JPH0549703B2 - - Google Patents

Info

Publication number: JPH0549703B2
Authority: JP; Japan
Prior art keywords: foam; amount; acid; acid catalyst; phenolic resin
Prior art date: 1982-01-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP339282A

Other languages

English (en)

Japanese (ja)

Other versions

JPS58120644A (ja

Inventor

Tsuneo Hogi

Nobuo Miura

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Asahi Chemical Industry Co Ltd

Original Assignee

Asahi Chemical Industry Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-01-14

Filing date

1982-01-14

Publication date

1993-07-27

1982-01-14 Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd

1982-01-14 Priority to JP339282A priority Critical patent/JPS58120644A/ja

1983-07-18 Publication of JPS58120644A publication Critical patent/JPS58120644A/ja

1993-07-27 Publication of JPH0549703B2 publication Critical patent/JPH0549703B2/ja

Status Granted legal-status Critical Current

Links

239000006260 foam Substances 0.000 claims description 59
239000003377 acid catalyst Substances 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 18
238000005187 foaming Methods 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 17
239000004593 Epoxy Substances 0.000 claims description 16
238000004519 manufacturing process Methods 0.000 claims description 14
239000011134 resol-type phenolic resin Substances 0.000 claims description 14
239000005011 phenolic resin Substances 0.000 claims description 13
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 12
IVIDDMGBRCPGLJ-UHFFFAOYSA-N 2,3-bis(oxiran-2-ylmethoxy)propan-1-ol Chemical compound C1OC1COC(CO)COCC1CO1 IVIDDMGBRCPGLJ-UHFFFAOYSA-N 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 11
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 11
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 10
230000000694 effects Effects 0.000 claims description 10
229920001568 phenolic resin Polymers 0.000 claims description 10
239000004604 Blowing Agent Substances 0.000 claims description 6
JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 3
239000012855 volatile organic compound Substances 0.000 claims description 2
210000004027 cell Anatomy 0.000 description 16
238000002474 experimental method Methods 0.000 description 16
230000007797 corrosion Effects 0.000 description 12
238000005260 corrosion Methods 0.000 description 12
238000012360 testing method Methods 0.000 description 12
238000000034 method Methods 0.000 description 10
239000002253 acid Substances 0.000 description 9
239000007864 aqueous solution Substances 0.000 description 8
238000009413 insulation Methods 0.000 description 8
230000009257 reactivity Effects 0.000 description 8
230000000052 comparative effect Effects 0.000 description 7
238000011156 evaluation Methods 0.000 description 7
230000000704 physical effect Effects 0.000 description 7
229910000831 Steel Inorganic materials 0.000 description 6
239000007788 liquid Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
239000000779 smoke Substances 0.000 description 6
239000010959 steel Substances 0.000 description 6
-1 hydroxy acid compound Chemical class 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
239000003054 catalyst Substances 0.000 description 4
AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
239000000284 extract Substances 0.000 description 3
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 3
229940029284 trichlorofluoromethane Drugs 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 2
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
239000004327 boric acid Substances 0.000 description 2
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 2
238000010586 diagram Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
239000002655 kraft paper Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
235000011007 phosphoric acid Nutrition 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
SLGOCMATMKJJCE-UHFFFAOYSA-N 1,1,1,2-tetrachloro-2,2-difluoroethane Chemical compound FC(F)(Cl)C(Cl)(Cl)Cl SLGOCMATMKJJCE-UHFFFAOYSA-N 0.000 description 1
ZXUJWPHOPHHZLR-UHFFFAOYSA-N 1,1,1-trichloro-2-fluoroethane Chemical compound FCC(Cl)(Cl)Cl ZXUJWPHOPHHZLR-UHFFFAOYSA-N 0.000 description 1
BAMUEXIPKSRTBS-UHFFFAOYSA-N 1,1-dichloro-1,2,2,2-tetrafluoroethane Chemical compound FC(F)(F)C(F)(Cl)Cl BAMUEXIPKSRTBS-UHFFFAOYSA-N 0.000 description 1
DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
AHFMSNDOYCFEPH-UHFFFAOYSA-N 1,2-difluoroethane Chemical compound FCCF AHFMSNDOYCFEPH-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
239000004338 Dichlorodifluoromethane Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
210000000170 cell membrane Anatomy 0.000 description 1
229960001701 chloroform Drugs 0.000 description 1
239000010960 cold rolled steel Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
229940105990 diglycerin Drugs 0.000 description 1
GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000011256 inorganic filler Substances 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
239000011810 insulating material Substances 0.000 description 1
239000012774 insulation material Substances 0.000 description 1
230000001788 irregular Effects 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
230000009972 noncorrosive effect Effects 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
239000000123 paper Substances 0.000 description 1
150000007965 phenolic acids Chemical class 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000012779 reinforcing material Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
229920003987 resole Polymers 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1

