåé¡ã®é²çå å·¥ããªã«ãŒãããŒãé¡
ãåŸãããããã®ããã«ããŠæ¬çºæã«åŸãããã²
ã³ãå«ãŸãªããã¿ã«ã€ããé¡ãçšããããšã«ã
ãã1.6mmã®å£åãã§ïŒ¶âïŒã®C1ããã³Brâãå«
ãŸãªãé²çå å·¥ããªã«ãŒãããŒãé¡ãåŸãããã
âïŒã¯ããã²ã³å«æååç©ã䜿çšãããš0.8mm
ã®å£åãã§åŸããããããã«ãæ¬çºæã«åŸãåŒ
ïŒïŒã®ãã¿ã«ã€ããé¡ã¯éåžžã®ããªã«ãŒãããŒ
ãå å·¥æ¡ä»¶äžã«ãããäœæ®çºæ§ã«ãã€ãŠãç¹åŸŽã¥
ããããŠããã ãããã®ããªã«ãŒãããŒãæåçšçµæç©é¡ã¯ã
127Ã12.7Ã3.2mmïŒ1/8â³ïŒãŸãã¯127Ã12.7Ã1.6
mmïŒ1/16â³ïŒãŸãã¯127Ã12.7Ã0.8mmïŒ1/32â³ïŒã®
寞æ³ãæããè©Šéšçäžã§ã¢ã³ããŒã©ã€ã¿ãŒã¹ã»ã©
ãã©ããªã€ã¹ã»ã€ã³ã³ãŒãã¬ãŒããããããªãã³
94ã®ç©è³ªåé¡ã«é¢ããççŒè©ŠéšïŒä»¥äžã§ã¯UL94
ãšç§°ããïŒã«åŸãççŒåé¡ïŒ¶âïŒãããªãã¡æ»Žäž
ãããããå¹³åïŒç§ããçãåŸâççŒæéãæã
ãåé¡ããåŸãã ããªã«ãŒãããŒãã®æ¥çæ§ã¯ã¢ã«ã«ãªéå±å¡©é¡
ã®æ·»å ã«ããæ¹è¯ã§ããããšã¯ç¥ãããŠãããã
ãã§ããªã«ãŒãããŒãé¡ã¯ããã²ã³ãå«ãŸãªãã
ã®ã§ããŸãã¯ããã²ã³â眮æãããŠãããã®ã§ã
ãããïŒäŸãã°ãã€ãå ¬éæ现æž1930257ããã€ã
å ¬éæ现æž2049358ããã€ãå ¬éæ现æž2112987ã
ãã€ãå ¬éæ现æž2149311ããã€ãå ¬éæ现æž
2253072䞊ã³ã«ãã€ãå ¬éæ现æž2458968ã
2461063ã2461146ããã³2461077åç §ïŒã ããªã«ãŒãããŒãé¡ã®æ¥çæ§ã¯ææ©å¡©çŽ ååç©
é¡ãšããçš®ã®ç¡æ©å¡©é¡ãšã®æ··åç©ã®æ·»å ã«ããæ¹
è¯ã§ããããšãç¥ãããŠããïŒäŸãã°ãã€ãå ¬é
æ现æž2013496åç §ãç¹ã«ç¡æ°Žããã©ã¯ãããã¿
ã«é žãé©åœãªææ©å¡©çŽ ååç©ãšããŠæããããŠã
ããïŒ ããªã«ãŒãããŒãé¡ãèçŽ åããããã¿ã«ã€ã
ãé¡ãçšããŠæ¥çæ§ã«ããããšãç¥ãããŠãã
ïŒç±³åœç¹èš±3873587åç §ïŒã ãã¿ã«ã€ããååç©é¡ãã¢ã«ã«ãªéå±å¡©æ·»å ç©
é¡ãšçµã¿åãããŠäœ¿çšã§ããããšãç¥ãããŠã
ããããã²ã³åããããã¿ã«ã€ããé¡ã ãã䜿çš
ãããïŒãã€ãå ¬éæ现æž2707928ããã€ãå ¬é
æ现æž2740850ããã³ãã€ãå ¬éæ现æž2703710å
ç §ïŒã ããªã«ãŒãããŒãé¡ãåºã«ããéåäœé åç©é¡
ã«æ¥çæ§å å·¥ãäŸããããã«ãäŸãã°ããã²ã³å
ããããã¿ã«ã€ããé¡ã®åŠãææ©ããã²ã³ååç©
é¡ããã¢ã«ã«ãªéå±å¡©é¡ããã³ããªã«ãŒãããŒã
é¡ã®æ»ŽäžåŸåãæžããç©è³ªãšãçµã¿åãããŠäœ¿çš
ã§ããããšãç¥ãããŠããïŒãã€ãå ¬éæ现æž
2918882ããã³ãã€ãå ¬éæ现æž2918883åç §ïŒã åæéç¶è³éŠæããªã«ãŒãããŒãé¡ã®æåçšçµ
æç©é¡ã«ã¢ã«ã«ãªéå±å¡©é¡ããã³ããã²ã³åãã
ããã¿ã«ã€ããé¡ããã³ä»ã®èçŽ å«æç©ãšäžç·ã«
極端ãªç«çæ¡ä»¶çšã®æ¥çå å·¥å€ãäŸããããšãç¥
ãããŠããïŒãã€ãå ¬éæ现æž3203905åç §ïŒã ããããªãããæã ã®æèŠã§ã¯äžèšã®åèæç®
é¡ã¯ïŒïŒåŒã®ãã¿ã«ã€ããé¡ãŸãã¯ããã²ã³ã
å«ãŸãªãããªã«ãŒãããŒãé¡çšã®é²ççžä¹å€ãšã
ãŠã®ãããã®äœ¿çšãäºæž¬ãããã¯ç€ºåããŠã¯ããª
ãã ããã«ãå¡©çŽ ãå«ãŸãªãããã³èçŽ ãå«ãŸãªã
ãã¿ã«ã€ããããã®ããã«å°ãªãééã§æ··åãã
åŸã«ã1/8â³ããã³1/16â³ã®äžŠã³ã«ããã²ã³å«æç
æç©ã®äœ¿çšæã«ã¯1/32â³ã®å£åãã«ãããŠUL94ã«
åŸãççŒåé¡ïŒ¶âïŒã®ããªã«ãŒãããŒãæåçšçµ
æç©é¡ãäŸãããããªæ·»å ç©çµæç©é¡ã¯ãããŸã§
ã«é瀺ãããŠããªãã€ãã æ¬çºæã«åŸã€ãŠç¹èš±è«æ±ãããŠããäžè¬åŒ
ïŒïŒã®ãã¿ã«ã€ããé¡ã®æ··åç©ã¯éåžžã«ç±å®å®
æ§ã§ãããäœãæ®çºæ§ãæããå æ°Žå解ã«å¯ŸããŠ
å®å®ã§ãããããŠå®¹æã«ããªã«ãŒãããŒãäžã«æ··
åã§ããããããããã®çš®é¡ã®ç©è³ªé¡ã¯ç¹ã«æå©
ã§ããã æ¬çºæã®æŠå¿µã«ãããé©åœãªç¡æ©é žé¡ã®ã¢ã«ã«
ãªéå±å¡©é¡ã®äŸã¯ãç¡æ©ãããã³é žé¡ã®ãã®ã§ã
