JPH0567226B2 - - Google Patents
Info
- Publication number
- JPH0567226B2 JPH0567226B2 JP19122586A JP19122586A JPH0567226B2 JP H0567226 B2 JPH0567226 B2 JP H0567226B2 JP 19122586 A JP19122586 A JP 19122586A JP 19122586 A JP19122586 A JP 19122586A JP H0567226 B2 JPH0567226 B2 JP H0567226B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- substituted
- image
- layer
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052709 silver Inorganic materials 0.000 claims description 59
- 239000004332 silver Substances 0.000 claims description 59
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 48
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 238000006386 neutralization reaction Methods 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 24
- 238000009792 diffusion process Methods 0.000 claims description 20
- 238000012546 transfer Methods 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 16
- 229920002678 cellulose Polymers 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 15
- 125000000623 heterocyclic group Chemical group 0.000 claims description 14
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 14
- 239000003513 alkali Substances 0.000 claims description 11
- 230000008021 deposition Effects 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 239000004627 regenerated cellulose Substances 0.000 claims description 9
- 125000003107 substituted aryl group Chemical group 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 239000012670 alkaline solution Substances 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 4
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 3
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 125000004423 acyloxy group Chemical group 0.000 claims description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 2
- 125000004414 alkyl thio group Chemical group 0.000 claims description 2
- 125000004391 aryl sulfonyl group Chemical group 0.000 claims description 2
- 125000004421 aryl sulphonamide group Chemical group 0.000 claims description 2
- 125000005110 aryl thio group Chemical group 0.000 claims description 2
- 125000005521 carbonamide group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 2
- 125000005415 substituted alkoxy group Chemical group 0.000 claims description 2
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- 125000001302 tertiary amino group Chemical group 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 103
- -1 silver halide Chemical class 0.000 description 37
- 125000004432 carbon atom Chemical group C* 0.000 description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 229920002301 cellulose acetate Polymers 0.000 description 21
- 229940081735 acetylcellulose Drugs 0.000 description 20
- 239000000243 solution Substances 0.000 description 18
- 238000012545 processing Methods 0.000 description 17
- 238000007127 saponification reaction Methods 0.000 description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- 230000021736 acetylation Effects 0.000 description 14
- 238000006640 acetylation reaction Methods 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 238000002845 discoloration Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 238000005562 fading Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 238000000151 deposition Methods 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 235000011187 glycerol Nutrition 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 125000004434 sulfur atom Chemical group 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- HNHULXNWXJKDCM-UHFFFAOYSA-N n-hexyl-4-(2-sulfanylidene-1h-imidazol-3-yl)benzamide Chemical compound C1=CC(C(=O)NCCCCCC)=CC=C1N1C(=S)NC=C1 HNHULXNWXJKDCM-UHFFFAOYSA-N 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 5
- 125000004430 oxygen atom Chemical group O* 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- AIXZBGVLNVRQSS-UHFFFAOYSA-N 5-tert-butyl-2-[5-(5-tert-butyl-1,3-benzoxazol-2-yl)thiophen-2-yl]-1,3-benzoxazole Chemical compound CC(C)(C)C1=CC=C2OC(C3=CC=C(S3)C=3OC4=CC=C(C=C4N=3)C(C)(C)C)=NC2=C1 AIXZBGVLNVRQSS-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 description 4
- KGVITRZHZPHLOI-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCOC(=O)C(C)=C KGVITRZHZPHLOI-UHFFFAOYSA-N 0.000 description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 150000002443 hydroxylamines Chemical class 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 206010070834 Sensitisation Diseases 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920001477 hydrophilic polymer Polymers 0.000 description 3
- 239000011133 lead Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 230000008313 sensitization Effects 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- NRUVOKMCGYWODZ-UHFFFAOYSA-N sulfanylidenepalladium Chemical compound [Pd]=S NRUVOKMCGYWODZ-UHFFFAOYSA-N 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229920000800 acrylic rubber Polymers 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 229940035893 uracil Drugs 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- NVHNGVXBCWYLFA-UHFFFAOYSA-N 1,3-diazinane-2-thione Chemical compound S=C1NCCCN1 NVHNGVXBCWYLFA-UHFFFAOYSA-N 0.000 description 1
- OXFSTTJBVAAALW-UHFFFAOYSA-N 1,3-dihydroimidazole-2-thione Chemical class SC1=NC=CN1 OXFSTTJBVAAALW-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical class N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- VPMMJSPGZSFEAH-UHFFFAOYSA-N 2,4-diaminophenol;hydrochloride Chemical compound [Cl-].NC1=CC=C(O)C([NH3+])=C1 VPMMJSPGZSFEAH-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- VXEUGLRMYAXWKM-UHFFFAOYSA-N 3-phenyl-1h-imidazole-2-thione Chemical compound S=C1NC=CN1C1=CC=CC=C1 VXEUGLRMYAXWKM-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- ZFSGODDPMKJGJV-UHFFFAOYSA-N 5,5-dimethylimidazolidine-2,4-dione;formaldehyde Chemical compound O=C.CC1(C)NC(=O)NC1=O ZFSGODDPMKJGJV-UHFFFAOYSA-N 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004348 Glyceryl diacetate Substances 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- GAMPNQJDUFQVQO-UHFFFAOYSA-N acetic acid;phthalic acid Chemical compound CC(O)=O.OC(=O)C1=CC=CC=C1C(O)=O GAMPNQJDUFQVQO-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229940125717 barbiturate Drugs 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000005392 carboxamide group Chemical group NC(=O)* 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000012494 forced degradation Methods 0.000 description 1
- 235000019443 glyceryl diacetate Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical class [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- BJOXIRAGBLTXIZ-UHFFFAOYSA-N n,n-bis(2-methoxyethyl)hydroxylamine Chemical compound COCCN(O)CCOC BJOXIRAGBLTXIZ-UHFFFAOYSA-N 0.000 description 1
- VDUIPQNXOQMTBF-UHFFFAOYSA-N n-ethylhydroxylamine Chemical compound CCNO VDUIPQNXOQMTBF-UHFFFAOYSA-N 0.000 description 1
- CPQCSJYYDADLCZ-UHFFFAOYSA-N n-methylhydroxylamine Chemical compound CNO CPQCSJYYDADLCZ-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- QHASIAZYSXZCGO-UHFFFAOYSA-N selanylidenenickel Chemical compound [Se]=[Ni] QHASIAZYSXZCGO-UHFFFAOYSA-N 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/24—Photosensitive materials characterised by the image-receiving section
- G03C8/26—Image-receiving layers
- G03C8/28—Image-receiving layers containing development nuclei or compounds forming such nuclei
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/52—Bases or auxiliary layers; Substances therefor
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯éå¡©æ¡æ£è»¢åæ³åçèŠçŽ ã«é¢ããã
æŽã«è©³ããã¯ããã®ååèŠçŽ ã«é¢ããã
ïŒåŸæ¥ã®æè¡ïŒ
åŸæ¥ãããã²ã³åéãªã©ã®éå¡©ãå©çšããæ¡æ£
転ååçæ³ãç¥ãããŠããããã®ãããªåçæ³ã«
ãããŠã¯é²å ãããããã²ã³åéåçä¹³å€ãå«æ
ããæå èŠçŽ ãšãéæ²ç©æ žãå«æããååèŠçŽ ãš
ãéãåããããããïŒã€ã®èŠçŽ ã®éã«ãçŸåäž»
è¬ã®ååšäžã§ããã²ã³åé溶å€ãå«ãã¢ã«ã«ãªæ§
åŠç液ãå¡ãã€ããŠåŠçããããšã«ãããååèŠ
çŽ äžã«çŽæ¥ã«ããžã®éç»åãåŸãæ¹æ³ãç¥ãããŠ
ããã ãã®æ¹æ³ã§ã¯ãæå èŠçŽ äžã®æªé²å ã®ããã²ã³
åéä¹³å€ããããã²ã³åé溶å€ã«ãã溶解ãããŠ
éã€ãªã³é¯äœãšããŠã¢ã«ã«ãªæ§åŠç液äžã«æº¶ãåº
ããååèŠçŽ ã«è»¢åããŠãååèŠçŽ äžã§éæ²ç©æ ž