Landscapes

Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

JP339282A 1982-01-14 1982-01-14 耐炎性に優れたフエノ−ルフオ−ムの製造方法 Granted JPS58120644A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP339282A JPS58120644A (ja)	1982-01-14	1982-01-14	耐炎性に優れたフエノ−ルフオ−ムの製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP339282A JPS58120644A (ja)	1982-01-14	1982-01-14	耐炎性に優れたフエノ−ルフオ−ムの製造方法

Publications (2)

Publication Number	Publication Date
JPS58120644A JPS58120644A (ja)	1983-07-18
JPH0549703B2 true JPH0549703B2 (fr)	1993-07-27

Family

ID=11556086

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP339282A Granted JPS58120644A (ja)	1982-01-14	1982-01-14	耐炎性に優れたフエノ−ルフオ−ムの製造方法

Country Status (1)

Country	Link
JP (1)	JPS58120644A (fr)

1982
- 1982-01-14 JP JP339282A patent/JPS58120644A/ja active Granted

Also Published As

Publication number	Publication date
JPS58120644A (ja)	1983-07-18

Publication	Publication Date	Title
US3389094A (en)	1968-06-18	Foaming phenol-formaldehyde resins with fluorocarbons
US4122045A (en)	1978-10-24	Non-punking non-corrosive phenolic foam containing sodium tetraborate
JPS6142549A (ja)	1986-03-01	フエノ−ル樹脂発泡体の製造方法
US4530939A (en)	1985-07-23	Low K-factor closed cell phenol-aldehyde foam and process for preparation thereof
NZ204806A (en)	1986-03-14	Phenolic resole compositions and manufacture of foams therefrom
NZ236825A (en)	1992-03-26	Blowing agents for producing synthetic resin foams comprising at least one fluorocarbon and at least one chlorofluorohydrocarbon or fluorohydrocarbon or a (cyclo)alkane having a boiling point below 120 o c
EP0170357B1 (fr)	1989-04-19	Procédé pour préparer des mousses phénoliques
JPH03190938A (ja)	1991-08-20	アルキルグルコシドを含有する改善された独立気泡フェノールフォーム
CA1068049A (fr)	1979-12-11	Polymeres phenolique, produits et procedes connexes
US4001148A (en)	1977-01-04	Process for the production of flame-resistant phenolic resin foam plastics
KR20180109073A (ko)	2018-10-05	폼 복합재
US4018725A (en)	1977-04-19	Phenolic foam products and method of making the same
JPH0549703B2 (fr)	1993-07-27
GB1604657A (en)	1981-12-16	Phenolic resins and products prepared therefrom
JPH05500532A (ja)	1993-02-04	安定な発泡アミノ樹脂及びその製造方法
JP2551481B2 (ja)	1996-11-06	発泡用フェノール樹脂組成物
US5489619A (en)	1996-02-06	Process for producing improved phenolic foams from phenolic resole resins
WO1989012658A1 (fr)	1989-12-28	Procede de production de mousses phenoliques
JPH0853563A (ja)	1996-02-27	フェノール樹脂発泡体の製造方法
JPS58120642A (ja)	1983-07-18	閉鎖気泡構造に富むフエノ−ル樹脂発泡体の製造方法
JP3139159B2 (ja)	2001-02-26	フエノール樹脂発泡体の製造方法
JPS59164343A (ja)	1984-09-17	フエノ−ル樹脂発泡体の製造方法
SU896007A1 (ru)	1982-01-07	Композици дл получени теплоизол ционного материала
DE1569490A1 (de)	1970-04-16	Verfahren zur Herstellung von Schaumstoffen
JPH0364542B2 (fr)	1991-10-07