ããæ¬çºæã®æŠå¿µã«ãããç¡æ©ãããã³é žé¡ã¯ã¢
ã«ã«ãªéå±å¡©é¡ã圢æã§ããããã³ã¹ãããé žé¡
ïŒãããã³ã¹ãããé žé¡ããšããèªã«é¢ããŠã¯ãã€
ãŒã¶ãŒã»ã¢ã³ãã»ãã€ãŒã¶ãŒã®ãææ©ååŠãã
1965ã595é ãã€ã³ã¿ãŒãµã€ãšã³ã¹ã»ãããªãã·
ã€ãŒã¹ãããŠãŒãšãŒã¯ãç±³åœåç §ïŒãäŸãã°ã¡ã¿
ãŒããªã«ããŒãŸãã¯ãããŒçé žé¡ããã³ãã«ãªã
éå±é¯ååç©é¡ã®ãããã³é žé¡ãã§ããã æ¬çºæã®æŠå¿µã«ãããé©åœãªææ©é žé¡ã®ã¢ã«ã«
ãªéå±å¡©é¡ã¯ã¢ã«ã«ãªéå±å¡©é¡ã圢æã§ããççŽ
æ°ãå°ãªããšãïŒã®ææ©ããã³ã¹ãããé žé¡ã®ã
ã®ã§ããããã®ãããªä»»æã«çœ®æãããŠããŠãã
ãææ©é žé¡ã¯ãOHâãŸãã¯NHâé žååç©é¡ã
äŸãã°ã¹ã«ãã³é žé¡ããã¹ãã³é žé¡ãããªãã¹ã
ã³é žé¡ããã³NHâé žã¹ã«ãã³ã¢ããé¡ãŸãã¯ã¹
ã«ãã³ã€ããé¡ãã§ããããšãã§ããããããã¯
å°ãªããšãïŒåã®ïŒ£ååãæããŠããªããã°ãªã
ãããããŠå¥œé©ã«ã¯ïŒã30åã®éã®ïŒ£ååãæã
ãããšãã§ããã æ¬çºæã«åŸãé©åœãªã¢ã«ã«ãªéå±å¡©é¡ã¯å¥œé©ã«
ã¯ãå¡©é¡ã®ïŒééïŒ åŒ·åºŠæ°Žæº¶æ¶²ãŸãã¯æžæ¿æ¶²ã«å¯Ÿ
ããŠ20âã§æž¬å®ãããïŒãïŒã®éã®ãç¹ã«6.5ã
7.5ã®éã®ãPHå€ãæããã§ããã 奜é©ãªã¢ã«ã«ãªéå±é¡ã¯ã«ãªãŠã ããããªãŠã
ããã³ãªããŠã å¡©é¡ãç¹ã«ã«ãªãŠã å¡©é¡ãã§ã
ãã 奜é©ãªææ©é žé¡ã®ã¢ã«ã«ãªéå±å¡©é¡ã¯ã«ãªãŠ
ã ããããªãŠã ããã³ãªããŠã å¡©é¡ãç¹ã«ææ©ã¹
ã«ãã³é žé¡ããã³ãã¹ãã³é žé¡ã®ã«ãªãŠã å¡©é¡ã
ã§ãããããã®ææ©åºã¯ä»»æã«äŸãã°åŒçŽ ãå¡©çŽ
ãŸãã¯èçŽ ã®åŠãããã²ã³é¡ã«ãã眮æãããŠã
ãŠããããäŸãšããŠæãããããã®ã¯ããã«ãã«
ãªããã¿ã³ã¹ã«ãã³é žãããªãŠã ãããã¯ã«ãªãŠ
ã ããã«ãã«ãªãã¡ã¿ã³ã¹ã«ãã³é žãããªãŠã ã
ããã¯ã«ãªãŠã ãïŒïŒïŒâãžã¯ãããã³ãŒã³ã¹ã«
ãã³é žãããªãŠã ãããã¯ã«ãªãŠã ãïŒïŒïŒïŒïŒ
âããªã¯ãããã³ãŒã³ã¹ã«ãã³é žãããªãŠã ãã
ãã¯ã«ãªãŠã ãïŒïŒâã¯ããããšãã«ïŒâãã¹ãã³
é žãããªãŠã ãããã¯ã«ãªãŠã ãã¡ãã«âãã¹ã
ã³é žãããªãŠã ãããã¯ã«ãªãŠã ïŒïŒâããšãã«
ãšãã«ïŒâãã¹ãã³é žãããªãŠã ãããã¯ã«ãªãŠ
ã ãããã³ããšãã«âãã¹ãã³é žãªããŠã ã§ã
ãã 奜é©ãªç¡æ©é žé¡ã®ã¢ã«ã«ãªéå±å¡©é¡ã¯ã«ãªãŠ
ã ããããªãŠã ããã³ãªããŠã å¡©é¡ãç¹ã«äŸãã°
ãã«ãªãéå±ååç©é¡ã®åŠããããã³é žé¯äœé¡
ã®ãããã³ã¡ã¿ãŒããªã«ããŒãŸãã¯ãããŒçé žé¡
ã®ã«ãªãŠã å¡©é¡ãã§ããã äŸãšããŠæãããããã®ã¯ããããµãã«ãªãã¢
ã«ãã³é žäžãããªãŠã ãŸãã¯äžã«ãªãŠã ããããµ
ãã«ãªããã¿ã³é žäºãããªãŠã ãŸãã¯äºã«ãªãŠ
ã ããããµãã«ãªãçªé žäºãããªãŠã ãŸãã¯äºã«
ãªãŠã ããããµãã«ãªããžã«ã³ã³é žäºãããªãŠã
ãŸãã¯äºã«ãªãŠã ãããçé žãããªãŠã ãŸãã¯ã«
ãªãŠã ãã¡ã¿çé žãããªãŠã ãŸãã¯ã«ãªãŠã ãã
ãã©ãã«ãªãããŠé žãããªãŠã ãŸãã¯ã«ãªãŠã ã
ãããµãã«ãªãçé žãããªãŠã ãŸãã¯ã«ãªãŠã ã
ããã³çé žãããªãŠã ãã«ãªãŠã ãŸãã¯ãªããŠã
ã§ããã ç¹ã«é©ããŠããå¡©é¡ã¯ããã«ãã«ãªããã¿ã³ã¹
ã«ãã³é žã«ãªãŠã ãŸãã¯ãããªãŠã ãïŒïŒïŒâãž
ã¯ãããã³ãŒã³ã¹ã«ãã³é žã«ãªãŠã ãŸãã¯ãããª
ãŠã ãïŒïŒïŒïŒïŒâããªã¯ãããã³ãŒã³ã¹ã«ãã³
é žã«ãªãŠã ãŸãã¯ãããªãŠã ããããµãã«ãªãã¢
ã«ãã³é žã«ãªãŠã ãããçé žã«ãªãŠã ãã¡ãã«â
ãã¹ãã³é žã«ãªãŠã ããããµãã«ãªã¢ã«ãã³é žã
ããªãŠã ããã³ããšãã«âãã¹ãã³é žãªããŠã ã§
ããã 該塩é¡ã®çžäºæ··åç©é¡ãé©ããŠããã æ¬çºæã®æŠå¿µã§ã¯ããã²ã³ãå«ãŸãªãè³éŠæå
æéç¶ç±å¯å¡æ§ããªã«ãŒãããŒãé¡ãšã¯ãããã²
ã³ãå«ãŸãªããžããšããŒã«é¡ãç¹ã«ããããã·ãž