ã®äœçšã«ããéç»åãšããŠæ²æ®¿ããããšã«ãã€
ãŠãçŽæ¥ããžç»åã圢æãããã ããããªããããã®ããã«ããŠããããååèŠ
çŽ ã«åœ¢æãããéç»åã¯ãä¿åäžã«å€è²ãããã
ããã¯éè²ããããããããšããæ¬ ç¹ããã€ãã
çœå°ã«ã¹ãã€ã³ãçºçãããããšããæ¬ ç¹ããã€
ãã ãã®æ¬ ç¹ãæ¹è¯ããæ¹æ³ãšããŠãç¹å ¬æ46â
5392ãç±³åœç¹èš±3533789ããã³è±åœç¹èš±1164642ã®
åæ现æžã«ã¯ãããããéç»åè¡šé¢ã«ã¢ã«ã«ãªäž
åæåãå«æãã氎溶æ§ããªããŒæ¶²ãå¡åžããæ¹
æ³ãèšèŒãããŠãããããããªããããã®æ¹æ³ã§
ã¯ãããªããŒæ°Žæº¶æ¶²ãå¡åžããè¡šé¢ãå®å šã«ä¹Ÿç¥
ãããŸã§ã«ããªãã®æéãèŠãããã®éãè¡šé¢ã
ããããããŠç²çæ§ã§ããã®ã§ããªã³ããéãã
ããšãã§ãããæçŽã塵åãä»çããããšããã°
ãã°ãã€ãããŸããéç»åã«ããã«ãã®ãããªæ¶²
ãå¡åžããããšã¯ç ©éã§ããã ãŸãã転ååãã倧æ°äžã«ååšããç¡«åæ°ŽçŽ ã«
ããå解ã«ããé»å€ããæ¬ é¥ã«å¯ŸããŠã¯ãç¹éæ
47â10937ã«ååå±€ã®ã¢ã«ã«ãªåºŠãäœäžãããäž
åãæãã¯å¹Ÿåé žæ§ã«ããããšãé瀺ãããŠãã
ããPHãäœäžããããã ãã§ã¯çš®ã ã®ä¿åæ¡ä»¶ã«
察ããŠã¯ååãªå¹æãäžããããšã¯ã§ããªãã ç¹å ¬æ56â44418æ现æžã«ã¯ãæ¯æäœã®äžã«ã
ïŒïŒæ¡æ£å¯èœã§éç»åã®æ§è³ªãå€ãããååç©
ãå«æããå æ°Žå解å¯èœã§ãå æ°Žå解ãããŠã¢ã«
ã«ãªæµžéæ§ã«ãªãã»ã«ããŒãºãšã¹ãã«ãããªãã
ã«ãšã¹ãã«ãŸãã¯ããªããã«ã¢ã»ã¿ãŒã«å±€ããã³
ãã®äžã«ïŒïŒéæ²æ®¿æ žãå«æããåçã»ã«ããŒ
ãºå±€ãèšããååèŠçŽ ãé瀺ãããŠããããã
ãŠãæ¡æ£å¯èœã§éç»åã®æ§è³ªãå€ãããååç©ãš
ããŠã¯ãææ©ã¡ã«ã«ããååç©ãèšèŒãããŠã
ãããã®å Žåãæ¡æ£è»¢ååŠç液ãå±€ã®ã¡ã«ã«ã
ãååç©ãåŸã ã«å±€ã«æ¡æ£ããŠããŠãå±€ã«ç
æããŠããéç»åãä¿è·ããå€è²ãéè²ãé²æ¢ã
ãå¹æãæããã ãã®ãããªå€è²ãã耪è²ãé²æ¢ããå¹æãå®å š
ã«çºæ®ãããããã«ã¯ãã¡ã«ã«ããååç©ãåå
ãªå€è€ªè²é²æ¢ã®èœåããã€ãŠããããã€ãæªçŸå
ã®ååèŠçŽ ãä¿åããŠããéããã³æ¡æ£è»¢ååŠç
äžã¯ãå±€ã«çãŸã€ãŠããŠãæ¡æ£è»¢ååŠçã«ãã€
ãŠéç»åã®çæåŸã«ãå±€ããå±€ãžæµžéããŠã
ã€ãŠãå±€ã«çæããç»åãä¿è·ããããšãå¿ èŠ
ã§ãããå®å šã«æ¡æ£è»¢ååŠçãçµäºããªããã¡
ã«ãã¡ã«ã«ããååç©ã®å±€ããå±€ãžã®æ¡æ£ã
èµ·ããšãçŸåãæå¶ãããååèŠçŽ äžã®è»¢åéç»
åã®å åŠæ¿åºŠãå šäœçã«äœäžããããŸããã¡ã«ã«
ããååç©ã®æ¡æ£ãé ããããšãã¡ã«ã«ããåå
ç©ã«ãã€ãŠéç»åãä¿è·ãããåã«ç»åã®å€è²ã
éè²ãèµ·ã€ãŠããŸãã ããããªãããç¹å ¬æ56â44418ã«èšèŒãããŠ
ããã¡ã«ã«ããååç©ã¯ãå€è²åã¯è€ªè²é²æ¢ã®èœ
åãäžå åã§ããç»åã®å€è²ã耪è²ãèµ·ãããã
æªçŸåã®ååèŠçŽ ãä¿åããŠããéã«å±€ãã
å±€ãžæ¡æ£ããŠçŸåãæå¶ãã転åéç»åã®å åŠæ¿
床ãäœäžããããšããæ¬ ç¹ããã€ãã ãŸããç¹éæ49â120634ã«ã¯ãéç»åã®æ§è³ªã
å€ããååç©ãå«æããããªããŒå±€ãšããŠå€äŸ¡ã¢
ã«ã³ãŒã«ã®ã¢ãã¢ã¯ãªã¬ãŒãåã¯ã¢ãã¡ã¿ã¢ã¯ãª
ã¬ãŒãã®ãã¢ããªããŒãã³ããªããŒããã³ã°ã©ã
ãããªããŒãçšããããšã«ãã€ãŠäœè£œããååèŠ
çŽ ã«ã€ããŠèšèŒãããŠããã ããããªãããç¹éæ49â120634ã«èšèŒãããŠ
ããååç©ã¯ãç¹å ¬æ56â44418ã«èšèŒãããŠã
ãååç©ãšåæ§ã«ç»åã®å€è²ãéè²é²æ¢ãäžåå
ã§ãã€ãããæªçŸåã®ååèŠçŽ ãä¿åããŠããé
ã«ã転åéç»åã®å åŠæ¿åºŠãäœäžãããšããæ¬ ç¹
ããã€ãã ããã«è±åœç¹èš±1276961ã«ã¯æ¡æ£è»¢åæ³ã§å®å®
ãªéç»åãåŸãããã«ïŒâã¡ã«ã«ããâïŒïŒïŒïŒ
ïŒâããªã¢ãŸãŒã«èªå°äœãçšããããšãé瀺ãã
ãŠããããŸãç±³åœç¹èš±3655380ã«ã¯ãïŒâã»ã¬ã
âïŒïŒïŒïŒïŒïŒïŒâããã©ãŸãŒã«èªå°äœããæ¡æ£
転åæ³ã§åŸãããéç»åã®è²èª¿ãäžç°è²ã«æ¹è¯ã§
ããã ãã§ãªããå®å®ãªéç»åãäžããããšãé
瀺ãããŠããã ãããã¯ç¹å ¬æ56â21140ãç¹è¡šæ56â500431
ã«ã¯ã貎éå±ååç©ãéç»åã«äœçšãããããšã«
ãã€ãŠéç»åã®éè²ãé²ãããšãé瀺ãããŠã
ãã ããããªããããããã®ææ©ã¡ã«ã«ããååç©
ã§ã¯ãæ¡æ£è»¢åæ³ã«ããåŸãããéç»åã®å®å®å
ã®å¹æã¯äžååã§ãããç»åã®å€è²ãéè²ãèµ·ã
ããšããæ¬ ç¹ããã€ãããŸãããããã®è²Žéå±å
åç©ã¯ãéç»åãä¿è·ããããã«å€éã«çµã¿èŸŒãŸ
ãã°ãªãããã¹ãã€ã³ãçºçããããç»å圢æé
床ã«å¥œãŸãããã¬åœ±é¿ãäžãããªã©ã®åé¡ã䌎ãª
ã€ãŠããããšãå€æããã éç»åå®å®åå€ã®å¥œãŸãããªãæ¡æ£ãé²æ¢ãã
ããã«ãç¹é¡æ58â148979å·ãå58â151355å·ãª
ã©ã§ã¯ãã¢ã«ã«ãªé浞éæ§ããªããŒã®éã«ã芪氎
æ§ããªããŒå±€ãèšãã±ã³å液ã®æ¡æ£é床ã®å·®ãå©
çšããŠãã±ã³åã®çšåºŠã調ç¯ãããã®çµæãšã
ãŠãæ·»å ããŠããéç»åå®å®åå€ã®æ¡æ£ã調ç¯ã
ãè©Šã¿ãé瀺ãããŠããããã®æ¹æ³ã§ã¯ã補é å·¥
çšãäžå·¥çšå¢å ããäžã«ã芪氎æ§å±€ãšçæ°Žæ§å±€ã®
å±€éã®æ¥çåã匱ãã補é æã«ãèã¯ãããçã
ããªã©ã®æ¬ ç¹ãçããã ããã«ãäžè¿°ãã芪氎æ§å±€ãèšçœ®ããªãã§ç»å
å®å®åå€ãäžåå±€ãäžåã¿ã€ãã³ã°å±€ã«æ·»å ãã
å®æœäŸã¯ãç¹é¡æ58â106464å·ã«èšèŒãããŠã
ãããã®å®æœäŸïŒã«ã¯ç»åå®å®åå€ãäžåã¿ã€ã
ã³ã°å±€ã«æ·»å ããã転ååã®åŒ·å¶å£åãã¹ãçµæ
ãèšèŒãããŠããã匷å¶å£åãã¹ãã§ã¯éåžžã«å¹
æã¯ããããåç¹èš±ã®å®æœäŸïŒã®èŠªæ°Žæ§å±€ããã®
äŸãšæ¯ã¹ããšãçŸååŠççŽåŸæ¿åºŠãäœãããã®å®
æœäŸã§ã¯ã±ã³å液ã«æ°Žãæ·»å ãããŠããããã®ã
ãã«ã±ã³åéãå€ãããšã«èµ·å ããŠããã芪氎æ§
å±€ããªãå Žåã«ã¯åã«ç»åå®å®åå€ã®äžåå±€ãã
ã³äžåã¿ã€ã³ãã³ã°å±€ã®å°ãªããšãïŒå±€ãžã®åé
ã ãã§ã¯è§£æ±ºãããªãã ïŒçºæã解決ããããšããåé¡ç¹ïŒ 以äžã®ããã«åŸæ¥ã®æè¡ã§ã¯çŸååŠçããå Žå
ã®æé«æ¿åºŠãååé«ãè²èª¿ãã°ã¬ãŒïŒäžç°è²ïŒã«
ä¿ã¡ãããã§ãããã€ãããªã³ãã®ç»åãé·æã®
ä¿åã«å¯ŸããŠãå®å®ã§ãå€è€ªè²ãããããçœå°ã®
ã¹ãã€ã³ã®äžæããªããã³ã¹ãã®å®ãååèŠçŽ ã
æäŸããããšãã§ããªãã€ãã åŸã€ãŠæ¬çºæã®ç®çã¯äžèšæ§èœãåæã«ç¢ºä¿ã
ããååèŠçŽ ãæäŸããããšã«ããã ïŒåé¡ç¹ã解決ããããã®ææ®µïŒ ãã®ãããªåé¡ã«ã€ããŠãéææ¹è¯ãæ€èšãã
çµæãååèŠçŽ äžã®ç»åå®å®åå€ã®æ·»å äœçœ®ãã
ã³éãšã±ã³ååå¿ã«äœ¿çšããã¢ã«ã«ãªã±ã³å液çµ
æãçµã¿åãããããšã«ããéæãããããšãèŠ
åºãããå³ã¡æ¯æäœäžã«æ¯æäœåŽããé 次ãå°ãª
ããšãã¢ã«ã«ãªäžåå±€ãäžåã¿ã€ãã³ã°å±€ãã»ã«
ããŒã¹ãšã¹ãã«ãå¡èšåŸã¢ã«ã«ãªæ¶²ã«ãã鹞åã
ãŠåŸãããåçã»ã«ããŒã¹äžã«éæ²ç©æ žãå«ãå
åå±€ãå«æããéå¡©æ¡æ£è»¢åæ³ååèŠçŽ ã«ãã
ãŠã該ã¢ã«ã«ãªæ¶²ãïŒå以äžã®æ°Žé žåºãæããå€
䟡ã¢ã«ã³ãŒã«åã¯ãã®èªå°äœãïŒã20ééïŒ å«æ
ãããã€è©²äžåå±€ããã³è©²äžåã¿ã€ãã³ã°å±€ã®å°
ãªããšãïŒå±€äžã«äžèšäžè¬åŒïŒïŒããŸãã¯ïŒïŒ
ã§è¡šããããååç©ãå°ãªããšãïŒã€å«æããã
ãšãç¹åŸŽãšããéå¡©æ¡æ£è»¢åæ³ååèŠçŽ ã«ãã€ãŠ
åèšã®åé¡ç¹ã解決ãããããšãèŠåºããã ïŒïŒ
転ååçæ³ãç¥ãããŠããããã®ãããªåçæ³ã«
ãããŠã¯é²å ãããããã²ã³åéåçä¹³å€ãå«æ
ããæå èŠçŽ ãšãéæ²ç©æ žãå«æããååèŠçŽ ãš
ãéãåããããããïŒã€ã®èŠçŽ ã®éã«ãçŸåäž»
è¬ã®ååšäžã§ããã²ã³åé溶å€ãå«ãã¢ã«ã«ãªæ§
åŠç液ãå¡ãã€ããŠåŠçããããšã«ãããååèŠ
çŽ äžã«çŽæ¥ã«ããžã®éç»åãåŸãæ¹æ³ãç¥ãããŠ
ããã ãã®æ¹æ³ã§ã¯ãæå èŠçŽ äžã®æªé²å ã®ããã²ã³
åéä¹³å€ããããã²ã³åé溶å€ã«ãã溶解ãããŠ
éã€ãªã³é¯äœãšããŠã¢ã«ã«ãªæ§åŠç液äžã«æº¶ãåº
ããååèŠçŽ ã«è»¢åããŠãååèŠçŽ äžã§éæ²ç©æ ž
ã®äœçšã«ããéç»åãšããŠæ²æ®¿ããããšã«ãã€
ãŠãçŽæ¥ããžç»åã圢æãããã ããããªããããã®ããã«ããŠããããååèŠ
çŽ ã«åœ¢æãããéç»åã¯ãä¿åäžã«å€è²ãããã
ããã¯éè²ããããããããšããæ¬ ç¹ããã€ãã
çœå°ã«ã¹ãã€ã³ãçºçãããããšããæ¬ ç¹ããã€
ãã ãã®æ¬ ç¹ãæ¹è¯ããæ¹æ³ãšããŠãç¹å ¬æ46â
5392ãç±³åœç¹èš±3533789ããã³è±åœç¹èš±1164642ã®
åæ现æžã«ã¯ãããããéç»åè¡šé¢ã«ã¢ã«ã«ãªäž
åæåãå«æãã氎溶æ§ããªããŒæ¶²ãå¡åžããæ¹
æ³ãèšèŒãããŠãããããããªããããã®æ¹æ³ã§
ã¯ãããªããŒæ°Žæº¶æ¶²ãå¡åžããè¡šé¢ãå®å šã«ä¹Ÿç¥
ãããŸã§ã«ããªãã®æéãèŠãããã®éãè¡šé¢ã
ããããããŠç²çæ§ã§ããã®ã§ããªã³ããéãã
ããšãã§ãããæçŽã塵åãä»çããããšããã°
ãã°ãã€ãããŸããéç»åã«ããã«ãã®ãããªæ¶²
ãå¡åžããããšã¯ç ©éã§ããã ãŸãã転ååãã倧æ°äžã«ååšããç¡«åæ°ŽçŽ ã«
ããå解ã«ããé»å€ããæ¬ é¥ã«å¯ŸããŠã¯ãç¹éæ
47â10937ã«ååå±€ã®ã¢ã«ã«ãªåºŠãäœäžãããäž
åãæãã¯å¹Ÿåé žæ§ã«ããããšãé瀺ãããŠãã
ããPHãäœäžããããã ãã§ã¯çš®ã ã®ä¿åæ¡ä»¶ã«
察ããŠã¯ååãªå¹æãäžããããšã¯ã§ããªãã ç¹å ¬æ56â44418æ现æžã«ã¯ãæ¯æäœã®äžã«ã
ïŒïŒæ¡æ£å¯èœã§éç»åã®æ§è³ªãå€ãããååç©
ãå«æããå æ°Žå解å¯èœã§ãå æ°Žå解ãããŠã¢ã«
ã«ãªæµžéæ§ã«ãªãã»ã«ããŒãºãšã¹ãã«ãããªãã
ã«ãšã¹ãã«ãŸãã¯ããªããã«ã¢ã»ã¿ãŒã«å±€ããã³
ãã®äžã«ïŒïŒéæ²æ®¿æ žãå«æããåçã»ã«ããŒ
ãºå±€ãèšããååèŠçŽ ãé瀺ãããŠããããã
ãŠãæ¡æ£å¯èœã§éç»åã®æ§è³ªãå€ãããååç©ãš
ããŠã¯ãææ©ã¡ã«ã«ããååç©ãèšèŒãããŠã
ãããã®å Žåãæ¡æ£è»¢ååŠç液ãå±€ã®ã¡ã«ã«ã
ãååç©ãåŸã ã«å±€ã«æ¡æ£ããŠããŠãå±€ã«ç
æããŠããéç»åãä¿è·ããå€è²ãéè²ãé²æ¢ã
ãå¹æãæããã ãã®ãããªå€è²ãã耪è²ãé²æ¢ããå¹æãå®å š
ã«çºæ®ãããããã«ã¯ãã¡ã«ã«ããååç©ãåå
ãªå€è€ªè²é²æ¢ã®èœåããã€ãŠããããã€ãæªçŸå
ã®ååèŠçŽ ãä¿åããŠããéããã³æ¡æ£è»¢ååŠç
äžã¯ãå±€ã«çãŸã€ãŠããŠãæ¡æ£è»¢ååŠçã«ãã€
ãŠéç»åã®çæåŸã«ãå±€ããå±€ãžæµžéããŠã
ã€ãŠãå±€ã«çæããç»åãä¿è·ããããšãå¿ èŠ
ã§ãããå®å šã«æ¡æ£è»¢ååŠçãçµäºããªããã¡
ã«ãã¡ã«ã«ããååç©ã®å±€ããå±€ãžã®æ¡æ£ã
èµ·ããšãçŸåãæå¶ãããååèŠçŽ äžã®è»¢åéç»
åã®å åŠæ¿åºŠãå šäœçã«äœäžããããŸããã¡ã«ã«
ããååç©ã®æ¡æ£ãé ããããšãã¡ã«ã«ããåå
ç©ã«ãã€ãŠéç»åãä¿è·ãããåã«ç»åã®å€è²ã
éè²ãèµ·ã€ãŠããŸãã ããããªãããç¹å ¬æ56â44418ã«èšèŒãããŠ
ããã¡ã«ã«ããååç©ã¯ãå€è²åã¯è€ªè²é²æ¢ã®èœ
åãäžå åã§ããç»åã®å€è²ã耪è²ãèµ·ãããã
æªçŸåã®ååèŠçŽ ãä¿åããŠããéã«å±€ãã
å±€ãžæ¡æ£ããŠçŸåãæå¶ãã転åéç»åã®å åŠæ¿
床ãäœäžããããšããæ¬ ç¹ããã€ãã ãŸããç¹éæ49â120634ã«ã¯ãéç»åã®æ§è³ªã
å€ããååç©ãå«æããããªããŒå±€ãšããŠå€äŸ¡ã¢
ã«ã³ãŒã«ã®ã¢ãã¢ã¯ãªã¬ãŒãåã¯ã¢ãã¡ã¿ã¢ã¯ãª
ã¬ãŒãã®ãã¢ããªããŒãã³ããªããŒããã³ã°ã©ã
ãããªããŒãçšããããšã«ãã€ãŠäœè£œããååèŠ
çŽ ã«ã€ããŠèšèŒãããŠããã ããããªãããç¹éæ49â120634ã«èšèŒãããŠ
ããååç©ã¯ãç¹å ¬æ56â44418ã«èšèŒãããŠã
ãååç©ãšåæ§ã«ç»åã®å€è²ãéè²é²æ¢ãäžåå
ã§ãã€ãããæªçŸåã®ååèŠçŽ ãä¿åããŠããé
ã«ã転åéç»åã®å åŠæ¿åºŠãäœäžãããšããæ¬ ç¹
ããã€ãã ããã«è±åœç¹èš±1276961ã«ã¯æ¡æ£è»¢åæ³ã§å®å®
ãªéç»åãåŸãããã«ïŒâã¡ã«ã«ããâïŒïŒïŒïŒ
ïŒâããªã¢ãŸãŒã«èªå°äœãçšããããšãé瀺ãã
ãŠããããŸãç±³åœç¹èš±3655380ã«ã¯ãïŒâã»ã¬ã
âïŒïŒïŒïŒïŒïŒïŒâããã©ãŸãŒã«èªå°äœããæ¡æ£
転åæ³ã§åŸãããéç»åã®è²èª¿ãäžç°è²ã«æ¹è¯ã§
ããã ãã§ãªããå®å®ãªéç»åãäžããããšãé
瀺ãããŠããã ãããã¯ç¹å ¬æ56â21140ãç¹è¡šæ56â500431
ã«ã¯ã貎éå±ååç©ãéç»åã«äœçšãããããšã«
ãã€ãŠéç»åã®éè²ãé²ãããšãé瀺ãããŠã
ãã ããããªããããããã®ææ©ã¡ã«ã«ããååç©
ã§ã¯ãæ¡æ£è»¢åæ³ã«ããåŸãããéç»åã®å®å®å
ã®å¹æã¯äžååã§ãããç»åã®å€è²ãéè²ãèµ·ã
ããšããæ¬ ç¹ããã€ãããŸãããããã®è²Žéå±å
åç©ã¯ãéç»åãä¿è·ããããã«å€éã«çµã¿èŸŒãŸ
ãã°ãªãããã¹ãã€ã³ãçºçããããç»å圢æé
床ã«å¥œãŸãããã¬åœ±é¿ãäžãããªã©ã®åé¡ã䌎ãª
ã€ãŠããããšãå€æããã éç»åå®å®åå€ã®å¥œãŸãããªãæ¡æ£ãé²æ¢ãã
ããã«ãç¹é¡æ58â148979å·ãå58â151355å·ãª
ã©ã§ã¯ãã¢ã«ã«ãªé浞éæ§ããªããŒã®éã«ã芪氎
æ§ããªããŒå±€ãèšãã±ã³å液ã®æ¡æ£é床ã®å·®ãå©
çšããŠãã±ã³åã®çšåºŠã調ç¯ãããã®çµæãšã
ãŠãæ·»å ããŠããéç»åå®å®åå€ã®æ¡æ£ã調ç¯ã
