JPH0515723B2 - - Google Patents

Info

Publication number: JPH0515723B2
Authority: JP; Japan
Prior art keywords: resin; acid; ions; amino; reaction
Prior art date: 1989-03-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP7328189A

Other languages

English (en)

Japanese (ja)

Other versions

JPH02251504A (ja

Inventor

Toshiro Yokoyama

Masatoshi Kanesato

Tetsuo Kimura

Toshishige Suzuki

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-03-24

Filing date

1989-03-24

Publication date

1993-03-02

1989-03-24 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1989-03-24 Priority to JP7328189A priority Critical patent/JPH02251504A/ja

1990-10-09 Publication of JPH02251504A publication Critical patent/JPH02251504A/ja

1993-03-02 Publication of JPH0515723B2 publication Critical patent/JPH0515723B2/ja

Status Granted legal-status Critical Current

Links

229920005989 resin Polymers 0.000 claims description 54
239000011347 resin Substances 0.000 claims description 54
239000013522 chelant Substances 0.000 claims description 28
238000006243 chemical reaction Methods 0.000 claims description 25
239000003446 ligand Substances 0.000 claims description 20
QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 8
239000011159 matrix material Substances 0.000 claims description 8
238000000034 method Methods 0.000 claims description 8
150000002668 lysine derivatives Chemical class 0.000 claims description 7
229920005990 polystyrene resin Polymers 0.000 claims description 7
125000003277 amino group Chemical group 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 6
229920000642 polymer Polymers 0.000 claims description 6
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims 1
229910021645 metal ion Inorganic materials 0.000 description 23
150000002500 ions Chemical class 0.000 description 22
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000000243 solution Substances 0.000 description 13
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 12
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 9
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
239000002952 polymeric resin Substances 0.000 description 6
229920003002 synthetic resin Polymers 0.000 description 6
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
239000010949 copper Substances 0.000 description 5
229910052802 copper Inorganic materials 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
238000009826 distribution Methods 0.000 description 4
229910052733 gallium Inorganic materials 0.000 description 4
238000001179 sorption measurement Methods 0.000 description 4
BOWUOGIPSRVRSJ-UHFFFAOYSA-N 2-aminohexano-6-lactam Chemical class NC1CCCCNC1=O BOWUOGIPSRVRSJ-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 3
229910001385 heavy metal Inorganic materials 0.000 description 3
239000000203 mixture Substances 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
239000000047 product Substances 0.000 description 3
KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
239000004472 Lysine Substances 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229940106681 chloroacetic acid Drugs 0.000 description 2
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000013078 crystal Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
229910052738 indium Inorganic materials 0.000 description 2
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
-1 polyethylene Polymers 0.000 description 2
238000010992 reflux Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
125000000218 acetic acid group Chemical class C(C)(=O)* 0.000 description 1
WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
229920001429 chelating resin Polymers 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
230000005588 protonation Effects 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006277 sulfonation reaction Methods 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000002351 wastewater Substances 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP7328189A 1989-03-24 1989-03-24 アミノポリカルボン酸型キレート樹脂の製造方法 Granted JPH02251504A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP7328189A JPH02251504A (ja)	1989-03-24	1989-03-24	アミノポリカルボン酸型キレート樹脂の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7328189A JPH02251504A (ja)	1989-03-24	1989-03-24	アミノポリカルボン酸型キレート樹脂の製造方法

Publications (2)

Publication Number	Publication Date
JPH02251504A JPH02251504A (ja)	1990-10-09
JPH0515723B2 true JPH0515723B2 (fr)	1993-03-02

Family

ID=13513605

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP7328189A Granted JPH02251504A (ja)	1989-03-24	1989-03-24	アミノポリカルボン酸型キレート樹脂の製造方法

Country Status (1)

Country	Link
JP (1)	JPH02251504A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2001029783A (ja) *	1999-07-13	2001-02-06	Tran Quang Minh	親和性固定化金属樹脂
JP4965245B2 (ja) *	2006-12-28	2012-07-04	株式会社オートネットワーク技術研究所	キレート導入高分子および高分子組成物ならびに被覆電線およびワイヤーハーネス

1989
- 1989-03-24 JP JP7328189A patent/JPH02251504A/ja active Granted

Also Published As

Publication number	Publication date
JPH02251504A (ja)	1990-10-09

Legal Events

Date	Code	Title	Description
2009-03-24	EXPY	Cancellation because of completion of term

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