ã¢ãªãŒã«ã¢ã«ã«ã³é¡ãããã¹ã²ã³ãŸãã¯çé žã®ãž
ãšã¹ãã«é¡ãšåå¿ãããããšã«ããåŸãããéçž®
åç©é¡ã§ãããããã§ã¯æªçœ®æã®ãžããããã·ãž
ã¢ãªãŒã«ã¢ã«ã«ã³é¡ã®ä»ã«ãã¢ãªãŒã«åºãããã
ãã·åºã«é¢ããŠïœâããã³ïŒãŸãã¯ïœâäœçœ®ã«ã¢
ã«ãã«åºãæãããžããããã·ãžã¢ãªãŒã«ã¢ã«ã«
ã³é¡ãé©ããŠããããããã®éçž®åç©é¡ã¯ïŒäœ¿çš
ãããžããšããŒã«é¡ãåºã«ããŠïŒ0.05ã2.0ã¢ã«
ïŒ ã®éã®äžå®èœæ§ä»¥äžã®ååç©é¡ãäŸãã°äžå以
äžã®ããšããŒã«ç³»ããããã·ã«åºãæãããã®ã
ã®æ·»å ã«ããåæéåãããŠããã ãã®åã®ããªã«ãŒãããŒãé¡ããã³ãããã®è£œ
é ã¯äŸãã°ãã€ãå ¬éæ现æž1570533ã1595762ã
21116974ããã³2113347ãè±åœç¹èš±æ现æž
1079821ãç±³åœç¹èš±æ现æž3544514ããã³ãã€ãå ¬
éæ现æž2500092äžã«èšãããŠããã ããã²ã³ãå«ãŸãªãè³éŠæåæéç¶ç±å¯å¡æ§ã
ãªã«ãŒãããŒãé¡ã¯ãCH2Cl2äžã§ã®25âããã³
0.5ïœïŒ100mlã®æ¿åºŠã«ãããçžå¯Ÿçç²åºŠã®æž¬å®ã«
ããé©åœãªæ€åºŠåŸã«æž¬å®ããã15000ã100000ã®
éã®ã奜é©ã«ã¯20000ã80000ã®éã®ãééå¹³åå
åéMwãæããã é©åœãªããã²ã³ãå«ãŸãªããžããšãŒããŒã«é¡ã®
äŸã¯ãããããã·ãã¬ãœã«ã·ããŒã«ãïŒïŒ4â²âãž
ããããã·ãžããšãã«ããã¹âïŒããããã·ããš
ãã«ïŒâã¢ã«ã«ã³é¡ãäŸãã°C1âC8âã¢ã«ãã¬ã³
âãŸãã¯C2âC8âã¢ã«ããªãã³âãã¹ããšããŒ
ã«é¡ããã¹âïŒããããã·ããšãã«ïŒâã·ã¯ãã¢ã«
ã«ã³é¡ãäŸãã°C5âC15âã·ã¯ãã¢ã«ãã¬ã³âãŸ
ãã¯C5âC15âã·ã¯ãã¢ã«ããªãã³âãã¹ããšã
ãŒã«é¡ãããã³ãã¹ïŒããããã·ããšãã«ïŒã¹ã«
ãã€ãé¡ããšãŒãã«é¡ãã±ãã³é¡ãã¹ã«ããã·ã
é¡ãŸãã¯ã¹ã«ãã³é¡ã䞊ã³ã«Î±ïŒÎ±â²âãã¹âïŒã
ãããã·ããšãã«ïŒâãžã€ãœãããã«ãã³ãŒã³ã
ãã³å¯Ÿå¿ããæ žâã¢ã«ãã«åãããååç©é¡ã§ã
ããïŒïŒïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâ
ãããã³ïŒãã¹ããšããŒã«ïŒ¡ïŒãïŒïŒïŒâãã¹
ïŒïŒâããããã·âïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâ
ãããã³ïŒããã©ã¡ãã«ãã¹ããšããŒã«ïŒ¡ïŒãŸã
ã¯ïŒïŒïŒâãã¹âïŒïŒâããããã·ããšãã«ïŒâã·
ã¯ããããµã³ïŒãã¹ããšããŒã«ïŒºïŒãåºã«ããã
ãªã«ãŒãããŒãé¡äžŠã³ã«äžæ žæ§ãã¹ããšããŒã«
é¡ãäŸãã°Î±ïŒÎ±â²âãã¹âïŒïŒâããããã·ããš
ãã«ïŒâïœâãžã€ãœãããã«ãã³ãŒã³ããåºã«ã
ããã®ã奜é©ã§ããã ããªã«ãŒãããŒãé¡ã®è£œé çšã«é©ããŠããä»ã®
ããã²ã³ãå«ãŸãªããžããšããŒã«é¡ã¯ç±³åœç¹èš±æ
现æž3028365ããã³3275601äžã«èšãããŠããã äžå以äžã®ããšããŒã«ç³»ããããã·åºãæãã
䜿çšã§ããååç©é¡ã®ããã€ãã®äŸã¯ããããã°
ã«ã·ããŒã«ãïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒâã
ãªâïŒïŒâããããã·ããšãã«ïŒâãããâïŒâãš
ã³ïŒïŒïŒïŒâãžã¡ãã«âïŒïŒïŒïŒïŒâããªâïŒïŒ
âããããã·ããšãã«ïŒâããã¿ã³ãïŒïŒïŒïŒïŒ
âããªâïŒïŒâããããã·ããšãã«ïŒâãã³ãŒã³ã
ïŒïŒïŒïŒïŒâããªâïŒïŒâããããã·ããšãã«ïŒâ
ãšã¿ã³ãããªâïŒïŒâããããã·ããšãã«ïŒâããš
ãã«ã¡ã¿ã³ãïŒïŒïŒâãã¹âïŒïŒïŒïŒâãã¹â
ïŒïŒâããããã·ããšãã«ïŒâã·ã¯ãããã·ã«ïŒã
ããã³ãïŒïŒïŒâãã¹âïŒïŒâããããã·ããšã
ã«âã€ãœãããã«ïŒããšããŒã«ãïŒïŒïŒâãã¹â
ïŒ2â²âããããã·â5â²âã¡ãã«âãã³ãžã«ïŒâïŒâ
ã¡ãã«ããšããŒã«ãïŒâïŒïŒâããããã·ããšã
ã«ïŒâïŒâïŒïŒïŒïŒâãžããããã·ããšãã«ïŒâã
ããã³ããããµâïŒïŒâïŒïŒâããããã·ããšãã«
âã€ãœãããã«ïŒâããšãã«ïŒâãªã«ãâãã¬ãã¿
ã«é žãšã¹ãã«ãããã©âïŒïŒâããããã·ããšã
ã«ïŒâã¡ã¿ã³ãããã©âïŒïŒâïŒïŒâããããã·ã