ãè©Šã¿ãé瀺ãããŠããããã®æ¹æ³ã§ã¯ã補é å·¥
çšãäžå·¥çšå¢å ããäžã«ã芪氎æ§å±€ãšçæ°Žæ§å±€ã®
å±€éã®æ¥çåã匱ãã補é æã«ãèã¯ãããçã
ããªã©ã®æ¬ ç¹ãçããã ããã«ãäžè¿°ãã芪氎æ§å±€ãèšçœ®ããªãã§ç»å
å®å®åå€ãäžåå±€ãäžåã¿ã€ãã³ã°å±€ã«æ·»å ãã
å®æœäŸã¯ãç¹é¡æ58â106464å·ã«èšèŒãããŠã
ãããã®å®æœäŸïŒã«ã¯ç»åå®å®åå€ãäžåã¿ã€ã
ã³ã°å±€ã«æ·»å ããã転ååã®åŒ·å¶å£åãã¹ãçµæ
ãèšèŒãããŠããã匷å¶å£åãã¹ãã§ã¯éåžžã«å¹
æã¯ããããåç¹èš±ã®å®æœäŸïŒã®èŠªæ°Žæ§å±€ããã®
äŸãšæ¯ã¹ããšãçŸååŠççŽåŸæ¿åºŠãäœãããã®å®
æœäŸã§ã¯ã±ã³å液ã«æ°Žãæ·»å ãããŠããããã®ã
ãã«ã±ã³åéãå€ãããšã«èµ·å ããŠããã芪氎æ§
å±€ããªãå Žåã«ã¯åã«ç»åå®å®åå€ã®äžåå±€ãã
ã³äžåã¿ã€ã³ãã³ã°å±€ã®å°ãªããšãïŒå±€ãžã®åé
ã ãã§ã¯è§£æ±ºãããªãã ïŒçºæã解決ããããšããåé¡ç¹ïŒ 以äžã®ããã«åŸæ¥ã®æè¡ã§ã¯çŸååŠçããå Žå
ã®æé«æ¿åºŠãååé«ãè²èª¿ãã°ã¬ãŒïŒäžç°è²ïŒã«
ä¿ã¡ãããã§ãããã€ãããªã³ãã®ç»åãé·æã®
ä¿åã«å¯ŸããŠãå®å®ã§ãå€è€ªè²ãããããçœå°ã®
ã¹ãã€ã³ã®äžæããªããã³ã¹ãã®å®ãååèŠçŽ ã
æäŸããããšãã§ããªãã€ãã åŸã€ãŠæ¬çºæã®ç®çã¯äžèšæ§èœãåæã«ç¢ºä¿ã
ããååèŠçŽ ãæäŸããããšã«ããã ïŒåé¡ç¹ã解決ããããã®ææ®µïŒ ãã®ãããªåé¡ã«ã€ããŠãéææ¹è¯ãæ€èšãã
çµæãååèŠçŽ äžã®ç»åå®å®åå€ã®æ·»å äœçœ®ãã
ã³éãšã±ã³ååå¿ã«äœ¿çšããã¢ã«ã«ãªã±ã³å液çµ
æãçµã¿åãããããšã«ããéæãããããšãèŠ
åºãããå³ã¡æ¯æäœäžã«æ¯æäœåŽããé 次ãå°ãª
ããšãã¢ã«ã«ãªäžåå±€ãäžåã¿ã€ãã³ã°å±€ãã»ã«
ããŒã¹ãšã¹ãã«ãå¡èšåŸã¢ã«ã«ãªæ¶²ã«ãã鹞åã
ãŠåŸãããåçã»ã«ããŒã¹äžã«éæ²ç©æ žãå«ãå
åå±€ãå«æããéå¡©æ¡æ£è»¢åæ³ååèŠçŽ ã«ãã
ãŠã該ã¢ã«ã«ãªæ¶²ãïŒå以äžã®æ°Žé žåºãæããå€
䟡ã¢ã«ã³ãŒã«åã¯ãã®èªå°äœãïŒã20ééïŒ å«æ
ãããã€è©²äžåå±€ããã³è©²äžåã¿ã€ãã³ã°å±€ã®å°
ãªããšãïŒå±€äžã«äžèšäžè¬åŒïŒïŒããŸãã¯ïŒïŒ
ã§è¡šããããååç©ãå°ãªããšãïŒã€å«æããã
ãšãç¹åŸŽãšããéå¡©æ¡æ£è»¢åæ³ååèŠçŽ ã«ãã€ãŠ
åèšã®åé¡ç¹ã解決ãããããšãèŠåºããã ïŒïŒ
ãåŒã
ïŒïŒ
ãåã
åŒäžRoã¯åãã§ãç°ãªã€ãŠããŠããããæ°ŽçŽ
ååãããã²ã³ååïŒäŸãã°ïŒŠãClãBrïŒãã¢ã«
ãã«åºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ã¢ã«ãã«åºïŒäŸ
ãã°ã¡ãã«åºããšãã«åºïŒã眮æã¢ã«ãã«åºå¥œãŸ
ããã¯ã¢ã«ãã«éšåã®ççŽ æ°ãïŒã14ã®çœ®æã¢ã«
ãã«åºã眮æãŸãã¯ç¡çœ®æã®ã·ã¯ãã¢ã«ãã«åºå¥œ
ãŸããã¯ççŽ æ°ïŒã14ã®ãã®ãã¢ã«ã³ãã·åºå¥œãŸ
ããã¯ççŽ æ°ïŒã14ã®ãã®ã眮æã¢ã«ã³ãã·åºå¥œ
ãŸããã¯ççŽ æ°ïŒã14ã®ãã®ïŒäŸãã°ã¡ããã·
åºããšããã·åºïŒã眮æãŸãã¯ç¡çœ®æã®ã¢ã«ãã«
ã¹ã«ããã«åºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ãã®ã眮
æãŸãã¯ç¡çœ®æã®ã¢ãªãŒã«ã¹ã«ããã«åºå¥œãŸãã
ã¯ççŽ æ°ïŒã14ã®ãã®ãã¹ã«ãã¢ã¢ã€ã«åºïŒãã
ã該ã¹ã«ãã¢ã¢ã€ã«åºã®çªçŽ ååã¯ççŽ æ°14以äž
ã®ã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«
åºã眮æã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢
ãªãŒã«åºãïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»
ååã®å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸãã¯
ç¡çœ®æã®è€çŽ ç°åºã§çœ®æãããŠããŠãããã該çª
çŽ ååäžã®ïŒã€ã®çœ®æåºãäºãã«é£ãªã€ãŠç°ã圢
æããŠããããïŒãã¢ã«ãã«ãŸãã¯ã¢ãªãŒã«ã¹ã«ã
ã³ã¢ããåºïŒãã ãã¢ã«ãã«éšåãŸãã¯ã¢ãªãŒã«
éšåã¯çœ®æåºãæããŠãããã該ã¹ã«ãã³ã¢ãã
åºã®çªçŽ ååã¯ãççŽ æ°14以äžã®ã¢ã«ãã«åºã眮
æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã眮æã·ã¯ãã¢
ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºãïŒãïŒ
å¡ã®çªçŽ ååãé žçŽ ååãç¡«é»ååã®å°ãªããšã
ïŒçš®ãïŒå以äžå«ã眮æãŸãã¯ç¡çœ®æã®è€çŽ ç°åº
ã§çœ®æãããŠããŠããããïŒãã«ã«ãã¢ã€ã«åºïŒã
ã ã該ã«ã«ãã¢ã€ã«åºã®çªçŽ ååã¯ççŽ æ°14以äž
ã®ã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«
åºã眮æã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢
ãªãŒã«åºãïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»
ååã®å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸãã¯
ç¡çœ®æã®è€çŽ ç°åºã§çœ®æãããŠããŠãããã該çª
çŽ ååäžã®ïŒã€ã®çœ®ãäºã«é£ãªã€ãŠç°ã圢æããŠ
ããŠããããïŒãã«ã«ãã¢ããåºïŒãã ã該ã«ã«ã
ã³ã¢ããåºã®çªçŽ ååã¯ççŽ æ°14以äžã®ã¢ã«ãã«
åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã眮æã·
ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºã
ïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»ååã®ãã¡
å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸãã¯ç¡çœ®æ
ã®è€çŽ ç°åºã§çœ®æãããŠããŠããããïŒãè€çŽ ç°åº
奜ãŸããã¯ïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»
ååã®ãã¡å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸ
ãã¯ç¡çœ®æã®è€çŽ ç°åºã眮æãŸãã¯ç¡çœ®æã®ã¢ãª
ãŒã«åºå¥œãŸããã¯ççŽ æ°14以äžã®ãã®ãã¢ã·ã«åº
奜ãŸããã¯ççŽ æ°14以äžã®ãã®ã眮æãŸãã¯ç¡çœ®
æã®ã¢ã«ã³ãã·ã«ã«ããã«åºå¥œãŸããã¯ççŽ æ°ïŒ
ã14ã®ãã®ã眮æãŸãã¯ç¡çœ®æã®ã¢ã·ã«ãªãã·åº
奜ãŸããã¯ççŽ æ°ïŒã14ã®ãã®ã眮æåã¯ç¡çœ®æ
ã®ã¢ã«ãã«ããªåºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ã
ã®ã眮æãŸãã¯ç¡çœ®æã®ã¢ãªãŒã«ããªåºå¥œãŸãã
ã¯ççŽ æ°ïŒã14ã®ãã®ãïŒçŽã¢ããåºãŸãã¯ãã®
å¡©ãççŽ æ°ïŒã14ã®ã¢ã«ãã«åºãŸãã¯ççŽ æ°ïŒã
14ã®ã¢ãªãŒã«åºã§çœ®æãããïŒçŽãŸãã¯ïŒçŽã¢ã
ãåºãŸãã¯ãã®å¡©ãäœãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒ
ã«åºã¯çœ®æåºãæããŠããŠãããããããåºãã
ãããã·åºãã«ã«ããã·ã«åºãã¹ã«ãã³é žåºããŸ
ãã¯ã·ã¢ãåºãè¡šãããR1ãR2ã¯åã æ°ŽçŽ ååã
ã¢ã«ãã«åºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ãã®ïŒäŸã
ã°ã¡ãã«åºããšãã«åºïŒã眮æã¢ã«ãã«åºå¥œãŸã
ãã¯ã¢ã«ãã«éšåã®ççŽ æ°ãïŒã14ã®ãã®ïŒäŸã
ã°ã¡ããã·ãšãã«åºããšããã·ãšãã«åºãã¯ãã«
ãšãã«åºããã³ãžã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ã
ãšãã«åºããããã«åºïŒãè¡šããã R3ãR4ã¯åã ãæ°ŽçŽ ååãã¢ã«ãã«åºå¥œãŸã
ãã¯ççŽ æ°ïŒã14ã®ãã®ïŒäŸãã°ããã«åºããã
ã·ã«åºããªã¯ãã«åºïŒã眮æã¢ã«ãã«åºå¥œãŸãã
ã¯ã¢ã«ãã«éšåã®ççŽ æ°ãïŒã14ã®ãã®ïŒäŸãã°
ã¡ããã·åºããã³ãžã«åºãããããã·ãšãã«åºïŒã
ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºããããã«åºïŒãŸ
ãã¯çœ®æã¢ãªãŒã«åºãè€çŽ ç°åºå¥œãŸããã¯ïŒãïŒ
å¡ã®çªçŽ ååãé žçŽ ååãç¡«é»ååã®ãã¡å°ãªã
ã®ãïŒçš®ãïŒå以äžå«ã眮æåã¯ç¡çœ®æã®è€çŽ ç°
åºãè¡šãããR3ãR4ã¯ïŒ®ååãšå ±ã«ïŒãïŒå¡ç°
ïŒäŸãã°ãããªãžã³ç°ãã¢ã«ããªã³ç°ïŒã圢æã
ãŠãè¯ããç°äžã«ããã«ãããååãå«ãã§ããŠ
ãè¯ãã R5ãR6ã¯åã æ°ŽçŽ ååãã¢ã«ãã«åºå¥œãŸãã
ã¯ççŽ æ°ïŒãïŒã®ãã®ïŒäŸãã°ã¡ãã«åºããšãã«
åºïŒã眮æã¢ã«ãã«åºå¥œãŸããã¯ã¢ã«ãã«éšåã®
ççŽ æ°ãïŒãïŒã®ãã®ïŒäŸãã°ã¡ããã·ãšãã«
åºãããããã·ãšãã«åºããã³ãžã«åºïŒãã¢ãªãŒ
ã«åºïŒäŸãã°ããšãã«åºïŒã眮æã¢ãªãŒã«åºãè€
çŽ ç°åºå¥œãŸããã¯ïŒãïŒå¡ã®çªçŽ ååãé žçŽ å
åãç¡«é»ååã®ãã¡å°ãªããšãïŒçš®ãïŒå以äžå«
ã眮æãŸãã¯ç¡çœ®æã®è€çŽ ç°åºãè¡šããã R1åã¯R2ã§è¡šãããã眮æã¢ã«ãã«åºã®çœ®æ
åºãšããŠã¯ãäŸãã°ã¢ã«ã³ãã·åºïŒäŸãã°ã¡ãã
ã·åºããšããã·åºïŒãããã²ã³ååïŒäŸãã°Clã
BrïŒããšãã«åºãæããããã R3ãR6ã§è¡šãããã眮æã¢ã«ãã«åºã®çœ®æåº
ãšããŠã¯äŸãã°ã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·
åºããšããã·åºïŒãããã²ã³ååïŒäŸãã°Clã
BrïŒãããšãã«åºãããããã·ã«åºãæããã
ãã R3ãR6ã§è¡šãããã眮æã¢ãªãŒã«åºã®çœ®æåº
ãšããŠã¯ãäŸãã°ã¢ã«ãã«åºïŒäŸããã¡ãã«åºã
ãšãã«åºïŒãã¢ã«ã³ãã·åºïŒã¡ããã·åºããšãã
ã·åºïŒãããã²ã³ååïŒClãBrïŒãæããããã A1ã¯äºäŸ¡ã®åºãè¡šããã奜ãŸããäºäŸ¡ã®åºãš
ããŠæ¬¡ã®ãã®ãæããããã ïŒâCH2âïŒo1 ïŒâCH2âïŒo1ãäœãn1ã¯ïŒãïŒã®
æŽæ°ã ïŒâCH2âïŒo2âãäœãn2ã¯ïŒã12ã®æŽæ°ã
ååãããã²ã³ååïŒäŸãã°ïŒŠãClãBrïŒãã¢ã«
ãã«åºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ã¢ã«ãã«åºïŒäŸ
ãã°ã¡ãã«åºããšãã«åºïŒã眮æã¢ã«ãã«åºå¥œãŸ
ããã¯ã¢ã«ãã«éšåã®ççŽ æ°ãïŒã14ã®çœ®æã¢ã«
ãã«åºã眮æãŸãã¯ç¡çœ®æã®ã·ã¯ãã¢ã«ãã«åºå¥œ
ãŸããã¯ççŽ æ°ïŒã14ã®ãã®ãã¢ã«ã³ãã·åºå¥œãŸ
ããã¯ççŽ æ°ïŒã14ã®ãã®ã眮æã¢ã«ã³ãã·åºå¥œ
ãŸããã¯ççŽ æ°ïŒã14ã®ãã®ïŒäŸãã°ã¡ããã·
åºããšããã·åºïŒã眮æãŸãã¯ç¡çœ®æã®ã¢ã«ãã«
ã¹ã«ããã«åºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ãã®ã眮
æãŸãã¯ç¡çœ®æã®ã¢ãªãŒã«ã¹ã«ããã«åºå¥œãŸãã
ã¯ççŽ æ°ïŒã14ã®ãã®ãã¹ã«ãã¢ã¢ã€ã«åºïŒãã
ã該ã¹ã«ãã¢ã¢ã€ã«åºã®çªçŽ ååã¯ççŽ æ°14以äž
ã®ã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«
åºã眮æã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢
ãªãŒã«åºãïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»
ååã®å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸãã¯
ç¡çœ®æã®è€çŽ ç°åºã§çœ®æãããŠããŠãããã該çª
çŽ ååäžã®ïŒã€ã®çœ®æåºãäºãã«é£ãªã€ãŠç°ã圢
æããŠããããïŒãã¢ã«ãã«ãŸãã¯ã¢ãªãŒã«ã¹ã«ã
ã³ã¢ããåºïŒãã ãã¢ã«ãã«éšåãŸãã¯ã¢ãªãŒã«
éšåã¯çœ®æåºãæããŠãããã該ã¹ã«ãã³ã¢ãã
åºã®çªçŽ ååã¯ãççŽ æ°14以äžã®ã¢ã«ãã«åºã眮
æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã眮æã·ã¯ãã¢
ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºãïŒãïŒ
å¡ã®çªçŽ ååãé žçŽ ååãç¡«é»ååã®å°ãªããšã
ïŒçš®ãïŒå以äžå«ã眮æãŸãã¯ç¡çœ®æã®è€çŽ ç°åº
ã§çœ®æãããŠããŠããããïŒãã«ã«ãã¢ã€ã«åºïŒã
ã ã該ã«ã«ãã¢ã€ã«åºã®çªçŽ ååã¯ççŽ æ°14以äž
ã®ã¢ã«ãã«åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«
åºã眮æã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢
ãªãŒã«åºãïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»
ååã®å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸãã¯
ç¡çœ®æã®è€çŽ ç°åºã§çœ®æãããŠããŠãããã該çª
çŽ ååäžã®ïŒã€ã®çœ®ãäºã«é£ãªã€ãŠç°ã圢æããŠ
ããŠããããïŒãã«ã«ãã¢ããåºïŒãã ã該ã«ã«ã
ã³ã¢ããåºã®çªçŽ ååã¯ççŽ æ°14以äžã®ã¢ã«ãã«
åºã眮æã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã眮æã·
ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºã
ïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»ååã®ãã¡
å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸãã¯ç¡çœ®æ
ã®è€çŽ ç°åºã§çœ®æãããŠããŠããããïŒãè€çŽ ç°åº
奜ãŸããã¯ïŒãïŒå¡ã®çªçŽ ååãé žçŽ ååãç¡«é»
ååã®ãã¡å°ãªããšãïŒçš®ãïŒå以äžå«ã眮æãŸ