ãšãã«âã€ãœãããã«ïŒâããšããã·ïŒâã¡ã¿ã³ã
ãã³ïŒïŒïŒâãã¹âïŒïŒ4â²ïŒ4â³âãžããããã·ããª
ããšãã«ïŒâã¡ãã«ïŒâãã³ãŒã³ã§ãããä»ã®äžå®
èœæ§ååç©é¡ã¯ãïŒïŒïŒâãžããããã·å®æ¯éŠ
é žãããªã¡ã·ã³é žãå¡©åã·ã¢ãã«ãïŒïŒïŒâãã¹
âïŒïŒâããããã·ããšãã«ïŒâïŒâãªããœâïŒïŒ
ïŒâãžãããã€ã³ããŒã«ããã³ïŒïŒïŒâãã¹â
ïŒïŒâããããã·âïŒâã¡ãã«âããšãã«ïŒâïŒâ
ãªããœâïŒïŒïŒâãžãããã€ã³ããŒã«ã§ããã ååéçé·ã調æŽããããã®é©åœãªéåæ¢å€é¡
ã¯äŸãã°ãå ¬ç¥ã®éã§äœ¿çšãããå ¬ç¥ã®ããšããŒ
ã«ããã³ã¢ã«ãã«ããšããŒã«é¡ã§ããã è³éŠæåæéç¶ç±å¯å¡æ§ããªã«ãŒãããŒãé¡
ã¯ãäŸãã°çžå¢çæ¹æ³ã«ãããŸãã¯å質溶質溶液
äžã§ã®æ¹æ³ã®åŠãå ¬ç¥ã®æ¹æ³ã«ããã補é ãã
ããè³éŠæç±å¯å¡æ§ããªã«ãŒãããŒãé¡ã¯å ¬ç¥ã®
ãšã¹ãã«äº€ææ¹æ³ã«ãã€ãŠã補é ã§ããã æ¬çºæã®æŠå¿µã«ãããŠç¹ã«å¥œé©ãªããªã«ãŒãã
ãŒãé¡ã¯ãïŒã¢ã«ã®ãã¹ããšããŒã«ïŒ¡ãåºã«ããŠ
0.3ã1.0ã¢ã«ïŒ ã®åæéåå€ãæãããã¹ããšã
ãŒã«ïŒ¡ãåºã«ããåæéç¶ããªã«ãŒãããŒãé¡ã§
ããã åŒã®é©åœãªã¢ãã³ã¯ ã§ããã ãã®ååç©ã¯ç±³åœç¹èš±æ现æž3753679äžã«èšã
ããŠããã åŒã®é©åœãªãã¿ã«ã€ããååç©é¡ã¯ã ããã³ ã§ããã ãããã®ååç©é¡ã¯å®æœäŸäžã®æ¹æ³ã«ããäžèš
ã®äžè¬çå·¥çšæ¡ä»¶äžã§è£œé ã§ããã æ¬çºæã«åŸãé²çœå å·¥å€é¡ã¯åã ã®æåé¡ãŸã
ã¯æ¿çž®ç©ãããªã«ãŒãããŒãäžã«æ··åããããšã«
ããäºã補é ããããšãã§ãããããŠäœ¿çšæãŸã§
貯èµããããšãã§ããã æ°èŠãªé²çœå å·¥å€çµæç©ã¯ããªã«ãŒãããŒãé¡
äžã«ãããã®åå¥æå圢ã§ãŸãã¯äžç·ã«ããŠãäŸ
ãã°æ··åããã®åŸ270â280âã«ãããŠïŒâã¹ã¯ãª
ãŠãŒæŒåºåšãéããŠç©è³ªãé¡ç²ã«ããããšã«ãã
å ããããšãã§ããã ããªã«ãŒãããŒããšé²çå å·¥å€çµæç©ãåºã«ã
ãæ¬çºæã«åŸãæåçšçµæç©é¡ã¯ãããªã«ãŒãã
ãŒãååŠã«ãããŠäžè¬çãªä»ã®æ·»å ç©é¡ãäŸãã°
é¡æãææãå å¡«æãå®å®å€ãŸãã¯åæãå€ãã
å«æã§ããã æ¬çºæã«åŸãæåçšçµæç©é¡ã¯æååé¡ãŸãã¯
ãã€ã«ã é¡ã«å å·¥ã§ããã æååé¡ã¯300â310âã®æž©åºŠã«ãããå°åºæå
æ¹æ³ã«ãã補é ãããã æ¬çºæã«åŸãæåçšçµæç©é¡ã¯äŸãã°é»æ°åé
ã«ãããŠã¹ã€ããã·ãŒã«ãããœã±ããããœã±ãã
ããã«ãã¹ã€ããããã¯ã¹çšãªã©ã«ã家å®çšåå
éã«ãããŠäœå® éšåçšã«ãã¢ã€ãã³ããã³ã³ãŒã
ãŒæ©æ¢°çšã«ã䞊ã³ã«å€ãã®é©çšåéã«ãããŠäŸã
ã°ã³ã³ããŠãŒã¿ãŒããŠãžã³ã°éšåçšã«äœ¿çšã§ã
ãã ççŒè©Šéšã®èšèŒ UL94è©ŠéšïŒã¢ã³ããŒã©ã€ã¿ãŒã¹ã»ã©ãã©ããª
ã€ã¹ã»ã€ã³ã³ãŒãã¬ãŒãããïŒã«åŸããããªã«ãŒ
ãããŒãè©Šæã127Ã12.7Ã3.2ïŒãŸãã¯1.6ãŸãã¯
0.8ïŒmm5.00Ã0.5Ã1/8ïŒãŸãã¯1/16ãŸãã¯1/3
ïŒïŒã€ã³ãã®å¯žæ³ãæããæ£ç¶ã«æåãããè©Š
éšçã®äžåŽãå 垯ç©è³ªçã®305mmäžã«ããããã«
æ£ãåçŽã«çœ®ãããåè©Šéšæ£ã10ç§éæç¶ããïŒ
åã®é£ç¶ççºç«æäœã«ããåã ã«çºç«ãããåçº
ç«æäœåŸã«ççŒç¹æ§ã芳å¯ãã次ã«è©Šæãè©äŸ¡ã
ãã3.73Ã104kJïŒm3ïŒ1.000BTUïŒå¹³æ¹ãã€ãŒ
ãïŒã®ç±å«æéãæãã10mmïŒ3/8ã€ã³ãïŒã®é«
ãã®å€©çã¬ã¹ã®éãçãçãããã³ãŒã³ã»ããŒã
ãŒãè©Šæã®çºç«çšã«äœ¿çšããã UL94VâïŒåé¡ã¯ãUL94ä»æ§ã«åŸãè©Šéšãã
ç©è³ªã®äžèšã®æ§è³ªã«é¢ãããã®ã§ããããã®åé¡
ã®ããªã«ãŒãããŒãã¯åè©Šéšçã®äœçšåŸã«10ç§ä»¥
äžçããè©Šæãå«ãã§ãããããããã¯äžçµã®è©Š
æã«å¯Ÿããäºåã®äœçšã«å¯ŸããŠã¯50ç§ä»¥äžã®åèš
ççŒæéã瀺ããããããã¯è©Šæã®äžç«¯ã«ä»ããŠ
ããæ¯æã¯ã©ã³ããŸã§å®å šã«ççŒããè©Šæãå«ã
ã§ãããããããã¯ççŒæ»ŽãŸãã¯ç²åã«ããè©Šæ
ã®äžã«çœ®ãããŠããã³ããã³ãŠãŒã«ãçºç«ããã