ãã¯ç¡çœ®æã®è€çŽ ç°åºã眮æãŸãã¯ç¡çœ®æã®ã¢ãª
ãŒã«åºå¥œãŸããã¯ççŽ æ°14以äžã®ãã®ãã¢ã·ã«åº
奜ãŸããã¯ççŽ æ°14以äžã®ãã®ã眮æãŸãã¯ç¡çœ®
æã®ã¢ã«ã³ãã·ã«ã«ããã«åºå¥œãŸããã¯ççŽ æ°ïŒ
ã14ã®ãã®ã眮æãŸãã¯ç¡çœ®æã®ã¢ã·ã«ãªãã·åº
奜ãŸããã¯ççŽ æ°ïŒã14ã®ãã®ã眮æåã¯ç¡çœ®æ
ã®ã¢ã«ãã«ããªåºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ã
ã®ã眮æãŸãã¯ç¡çœ®æã®ã¢ãªãŒã«ããªåºå¥œãŸãã
ã¯ççŽ æ°ïŒã14ã®ãã®ãïŒçŽã¢ããåºãŸãã¯ãã®
å¡©ãççŽ æ°ïŒã14ã®ã¢ã«ãã«åºãŸãã¯ççŽ æ°ïŒã
14ã®ã¢ãªãŒã«åºã§çœ®æãããïŒçŽãŸãã¯ïŒçŽã¢ã
ãåºãŸãã¯ãã®å¡©ãäœãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒ
ã«åºã¯çœ®æåºãæããŠããŠãããããããåºãã
ãããã·åºãã«ã«ããã·ã«åºãã¹ã«ãã³é žåºããŸ
ãã¯ã·ã¢ãåºãè¡šãããR1ãR2ã¯åã æ°ŽçŽ ååã
ã¢ã«ãã«åºå¥œãŸããã¯ççŽ æ°ïŒã14ã®ãã®ïŒäŸã
ã°ã¡ãã«åºããšãã«åºïŒã眮æã¢ã«ãã«åºå¥œãŸã
ãã¯ã¢ã«ãã«éšåã®ççŽ æ°ãïŒã14ã®ãã®ïŒäŸã
ã°ã¡ããã·ãšãã«åºããšããã·ãšãã«åºãã¯ãã«
ãšãã«åºããã³ãžã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ã
ãšãã«åºããããã«åºïŒãè¡šããã R3ãR4ã¯åã ãæ°ŽçŽ ååãã¢ã«ãã«åºå¥œãŸã
ãã¯ççŽ æ°ïŒã14ã®ãã®ïŒäŸãã°ããã«åºããã
ã·ã«åºããªã¯ãã«åºïŒã眮æã¢ã«ãã«åºå¥œãŸãã
ã¯ã¢ã«ãã«éšåã®ççŽ æ°ãïŒã14ã®ãã®ïŒäŸãã°
ã¡ããã·åºããã³ãžã«åºãããããã·ãšãã«åºïŒã
ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºããããã«åºïŒãŸ
ãã¯çœ®æã¢ãªãŒã«åºãè€çŽ ç°åºå¥œãŸããã¯ïŒãïŒ
å¡ã®çªçŽ ååãé žçŽ ååãç¡«é»ååã®ãã¡å°ãªã
ã®ãïŒçš®ãïŒå以äžå«ã眮æåã¯ç¡çœ®æã®è€çŽ ç°
åºãè¡šãããR3ãR4ã¯ïŒ®ååãšå ±ã«ïŒãïŒå¡ç°
ïŒäŸãã°ãããªãžã³ç°ãã¢ã«ããªã³ç°ïŒã圢æã
ãŠãè¯ããç°äžã«ããã«ãããååãå«ãã§ããŠ
ãè¯ãã R5ãR6ã¯åã æ°ŽçŽ ååãã¢ã«ãã«åºå¥œãŸãã
ã¯ççŽ æ°ïŒãïŒã®ãã®ïŒäŸãã°ã¡ãã«åºããšãã«
åºïŒã眮æã¢ã«ãã«åºå¥œãŸããã¯ã¢ã«ãã«éšåã®
ççŽ æ°ãïŒãïŒã®ãã®ïŒäŸãã°ã¡ããã·ãšãã«
åºãããããã·ãšãã«åºããã³ãžã«åºïŒãã¢ãªãŒ
ã«åºïŒäŸãã°ããšãã«åºïŒã眮æã¢ãªãŒã«åºãè€
çŽ ç°åºå¥œãŸããã¯ïŒãïŒå¡ã®çªçŽ ååãé žçŽ å
åãç¡«é»ååã®ãã¡å°ãªããšãïŒçš®ãïŒå以äžå«
ã眮æãŸãã¯ç¡çœ®æã®è€çŽ ç°åºãè¡šããã R1åã¯R2ã§è¡šãããã眮æã¢ã«ãã«åºã®çœ®æ
åºãšããŠã¯ãäŸãã°ã¢ã«ã³ãã·åºïŒäŸãã°ã¡ãã
ã·åºããšããã·åºïŒãããã²ã³ååïŒäŸãã°Clã
BrïŒããšãã«åºãæããããã R3ãR6ã§è¡šãããã眮æã¢ã«ãã«åºã®çœ®æåº
ãšããŠã¯äŸãã°ã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·
åºããšããã·åºïŒãããã²ã³ååïŒäŸãã°Clã
BrïŒãããšãã«åºãããããã·ã«åºãæããã
ãã R3ãR6ã§è¡šãããã眮æã¢ãªãŒã«åºã®çœ®æåº
ãšããŠã¯ãäŸãã°ã¢ã«ãã«åºïŒäŸããã¡ãã«åºã
ãšãã«åºïŒãã¢ã«ã³ãã·åºïŒã¡ããã·åºããšãã
ã·åºïŒãããã²ã³ååïŒClãBrïŒãæããããã A1ã¯äºäŸ¡ã®åºãè¡šããã奜ãŸããäºäŸ¡ã®åºãš
ããŠæ¬¡ã®ãã®ãæããããã ïŒâCH2âïŒo1 ïŒâCH2âïŒo1ãäœãn1ã¯ïŒãïŒã®
æŽæ°ã ïŒâCH2âïŒo2âãäœãn2ã¯ïŒã12ã®æŽæ°ã
ãåã
äœãn3ã¯ïŒãïŒã®æŽæ°ã
ïŒâCH2âïŒo4 A2ïŒâCH2âïŒo4äœããn4ã¯ïŒãïŒã®
æŽæ°ã A2ã¯
æŽæ°ã A2ã¯
ãåŒã
ãåŒãïŒn5ã¯ïŒã10ã®æŽæ°ïŒã
ïœã¯ïŒãåã¯ïŒãïŒã®æŽæ°ãè¡šãããïœã¯ïŒã
ïŒåã¯ïŒãè¡šããã R1ãR6ã§è¡šããããã¢ã«ãã«åºåã¯ã¢ã«ãã«
éšåã¯çŽéã§ãåå²ããŠããŠãããã åèšäžè¬åŒïŒïŒã«ãããŠR1ãR2åã³R4ãæ°Ž
çŽ ååã§ãããïœãïŒã§ãããïœãïŒã§ãã€ãŠã
ãã€R3ãççŽ æ°ïŒã14ã®ã¢ã«ãã«åºåã¯ã¢ã«ã
ã«éšåã®ççŽ æ°ãïŒã14ã§ãã眮æã¢ã«ãã«åºã
è¡šããå Žåã奜ãŸããã åèšäžè¬åŒïŒïŒã«ãããŠãR1ãR2ãR5åã³
R6ãæ°ŽçŽ ååã§ãããïœãïŒã§ãã€ãŠããã€A1
ãççŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³åºãè¡šããå Žåã奜
ãŸãããããã«A1ããšãã¬ã³åºããããã¬ã³åºã
ããã¬ã³åºããã³ãã¬ã³åºããããã¬ã³åºããªã¯
ãã¬ã³åºã§ããå Žåããšãã«å¥œãŸããã äžè¬åŒïŒïŒãåã¯ïŒïŒã®äžã§æå¹ãªååç©
ã以äžã«äŸç€ºããããæ¬çºæã§ã¯ãããã®ååç©
ã«ã®ã¿éå®ããããã®ã§ã¯ãªãã
ïŒåã¯ïŒãè¡šããã R1ãR6ã§è¡šããããã¢ã«ãã«åºåã¯ã¢ã«ãã«
éšåã¯çŽéã§ãåå²ããŠããŠãããã åèšäžè¬åŒïŒïŒã«ãããŠR1ãR2åã³R4ãæ°Ž
çŽ ååã§ãããïœãïŒã§ãããïœãïŒã§ãã€ãŠã
ãã€R3ãççŽ æ°ïŒã14ã®ã¢ã«ãã«åºåã¯ã¢ã«ã
ã«éšåã®ççŽ æ°ãïŒã14ã§ãã眮æã¢ã«ãã«åºã
è¡šããå Žåã奜ãŸããã åèšäžè¬åŒïŒïŒã«ãããŠãR1ãR2ãR5åã³
R6ãæ°ŽçŽ ååã§ãããïœãïŒã§ãã€ãŠããã€A1
ãççŽ æ°ïŒãïŒã®ã¢ã«ãã¬ã³åºãè¡šããå Žåã奜
ãŸãããããã«A1ããšãã¬ã³åºããããã¬ã³åºã
ããã¬ã³åºããã³ãã¬ã³åºããããã¬ã³åºããªã¯
ãã¬ã³åºã§ããå Žåããšãã«å¥œãŸããã äžè¬åŒïŒïŒãåã¯ïŒïŒã®äžã§æå¹ãªååç©
ã以äžã«äŸç€ºããããæ¬çºæã§ã¯ãããã®ååç©
ã«ã®ã¿éå®ããããã®ã§ã¯ãªãã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåã
ãåŒã
ãåã
ãåã
ãåã
ãåã
ãåã
æ¬çºæã®ååç©ã®åæã¯æ¢ç¥ã®ææ³ã§å®æœã§ã
ãããããã€ãã®ååç©ã«ã€ããŠã¯ãç¹éæ59â
231537å·ã«èšèŒã®åææ³çã§åæã§ããã æ¬çºæã®ç»åå®å®åå€ã¯ãå°ãªããšãäžåå±€ã«
æ·»å ãããåŠçãããšãã®éç»åã®è²èª¿ãé調ã
æ床ãåŠçåŸã®ä¿åå®å®æ§ã調ç¯æ¹è¯ããããã«
䜵ããŠäžåã¿ã€ãã³ã°å±€ãååå±€åã³ãã®ä»ã®è£
å©å±€ã®å°ãªããšãïŒå±€ã«æ·»å ããããšãã§ããã æ·»å éã¯ãæ²ç©ããéã®éãªã©ã§ç°ãªãããäž
è¬çã«ã¯1.0Ã10-4ã1.65Ã10-3ã¢ã«ïŒm2ããã奜
ãŸããã¯2.0Ã10-4ã13.2Ã10-4ã¢ã«ïŒm2ã®å¡åžé
ã§ããã æ¬çºæã®ã¢ã«ã«ãªäžåå±€ãäžåã¿ã€ãã³ã°å±€ã
ã±ã³åããåã®ååå±€ã«äœ¿çšããããã»ã«ããŒã¹
ãšã¹ãã«ã¯ã»ã«ããŒã¹ã®æ°Žé žåºã®äžéšåã¯å šéšã
ãšã¹ãã«åããããã®ã§ããã°ãåççã«ã¯ã©ã
ã§ã䜿çšå¯èœã§ããããé ¢é žã»ã«ããŒã¹ãããã
ãªã³é žã»ã«ããŒã¹ãé ªé žã»ã«ããŒã¹ãªã©ã®èèªé ž
ã»ã«ããŒã¹ãç¡«é žã»ã«ããŒã¹ããªã³é žã»ã«ããŒã¹
ããã³ãããã»ã«ããŒã¹ãå«ãŸãããåç¡é žé ¢é ž
ã»ã«ããŒã¹ã®ããã«æ··æãšã¹ãã«ã䜿çšã§ããã ã»ã«ããŒã¹ã®æ°Žé žåºã®ãšã¹ãã«ãžã®çœ®æ床ãã
䜿çšãã溶åªçµæãã±ã³ååå¿ã®é床ããã³åå
å±€ã®åçæ¹æ³ïŒæº¶è§£ããéã®åžçé床ïŒã«ãã€
ãŠãäžèšã®ã»ã«ããŒã¹ãšã¹ãã«ã®äžã§åã æé©å€
ãéžã¶å¿ èŠããããäžè¬çã«ã¯èŠå®ã§ããªãã 奜ãŸããã»ã«ããŒã¹ãšã¹ãã«ã¯ãèèªé žã»ã«ã
ãŒã¹ã§ãããç¹ã«å¥œãŸãããã®ã¯é ¢é žã»ã«ããŒã¹
ã§ããã ããã«æ¬çºæã®å¥œãŸããå®æœã«ã¯é ¢é žã»ã«ããŒ
ã¹ã§çœ®æ床ã奜ãŸããã¯1.53ïŒé ¢å床40ïŒ ïŒãã
27ïŒé ¢å床58ïŒ ïŒã§ããããã奜ãŸãã眮æ床ã¯
1.7ã2.6ã§ããã æ¬çºæã«äœ¿çšããäžåã¿ã€ãã³ã°å±€ã«ãããé ¢
é žã»ã«ããŒã¹ã®å¡åžéã¯ïŒã12ïœïŒm2ã§ãããã
ã奜ãŸããã¯ïŒã10ïœïŒm2ã§ããã æ¬çºæã«çšããã¢ã«ã«ãªäžåå±€ã«ã¯ããšãã°ç¹
å ¬æ48â33697ã«èšèŒã®éåäœé žãªã©ãçšããã
ãã奜ãŸããéåäœé žãšããŠã¯ç¡æ°Žãã¬ã€ã³é žå ±
éåäœäŸãã°ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éå
äœãã¡ãã«ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±é
åäœããšãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãªã©ã
ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒå ±ïŒéåäœäŸãã°ãã¢ã¯ãª
ã«é žâã¢ã«ãã«ã¢ã¯ãªã¬ãŒãå ±éåäœãã¢ã¯ãªã«
é žâã¢ã«ãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãå ±éåäœãã¡ã¿ã¢
ã¯ãªã«é žâã¢ã«ãã«ã¢ã¯ãªã¬ãŒãå ±éåäœãã¡ã¿
ã¢ã¯ãªã«é žâã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±éåäœãª
ã©ãæããããããŸãèç©çæ§æ¹è¯ã®ç®çã§ãã
ãã®éåäœé žãšåèšã®å æ°Žå解å¯èœãªã¢ã«ã«ãªé
浞éæ§ããªããŒãŸãã¯ã¢ã«ã«ãªæµžéæ§ããªããŒã
æ··åããŠçšããŠãããã éåäœé žã®å¡åžéã¯ãåŠç液äžã«å«ãŸããã¢ã«
ã«ãªéã§æé©å€ãå€åããããåŠç液ã®ã¢ã«ã«ãª
éã«å¯Ÿãã25ã150ïŒ ïŒã¢ã«æ¯ïŒã奜ãŸãããã
奜ãŸããã¯40ã100ïŒ ïŒã¢ã«æ¯ïŒã®ç¯å²ã§ããã ååå±€ã¯å°ãªããšãéæ²ç©æ žãå«ã¿ããã€ã³ã
ãŒã®å°ãªããšãäžéšã¯ã»ã«ããŒã¹ãšã¹ãã«ããã
åããŠèªå°ãããåçã»ã«ããŒã¹ã§ãããååå±€
ã®äœè£œæ¹æ³ãšããŠç±³åœç¹èš±3179517ã«é瀺ãããŠ
ããåŠããã¢ã»ãã«ã»ã«ããŒã¹å±€ãã¢ã«ã«ãªã§ã±
ã³åããŠåçã»ã«ããŒã¹ã®å±€ã圢æãã次ã§ãã®
åçã»ã«ããŒã¹å±€ãéå±å¡©æº¶æ¶²ãšéå å€æº¶æ¶²ãšã«
浞挬ããŠããã®å±€ã®äžã§åå¿ãããŠéå±ã³ãã€ã
ã®éæ²ç©æ žã«ããæ¹æ³ïŒç¹å ¬æ44â32754ã«é瀺
ãããŠããåŠããã»ã«ããŒã¹ãšã¹ãã«ã«ç空èžç
ã«ãã€ãŠéæ²ç©æ žãå«ãŸããåŸã§æº¶åªã«æº¶ããã
ãããå¡åžä¹Ÿç¥ããã®ã¡ã±ã³åããŠåçã»ã«ããŒ
ã¹ã«ããæ¹æ³ïŒç¹å ¬æ46â43944ã«èšèŒãããŠã
ããããªã¢ã»ãã«ã»ã«ããŒã¹ã®æº¶æ¶²ã®äžã§éæ²ç©
æ žã圢æãå¡åžããŠããã±ã³åããŠåçã»ã«ããŒ
ã¹ã«ããæ¹æ³ãªã©ãããããããã®æ¹æ³ã«ãããŠ
ãã¢ã«ã«ãªã±ã³å液ã«ãïŒå以äžã®æ°Žé žåºãå«ã
å€äŸ¡ã¢ã«ã³ãŒã«ãŸãã¯ãã®èªå°äœãïŒã20ééã
ãŒã»ã³ãæ·»å ããããšãç¹åŸŽã§ããã å€äŸ¡ã¢ã«ã³ãŒã«ãŸãã¯ãã®èªå°äœãšããŠã¯ãã°
ãªã»ãªã³ããšãã¬ã³ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãª
ã³ãŒã«ããžã°ãªã»ãªã³ãããªã°ãªã»ãªã³ãããªã¹
ããããã·ã¡ãã«ãããã³ãããªã¹ããããã·ã¡
ãã«ãšã¿ã³ãã¢ãã¢ã»ãã³ããžã¢ã»ãã³ãããªã¢
ã»ãã³ãªã©ãããããåç¬ã§ããŸãã¯ïŒçš®é¡ä»¥äž
æ··åãããã®ãçšããäºã奜ãŸãããããããã«
éå®ããããã®ã§ã¯ãªããæã奜ãŸããååç©ã¯
ã°ãªã»ãªã³ã§ãããã¢ã«ã«ãªæ¶²ã«æ·»å ããå€äŸ¡ã¢
ã«ã³ãŒã«ãŸãã¯ãã®èªå°äœã®éã¯ãå®ææ¶²å šéã«
察ãïŒã20ééããŒã»ã³ãã§ããã奜ãŸããã¯ïŒ
ã12ééããŒã»ã³ãã§ããã äŸãã°ãã¢ã«ã«ãªæ¶²ãšããŠæ°Žé žåãããªãŠã ã®
ã¡ã¿ããŒã«æº¶æ¶²ã«ã°ãªã»ãªã³ãæ·»å ããŠã»ã«ããŒ
ã¹ãšã¹ãã«å±€ãã±ã³åããå Žåãæ·»å ããªãã€ã
å Žåã«æ¯ã¹æµ ãããåé²è¡ã«æããããšãã§ã
ãã ã¢ã«ã«ãªããå液ã«çšããã¢ã«ã«ãªæ§ååç©ãš
ããŠã¯ãã¢ã«ã«ãªéå±ã®æ°Žé žåç©ãäŸãã°æ°Žé žå
ãããªãŠã ãããã¯æ°Žé žåã«ãªãŠã ã奜ãŸããã
ãŸãã溶åªãšããŠã¯äœçŽã¢ã«ã³ãŒã«ãäŸãã°ã¡ã¿
ããŒã«ããšã¿ããŒã«ãªã©ã奜ãŸãããå Žåã«ãã€
ãŠã¯æ°ŽïŒå®¹éã§50ïŒ äœãŸã§ïŒãæ··åããŠãè¯ãã é©åœãªéæ²ç©æ žã®äŸãšããŠãééå±ãããšãã°
éãéãäºéãããã±ã«ãã«ãããŠã ãã¹ãºãã¯
ãã ãé ãã³ãã«ããç¹ã«è²Žéå±ãããšãã°éã
éãçœéããã³ãã©ãžãŠã ããããä»ã®æçšãªé
æ²ç©æ žã¯ééå±ã®ç¡«åç©ããã³ã»ã¬ã³åç©ãç¹ã«
æ°Žéãé ãã¢ã«ãããŠã ãäºéãã«ãããŠã ãã³
ãã«ããããã±ã«ãéããã©ãžãŠã ãéãã¢ã³ã
ã¢ã³ããã¹ãã¹ãã»ãªãŠã ããã³ãã°ãã·ãŠã ã®
ç¡«åç©ãããã³éãäºéãã¢ã³ãã¢ã³ããã³ãã
ã±ã«ã®ã»ã¬ã³åç©ããããããšãã§ããã å ¬ç¥ã®æè¡ã®ããã«ãéæ²ç©æ žã¯æ¥µãå°éãã
ãšãã°çŽïŒã25Ã10-6molïŒm2ã§ååšããŠããã
éåžžãå¯èœãªæäœã®æ°Žæºãçšããããããããã
é«ãæ¿åºŠã§ã¯ãéå°ã®éãæ²ç©ããããããã¯ã
ã€ã©ã€ãé åã«ãããŠæãŸãããªãèæ¯ã®æ¿åºŠ
ïŒdensityïŒãçããŠããŸãããšãããããã§ã
ããæ··åéæ²æ®¿å€ãçšããŠãããããã®ããã«å
åå±€ã¯ãéæ²ç©æ žã®ååšã«é¢ããéãå®è³ªçã«ç¡
è²äžã€å®è³ªçã«éæã§ãããšè¿°ã¹ãããšãã§ã
ãã ããã«ååå±€ã«ã¯è²èª¿å€ãšããŠãã³ãºã€ãããŸ
ãŒã«é¡ãã¡ã«ã«ããã€ãããŸãŒã«é¡ããã³ãã³ãŸ
ããªã¢ãŸãŒã«é¡ãªã©ãã¯ãããšã€ïŒãããïŒA.
RottïŒãã€ãŒïŒã¯ã€ãïŒE.WeydeïŒãâããªãã°ã©
ãã€ã㯠ã·ã«ã㌠ãã€ããŠãŒãžãšã³ ãã©ã³
ã¹ãã¢ãŒ ããã»ã¹ã€ãºïŒPhotographic Silver
Diffusion Transfer ProcessesïŒâããªãŒã«ã«
ãã¬ã¹ ãã³ãã³ FocalãPressãLondonã
1972 第ïŒãïŒãïŒãïŒç« ã61ã65é ãç±³åœç¹èš±
3756825ããã€ãç¹èš±1903741ãã€ã®ãªã¹ç¹èš±
1230470ããã©ã³ã¹ç¹èš±2090476ã®åå·ã«èšèŒã®å
åç©ãæå¹ã«çšããããšãã§ããã è²èª¿å€ã¯ãéæ²ç©æ žã«ãéãæ²ç©ãå§ãããã
åæããäœçšããå¿ èŠãããã®ã§ãååå±€ãã
ã³ïŒåã¯åŠç液äžã«æ·»å ãããããšã奜ãŸããã ãããååå±€ã«å€éã«æ·»å ããŠåç¬ã§æºè¶³ãã
è²èª¿ã«ããããšãããšãçŸåãæå¶ãç»åæ¿åºŠã
äœããªãæ¬ ç¹ãæããããããã®ããã«ååå±€ã«
ã¯è²èª¿å€ã¯å¿ èŠã§ã¯ãããæå°é床ã«ãšã©ãç»å
æ¿åºŠãžã®åŒå®³ããããå¿ èŠãããã ãã®æ¹æ³ã§çšããããååèŠçŽ ã¯ãéåžžããã©
ã€ã¿çŽãããªãšãã¬ã³ã©ãããŒãçŽãã©ãã«ãŒ
çŽãåæçŽãªã©ã®çŽæ¯æäœããããã¯ãã¢ã»ãã«
ã»ã«ããŒã¹ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããª
ã¹ãã¬ã³ãªã©ã®ãã€ã«ã æ¯æäœãçšããããããª
ãšãã¬ã³ã©ãããŒãçŽãç¹ã«å¥œãŸããã 奜ãŸããå®æœæ æ§ã«ãããŠã¯åèšäžåã¿ã€ãã³
ã°å±€ãšåèšååå±€ãšã®éã«ã¯åçã»ã«ããŒã¹ãäž»
æåãšãã局以å€ã®èŠªæ°Žæ§ããªããŒå±€ãæããŠã
ãªãã ããã«ãååå±€ã®äžã«ãåŠç液ã®å¥é¢æ§ãæ¹è¯
ããç®çã§ã芪氎æ§ããªããŒãããšãã°ã«ã«ãã
ã·ã¡ãã«ã»ã«ããŒã¹ããŒã©ãã³ãã¢ã©ãã¢ãŽã ã
ãžã¡ãã«ããã³ãã€ã³âãã«ã ã¢ã«ãããçž®å
ç©ãé ¢é žãã¿ã«é žæ°ŽçŽ ã»ã«ããŒã¹ãªã©ã®å±€ãå¡åž
ããããšãæå¹ã§ããã ããã«ãçœè²åºŠãåäžããããã«èå å¢çœå€ã
æ·»å ããããšãã§ãããããŸãå¡åžãããããªã
ãŒå±€ãè»ãããããããã«å¯å¡å€ã®æ·»å ãæå¹ã§
ããã ãŸãååå±€äžã«ç»åå®å®åã®ããã«ç¹é¡æ60â
9344å·ãªã©ã«èšèŒã®ç»åå®å®åå±€ãèšããŠãã
ããæ¬çºæã«ãããŠãæŽã«ããããå¹æãçãã æ¬çºæã§çšããããæå èŠçŽ ã¯ãæ¯æäœäžã«äž
çš®åã¯äžçš®ä»¥äžã®ããã²ã³åéä¹³å€ãå«ãæå å±€
ãæãããããã²ã³åéã¯é«æ床ã®æ²èåéïŒæ²
床å«éïŒã10ã¢ã«ïŒ ïŒããç¹ã«å¥œãŸãããããã
ã¯é©åœãªä¿è·ã³ãã€ãç©è³ªãäŸãã°ãŒã©ãã³ãå¯
倩ãã¢ã«ãã¡ã³ãã«ãŒã€ã³ãã³ããžãªã³ãã»ã«ã
ãŒãºåç©è³ªäŸãã°ã«ã«ããã·ã¡ãã«ã»ã«ããŒãºã
ããã«ããªããŒäŸãã°ããªããã«ã¢ã«ã³ãŒã«åã¯
ç·ç¶ããªã¢ããäŸãã°ããªãããµã¡ãã¬ã³ã¢ãžã
ã¢ããäžã«åæ£å«æããããããããããçšéã«
é©åœãªä¹³å€ã¯ããŒã»ã°ã©ãããïŒP.GlafkidesïŒ
è ãã ãšã ãã€ãžã€ã㯠ããªãã°ã©ãã€
ãã¯ïŒChimie et Physique PhotographiqueïŒ
ïŒPaul Montel瀟åã1967幎ïŒããžãŒã»ãšãã»ãã
ã€ã³ïŒG.F.DuffinïŒè ããªãã°ã©ãã€ã㯠ãš
ãã«ãžãšã³ ã±ãã¹ããªãŒïŒPhotographic
Emulsion ChemistryïŒïŒThe Focal Presså
1966幎ïŒããã€ã»ãšã«ã»ãŒãªã¯ãã³çïŒV.L.
Zelikman et alïŒã®ã¡ãŒãã³ã° ã¢ã³ã ã³ãŒ
ãã³ã° ããªãã°ã©ãã€ã㯠ãšãã«ãžãšã³
ïŒMaking and Coating Photographic
EmulsionïŒïŒThe Focal Pressåã1964幎ïŒãªã©
ã«èšèŒãããæ¹æ³ãçšããŠèª¿è£œããããšãã§ã
ãã ãããã®ããã²ã³åéä¹³å€ã¯å¿ èŠã«å¿ããŠååŠ
å¢æãããã³åå å¢æã匷è²å¢æãè¡ãããšãã§
ããããŸããéåžžç¥ãããŠããã«ããªé²æ¢å€ã硬
èå€ãçŸåä¿é²å€ãçé¢æŽ»æ§å€ã垯é»é²æ¢å€ãªã©
ãå«ãŸããããšãã§ããã ãŸããæå å±€ã®äžã«ä¿è·å±€ãèšããç©ççæå·
ããæå å±€ãä¿è·ããããã«è©²ä¿è·å±€ã«ãããå€
ç²åãå ããŠãè¡šé¢ãã¹ãæ§ãæ¹è¯ãããŸãæ¥ç
ãé²æ¢ããããšãæçšã§ããã æ¬çºæã§çšããããåŠçèŠçŽ ãšããŠã¯ãçš®ã ã®
åŠççµæç©ãçšããããã奜ãŸããã¯åŠççµæç©
ã«ã¯ãçŸåäž»è¬ãšããã²ã³åé溶å€ãšãã¢ã«ã«ãª
å€ãšãå«ãŸããŠããããç®çã«å¿ããŠãçŸåäž»è¬
åã³ããã²ã³åé溶å€ã®å°ãªããšãïŒã€ãæå èŠ
çŽ äžåã³ååèŠçŽ äžã®å°ãªããšãïŒã€ã«å«ãŸããŠ
ããããšãã§ããã é©åœãªããã²ã³åéçŸåè¬ã«ã¯å°ãªããšãïŒã€
ã®ããããã·ã«åã³ã¢ããåºã®å°ãªããšãïŒã€ã
ãã³ãŒã³æ žã®ãªã«ãåã¯ãã©äœã«çœ®æãããŠãã
ãã³ãŒã³èªå°äœäŸãã°ãã€ããããã³ãã¢ãããŒ
ã«ãã¡ããŒã«ãã°ãªã·ã³ãïœâã¢ããããšããŒã«
åã³ããã¬ããŒã«ïŒåã³ããããã·ã«ã¢ãã³é¡ç¹
ã«ç¬¬äžçŽåã³ç¬¬äºçŽèèªæåã³è³éŠæâ眮æå
ã¯Î²âããããã·ã«ã¢ãã³é¡ã§ãããã¯æ°Žæ§ã¢ã«
ã«ãªã«å¯æº¶æ§ã§ããäŸãã°ããããã·ã«ã¢ãã³ã
âã¡ãã«ããããã·ã«ã¢ãã³ãâãšãã«ãã
ããã·ã«ã¢ãã³åã³ç±³åœç¹èš±2857276ã«èšèŒãã
ãŠãããã®åã³ç±³åœç¹èš±3293034ã«èšèŒãããŠã
ãåŠãâã¢ã«ã³ãã·ã¢ã«ãã«ãŒçœ®æããããã·
ã«ã¢ãã³é¡ãå å«ãããã ãŸããç¹éæ49â88521ã«èšèŒãããŠãããã
ã©ããããã«ããªã«åºããã€ããããã·ã«ã¢ãã³
èªå°äœãçšããããã ãŸãã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2009054ãå
2009055ããã³å2009078ã«èšèŒãããŠããã¢ãã
ã¬ãã¯ãã³é¡ããç±³åœç¹èš±4128425ã«èšèŒãããŠ
ããè€çŽ ç°ã¢ããã¬ãã¯ãã³ãçšããããã ããã«ãç±³åœç¹èš±3615440ã«èšèŒãããŠããã
ãã©ã¢ã«ãã«ã¬ãã¯ãã³é žãçšããããšãåºæ¥
ãã ãŸããè£å©çŸåå€ã®ããšããã³ååç©ãïœã¢ã
ãããšããŒã«ååç©ããã³ã¢ã¹ã³ã«ãã³é žãšäžèš
çŸåå€ã䜵çšããããšãã§ããã é©åœãªããã²ã³å¯é溶åªã«ã¯éåžžã®å®çå€äŸã
ã°ãããªãŠã ããªãµã«ããšãŒãããããªãŠã ããª
ã·ã¢ããŒããã¢ã³ã¢ããŠã ããªãµã«ããšãŒãåã³
ãã®ä»äžè¿°ã®ç±³åœç¹èš±2543181ã«èšèŒãããŠãã
ãã®ïŒåã³ç°åŒã€ãããšçªçŽ å¡©åºã®çµåãããã
ã®äŸãã°ãã«ããã¬ãŒãåã¯ãŠã©ã·ã«ãšã¢ã³ã¢ã
ã¢åã¯ã¢ãã³ãšçµåããããã®åã³ç±³åœç¹èš±
2857274ã«èšèŒãããŠãããããªçµåããå å«ã
ããã ãŸããïŒïŒïŒâãã¹ã¹ã«ããã«ã¢ã«ã«ã³ããã³
ãã®èªå°äœãç¥ãããŠãããæ¬çºæã®ããã²ã³å
é溶å€ãšããŠäœ¿ãããšãã§ããã åŠççµæç©ã¯ã¢ã«ã«ãªé¡ã奜ãŸããã¯ã¢ã«ã«ãª
éå±ã®æ°Žé žåç©ãããšãã°æ°Žé žåãããªãŠã ãã
ãã¯æ°Žé žåã«ãªãŠã ãå«ãã§ãããéãåããã
ãæå æ§ã®èŠçŽ ãšååèŠçŽ ãšã®éã«èãå±€ãšããŠ
åŠççµæç©ãååžãããããšã«ãããããé©çšã
ããªãã°ãåŠççµæç©ã¯éåäœãã€ã«ã 圢æå€ã
æ¿ååå€ãããã¯å¢ç²å€ãå«ãã§ãããšå¥œãŸã
ããããããã·ãšãã«ã»ã«ããŒã¹ããã³ãããªãŠ
ã ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ã¯ããã®ç®çã®ã
ãã«ç¹ã«æçšã§ãããæ¡æ£è»¢ååçæ³ã®å ¬ç¥ã®å
çã«ããé©åœãªç²åºŠãäžããã®ã«å¹æçãªæ¿åºŠã§
åŠççµæç©ã®äžã«å«æããããåŠççµæç©ã¯ãã
ã«ãéå¡©æ¡æ£è»¢åæ³ã«ãããŠå ¬ç¥ã®å¥ã®å©å€ãã
ãšãã°ãã¶ãé²æ¢å€ã調è²å€ïŒtoning agentsïŒã
å®å®åå€çãå«æãããŠãããã ïŒå®æœäŸïŒ 以äžã«ãå®æœäŸããã³æ¯èŒäŸããããŠãæ¬çºæ
ãããã«è©³çŽ°ã«èª¬æããã å®æœäŸ ïŒ ååã·ãŒãã®äœæ ïŒ ååã·ãŒã(1)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ãããŒãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(1)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒãïŒ
âïŒïŒâããã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâ
ïŒïŒïŒâãžãããã€ãããŸãŒã«âïŒâããªã³
ïŒ0.06ïŒ (3) ååå±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒïŒ1.5ïŒãç¡«
åãã©ãžãŠã ïŒ7.5Ã10-4ïŒãïŒâïŒïŒâãã
ã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãžã
ããã€ãããŸãŒã«âïŒâããªã³ïŒ0.02ïŒãå¡
åžããã®ã¡æ°Žé žåãããªãŠã 9.0ïœãã¡ã¿ã
ãŒã«240mlããã³æ°Ž60mlã«æº¶è§£ãããã±ã³å
液ã«ããè¡šé¢ããã±ã³åããŠååå±€ãšããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(2)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ããâãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(2)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ ïŒâïŒïŒâããã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒ
âïŒïŒïŒâãžãããã€ãããŸãŒã«âïŒâããª
ã³ïŒ0.25ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒã (3) ååå±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒïŒ1.5ïŒãç¡«
åãã©ãžãŠã ïŒ7.5Ã10-4ïŒãïŒâïŒïŒâãã
ã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãžã
ããã€ãããŸãŒã«âïŒâããªã³ïŒ0.01ïŒãå¡
åžããã®ã¡æ°Žé žåãããªãŠã 9.0ïœãã¡ã¿ã
ãŒã«240mlããã³æ°Ž60mlã«æº¶è§£ãããã±ã³å
液ã«ããè¡šé¢ããã±ã³åããŠååå±€ãšããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(3)ã®äœæ ååã·ãŒã(2)ã®å±€(3)ååå±€ã®ã±ã³å液ãæ°Žé ž