è©Šæãå«ãã§ãããããããã¯ãŸãè©Šéšçãé€ã
ãåŸã«30ç§ä»¥äžèµ€ç±ïŒglowïŒããŠããè©Šæãå«
ãã§ããªãã€ãã ä»ã®UL94åé¡ã¯ãããããæ¥çæ§ããã³èªå·±
æ¶ç«æ§ãå°ãããç滎ãŸãã¯ç²åãçããè©Šæã
è¡šãããŠããããããã®åé¡ã¯UL94VâïŒãã
ã³ïŒ¶âïŒãšè¡šç€ºãããã æ¬çºæã®ç¯å²å ã®ããªã«ãŒãããŒãé¡ã¯ç¹åŸŽç
ã«UL94VâïŒåé¡çšã«å¿ èŠãªæ§è³ªã瀺ããŠããã å®æœäŸ  åŒïŒïŒã®ãã¿ã«ã€ããé¡ã®è£œé  ïŒ ç¡æ°Žããã©ã¯ãããã¿ã«é žã䜿çšããäž
è¬åŒïŒïŒã®ãã¿ã«ã€ããã®è£œé æåã«1600mlã®æ°·é ¢é žãã枩床èšãæ¹æåšã
ãã³æ°Žåé¢åšãåããäžéŠãã©ã¹ã³äžã«å ãã
ãããŠ55âã«æããã次ã«171.6ïœïŒ0.6ã¢ã«ïŒ
ã®ç¡æ°Žããã©ã¯ãããã¿ã«é žããã³157.8ïœ
ïŒ0.6ã¢ã«ïŒã®ïŒâã¢ããâïŒâã¡ããã·âãžã
ãšãã«ã¹ã«ãã³ã®æ··åç©ãå ãããããŠæ··åç©
ãæ¿ããæ¹æãããåå¿æ··åç©ã118âã«ãã
ãŠéæµäžã§2.5æéä¿ã¡ã次ã«å·åŽããã150ml
ã®ã·ã¯ããããµã³ã®æ·»å åŸã«ãåå¿æ··åç©ãç°
æµäžã§ïŒæéä¿ã¡ããã®éã«åå¿æ°Žã¯æ°Žåé¢åš
äžã§é€å»ã§ããã çæããåºäœãç±æã«åžåŒæ¿Ÿå¥ããæ°·é ¢é žã§
æŽæµããç±ãã¢ã»ãã³äžã«æžæ¿ããããããŠä¹Ÿ
ç¥ããã ïŒ ïŒ® çè«å€ïŒ2.64ïŒ ïŒ ïŒ£ çè«å€ïŒ47.5ïŒ
ïŒ ïŒš çè«å€ïŒ2.1ïŒ ïŒ Cl çè«å€ïŒ26.7ã ïŒ ïŒ® å®æž¬å€ïŒ2.86ïŒ ïŒ ïŒ£ å®æž¬å€ïŒ47.5ïŒ
ïŒ ïŒš å®æž¬å€ïŒ2.05ïŒ ïŒ Cl å®æž¬å€ïŒ
26.5ã  ïŒ ç¡æ°Žãã¿ã«é žã䜿çšããäžè¬åŒïŒïŒã®
ãã¿ã«ã€ããã®è£œé ç¡æ°Žãã¿ã«é žã䜿çšããŠA1ã«åŸããã¿ã«ã€
ããã補é ããã ïŒ ïŒ® çè«å€ïŒ3.56ïŒ ïŒ ïŒ£ çè«å€ïŒ64.1ïŒ
ïŒ ïŒš çè«å€ïŒ3.82 ïŒ ïŒ® å®æž¬å€ïŒ3.54ïŒïŒ  å®æž¬å€ïŒ64.0ïŒ
ïŒ ïŒš å®æž¬å€ïŒ3.84ã  æ¥çæ§ã®åæéç¶ããªã«ãŒãããŒãé¡ ïŒCH2Cl2äžã§25âããã³0.5gïŒ100mlã®æ¿åºŠã«
ãããŠæž¬å®ãããïŒ1.31ã®æº¶æ¶²ç²åºŠãæãããã
ã¹ããšããŒã«ïŒ¡ã0.5ã¢ã«ïŒ ã®ïŒïŒïŒâãã¹âïŒïŒ
âããããã·âïŒâã¡ãã«ããšãã«ïŒâïŒâãªã
ãœâïŒïŒïŒâãžãããã€ã³ããŒã«ã3.0ã¢ã«ïŒ ã®
éåæ¢å€ãšããŠã®ããšããŒã«ãããã³ãã¹ã²ã³ã
åºã«ããåæéç¶ã®ããªã«ãŒãããŒãã0.1ïŒ ã®
ïœâãã«ãã«ãªããã¿ã³ã¹ã«ãã³é žã®ïŒ«å¡©ãšãŸã
ã¯æ¬çºæã«åŸããã¿ã«ã€ããé¡ãšæ··åããæ··åç©
ãæŒåºãããããŠããã®æ¥çæ§ã3.2mmã1.6mmã
ãã³0.8mmã®åãã«ãããŠUL94ã«åŸãè©Šéšããã äžè¡šã«çµæã瀺ãïŒ å®æœäŸïŒ
ãè¡šã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒ åŒäžã ã¯æ°ŽçŽ ãŸãã¯ïŒåãŸã§ã®ããã²ã³ã瀺ãã ãã㊠ïœã¯ïŒãŸãã¯ïŒã瀺ã ã®ãã¿ã«ã€ããé¡ã ïŒ äžèšã®åŒ ãæãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ãã¿ã«ã€
ããé¡ã ïŒ äžèšã®åŒ ãæãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ãã¿ã«ã€
ããé¡ã ïŒ äžè¬åŒ åŒäžã ã¯æ°ŽçŽ ãŸãã¯ïŒåãŸã§ã®ããã²ã³ã瀺ã ã®ç¡æ°Žãã¿ã«é žãäžè¬åŒïŒïŒ åŒäžãïœã¯ïŒãŸãã¯ïŒã瀺ã ã®ã¢ãã³ãšå®è³ªçã«çã¢ã«éã§117âã«ãããŠã
溶åªãšããŠã®æ°·é ¢é žããã³æ°Žâæ æå€ãšããŠã®ã·
ã¯ããããµã³ã®ååšäžã§åå¿ãããããšãç¹åŸŽãš
ããäžè¬åŒ åŒäžãããã³ïœã®å®çŸ©ã¯äžèšã«åãã§ããã
ã®ãã¿ã«ã€ããé¡ã®è£œé æ¹æ³ã ïŒ æ°·é ¢é žãïŒã¢ã«ã®åŒïŒïŒã®ã¢ãã³åœãã
2.5ã3.0ãªããã«ã®éã§ååšããŠãããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ã·ã¯ããããµã³ãïŒã¢ã«ã®åŒïŒïŒã®ã¢ãã³