åãããªãŠã 10.7ïœãã¡ã¿ããŒã«280mlããã³
ã°ãªã»ãªã³24ïœã«æº¶è§£ããããã®ãšãã以å€å
åã·ãŒã(2)ãšåãã«äœæããã ïŒ ååã·ãŒã(4)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ãããŒãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(4)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ ïŒâïŒïŒâããã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒ
âïŒïŒïŒâãžãããã€ãããŸãŒã«âïŒâããª
ã³ïŒ0.10ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒã (3) ååå±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒïŒ1.5ïŒãç¡«
åãã©ãžãŠã ïŒ7.5Ã10-4ïŒãïŒâïŒïŒâãã
ã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãžã
ããã€ãããŸãŒã«âïŒâããªã³ïŒ0.04ïŒãå¡
åžããã®ã¡æ°Žé žåãããªãŠã 10.7ïœãã¡ã¿ã
ãŒã«280mlããã³ã°ãªã»ãªã³24ïœã«æº¶è§£ãã
ãã±ã³å液ã«ããè¡šé¢ããã±ã³åããŠååå±€
ãšããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(5)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ãããŒãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(5)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ ïŒâããšãã«âïŒïŒïŒâãžãããã€ãããŸ
ãŒã«âïŒâããªã³ïŒ0.15ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒã (3) ååå±€ ååã·ãŒã(4)ã®å±€(3)ååå±€ã®ïŒâïŒïŒâã
ãã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãž
ãããã€ãããŸãŒã«âïŒâããªã³ïŒ0.04ïŒã
ïŒâããšãã«âïŒïŒïŒâãžãããã€ãããŸãŒ
ã«âïŒâããªã³ïŒ0.01ïŒãšãã以å€ã¯ååã·
ãŒã(4)ãšåãã«ããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(6)ã®äœæ ååã·ãŒã(3)ã«ãããŠãå±€(1)äžåå±€ãšå±€(2)äž
åã¿ã€ãã³ã°å±€ã®éã«äžèšå±€ïŒ1â²ïŒç»åå®å®å
å±€ãèšãã以å€ãååã·ãŒã(3)ãšåãã«äœæã
ãã (1â²) ç»åå®å®åå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床46ïŒ ïŒïŒ4.2ïŒãäž
èšååç©ïŒ2.1ïŒ
ãããããã€ãã®ååç©ã«ã€ããŠã¯ãç¹éæ59â
231537å·ã«èšèŒã®åææ³çã§åæã§ããã æ¬çºæã®ç»åå®å®åå€ã¯ãå°ãªããšãäžåå±€ã«
æ·»å ãããåŠçãããšãã®éç»åã®è²èª¿ãé調ã
æ床ãåŠçåŸã®ä¿åå®å®æ§ã調ç¯æ¹è¯ããããã«
䜵ããŠäžåã¿ã€ãã³ã°å±€ãååå±€åã³ãã®ä»ã®è£
å©å±€ã®å°ãªããšãïŒå±€ã«æ·»å ããããšãã§ããã æ·»å éã¯ãæ²ç©ããéã®éãªã©ã§ç°ãªãããäž
è¬çã«ã¯1.0Ã10-4ã1.65Ã10-3ã¢ã«ïŒm2ããã奜
ãŸããã¯2.0Ã10-4ã13.2Ã10-4ã¢ã«ïŒm2ã®å¡åžé
ã§ããã æ¬çºæã®ã¢ã«ã«ãªäžåå±€ãäžåã¿ã€ãã³ã°å±€ã
ã±ã³åããåã®ååå±€ã«äœ¿çšããããã»ã«ããŒã¹
ãšã¹ãã«ã¯ã»ã«ããŒã¹ã®æ°Žé žåºã®äžéšåã¯å šéšã
ãšã¹ãã«åããããã®ã§ããã°ãåççã«ã¯ã©ã
ã§ã䜿çšå¯èœã§ããããé ¢é žã»ã«ããŒã¹ãããã
ãªã³é žã»ã«ããŒã¹ãé ªé žã»ã«ããŒã¹ãªã©ã®èèªé ž
ã»ã«ããŒã¹ãç¡«é žã»ã«ããŒã¹ããªã³é žã»ã«ããŒã¹
ããã³ãããã»ã«ããŒã¹ãå«ãŸãããåç¡é žé ¢é ž
ã»ã«ããŒã¹ã®ããã«æ··æãšã¹ãã«ã䜿çšã§ããã ã»ã«ããŒã¹ã®æ°Žé žåºã®ãšã¹ãã«ãžã®çœ®æ床ãã
䜿çšãã溶åªçµæãã±ã³ååå¿ã®é床ããã³åå
å±€ã®åçæ¹æ³ïŒæº¶è§£ããéã®åžçé床ïŒã«ãã€
ãŠãäžèšã®ã»ã«ããŒã¹ãšã¹ãã«ã®äžã§åã æé©å€
ãéžã¶å¿ èŠããããäžè¬çã«ã¯èŠå®ã§ããªãã 奜ãŸããã»ã«ããŒã¹ãšã¹ãã«ã¯ãèèªé žã»ã«ã
ãŒã¹ã§ãããç¹ã«å¥œãŸãããã®ã¯é ¢é žã»ã«ããŒã¹
ã§ããã ããã«æ¬çºæã®å¥œãŸããå®æœã«ã¯é ¢é žã»ã«ããŒ
ã¹ã§çœ®æ床ã奜ãŸããã¯1.53ïŒé ¢å床40ïŒ ïŒãã
27ïŒé ¢å床58ïŒ ïŒã§ããããã奜ãŸãã眮æ床ã¯
1.7ã2.6ã§ããã æ¬çºæã«äœ¿çšããäžåã¿ã€ãã³ã°å±€ã«ãããé ¢
é žã»ã«ããŒã¹ã®å¡åžéã¯ïŒã12ïœïŒm2ã§ãããã
ã奜ãŸããã¯ïŒã10ïœïŒm2ã§ããã æ¬çºæã«çšããã¢ã«ã«ãªäžåå±€ã«ã¯ããšãã°ç¹
å ¬æ48â33697ã«èšèŒã®éåäœé žãªã©ãçšããã
ãã奜ãŸããéåäœé žãšããŠã¯ç¡æ°Žãã¬ã€ã³é žå ±
éåäœäŸãã°ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éå
äœãã¡ãã«ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±é
åäœããšãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãªã©ã
ïŒã¡ã¿ïŒã¢ã¯ãªã«é žïŒå ±ïŒéåäœäŸãã°ãã¢ã¯ãª
ã«é žâã¢ã«ãã«ã¢ã¯ãªã¬ãŒãå ±éåäœãã¢ã¯ãªã«
é žâã¢ã«ãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãå ±éåäœãã¡ã¿ã¢
ã¯ãªã«é žâã¢ã«ãã«ã¢ã¯ãªã¬ãŒãå ±éåäœãã¡ã¿
ã¢ã¯ãªã«é žâã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±éåäœãª
ã©ãæããããããŸãèç©çæ§æ¹è¯ã®ç®çã§ãã
ãã®éåäœé žãšåèšã®å æ°Žå解å¯èœãªã¢ã«ã«ãªé
浞éæ§ããªããŒãŸãã¯ã¢ã«ã«ãªæµžéæ§ããªããŒã
æ··åããŠçšããŠãããã éåäœé žã®å¡åžéã¯ãåŠç液äžã«å«ãŸããã¢ã«
ã«ãªéã§æé©å€ãå€åããããåŠç液ã®ã¢ã«ã«ãª
éã«å¯Ÿãã25ã150ïŒ ïŒã¢ã«æ¯ïŒã奜ãŸãããã
奜ãŸããã¯40ã100ïŒ ïŒã¢ã«æ¯ïŒã®ç¯å²ã§ããã ååå±€ã¯å°ãªããšãéæ²ç©æ žãå«ã¿ããã€ã³ã
ãŒã®å°ãªããšãäžéšã¯ã»ã«ããŒã¹ãšã¹ãã«ããã
åããŠèªå°ãããåçã»ã«ããŒã¹ã§ãããååå±€
ã®äœè£œæ¹æ³ãšããŠç±³åœç¹èš±3179517ã«é瀺ãããŠ
ããåŠããã¢ã»ãã«ã»ã«ããŒã¹å±€ãã¢ã«ã«ãªã§ã±
ã³åããŠåçã»ã«ããŒã¹ã®å±€ã圢æãã次ã§ãã®
åçã»ã«ããŒã¹å±€ãéå±å¡©æº¶æ¶²ãšéå å€æº¶æ¶²ãšã«
浞挬ããŠããã®å±€ã®äžã§åå¿ãããŠéå±ã³ãã€ã
ã®éæ²ç©æ žã«ããæ¹æ³ïŒç¹å ¬æ44â32754ã«é瀺
ãããŠããåŠããã»ã«ããŒã¹ãšã¹ãã«ã«ç空èžç
ã«ãã€ãŠéæ²ç©æ žãå«ãŸããåŸã§æº¶åªã«æº¶ããã
ãããå¡åžä¹Ÿç¥ããã®ã¡ã±ã³åããŠåçã»ã«ããŒ
ã¹ã«ããæ¹æ³ïŒç¹å ¬æ46â43944ã«èšèŒãããŠã
ããããªã¢ã»ãã«ã»ã«ããŒã¹ã®æº¶æ¶²ã®äžã§éæ²ç©
æ žã圢æãå¡åžããŠããã±ã³åããŠåçã»ã«ããŒ
ã¹ã«ããæ¹æ³ãªã©ãããããããã®æ¹æ³ã«ãããŠ
ãã¢ã«ã«ãªã±ã³å液ã«ãïŒå以äžã®æ°Žé žåºãå«ã
å€äŸ¡ã¢ã«ã³ãŒã«ãŸãã¯ãã®èªå°äœãïŒã20ééã
ãŒã»ã³ãæ·»å ããããšãç¹åŸŽã§ããã å€äŸ¡ã¢ã«ã³ãŒã«ãŸãã¯ãã®èªå°äœãšããŠã¯ãã°
ãªã»ãªã³ããšãã¬ã³ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãª
ã³ãŒã«ããžã°ãªã»ãªã³ãããªã°ãªã»ãªã³ãããªã¹
ããããã·ã¡ãã«ãããã³ãããªã¹ããããã·ã¡
ãã«ãšã¿ã³ãã¢ãã¢ã»ãã³ããžã¢ã»ãã³ãããªã¢
ã»ãã³ãªã©ãããããåç¬ã§ããŸãã¯ïŒçš®é¡ä»¥äž
æ··åãããã®ãçšããäºã奜ãŸãããããããã«
éå®ããããã®ã§ã¯ãªããæã奜ãŸããååç©ã¯
ã°ãªã»ãªã³ã§ãããã¢ã«ã«ãªæ¶²ã«æ·»å ããå€äŸ¡ã¢
ã«ã³ãŒã«ãŸãã¯ãã®èªå°äœã®éã¯ãå®ææ¶²å šéã«
察ãïŒã20ééããŒã»ã³ãã§ããã奜ãŸããã¯ïŒ
ã12ééããŒã»ã³ãã§ããã äŸãã°ãã¢ã«ã«ãªæ¶²ãšããŠæ°Žé žåãããªãŠã ã®
ã¡ã¿ããŒã«æº¶æ¶²ã«ã°ãªã»ãªã³ãæ·»å ããŠã»ã«ããŒ
ã¹ãšã¹ãã«å±€ãã±ã³åããå Žåãæ·»å ããªãã€ã
å Žåã«æ¯ã¹æµ ãããåé²è¡ã«æããããšãã§ã
ãã ã¢ã«ã«ãªããå液ã«çšããã¢ã«ã«ãªæ§ååç©ãš
ããŠã¯ãã¢ã«ã«ãªéå±ã®æ°Žé žåç©ãäŸãã°æ°Žé žå
ãããªãŠã ãããã¯æ°Žé žåã«ãªãŠã ã奜ãŸããã
ãŸãã溶åªãšããŠã¯äœçŽã¢ã«ã³ãŒã«ãäŸãã°ã¡ã¿
ããŒã«ããšã¿ããŒã«ãªã©ã奜ãŸãããå Žåã«ãã€
ãŠã¯æ°ŽïŒå®¹éã§50ïŒ äœãŸã§ïŒãæ··åããŠãè¯ãã é©åœãªéæ²ç©æ žã®äŸãšããŠãééå±ãããšãã°
éãéãäºéãããã±ã«ãã«ãããŠã ãã¹ãºãã¯
ãã ãé ãã³ãã«ããç¹ã«è²Žéå±ãããšãã°éã
éãçœéããã³ãã©ãžãŠã ããããä»ã®æçšãªé
æ²ç©æ žã¯ééå±ã®ç¡«åç©ããã³ã»ã¬ã³åç©ãç¹ã«
æ°Žéãé ãã¢ã«ãããŠã ãäºéãã«ãããŠã ãã³
ãã«ããããã±ã«ãéããã©ãžãŠã ãéãã¢ã³ã
ã¢ã³ããã¹ãã¹ãã»ãªãŠã ããã³ãã°ãã·ãŠã ã®
ç¡«åç©ãããã³éãäºéãã¢ã³ãã¢ã³ããã³ãã
ã±ã«ã®ã»ã¬ã³åç©ããããããšãã§ããã å ¬ç¥ã®æè¡ã®ããã«ãéæ²ç©æ žã¯æ¥µãå°éãã
ãšãã°çŽïŒã25Ã10-6molïŒm2ã§ååšããŠããã
éåžžãå¯èœãªæäœã®æ°Žæºãçšããããããããã
é«ãæ¿åºŠã§ã¯ãéå°ã®éãæ²ç©ããããããã¯ã
ã€ã©ã€ãé åã«ãããŠæãŸãããªãèæ¯ã®æ¿åºŠ
ïŒdensityïŒãçããŠããŸãããšãããããã§ã
ããæ··åéæ²æ®¿å€ãçšããŠãããããã®ããã«å
åå±€ã¯ãéæ²ç©æ žã®ååšã«é¢ããéãå®è³ªçã«ç¡
è²äžã€å®è³ªçã«éæã§ãããšè¿°ã¹ãããšãã§ã
ãã ããã«ååå±€ã«ã¯è²èª¿å€ãšããŠãã³ãºã€ãããŸ
ãŒã«é¡ãã¡ã«ã«ããã€ãããŸãŒã«é¡ããã³ãã³ãŸ
ããªã¢ãŸãŒã«é¡ãªã©ãã¯ãããšã€ïŒãããïŒA.