åœãã250ã300mlã®éã§ååšããŠãããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒãŸãã¯ïŒé ã«èšèŒã®æ¹æ³ã ïŒ åŒïŒïŒã®ã¢ãã³ãåŒ ã®ååç©ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé ã®ã
ãããã«èšèŒã®æ¹æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19833337857 DE3337857A1 (de) | 1983-10-18 | 1983-10-18 | Neue flammschutzmittel, ihre herstellung und ihre verwendung zur flammfestausruestung von polycarbonaten |
| DE3337857.6 | 1983-10-18 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2118828A Division JPH0341188A (ja) | 1983-10-18 | 1990-05-10 | é²çå å·¥å€çµæç©ããã³ããã«ããããªã«ãŒãããŒãé¡ã®èçæ§åŠç |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6097954A JPS6097954A (ja) | 1985-05-31 |
| JPH037667B2 true JPH037667B2 (ja) | 1991-02-04 |
Family
ID=6212131
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59214463A Granted JPS6097954A (ja) | 1983-10-18 | 1984-10-15 | ãã¿ã«ã€ããé¡ããã³ãã®è£œé æ³ |
| JP2118828A Pending JPH0341188A (ja) | 1983-10-18 | 1990-05-10 | é²çå å·¥å€çµæç©ããã³ããã«ããããªã«ãŒãããŒãé¡ã®èçæ§åŠç |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2118828A Pending JPH0341188A (ja) | 1983-10-18 | 1990-05-10 | é²çå å·¥å€çµæç©ããã³ããã«ããããªã«ãŒãããŒãé¡ã®èçæ§åŠç |
Country Status (4)
| Country | Link |
|---|---|
| US (3) | US4661543A (ja) |
| EP (1) | EP0138173B1 (ja) |
| JP (2) | JPS6097954A (ja) |
| DE (2) | DE3337857A1 (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3337857A1 (de) * | 1983-10-18 | 1985-04-25 | Bayer Ag, 5090 Leverkusen | Neue flammschutzmittel, ihre herstellung und ihre verwendung zur flammfestausruestung von polycarbonaten |
| IL88582A (en) * | 1987-12-08 | 1993-03-15 | Tosoh Corp | 4,4)-bis (phthalimido) diphenyl sulfone compounds, processes for their production and flame retardant polymer compositions containing them |
| BE1006984A3 (nl) * | 1993-04-08 | 1995-02-07 | Dsm Nv | Vlamdovende polycarbonaat bevattende polymeersamenstellingen. |
| WO2012094395A2 (en) | 2011-01-04 | 2012-07-12 | Primex Plastics Corporation | Fire retardant and method of use |
| DE102013005307A1 (de) * | 2013-03-25 | 2014-09-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von organischen Oxyimiden als Flammschutzmittel fÌr Kunststoffe sowie flammgeschÌtzte Kunststoffzusammensetzung und hieraus hergestelltem Formteil |
| US10329421B2 (en) | 2014-06-11 | 2019-06-25 | Sabic Global Technologies B.V. | Polycarbonate compositions, method of manufacture thereof, and articles therefrom |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3808230A (en) * | 1960-01-21 | 1974-04-30 | Delmar Chem | 2-oxy-4-phthaloylamido-5-halobenzoate compounds |
| DE1445783A1 (de) * | 1964-10-30 | 1969-01-23 | Hoechst Ag | Verfahren zur Herstellung von Benzolsulfonylharnstoffen |
| US3753679A (en) * | 1968-05-03 | 1973-08-21 | Exxon Research Engineering Co | Herbicidal s-aryl arylamides as herbicides |
| DE2147535A1 (de) * | 1971-09-23 | 1973-03-29 | Akzo Gmbh | Verfahren zur herstellung von cyclischen carbonsaeureimiden |
| US3922284A (en) * | 1973-03-30 | 1975-11-25 | Gen Electric | N-Substituted aromatic thioetherophthalimides |
| US3873587A (en) * | 1973-08-20 | 1975-03-25 | Atlantic Richfield Co | Production of peroxytitanium complexes from organic hydroperoxides |
| US3950307A (en) * | 1975-03-10 | 1976-04-13 | Velsicol Chemical Corporation | Halobenzoyl tetrahalophthalimides |
| US4000307A (en) * | 1975-11-19 | 1976-12-28 | Sandoz, Inc. | Alkanoyl isoindolinylmethyl alkylphenones |
| US4344830A (en) * | 1976-02-23 | 1982-08-17 | General Electric Company | UV Curable resins and sulfonate esters of benzotriazoles used in such resins |
| NL175407C (nl) * | 1976-10-18 | 1984-11-01 | Sagami Chem Res | Werkwijze voor het bereiden van op de alfa-arylalkaancarbonzuurverbindingen. |
| US4208489A (en) * | 1977-01-29 | 1980-06-17 | Bayer Aktiengesellschaft | Polycarbonate molding compositions with improved flame-repellency |
| DE2918883A1 (de) * | 1979-05-10 | 1980-11-20 | Bayer Ag | Flammwidrige pc-legierungen mit erhoehter spannungsrisskorrosionsbestaendigkeit |
| DE2918882A1 (de) * | 1979-05-10 | 1980-11-13 | Bayer Ag | Flammwidrige polycarbonat-legierungen mit erhoehter waermeformbestaendigkeit |
| US4320049A (en) * | 1980-07-14 | 1982-03-16 | Mobay Chemical Corporation | Flame retarding agents for polycarbonates |
| US4459414A (en) * | 1981-04-08 | 1984-07-10 | Ciba-Geigy Corporation | Tetrasubstituted phthalic acid derivatives, and a process for their preparation |
| DE3203905A1 (de) * | 1982-02-05 | 1983-08-11 | Bayer Ag, 5090 Leverkusen | Polycarbonat-formmassen mit verbesserter flammwidrigkeit |
| DE3337857A1 (de) * | 1983-10-18 | 1985-04-25 | Bayer Ag, 5090 Leverkusen | Neue flammschutzmittel, ihre herstellung und ihre verwendung zur flammfestausruestung von polycarbonaten |
-
1983
- 1983-10-18 DE DE19833337857 patent/DE3337857A1/de not_active Withdrawn
-
1984
- 1984-10-06 DE DE8484111996T patent/DE3468213D1/de not_active Expired
- 1984-10-06 EP EP84111996A patent/EP0138173B1/de not_active Expired
- 1984-10-15 JP JP59214463A patent/JPS6097954A/ja active Granted
- 1984-10-17 US US06/661,770 patent/US4661543A/en not_active Expired - Fee Related
-
1986
- 1986-11-26 US US06/935,448 patent/US4713462A/en not_active Expired - Fee Related
-
1987
- 1987-08-24 US US07/088,929 patent/US4776981A/en not_active Expired - Fee Related
-
1990
- 1990-05-10 JP JP2118828A patent/JPH0341188A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6097954A (ja) | 1985-05-31 |
| US4713462A (en) | 1987-12-15 |
| US4776981A (en) | 1988-10-11 |
| DE3468213D1 (en) | 1988-02-04 |
| EP0138173A2 (de) | 1985-04-24 |
| DE3337857A1 (de) | 1985-04-25 |
| JPH0341188A (ja) | 1991-02-21 |
| EP0138173B1 (de) | 1987-12-23 |
| EP0138173A3 (ja) | 1985-06-05 |
| US4661543A (en) | 1987-04-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1064191A (en) | Branched, high-molecular weight thermoplastic polycarbonates | |
| US4615832A (en) | Flameproofing agents, their preparation and their use for flameproofing polycarbonates | |
| CA2231571C (en) | Carbonate polymer resins containing low volatility aromatic phosphate ester compounds | |
| TW200300782A (en) | Translucent flame retardant polycarbonate compositions | |
| US4786671A (en) | Flameproofing agent combinations and their use in thermoplastic moulding compositions of polycarbonates and ABS polymers | |
| US4039538A (en) | Preparation of tris-(halophenoxy)-sym.-triazines | |
| JP3503095B2 (ja) | é£çæ§ããªã«ãŒãããŒãçµæç© | |
| JPH037667B2 (ja) | ||
| US4320049A (en) | Flame retarding agents for polycarbonates | |
| US4444978A (en) | Thermally stable carbonate polymer | |
| JPS6121154A (ja) | ç±å¯å¡æ§è³éŠæããªã«ãŒãããŒããåºã«ããæåçšçµæç©ããã³ãã®è£œé æ¹æ³ | |
| JPH04202465A (ja) | ããªã«ãŒãããŒãæš¹èçµæç© | |
| US4826634A (en) | Fluorinated alkylamidosulphonates, their preparation, their use as flame retardants, and polycarbonate moulding compositions containing them | |
| US5234979A (en) | Thermoplastic mounding compositions with flame-repellant properties | |
| US4594375A (en) | Bis-(imide-sulfonate) flameproofing agents, their preparation and their use for flameproofing in polycarbonate | |
| US5399600A (en) | Stabilized, flame resistant polycarbonate moulding compounds | |
| US20070272903A1 (en) | Arylalkylsilyls Used as a Flame Retardant Additives | |
| EP0183107B1 (en) | Flame retardant molding compositions | |
| CN112143028B (zh) | åä»£ç¡ åºè¯ç£ºé žçåšé«ååææé»çæ¹æ§äžçåºçšåé»çé«ååææ | |
| JPS63170416A (ja) | ã³ããªã«ãŒãããŒãããã³ãã®è£œé æ¹æ³ | |
| JPS5935924B2 (ja) | é²çæ§ç±å¯å¡æ§æš¹èçµæç© |