RottïŒãã€ãŒïŒã¯ã€ãïŒE.WeydeïŒãâããªãã°ã©
ãã€ã㯠ã·ã«ã㌠ãã€ããŠãŒãžãšã³ ãã©ã³
ã¹ãã¢ãŒ ããã»ã¹ã€ãºïŒPhotographic Silver
Diffusion Transfer ProcessesïŒâããªãŒã«ã«
ãã¬ã¹ ãã³ãã³ FocalãPressãLondonã
1972 第ïŒãïŒãïŒãïŒç« ã61ã65é ãç±³åœç¹èš±
3756825ããã€ãç¹èš±1903741ãã€ã®ãªã¹ç¹èš±
1230470ããã©ã³ã¹ç¹èš±2090476ã®åå·ã«èšèŒã®å
åç©ãæå¹ã«çšããããšãã§ããã è²èª¿å€ã¯ãéæ²ç©æ žã«ãéãæ²ç©ãå§ãããã
åæããäœçšããå¿ èŠãããã®ã§ãååå±€ãã
ã³ïŒåã¯åŠç液äžã«æ·»å ãããããšã奜ãŸããã ãããååå±€ã«å€éã«æ·»å ããŠåç¬ã§æºè¶³ãã
è²èª¿ã«ããããšãããšãçŸåãæå¶ãç»åæ¿åºŠã
äœããªãæ¬ ç¹ãæããããããã®ããã«ååå±€ã«
ã¯è²èª¿å€ã¯å¿ èŠã§ã¯ãããæå°é床ã«ãšã©ãç»å
æ¿åºŠãžã®åŒå®³ããããå¿ èŠãããã ãã®æ¹æ³ã§çšããããååèŠçŽ ã¯ãéåžžããã©
ã€ã¿çŽãããªãšãã¬ã³ã©ãããŒãçŽãã©ãã«ãŒ
çŽãåæçŽãªã©ã®çŽæ¯æäœããããã¯ãã¢ã»ãã«
ã»ã«ããŒã¹ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããª
ã¹ãã¬ã³ãªã©ã®ãã€ã«ã æ¯æäœãçšããããããª
ãšãã¬ã³ã©ãããŒãçŽãç¹ã«å¥œãŸããã 奜ãŸããå®æœæ æ§ã«ãããŠã¯åèšäžåã¿ã€ãã³
ã°å±€ãšåèšååå±€ãšã®éã«ã¯åçã»ã«ããŒã¹ãäž»
æåãšãã局以å€ã®èŠªæ°Žæ§ããªããŒå±€ãæããŠã
ãªãã ããã«ãååå±€ã®äžã«ãåŠç液ã®å¥é¢æ§ãæ¹è¯
ããç®çã§ã芪氎æ§ããªããŒãããšãã°ã«ã«ãã
ã·ã¡ãã«ã»ã«ããŒã¹ããŒã©ãã³ãã¢ã©ãã¢ãŽã ã
ãžã¡ãã«ããã³ãã€ã³âãã«ã ã¢ã«ãããçž®å
ç©ãé ¢é žãã¿ã«é žæ°ŽçŽ ã»ã«ããŒã¹ãªã©ã®å±€ãå¡åž
ããããšãæå¹ã§ããã ããã«ãçœè²åºŠãåäžããããã«èå å¢çœå€ã
æ·»å ããããšãã§ãããããŸãå¡åžãããããªã
ãŒå±€ãè»ãããããããã«å¯å¡å€ã®æ·»å ãæå¹ã§
ããã ãŸãååå±€äžã«ç»åå®å®åã®ããã«ç¹é¡æ60â
9344å·ãªã©ã«èšèŒã®ç»åå®å®åå±€ãèšããŠãã
ããæ¬çºæã«ãããŠãæŽã«ããããå¹æãçãã æ¬çºæã§çšããããæå èŠçŽ ã¯ãæ¯æäœäžã«äž
çš®åã¯äžçš®ä»¥äžã®ããã²ã³åéä¹³å€ãå«ãæå å±€
ãæãããããã²ã³åéã¯é«æ床ã®æ²èåéïŒæ²
床å«éïŒã10ã¢ã«ïŒ ïŒããç¹ã«å¥œãŸãããããã
ã¯é©åœãªä¿è·ã³ãã€ãç©è³ªãäŸãã°ãŒã©ãã³ãå¯
倩ãã¢ã«ãã¡ã³ãã«ãŒã€ã³ãã³ããžãªã³ãã»ã«ã
ãŒãºåç©è³ªäŸãã°ã«ã«ããã·ã¡ãã«ã»ã«ããŒãºã
ããã«ããªããŒäŸãã°ããªããã«ã¢ã«ã³ãŒã«åã¯
ç·ç¶ããªã¢ããäŸãã°ããªãããµã¡ãã¬ã³ã¢ãžã
ã¢ããäžã«åæ£å«æããããããããããçšéã«
é©åœãªä¹³å€ã¯ããŒã»ã°ã©ãããïŒP.GlafkidesïŒ
è ãã ãšã ãã€ãžã€ã㯠ããªãã°ã©ãã€
ãã¯ïŒChimie et Physique PhotographiqueïŒ
ïŒPaul Montel瀟åã1967幎ïŒããžãŒã»ãšãã»ãã
ã€ã³ïŒG.F.DuffinïŒè ããªãã°ã©ãã€ã㯠ãš
ãã«ãžãšã³ ã±ãã¹ããªãŒïŒPhotographic
Emulsion ChemistryïŒïŒThe Focal Presså
1966幎ïŒããã€ã»ãšã«ã»ãŒãªã¯ãã³çïŒV.L.
Zelikman et alïŒã®ã¡ãŒãã³ã° ã¢ã³ã ã³ãŒ
ãã³ã° ããªãã°ã©ãã€ã㯠ãšãã«ãžãšã³
ïŒMaking and Coating Photographic
EmulsionïŒïŒThe Focal Pressåã1964幎ïŒãªã©
ã«èšèŒãããæ¹æ³ãçšããŠèª¿è£œããããšãã§ã
ãã ãããã®ããã²ã³åéä¹³å€ã¯å¿ èŠã«å¿ããŠååŠ
å¢æãããã³åå å¢æã匷è²å¢æãè¡ãããšãã§
ããããŸããéåžžç¥ãããŠããã«ããªé²æ¢å€ã硬
èå€ãçŸåä¿é²å€ãçé¢æŽ»æ§å€ã垯é»é²æ¢å€ãªã©
ãå«ãŸããããšãã§ããã ãŸããæå å±€ã®äžã«ä¿è·å±€ãèšããç©ççæå·
ããæå å±€ãä¿è·ããããã«è©²ä¿è·å±€ã«ãããå€
ç²åãå ããŠãè¡šé¢ãã¹ãæ§ãæ¹è¯ãããŸãæ¥ç
ãé²æ¢ããããšãæçšã§ããã æ¬çºæã§çšããããåŠçèŠçŽ ãšããŠã¯ãçš®ã ã®
åŠççµæç©ãçšããããã奜ãŸããã¯åŠççµæç©
ã«ã¯ãçŸåäž»è¬ãšããã²ã³åé溶å€ãšãã¢ã«ã«ãª
å€ãšãå«ãŸããŠããããç®çã«å¿ããŠãçŸåäž»è¬
åã³ããã²ã³åé溶å€ã®å°ãªããšãïŒã€ãæå èŠ
çŽ äžåã³ååèŠçŽ äžã®å°ãªããšãïŒã€ã«å«ãŸããŠ
ããããšãã§ããã é©åœãªããã²ã³åéçŸåè¬ã«ã¯å°ãªããšãïŒã€
ã®ããããã·ã«åã³ã¢ããåºã®å°ãªããšãïŒã€ã
ãã³ãŒã³æ žã®ãªã«ãåã¯ãã©äœã«çœ®æãããŠãã
ãã³ãŒã³èªå°äœäŸãã°ãã€ããããã³ãã¢ãããŒ
ã«ãã¡ããŒã«ãã°ãªã·ã³ãïœâã¢ããããšããŒã«
åã³ããã¬ããŒã«ïŒåã³ããããã·ã«ã¢ãã³é¡ç¹
ã«ç¬¬äžçŽåã³ç¬¬äºçŽèèªæåã³è³éŠæâ眮æå
ã¯Î²âããããã·ã«ã¢ãã³é¡ã§ãããã¯æ°Žæ§ã¢ã«
ã«ãªã«å¯æº¶æ§ã§ããäŸãã°ããããã·ã«ã¢ãã³ã
âã¡ãã«ããããã·ã«ã¢ãã³ãâãšãã«ãã
ããã·ã«ã¢ãã³åã³ç±³åœç¹èš±2857276ã«èšèŒãã
ãŠãããã®åã³ç±³åœç¹èš±3293034ã«èšèŒãããŠã
ãåŠãâã¢ã«ã³ãã·ã¢ã«ãã«ãŒçœ®æããããã·
ã«ã¢ãã³é¡ãå å«ãããã ãŸããç¹éæ49â88521ã«èšèŒãããŠãããã
ã©ããããã«ããªã«åºããã€ããããã·ã«ã¢ãã³
èªå°äœãçšããããã ãŸãã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2009054ãå
2009055ããã³å2009078ã«èšèŒãããŠããã¢ãã
ã¬ãã¯ãã³é¡ããç±³åœç¹èš±4128425ã«èšèŒãããŠ
ããè€çŽ ç°ã¢ããã¬ãã¯ãã³ãçšããããã ããã«ãç±³åœç¹èš±3615440ã«èšèŒãããŠããã
ãã©ã¢ã«ãã«ã¬ãã¯ãã³é žãçšããããšãåºæ¥
ãã ãŸããè£å©çŸåå€ã®ããšããã³ååç©ãïœã¢ã
ãããšããŒã«ååç©ããã³ã¢ã¹ã³ã«ãã³é žãšäžèš
çŸåå€ã䜵çšããããšãã§ããã é©åœãªããã²ã³å¯é溶åªã«ã¯éåžžã®å®çå€äŸã
ã°ãããªãŠã ããªãµã«ããšãŒãããããªãŠã ããª
ã·ã¢ããŒããã¢ã³ã¢ããŠã ããªãµã«ããšãŒãåã³
ãã®ä»äžè¿°ã®ç±³åœç¹èš±2543181ã«èšèŒãããŠãã
ãã®ïŒåã³ç°åŒã€ãããšçªçŽ å¡©åºã®çµåãããã
ã®äŸãã°ãã«ããã¬ãŒãåã¯ãŠã©ã·ã«ãšã¢ã³ã¢ã
ã¢åã¯ã¢ãã³ãšçµåããããã®åã³ç±³åœç¹èš±
2857274ã«èšèŒãããŠãããããªçµåããå å«ã
ããã ãŸããïŒïŒïŒâãã¹ã¹ã«ããã«ã¢ã«ã«ã³ããã³
ãã®èªå°äœãç¥ãããŠãããæ¬çºæã®ããã²ã³å
é溶å€ãšããŠäœ¿ãããšãã§ããã åŠççµæç©ã¯ã¢ã«ã«ãªé¡ã奜ãŸããã¯ã¢ã«ã«ãª
éå±ã®æ°Žé žåç©ãããšãã°æ°Žé žåãããªãŠã ãã
ãã¯æ°Žé žåã«ãªãŠã ãå«ãã§ãããéãåããã
ãæå æ§ã®èŠçŽ ãšååèŠçŽ ãšã®éã«èãå±€ãšããŠ
åŠççµæç©ãååžãããããšã«ãããããé©çšã
ããªãã°ãåŠççµæç©ã¯éåäœãã€ã«ã 圢æå€ã
æ¿ååå€ãããã¯å¢ç²å€ãå«ãã§ãããšå¥œãŸã
ããããããã·ãšãã«ã»ã«ããŒã¹ããã³ãããªãŠ
ã ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ã¯ããã®ç®çã®ã
ãã«ç¹ã«æçšã§ãããæ¡æ£è»¢ååçæ³ã®å ¬ç¥ã®å
çã«ããé©åœãªç²åºŠãäžããã®ã«å¹æçãªæ¿åºŠã§
åŠççµæç©ã®äžã«å«æããããåŠççµæç©ã¯ãã
ã«ãéå¡©æ¡æ£è»¢åæ³ã«ãããŠå ¬ç¥ã®å¥ã®å©å€ãã
ãšãã°ãã¶ãé²æ¢å€ã調è²å€ïŒtoning agentsïŒã
å®å®åå€çãå«æãããŠãããã ïŒå®æœäŸïŒ 以äžã«ãå®æœäŸããã³æ¯èŒäŸããããŠãæ¬çºæ
ãããã«è©³çŽ°ã«èª¬æããã å®æœäŸ ïŒ ååã·ãŒãã®äœæ ïŒ ååã·ãŒã(1)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ãããŒãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(1)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒãïŒ
âïŒïŒâããã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâ
ïŒïŒïŒâãžãããã€ãããŸãŒã«âïŒâããªã³
ïŒ0.06ïŒ (3) ååå±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒïŒ1.5ïŒãç¡«
åãã©ãžãŠã ïŒ7.5Ã10-4ïŒãïŒâïŒïŒâãã
ã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãžã
ããã€ãããŸãŒã«âïŒâããªã³ïŒ0.02ïŒãå¡
åžããã®ã¡æ°Žé žåãããªãŠã 9.0ïœãã¡ã¿ã
ãŒã«240mlããã³æ°Ž60mlã«æº¶è§£ãããã±ã³å
液ã«ããè¡šé¢ããã±ã³åããŠååå±€ãšããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(2)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ããâãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(2)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ ïŒâïŒïŒâããã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒ
âïŒïŒïŒâãžãããã€ãããŸãŒã«âïŒâããª
ã³ïŒ0.25ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒã (3) ååå±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒïŒ1.5ïŒãç¡«
åãã©ãžãŠã ïŒ7.5Ã10-4ïŒãïŒâïŒïŒâãã
ã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãžã
ããã€ãããŸãŒã«âïŒâããªã³ïŒ0.01ïŒãå¡
åžããã®ã¡æ°Žé žåãããªãŠã 9.0ïœãã¡ã¿ã
ãŒã«240mlããã³æ°Ž60mlã«æº¶è§£ãããã±ã³å
液ã«ããè¡šé¢ããã±ã³åããŠååå±€ãšããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(3)ã®äœæ ååã·ãŒã(2)ã®å±€(3)ååå±€ã®ã±ã³å液ãæ°Žé ž
åãããªãŠã 10.7ïœãã¡ã¿ããŒã«280mlããã³
ã°ãªã»ãªã³24ïœã«æº¶è§£ããããã®ãšãã以å€å
åã·ãŒã(2)ãšåãã«äœæããã ïŒ ååã·ãŒã(4)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ãããŒãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(4)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ ïŒâïŒïŒâããã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒ
âïŒïŒïŒâãžãããã€ãããŸãŒã«âïŒâããª
ã³ïŒ0.10ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒã (3) ååå±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒïŒ1.5ïŒãç¡«
åãã©ãžãŠã ïŒ7.5Ã10-4ïŒãïŒâïŒïŒâãã
ã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãžã
ããã€ãããŸãŒã«âïŒâããªã³ïŒ0.04ïŒãå¡
åžããã®ã¡æ°Žé žåãããªãŠã 10.7ïœãã¡ã¿ã
ãŒã«280mlããã³ã°ãªã»ãªã³24ïœã«æº¶è§£ãã
ãã±ã³å液ã«ããè¡šé¢ããã±ã³åããŠååå±€
ãšããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(5)ã®äœæ æ¯æäœããªãšãã¬ã³ã©ãããŒãçŽã®äžã«é ã«
次ã®å±€ãèšãååã·ãŒã(5)ãäœæãããïŒ ïŒ
å ã®æ°å€ã¯å¡åžéãïœïŒm2ã§ç€ºããã®ã§ããã (1) äžåå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床53ïŒ ïŒ(6)ãã¡ãã«
ããã«ãšãŒãã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœ
(4)ããŠãããã¯ã¹ïŒuvitexïŒOBïŒããã¬ã€ã®
ãŒç€Ÿã®åååïŒïŒ0.04ïŒ ïŒâããšãã«âïŒïŒïŒâãžãããã€ãããŸ
ãŒã«âïŒâããªã³ïŒ0.15ïŒ (2) äžåã¿ã€ãã³ã°å±€ é ¢é žã»ã«ããŒã¹ïŒé ¢å床55ïŒ ïŒïŒ8.5ïŒã (3) ååå±€ ååã·ãŒã(4)ã®å±€(3)ååå±€ã®ïŒâïŒïŒâã
ãã·ã«ã«ã«ãã¢ã€ã«ããšãã«ïŒâïŒïŒïŒâãž
ãããã€ãããŸãŒã«âïŒâããªã³ïŒ0.04ïŒã
ïŒâããšãã«âïŒïŒïŒâãžãããã€ãããŸãŒ
ã«âïŒâããªã³ïŒ0.01ïŒãšãã以å€ã¯ååã·
ãŒã(4)ãšåãã«ããã (4) å¥é¢å±€ ããã«ã¡ã¿ã¢ã¯ãªã¬ãŒãâã¢ã¯ãªã«é žå ±é
åäœïŒã¢ã«æ¯15ïŒ85ïŒïŒ0.03ïŒ ïŒ ååã·ãŒã(6)ã®äœæ ååã·ãŒã(3)ã«ãããŠãå±€(1)äžåå±€ãšå±€(2)äž
åã¿ã€ãã³ã°å±€ã®éã«äžèšå±€ïŒ1â²ïŒç»åå®å®å
å±€ãèšãã以å€ãååã·ãŒã(3)ãšåãã«äœæã
ãã (1â²) ç»åå®å®åå±€ïŒ é ¢é žã»ã«ããŒã¹ïŒé ¢å床46ïŒ ïŒïŒ4.2ïŒãäž
èšååç©ïŒ2.1ïŒ
ãåã
ïŒ ååã·ãŒã(7)ã®äœæ
ååã·ãŒã(6)ã®å±€(3)ååå±€ã®ã±ã³å液ãæ°Žé
ž
åãããªãŠã 10.7ïœãã¡ã¿ããŒã«290mlããã³
ã°ãªã»ãªã³12ïœã«æº¶è§£ããããã®ãšãã以å€å
åã·ãŒã(6)ãšåãã«äœæããã æå ã·ãŒãã®äœæ æ¯æäœïŒé»è²ããªãšã¹ãã«ãã€ã«ã ïŒã®äžã«é
ã«æ¬¡ã®å±€ãèšããïŒ (1) å¹³åç²åŸ1.0ÎŒïœã®æ²èåéïŒæ²çŽ å«é6.5ã¢
ã«ïŒ ïŒïŒééã§0.59ïœïŒm2ïŒããŒã©ãã³ïŒ3.5ïŒ (2) ä¿è·å±€ ãŒã©ãã³ïŒ0.7ïŒãããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
ç²åïŒ0.1ïŒ åŠç液ã®èª¿è£œ æ°Žé žåã«ãªãŠã ïŒ40ïŒ KOHæ°Žæº¶æ¶²ïŒ 323c.c. äºé žåãã¿ã³ ïŒïœ ããããã·ãšãã«ã»ã«ããŒã¹ 79ïœ é žåäºé 9.75ïœ ïŒ®ïŒïŒ®âãã¹âã¡ããã·ãšãã«ããããã·ã¢ãã³
75ïœ ããªãšã¿ããŒã«ã¢ãã³æº¶æ¶²ïŒæ°Ž6.2éšã«å¯ŸããŠã
ãªãšã¿ããŒã«ã¢ãã³4.5éšïŒ 17.14ïœ ããã©ãããããªããžã³ããªã³ 0.4ïœ ïŒïŒïŒâãžã¡ãã«ã«ããããªããžã³ 0.35ïœ ãŠã©ã·ã« 80ïœ æ°Ž 1193ïœ æå ã·ãŒããè²æž©åºŠ5400Kã®å æºããã€æå èš
ãçšããŠå æ¥é²å ãè¡ãªã€ãããã®é²å æžã®æå
ã·ãŒããšå®æœäŸïŒã®ååã·ãŒããéããã®éã«äž
èšåŠç液ã0.035mmã®åãã§å±éãæ¡æ£è»¢åçŸå
ã30ç§åŸã«å¥é¢ããŠããžããªã³ããåŸããåŠçã¯
25âã«ãŠè¡ã€ãã åŸãããããžããªã³ããå¯å£«åçãã€ã«ã 瀟補
TCDåèªå·±æ¿åºŠèšãçšããŠæž¬å®ãæ倧æ¿åºŠãæ±
ããã è¡šïŒã«ç€ºããåŠãæ¬çºæã®ååã·ãŒãã¯Dmax
ãé«ãè¯å¥œãªããžç»åãäžããã å®æœäŸ ïŒ å®æœäŸïŒã®ååã·ãŒãã»æå ã·ãŒãã»åŠç液ã
䜿çšããŠå¥é¢æéã10åãšãã以å€ãå®æœäŸïŒãš
åæ§ã«åŠçããŠããžããªã³ããåŸãããããå¯å£«
ãã€ã«ã 瀟補TCDåèªèšæ¿åºŠèšãçšããŠæž¬å®ã
ãã®ã¡ïŒæ©å®€å ã§æŸçœ®ããã®ã¡ããã®åŸ60â30ïŒ
RHã®æ¡ä»¶ã«ïŒæ¥éçµæããããçµæååŸã§ã®
Dminã®å·®ã«ããã¹ãã€ã³ãè©äŸ¡ããã ãŸããåæ§ã«60â80ïŒ RHã®æ¡ä»¶ã«ïŒæ¥éæŸçœ®
ããŠæåæ¿åºŠ0.5ã§ãã€ãéšåã®æ¿åºŠäœäžãšè²èª¿
ã®å€åã«ããä¿åå®å®æ§ãè©äŸ¡ããã è¡šïŒã«ç€ºããåŠããæ¬çºæã®ååã·ãŒãã¯ã¹ã
ã€ã³ã®å¢å ãå°ãªããä¿åå®å®æ§ã«ãããæ¿åºŠäœ
äžãå°ããè²èª¿å€åãå°ãªãè¯å¥œã§ãã€ãã
åãããªãŠã 10.7ïœãã¡ã¿ããŒã«290mlããã³
ã°ãªã»ãªã³12ïœã«æº¶è§£ããããã®ãšãã以å€å
åã·ãŒã(6)ãšåãã«äœæããã æå ã·ãŒãã®äœæ æ¯æäœïŒé»è²ããªãšã¹ãã«ãã€ã«ã ïŒã®äžã«é
ã«æ¬¡ã®å±€ãèšããïŒ (1) å¹³åç²åŸ1.0ÎŒïœã®æ²èåéïŒæ²çŽ å«é6.5ã¢
ã«ïŒ ïŒïŒééã§0.59ïœïŒm2ïŒããŒã©ãã³ïŒ3.5ïŒ (2) ä¿è·å±€ ãŒã©ãã³ïŒ0.7ïŒãããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
ç²åïŒ0.1ïŒ åŠç液ã®èª¿è£œ æ°Žé žåã«ãªãŠã ïŒ40ïŒ KOHæ°Žæº¶æ¶²ïŒ 323c.c. äºé žåãã¿ã³ ïŒïœ ããããã·ãšãã«ã»ã«ããŒã¹ 79ïœ é žåäºé 9.75ïœ ïŒ®ïŒïŒ®âãã¹âã¡ããã·ãšãã«ããããã·ã¢ãã³
75ïœ ããªãšã¿ããŒã«ã¢ãã³æº¶æ¶²ïŒæ°Ž6.2éšã«å¯ŸããŠã
ãªãšã¿ããŒã«ã¢ãã³4.5éšïŒ 17.14ïœ ããã©ãããããªããžã³ããªã³ 0.4ïœ ïŒïŒïŒâãžã¡ãã«ã«ããããªããžã³ 0.35ïœ ãŠã©ã·ã« 80ïœ æ°Ž 1193ïœ æå ã·ãŒããè²æž©åºŠ5400Kã®å æºããã€æå èš
ãçšããŠå æ¥é²å ãè¡ãªã€ãããã®é²å æžã®æå
ã·ãŒããšå®æœäŸïŒã®ååã·ãŒããéããã®éã«äž
èšåŠç液ã0.035mmã®åãã§å±éãæ¡æ£è»¢åçŸå
ã30ç§åŸã«å¥é¢ããŠããžããªã³ããåŸããåŠçã¯
25âã«ãŠè¡ã€ãã åŸãããããžããªã³ããå¯å£«åçãã€ã«ã 瀟補
TCDåèªå·±æ¿åºŠèšãçšããŠæž¬å®ãæ倧æ¿åºŠãæ±
ããã è¡šïŒã«ç€ºããåŠãæ¬çºæã®ååã·ãŒãã¯Dmax
ãé«ãè¯å¥œãªããžç»åãäžããã å®æœäŸ ïŒ å®æœäŸïŒã®ååã·ãŒãã»æå ã·ãŒãã»åŠç液ã
䜿çšããŠå¥é¢æéã10åãšãã以å€ãå®æœäŸïŒãš
åæ§ã«åŠçããŠããžããªã³ããåŸãããããå¯å£«
ãã€ã«ã 瀟補TCDåèªèšæ¿åºŠèšãçšããŠæž¬å®ã
ãã®ã¡ïŒæ©å®€å ã§æŸçœ®ããã®ã¡ããã®åŸ60â30ïŒ
RHã®æ¡ä»¶ã«ïŒæ¥éçµæããããçµæååŸã§ã®
Dminã®å·®ã«ããã¹ãã€ã³ãè©äŸ¡ããã ãŸããåæ§ã«60â80ïŒ RHã®æ¡ä»¶ã«ïŒæ¥éæŸçœ®
ããŠæåæ¿åºŠ0.5ã§ãã€ãéšåã®æ¿åºŠäœäžãšè²èª¿
ã®å€åã«ããä¿åå®å®æ§ãè©äŸ¡ããã è¡šïŒã«ç€ºããåŠããæ¬çºæã®ååã·ãŒãã¯ã¹ã
ã€ã³ã®å¢å ãå°ãªããä¿åå®å®æ§ã«ãããæ¿åºŠäœ
äžãå°ããè²èª¿å€åãå°ãªãè¯å¥œã§ãã€ãã
ãè¡šã
ãè¡šã
å®æœäŸ ïŒ
å®æœäŸïŒã®ååã·ãŒã(6)ã®å±€(3)ååå±€ã«ããã
ã±ã³å液äžã®ã°ãªã»ãªã³ãããªã¹ããããã·ã¡ã
ã«ãããã³ããã³ããªã¢ã»ãã³ã«å€ãã以å€åã
ååã·ãŒããäœè£œããã®ã¡å®æœäŸïŒããã³å®æœäŸ
ïŒã®åŠçãæœãè¯å¥œãªçµæãåŸãã
ã±ã³å液äžã®ã°ãªã»ãªã³ãããªã¹ããããã·ã¡ã
ã«ãããã³ããã³ããªã¢ã»ãã³ã«å€ãã以å€åã
ååã·ãŒããäœè£œããã®ã¡å®æœäŸïŒããã³å®æœäŸ
ïŒã®åŠçãæœãè¯å¥œãªçµæãåŸãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«æ¯æäœåŽããé 次å°ãªããšãã¢ã«
ã«ãªäžåå±€ãäžåã¿ã€ãã³ã°å±€ãã»ã«ããŒã¹ãšã¹
ãã«ãå¡èšåŸã¢ã«ã«ãªæ¶²ã«ãã鹞åããŠåŸããã
åçã»ã«ããŒã¹äžã«éæ²ç©æ žãå«ãååå±€ãå«æ
ããéå¡©æ¡æ£è»¢åæ³ååèŠçŽ ã«ãããŠã該ã¢ã«ã«
ãªæ¶²ãïŒå以äžã®æ°Žé žåºãæããå€äŸ¡ã¢ã«ã³ãŒã«
åã¯ãã®èªå°äœãïŒã20ééïŒ å«æãããã€è©²äž
åå±€ããã³è©²äžåã¿ã€ãã³ã°å±€ã®å°ãªããšãïŒå±€
äžã«äžèšäžè¬åŒïŒïŒããŸãã¯ïŒïŒã§è¡šããã
ãååç©ãå°ãªããšãïŒã€å«æããããšãç¹åŸŽãš
ããéå¡©æ¡æ£è»¢åæ³ååèŠçŽ ã ïŒïŒãåŒã ïŒïŒ ãåã åŒäžR0ã¯åãã§ãç°ãªã€ãŠããããæ°ŽçŽ ååã
ããã²ã³ååãã¢ã«ãã«åºã眮æã¢ã«ãã«åºã眮
æãŸãã¯ç¡çœ®æã®ã·ã¯ãã¢ã«ãã«åºãã¢ã«ã³ãã·
åºã眮æã¢ã«ã³ãã·åºã眮æãŸãã¯ç¡çœ®æã®ã¢ã«
ãã«ã¹ã«ããã«åºã眮æãŸãã¯ç¡çœ®æã®ã¢ãªãŒã«
ã¹ã«ããã«åºãã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ãŸã
ã¯ã¢ãªãŒã«ã¹ã«ãã³ã¢ããåºãã«ã«ãã¢ã€ã«åºã
ã«ã«ãã³ã¢ããåºãè€çŽ ç°åºã眮æãŸãã¯ç¡çœ®æ
ã®ã¢ãªãŒã«åºãã¢ã·ã«åºã眮æãŸãã¯ç¡çœ®æã®ã¢
ã«ã³ãã·ã«ã«ããã«åºã眮æãŸãã¯ç¡çœ®æã®ã¢ã·
ã«ãªãã·åºã眮æãŸãã¯ç¡çœ®æã®ã¢ã«ãã«ããª
åºã眮æãŸãã¯ç¡çœ®æã®ã¢ãªãŒã«ããªåºãïŒçŽã¢
ããåºãŸãã¯ãã®å¡©ãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«
åºã§çœ®æãããïŒçŽãŸãã¯ïŒçŽã¢ããåºãŸãã¯ã
ã®å¡©ããããåºãããããã·åºãã«ã«ããã·ã«
åºãã¹ã«ãã³é žåºããŸãã¯ã·ã¢ãåºãè¡šããã R1ãR2ã¯åã æ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢
ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºãè¡šããã R3ãR4ã¯åã æ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢
ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºãŸãã¯è€
çŽ ç°åºãè¡šããã R3ãR4ã¯ïŒ®ååãšå ±ã«ïŒãïŒå¡ç°ã圢æããŠ
ããããç°äžã«ããã«ãããååãå«ãã§ããŠã
ããã R5ãR6ã¯åã æ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢
ã«ãã«åºãã¢ãªãŒã«åºã眮æã¢ãªãŒã«åºãŸãã¯è€
çŽ ç°åºãè¡šããã A1ã¯äºäŸ¡ã®åºãè¡šãããïœã¯ïŒãåã¯ïŒãïŒ
ã®æŽæ°ãè¡šãããïœã¯ïŒãïŒåã¯ïŒãè¡šããã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19122586A JPS6347758A (ja) | 1986-08-15 | 1986-08-15 | éå¡©æ¡æ£è»¢åæ³ååèŠçŽ |
| US07/418,692 US4945026A (en) | 1986-08-15 | 1989-10-02 | Image receiving element for use in a silver salt diffusion transfer process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19122586A JPS6347758A (ja) | 1986-08-15 | 1986-08-15 | éå¡©æ¡æ£è»¢åæ³ååèŠçŽ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6347758A JPS6347758A (ja) | 1988-02-29 |
| JPH0567226B2 true JPH0567226B2 (ja) | 1993-09-24 |
Family
ID=16270975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19122586A Granted JPS6347758A (ja) | 1986-08-15 | 1986-08-15 | éå¡©æ¡æ£è»¢åæ³ååèŠçŽ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6347758A (ja) |
-
1986
- 1986-08-15 JP JP19122586A patent/JPS6347758A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6347758A (ja) | 1988-02-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS59180548A (ja) | ç»å圢ææ¹æ³ | |
| JPH0535415B2 (ja) | ||
| US3015562A (en) | Receiving sheet for use in photographic silver transfer process | |
| GB2138583A (en) | A silver halide photographic material | |
| US4945026A (en) | Image receiving element for use in a silver salt diffusion transfer process | |
| US3753764A (en) | Photographic diffusion transfer product and process | |
| US3706568A (en) | Photographic diffusion transfer product and process | |
| EP0131311B1 (en) | Image-receiving element for silver salt diffusion process | |
| JPH0567226B2 (ja) | ||
| US4569899A (en) | Photographic element for silver salt diffusion transfer process | |
| US3642482A (en) | Photographic element and process | |
| JPH0693109B2 (ja) | éå¡©æ¡æ£è»¢åæ³ååèŠçŽ | |
| US4310613A (en) | Liquid processing composition for silver complex diffusion transfer process | |
| US5290661A (en) | Method for forming images by silver salt diffusion transfer | |
| US3326681A (en) | Photographic products and processes | |
| JPH0533776B2 (ja) | ||
| US5618652A (en) | Image formation method by silver salt diffusion transfer | |
| JPH0554103B2 (ja) | ||
| US5204211A (en) | Image receiver element for use in silver salt diffusion transfer | |
| US5006440A (en) | Process for stabilizing photographic silver images | |
| JPS6347760A (ja) | éå¡©æ¡æ£è»¢åæ³ååèŠçŽ | |
| JPH06161069A (ja) | éå¡©æ¡æ£è»¢åæ³çšååèŠçŽ | |
| JPS6347759A (ja) | éå¡©æ¡æ£è»¢åæ³ååèŠçŽ | |
| JPH04151147A (ja) | éå¡©æ¡æ£è»¢åæ³çšååèŠçŽ | |
| JPH08272062A (ja) | éå¡©æ¡æ£è»¢åæ³çšååèŠçŽ |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |