JPH0575100B2 - - Google Patents
Info
- Publication number
- JPH0575100B2 JPH0575100B2 JP5626386A JP5626386A JPH0575100B2 JP H0575100 B2 JPH0575100 B2 JP H0575100B2 JP 5626386 A JP5626386 A JP 5626386A JP 5626386 A JP5626386 A JP 5626386A JP H0575100 B2 JPH0575100 B2 JP H0575100B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver halide
- silver
- layer
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052709 silver Inorganic materials 0.000 claims description 97
- 239000004332 silver Substances 0.000 claims description 97
- -1 silver halide Chemical class 0.000 claims description 86
- 239000000463 material Substances 0.000 claims description 50
- 239000000839 emulsion Substances 0.000 claims description 48
- 229920001296 polysiloxane Polymers 0.000 claims description 45
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 239000000470 constituent Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 238000000034 method Methods 0.000 description 70
- 239000010410 layer Substances 0.000 description 68
- 239000000975 dye Substances 0.000 description 59
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 37
- 230000001235 sensitizing effect Effects 0.000 description 27
- 108010010803 Gelatin Proteins 0.000 description 25
- 239000008273 gelatin Substances 0.000 description 25
- 229920000159 gelatin Polymers 0.000 description 25
- 235000019322 gelatine Nutrition 0.000 description 25
- 235000011852 gelatine desserts Nutrition 0.000 description 25
- 239000000243 solution Substances 0.000 description 25
- 238000011161 development Methods 0.000 description 23
- 238000011282 treatment Methods 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000006185 dispersion Substances 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 239000011241 protective layer Substances 0.000 description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 11
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 11
- 238000012545 processing Methods 0.000 description 10
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000084 colloidal system Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 238000004061 bleaching Methods 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000004848 polyfunctional curative Substances 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910021612 Silver iodide Inorganic materials 0.000 description 6
- 239000012190 activator Substances 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 125000003944 tolyl group Chemical group 0.000 description 6
- 206010070834 Sensitisation Diseases 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 230000008313 sensitization Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000005023 xylyl group Chemical group 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000006224 matting agent Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 2
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- AQGAOQUTCJMIBW-UHFFFAOYSA-M sodium 4-(3-ethyloctan-3-yloxy)-4-oxobutanoate Chemical compound C(CCC(=O)[O-])(=O)OC(CCCCC)(CC)CC.[Na+] AQGAOQUTCJMIBW-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- ZKGIQGUWLGYKMA-UHFFFAOYSA-N 1,2-bis(ethenylsulfonyl)ethane Chemical compound C=CS(=O)(=O)CCS(=O)(=O)C=C ZKGIQGUWLGYKMA-UHFFFAOYSA-N 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical class C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- 150000001473 2,4-thiazolidinediones Chemical class 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical class O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 229940090898 Desensitizer Drugs 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical class NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 108091005647 acylated proteins Proteins 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- ZUIVNYGZFPOXFW-UHFFFAOYSA-N chembl1717603 Chemical compound N1=C(C)C=C(O)N2N=CN=C21 ZUIVNYGZFPOXFW-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine group Chemical group N1=CCC2=CC=CC=C12 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000007344 nucleophilic reaction Methods 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 150000004989 p-phenylenediamines Chemical class 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NHQVTOYJPBRYNG-UHFFFAOYSA-M sodium;2,4,7-tri(propan-2-yl)naphthalene-1-sulfonate Chemical compound [Na+].CC(C)C1=CC(C(C)C)=C(S([O-])(=O)=O)C2=CC(C(C)C)=CC=C21 NHQVTOYJPBRYNG-UHFFFAOYSA-M 0.000 description 1
- QCLLFDRXTCSDTP-UHFFFAOYSA-M sodium;4-oxo-4-pentadecoxy-3-sulfobutanoate Chemical compound [Na+].CCCCCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O QCLLFDRXTCSDTP-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003459 sulfonic acid esters Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
Description
ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãã¹ããªæ§ããã³èæ¥çæ§ã®æ¹è¯ãã
ãããã²ã³åéåçæå ææã«é¢ããæŽã«è©³ãã
ã¯ãç¹å®ã®ãªã«ã¬ãããªã·ãããµã³ãçšããŠè¡šé¢
ã®ç©ççæ§è³ªãæ¹è¯ããããã²ã³åéåçæå æ
æã«é¢ããã çºæã®èæ¯ïŒœ ããã²ã³åéåçæå ææã¯äžè¬ã«ãçŽãã¬ã©
ã¹ãã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ãããªãšã¹ã
ã«ãã€ã«ã çã®æ¯æäœäžã«ãå°ãªããšãäžå±€ã®ã
ãã²ã³åéä¹³å€å±€ããã³å°ãªããšãäžå±€ã®éæå
æ§å±€ããæ§æãããåçæ§æå±€ãæããŠãªããã
åçæ§æå±€ã«çšãããããã€ã³ããŒãšããŠé垞芪
æ°Žæ§ã³ãã€ããäžã§ããŒã©ãã³ãçšããããŠã
ãã ãã®ãŒã©ãã³ããæãå¡åžèã¯ä»ã®éå±é¢ãã
ãã¯ãŒã©ãã³é¢ã«å¯Ÿããæ©æŠä¿æ°ãé«ãããã®ã
ãäžè¬ã«ãã€ã³ããŒãšããŠèŠªæ°Žæ§ã³ãã€ããç¹ã«
ãŒã©ãã³ãçšããŠããããã²ã³åéåçæå ææ
ã¯ãè¡šé¢ãæ¥è§Šãæ©æŠçã«ããå·ãã€ãããããš
ããé倧ãªæ¬ ç¹ãæããŠãããç¹ã«ããã²ã³åé
åçæå ææã¯ãæå æ§ç©è³ªãšããŠçšããããã²
ã³åéãå§åã«å¯ŸããŠãéæã«æå¿ããããã«ã
æ¥è§Šãæ©æŠçã«ããå·ã¯æã«å§åã«ããªãå§åã«
ããæžæçãæ¹èµ·ãåçç»åã«èŽåœçãªåœ±é¿ãäž
ããããŸãããŒã©ãã³ããã€ã³ããŒãšããŠçšããŠ
ãããããé«æ¹¿äžã«ãããŠã¯ãè¡šé¢ã«ç²çæ§ãã
ããæå ææã©ãããæ¥çãããããªããšããæ¬
ç¹ãæããŠããããã®ããéåžžããã²ã³åéåç
æå ææã«ãããŠã¯ãæå æ§ããã²ã³åéä¹³å€å±€
ã®å€åŽã«éæå æ§ã®ä¿è·å±€ãèšããããã«ã·ãª
ã«ãã¬ã©ã¹ãåææš¹èçã該ä¿è·å±€äžã«ååšãã
ããããšã«ãããã€ã«ã è¡šé¢ãç²é¢åããæ¥è§Šé¢
ç©ãæžå°ãããŠãæ©æŠä¿æ°ãã³ã³ãããŒã«ããæ
å ææã©ããã®æ¥çãå§åã«ããã«ããªã®çºçã
é²æ¢ãããããããã¯æŠéå·ããããã²ã³åéå
çæå ææãä¿è·ããçã®æ¹æ³ãè¡ãããŠããã
ããã«è¿å¹Žã§ã¯é«æ²žç¹æº¶åªãåºäœãã©ãã€ã³ã鯚
æ²¹çããŒã©ãã³æ°Žæº¶æ¶²ã«åæ£ããŠããã²ã³åéå
çæå ææã«é©çšããæ¹æ³ããäŸãã°ç±³åœç¹èš±ç¬¬
3121060å·æ现æžãããã¯ç¹éæ49â5017å·å ¬å ±
ã«èšèŒãããŠããã ãããã¯æå¹ãªæ¹æ³ã§ããããããããããã
ç¹åŸŽãæããŠããããåé¢ä»¥äžã®ãããªæ¬ ç¹ãæ
ããŠãããäŸãã°ã·ãªã«ãã¬ã©ã¹ãããã¯åææš¹
èçã¯ã¹ãªããºé²æ¢ãšããç¹ã§å£ã€ãŠãããç¹ã«
è£é¢ã«é©çšããå Žåã«ã¯ããºãã€ãããããªããš
ããæ¬ ç¹ãããããŸãããããã®ãã®ãå€éã«çš
ãããšãæå ææã®éæ床ãäœäžãããã®çµæç»
åã®é®®éæ§ãå£åããããšããæ¬ ç¹ãæããŠã
ãã ãŸããããã¯ãåã«ãã©ãŒã®æº¶åªãšããŠã䜿çš
ãããé«æ²žç¹æº¶åªãã¹ããªå€ãšããŠäœ¿çšãããšã
é«æž©é«æ¹¿ã®æ¡ä»¶äžã§é«æ²žç¹æº¶åªãå±€äžããè¡šé¢ã«
移è¡ãããã€ã«ã åå¿ãæ¥çãèµ·ããåå ãšãª
ãããŸãé«æ²žç¹æº¶åªã®ã³ãã€ãåæ£æ¶²ã®å®å®æ§ã¯
液ã®ç²åºŠã掻æ§å€ã®æ¿åºŠçã«å€§ããäŸåããã
ããåæ£æ¶²ã®èª¿è£œãé£ããçã®æ¬ ç¹ãããã ããã«ãŸãåºäœãã©ãã€ã³ã¯åæ£æ§ãæªããç¹
ã«åæ£æ§ã枩床ã«åŒ·ãäŸåããŠããããã«ãå®å®
ã«åäžãªåŸ®ç²ååæ£æ¶²ãäœãã«ãããŸãåºäœãã©
ãã€ã³ã¯å®¹åšãããã¯é 管çã®å£ã«ä»çããã
ãããããé€ãããã«å®¹åšãããã¯é ç®¡å šäœãä¿
æž©ããªããã°ãªããªãçã®æ¬ ç¹ãããã ããã«ãŸããçé¢æŽ»æ§å€ãçšããŠããã²ã³åé
åçæå ææã®ã¹ããªæ§ãã³ã³ãããŒã«ããæ¹æ³
ãç¥ãããŠããããçé¢æŽ»æ§å€ãåŠçäžã«åŠç液
ã«æº¶åºãããã®çµæåŠç液ãçºæ³¡ããçã®äžéœå
ãçããããã«ã䜿çšéãå¶éãããŠããŸãçã®
æ¬ ç¹ãããã ãŸãããªã«ã¬ãããªã·ããã¶ã³ãããã²ã³åé
ä¹³å€å±€ãä¿è·å±€åã¯ããã¯ã³ãŒãã€ã³ã°å±€ã«å«æ
ãããŠãæå ææè¡šé¢ã®ã¹ããªæ§ãæ¹è¯ããæ¹æ³
ãç¥ãããŠãããäŸãã°ãç±³åœç¹èš±ç¬¬3042522å·
ã«èšèŒãããŠãããããªãžã¡ãã«ã·ãªã³ãŒã³ãšç¹
å®ã®çé¢æŽ»æ§å€ãšãåæã«çšããæ¹æ³ãç±³åœç¹èš±
第3080317å·ã«èšèŒãããŠãããããªãžã¡ãã«ã·
ãªã³ãŒã³ãšãžããšãã«ã·ãªã³ãŒã³ãšã®æ··åç©ãçš
ããæ¹æ³ãè±åœç¹èš±ç¬¬1143118å·ã«èšèŒãããŠã
ããããªããªããšãã«æ«ç«¯ã®ã¡ãã«ããšãã«ã·ãª
ã³ãŒã³ãçšããæ¹æ³ãç±³åœç¹èš±ç¬¬3489567å·ã«èš
èŒãããŠãããããªãžäœçŽã¢ã«ãã«ã·ãªã³ãŒã³ãš
ç¹å®ã®çé¢æŽ»æ§å€ãçšããæ¹æ³ãç¹å ¬æ53â292
å·ã«èšèŒãããŠãããããªåŽéã«é·éã¢ã«ãã«åº
ãæãããªã«ã¬ãããªã·ãããµã³ãçšããæ¹æ³ã
ç¹å ¬æ55â92843å·ã«èšèŒãããŠãããããªåŽé
ã«ããªãªãã·ãšãã¬ã³åºãæãããªã«ã¬ãããªã·
ãããµã³ãçšããæ¹æ³ãªã©ãããã ãããã®ãªã«ã¬ãããªã·ãããµã³ååç©ã«ãã€
ãŠæå ææã®ã¹ããªæ§ã¯è¥å¹²æ¹è¯ããããã®ã®ã
å åãªæ§èœãåŸããããã®ã¯ãªããããããã€ã«
ã è¡šé¢ã®ç²çæ§ãå®å šã«é€ãããšã¯ã§ããããã
ã«ããã²ã³åéã«ã©ãŒåçæå ææã®å Žåããã
ãã¯ãåã«ãã©ãŒã®æº¶åªãšããŠäœ¿ãããŠããé«æ²ž
ç¹ææ©æº¶å€ããé«æž©ãé«æ¹¿äžã§æäžå±€ãŸã§ç§»è¡
ãããã€ã«ã åå¿ãæ¥çããçŸè±¡ãèŠããããã
ã®çŸè±¡ã®æ¹è¯ã«ã¯ãäœã圹ã«ç«ããªãã€ãã çºæã®ç®ç æ¬çºæã®ç¬¬ïŒã®ç®çã¯ããã¹ãæ§ã®è¯å¥œãªãã
ã²ã³åéåçæå ææãæäŸããããšã«ããã ãŸã第ïŒã®ç®çã¯ãé«æž©ãé«æ¹¿æã«ä¿åããã
æã®ããã²ã³åéåçæå ææã©ããã®æ¥çãé²
æ¢ãããããã²ã³åéåçæå ææãæäŸããã
ãšã«ããã çºæã®æ§æ æ¬çºæã®äžèšç®çã¯ãæ¯æäœäžã«ãå°ãªããšã
äžå±€ã®ããã²ã³åéä¹³å€å±€ãæããããã²ã³åé
åçæå ææã«ãããŠãåèšæ¯æäœäžã«èšããã
ãããã²ã³åéåçæå ææãæ§æããåçæ§æ
å±€ã®å°ãªããšãäžå±€ã«ãäžèšäžè¬åŒïŒ»ïŒœã§è¡šã
ãããæ§æåäœããã³ïŒãŸãã¯äžèšäžè¬åŒïŒ»ïŒœ
ã§è¡šããããåºãæãããªã«ã¬ãããªã·ãããµã³
ãå«æããããããšã«ããéæãããã äžè¬åŒïŒ»ïŒœ
ãããã²ã³åéåçæå ææã«é¢ããæŽã«è©³ãã
ã¯ãç¹å®ã®ãªã«ã¬ãããªã·ãããµã³ãçšããŠè¡šé¢
ã®ç©ççæ§è³ªãæ¹è¯ããããã²ã³åéåçæå æ
æã«é¢ããã çºæã®èæ¯ïŒœ ããã²ã³åéåçæå ææã¯äžè¬ã«ãçŽãã¬ã©
ã¹ãã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ãããªãšã¹ã
ã«ãã€ã«ã çã®æ¯æäœäžã«ãå°ãªããšãäžå±€ã®ã
ãã²ã³åéä¹³å€å±€ããã³å°ãªããšãäžå±€ã®éæå
æ§å±€ããæ§æãããåçæ§æå±€ãæããŠãªããã
åçæ§æå±€ã«çšãããããã€ã³ããŒãšããŠé垞芪
æ°Žæ§ã³ãã€ããäžã§ããŒã©ãã³ãçšããããŠã
ãã ãã®ãŒã©ãã³ããæãå¡åžèã¯ä»ã®éå±é¢ãã
ãã¯ãŒã©ãã³é¢ã«å¯Ÿããæ©æŠä¿æ°ãé«ãããã®ã
ãäžè¬ã«ãã€ã³ããŒãšããŠèŠªæ°Žæ§ã³ãã€ããç¹ã«
ãŒã©ãã³ãçšããŠããããã²ã³åéåçæå ææ
ã¯ãè¡šé¢ãæ¥è§Šãæ©æŠçã«ããå·ãã€ãããããš
ããé倧ãªæ¬ ç¹ãæããŠãããç¹ã«ããã²ã³åé
åçæå ææã¯ãæå æ§ç©è³ªãšããŠçšããããã²
ã³åéãå§åã«å¯ŸããŠãéæã«æå¿ããããã«ã
æ¥è§Šãæ©æŠçã«ããå·ã¯æã«å§åã«ããªãå§åã«
ããæžæçãæ¹èµ·ãåçç»åã«èŽåœçãªåœ±é¿ãäž
ããããŸãããŒã©ãã³ããã€ã³ããŒãšããŠçšããŠ
ãããããé«æ¹¿äžã«ãããŠã¯ãè¡šé¢ã«ç²çæ§ãã
ããæå ææã©ãããæ¥çãããããªããšããæ¬
ç¹ãæããŠããããã®ããéåžžããã²ã³åéåç
æå ææã«ãããŠã¯ãæå æ§ããã²ã³åéä¹³å€å±€
ã®å€åŽã«éæå æ§ã®ä¿è·å±€ãèšããããã«ã·ãª
ã«ãã¬ã©ã¹ãåææš¹èçã該ä¿è·å±€äžã«ååšãã
ããããšã«ãããã€ã«ã è¡šé¢ãç²é¢åããæ¥è§Šé¢
ç©ãæžå°ãããŠãæ©æŠä¿æ°ãã³ã³ãããŒã«ããæ
å ææã©ããã®æ¥çãå§åã«ããã«ããªã®çºçã
é²æ¢ãããããããã¯æŠéå·ããããã²ã³åéå
çæå ææãä¿è·ããçã®æ¹æ³ãè¡ãããŠããã
ããã«è¿å¹Žã§ã¯é«æ²žç¹æº¶åªãåºäœãã©ãã€ã³ã鯚
æ²¹çããŒã©ãã³æ°Žæº¶æ¶²ã«åæ£ããŠããã²ã³åéå
çæå ææã«é©çšããæ¹æ³ããäŸãã°ç±³åœç¹èš±ç¬¬
3121060å·æ现æžãããã¯ç¹éæ49â5017å·å ¬å ±
ã«èšèŒãããŠããã ãããã¯æå¹ãªæ¹æ³ã§ããããããããããã
ç¹åŸŽãæããŠããããåé¢ä»¥äžã®ãããªæ¬ ç¹ãæ
ããŠãããäŸãã°ã·ãªã«ãã¬ã©ã¹ãããã¯åææš¹
èçã¯ã¹ãªããºé²æ¢ãšããç¹ã§å£ã€ãŠãããç¹ã«
è£é¢ã«é©çšããå Žåã«ã¯ããºãã€ãããããªããš
ããæ¬ ç¹ãããããŸãããããã®ãã®ãå€éã«çš
ãããšãæå ææã®éæ床ãäœäžãããã®çµæç»
åã®é®®éæ§ãå£åããããšããæ¬ ç¹ãæããŠã
ãã ãŸããããã¯ãåã«ãã©ãŒã®æº¶åªãšããŠã䜿çš
ãããé«æ²žç¹æº¶åªãã¹ããªå€ãšããŠäœ¿çšãããšã
é«æž©é«æ¹¿ã®æ¡ä»¶äžã§é«æ²žç¹æº¶åªãå±€äžããè¡šé¢ã«
移è¡ãããã€ã«ã åå¿ãæ¥çãèµ·ããåå ãšãª
ãããŸãé«æ²žç¹æº¶åªã®ã³ãã€ãåæ£æ¶²ã®å®å®æ§ã¯
液ã®ç²åºŠã掻æ§å€ã®æ¿åºŠçã«å€§ããäŸåããã
ããåæ£æ¶²ã®èª¿è£œãé£ããçã®æ¬ ç¹ãããã ããã«ãŸãåºäœãã©ãã€ã³ã¯åæ£æ§ãæªããç¹
ã«åæ£æ§ã枩床ã«åŒ·ãäŸåããŠããããã«ãå®å®
ã«åäžãªåŸ®ç²ååæ£æ¶²ãäœãã«ãããŸãåºäœãã©
ãã€ã³ã¯å®¹åšãããã¯é 管çã®å£ã«ä»çããã
ãããããé€ãããã«å®¹åšãããã¯é ç®¡å šäœãä¿
æž©ããªããã°ãªããªãçã®æ¬ ç¹ãããã ããã«ãŸããçé¢æŽ»æ§å€ãçšããŠããã²ã³åé
åçæå ææã®ã¹ããªæ§ãã³ã³ãããŒã«ããæ¹æ³
ãç¥ãããŠããããçé¢æŽ»æ§å€ãåŠçäžã«åŠç液
ã«æº¶åºãããã®çµæåŠç液ãçºæ³¡ããçã®äžéœå
ãçããããã«ã䜿çšéãå¶éãããŠããŸãçã®
æ¬ ç¹ãããã ãŸãããªã«ã¬ãããªã·ããã¶ã³ãããã²ã³åé
ä¹³å€å±€ãä¿è·å±€åã¯ããã¯ã³ãŒãã€ã³ã°å±€ã«å«æ
ãããŠãæå ææè¡šé¢ã®ã¹ããªæ§ãæ¹è¯ããæ¹æ³
ãç¥ãããŠãããäŸãã°ãç±³åœç¹èš±ç¬¬3042522å·
ã«èšèŒãããŠãããããªãžã¡ãã«ã·ãªã³ãŒã³ãšç¹
å®ã®çé¢æŽ»æ§å€ãšãåæã«çšããæ¹æ³ãç±³åœç¹èš±
第3080317å·ã«èšèŒãããŠãããããªãžã¡ãã«ã·
ãªã³ãŒã³ãšãžããšãã«ã·ãªã³ãŒã³ãšã®æ··åç©ãçš
ããæ¹æ³ãè±åœç¹èš±ç¬¬1143118å·ã«èšèŒãããŠã
ããããªããªããšãã«æ«ç«¯ã®ã¡ãã«ããšãã«ã·ãª
ã³ãŒã³ãçšããæ¹æ³ãç±³åœç¹èš±ç¬¬3489567å·ã«èš
èŒãããŠãããããªãžäœçŽã¢ã«ãã«ã·ãªã³ãŒã³ãš
ç¹å®ã®çé¢æŽ»æ§å€ãçšããæ¹æ³ãç¹å ¬æ53â292
å·ã«èšèŒãããŠãããããªåŽéã«é·éã¢ã«ãã«åº
ãæãããªã«ã¬ãããªã·ãããµã³ãçšããæ¹æ³ã
ç¹å ¬æ55â92843å·ã«èšèŒãããŠãããããªåŽé
ã«ããªãªãã·ãšãã¬ã³åºãæãããªã«ã¬ãããªã·
ãããµã³ãçšããæ¹æ³ãªã©ãããã ãããã®ãªã«ã¬ãããªã·ãããµã³ååç©ã«ãã€
ãŠæå ææã®ã¹ããªæ§ã¯è¥å¹²æ¹è¯ããããã®ã®ã
å åãªæ§èœãåŸããããã®ã¯ãªããããããã€ã«
ã è¡šé¢ã®ç²çæ§ãå®å šã«é€ãããšã¯ã§ããããã
ã«ããã²ã³åéã«ã©ãŒåçæå ææã®å Žåããã
ãã¯ãåã«ãã©ãŒã®æº¶åªãšããŠäœ¿ãããŠããé«æ²ž
ç¹ææ©æº¶å€ããé«æž©ãé«æ¹¿äžã§æäžå±€ãŸã§ç§»è¡
ãããã€ã«ã åå¿ãæ¥çããçŸè±¡ãèŠããããã
ã®çŸè±¡ã®æ¹è¯ã«ã¯ãäœã圹ã«ç«ããªãã€ãã çºæã®ç®ç æ¬çºæã®ç¬¬ïŒã®ç®çã¯ããã¹ãæ§ã®è¯å¥œãªãã
ã²ã³åéåçæå ææãæäŸããããšã«ããã ãŸã第ïŒã®ç®çã¯ãé«æž©ãé«æ¹¿æã«ä¿åããã
æã®ããã²ã³åéåçæå ææã©ããã®æ¥çãé²
æ¢ãããããã²ã³åéåçæå ææãæäŸããã
ãšã«ããã çºæã®æ§æ æ¬çºæã®äžèšç®çã¯ãæ¯æäœäžã«ãå°ãªããšã
äžå±€ã®ããã²ã³åéä¹³å€å±€ãæããããã²ã³åé
åçæå ææã«ãããŠãåèšæ¯æäœäžã«èšããã
ãããã²ã³åéåçæå ææãæ§æããåçæ§æ
å±€ã®å°ãªããšãäžå±€ã«ãäžèšäžè¬åŒïŒ»ïŒœã§è¡šã
ãããæ§æåäœããã³ïŒãŸãã¯äžèšäžè¬åŒïŒ»ïŒœ
ã§è¡šããããåºãæãããªã«ã¬ãããªã·ãããµã³
ãå«æããããããšã«ããéæãããã äžè¬åŒïŒ»ïŒœ
ãåã
åŒäžãR1ã¯æ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ã¢
ãªãŒã«åºãè¡šãããR2ã¯ççŽ ååæ°ïŒä»¥äžã®ã¢
ãªãã«åºãè¡šãããã¯ã¢ã«ãã¬ã³åºãè¡šããã
ïœã¯ïŒãŸãã¯ïŒãè¡šããããŸããã¯ââïŒâ
COOâïŒâOCOâïŒâNHCOâïŒâCONHâïŒâ
âïŒâSO2âïŒâSO2NHâãŸãã¯âNHSO2âãè¡š
ããã äžè¬åŒïŒ»ïŒœ
ãªãŒã«åºãè¡šãããR2ã¯ççŽ ååæ°ïŒä»¥äžã®ã¢
ãªãã«åºãè¡šãããã¯ã¢ã«ãã¬ã³åºãè¡šããã
ïœã¯ïŒãŸãã¯ïŒãè¡šããããŸããã¯ââïŒâ
COOâïŒâOCOâïŒâNHCOâïŒâCONHâïŒâ
âïŒâSO2âïŒâSO2NHâãŸãã¯âNHSO2âãè¡š
ããã äžè¬åŒïŒ»ïŒœ
ãåã
åŒäžãR2ïŒïŒ¡ïŒïŒ¢ããã³ïœã¯äžè¬åŒïŒ»ïŒœ
ã«ãããR2ïŒïŒ¡ïŒïŒ¢ïŒïœãšå矩ã§ãããR3ãã
ã³R4ã¯ãããããæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ãª
ãŒã«åºãŸãã¯ïŒâânâââR2ãè¡šããã çºæã®å ·äœçæ§æ æ¬çºæã«ãããŠçšããããäžèšäžè¬åŒïŒ»ïŒœã§
è¡šããããæ§æåäœããã³ïŒãŸãã¯äžèšäžè¬åŒ
ã§è¡šããããåºãæãããªã«ã¬ãããªã·ã
ããµã³ïŒä»¥äžãç¹ã«æããã®ãªãéããæ¬çºæã®
ãªã«ã¬ãããªã·ãããµã³ãšãããïŒã«ã€ããŠèª¬æ
ããã äžè¬åŒïŒ»ïŒœ
ã«ãããR2ïŒïŒ¡ïŒïŒ¢ïŒïœãšå矩ã§ãããR3ãã
ã³R4ã¯ãããããæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ãª
ãŒã«åºãŸãã¯ïŒâânâââR2ãè¡šããã çºæã®å ·äœçæ§æ æ¬çºæã«ãããŠçšããããäžèšäžè¬åŒïŒ»ïŒœã§
è¡šããããæ§æåäœããã³ïŒãŸãã¯äžèšäžè¬åŒ
ã§è¡šããããåºãæãããªã«ã¬ãããªã·ã
ããµã³ïŒä»¥äžãç¹ã«æããã®ãªãéããæ¬çºæã®
ãªã«ã¬ãããªã·ãããµã³ãšãããïŒã«ã€ããŠèª¬æ
ããã äžè¬åŒïŒ»ïŒœ
ãåã
äžè¬åŒïŒ»ïŒœã«ãããŠãR1ã¯æ°ŽçŽ ååãã¢ã«
ãã«åºãŸãã¯ã¢ãªãŒã«åºãè¡šãããã¢ã«ãã«åºãš
ããŠå ·äœçã«ã¯ãã¡ãã«åºããšãã«åºããããã«
åºãïœâãããã«åºãããã«åºãïœâããã«åºç
ãæããããããŸãR1ã®ã¢ãªãŒã«åºãšããŠã¯å ·
äœçã«ã¯ãããšãã«åºãããªã«åºããã·ãªã«åºç
ãæãããããR1ãšããŠå¥œãŸããã®ã¯ãã¡ãã«
åºãŸãã¯ããšãã«åºã§ããã R2ã¯ççŽ ååæ°ïŒä»¥äžã®ã¢ã«ãã«åºãè¡šããã
R2ãšããŠå¥œãŸããã®ã¯ççŽ ååæ°ïŒã18ã®ã¢ã«
ãã«åºã§ãå ·äœçã«ã¯ãã³ãã«åºãããã·ã«åºã
ãªã¯ãã«åºããã·ã«åºãããã·ã«åºããã³ã¿ãã·
ã«åºãããã¿ãã·ã«åºããªã¯ã¿ãã·ã«åºçãæã
ãããã ã¯ã¢ã«ãã¬ã³åºãè¡šããããšããŠå¥œãŸãã
ã®ã¯ãççŽ ååæ°ïŒãïŒã®ã¢ã«ãã¬ã³åºã§ãå ·äœ
çã«ã¯ãžã¡ãã¬ã³åºãããªã¡ãã¬ã³åºãããã©ã¡
ãã¬ã³åºããããµã¡ãã¬ã³åºçãæããããããŸ
ãïœã¯ïŒãŸãã¯ïŒãè¡šããã ã¯ââïŒâCOOâïŒâOCOâïŒâNHCOâïŒ
âCONHâïŒââïŒâSO2âïŒâSO2NHâãŸãã¯
âNHSO2âãè¡šããã äžè¬åŒïŒ»ïŒœ
ãã«åºãŸãã¯ã¢ãªãŒã«åºãè¡šãããã¢ã«ãã«åºãš
ããŠå ·äœçã«ã¯ãã¡ãã«åºããšãã«åºããããã«
åºãïœâãããã«åºãããã«åºãïœâããã«åºç
ãæããããããŸãR1ã®ã¢ãªãŒã«åºãšããŠã¯å ·
äœçã«ã¯ãããšãã«åºãããªã«åºããã·ãªã«åºç
ãæãããããR1ãšããŠå¥œãŸããã®ã¯ãã¡ãã«
åºãŸãã¯ããšãã«åºã§ããã R2ã¯ççŽ ååæ°ïŒä»¥äžã®ã¢ã«ãã«åºãè¡šããã
R2ãšããŠå¥œãŸããã®ã¯ççŽ ååæ°ïŒã18ã®ã¢ã«
ãã«åºã§ãå ·äœçã«ã¯ãã³ãã«åºãããã·ã«åºã
ãªã¯ãã«åºããã·ã«åºãããã·ã«åºããã³ã¿ãã·
ã«åºãããã¿ãã·ã«åºããªã¯ã¿ãã·ã«åºçãæã
ãããã ã¯ã¢ã«ãã¬ã³åºãè¡šããããšããŠå¥œãŸãã
ã®ã¯ãççŽ ååæ°ïŒãïŒã®ã¢ã«ãã¬ã³åºã§ãå ·äœ
çã«ã¯ãžã¡ãã¬ã³åºãããªã¡ãã¬ã³åºãããã©ã¡
ãã¬ã³åºããããµã¡ãã¬ã³åºçãæããããããŸ
ãïœã¯ïŒãŸãã¯ïŒãè¡šããã ã¯ââïŒâCOOâïŒâOCOâïŒâNHCOâïŒ
âCONHâïŒââïŒâSO2âïŒâSO2NHâãŸãã¯
âNHSO2âãè¡šããã äžè¬åŒïŒ»ïŒœ
ãåã
äžè¬åŒïŒ»ïŒœã«ãããŠãR2ïŒïŒ¡ïŒïŒ¢ããã³ïœ
ã¯äžè¬åŒïŒ»ïŒœã«ãããR2ïŒïŒ¡ïŒïŒ¢ïŒïœãšå矩
ã§ãããR3ããã³R4ã¯ãåãã§ãã€ãŠãç°ã€ã
åºã§ãã€ãŠãããããããããæ°ŽçŽ ååãã¢ã«ã
ã«åºãã¢ãªãŒã«åºãŸãã¯ïŒâânâââR2ãè¡šã
ãã R3ããã³R4ã§è¡šããããã¢ã«ãã«åºãšããŠå ·
äœçã«ã¯ãã¡ãã«åºããšãã«åºããããã«åºãïœ
âãããã«åºãããã«åºãïœâããã«åºçãæã
ããããŸããã¢ãªãŒã«åºãšããŠå ·äœçã«ã¯ãããš
ãã«åºãããªã«åºããã·ãªã«åºçãæããããã
R3ããã³R4ã§è¡šããããã¢ã«ãã«åºã¯çœ®æåºã
äŸãã°ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºçïŒçã§çœ®
æãããŠãããã®ãå«ãã R3ããã³R4ãšããŠå¥œãŸããã®ã¯ãã¡ãã«åºãŸ
ãã¯ããšãã«åºã§ããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãäžè¬åŒ
ã§è¡šããããåºãæãããšãã«ã¯ã䞡端ã®
äžæ¹ãäžè¬åŒïŒ»ïŒœã§è¡šããããåºã§ä»æ¹ã¯äžè¬
åŒïŒ»ïŒœã§è¡šããããåºã§ãªãå Žåã§ãã䞡端ã
å ±ã«äžè¬åŒïŒ»ïŒœã§è¡šããããåºã§ããå Žåã§ã
ããããäž¡ç«¯å ±äžè¬åŒïŒ»ïŒœã§è¡šãããåºã§ãã
å Žåã奜ãŸããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äž¡ç«¯ã«äžè¬
åŒïŒ»ïŒœã§è¡šããããåºããããšãã¯ããããäž¡
端ã®ïŒã€ã®åºã§R2ïŒR3ïŒR4ïŒïŒ¡ïŒïŒ¢ïŒïœã¯äºã
ã«åãã§ãã€ãŠãç°ãªã€ãŠããŠãããããåãã§
ããå Žåã奜ãŸããã ãŸãæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã¯åèšäž
è¬åŒïŒ»ïŒœã§è¡šããããæ§æåäœã®ä»ã«æ¬¡ã®äžè¬
åŒïŒ»ïŒœã§è¡šããããæ§æåäœãæããŠããŠãã
ããããã«ãŸããæ¬çºæã®ãªã«ã¬ãããªã·ãããµ
ã³ã¯åèšäžè¬åŒïŒ»ïŒœã§è¡šããããåºãæããŠã
ããšãã«ã¯ãäžè¬åŒïŒ»ïŒœã§è¡šããããæ§æåäœ
ã®ã¿ãæããŠããŠãããã äžè¬åŒïŒ»ïŒœ
ã¯äžè¬åŒïŒ»ïŒœã«ãããR2ïŒïŒ¡ïŒïŒ¢ïŒïœãšå矩
ã§ãããR3ããã³R4ã¯ãåãã§ãã€ãŠãç°ã€ã
åºã§ãã€ãŠãããããããããæ°ŽçŽ ååãã¢ã«ã
ã«åºãã¢ãªãŒã«åºãŸãã¯ïŒâânâââR2ãè¡šã
ãã R3ããã³R4ã§è¡šããããã¢ã«ãã«åºãšããŠå ·
äœçã«ã¯ãã¡ãã«åºããšãã«åºããããã«åºãïœ
âãããã«åºãããã«åºãïœâããã«åºçãæã
ããããŸããã¢ãªãŒã«åºãšããŠå ·äœçã«ã¯ãããš
ãã«åºãããªã«åºããã·ãªã«åºçãæããããã
R3ããã³R4ã§è¡šããããã¢ã«ãã«åºã¯çœ®æåºã
äŸãã°ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºçïŒçã§çœ®
æãããŠãããã®ãå«ãã R3ããã³R4ãšããŠå¥œãŸããã®ã¯ãã¡ãã«åºãŸ
ãã¯ããšãã«åºã§ããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãäžè¬åŒ
ã§è¡šããããåºãæãããšãã«ã¯ã䞡端ã®
äžæ¹ãäžè¬åŒïŒ»ïŒœã§è¡šããããåºã§ä»æ¹ã¯äžè¬
åŒïŒ»ïŒœã§è¡šããããåºã§ãªãå Žåã§ãã䞡端ã
å ±ã«äžè¬åŒïŒ»ïŒœã§è¡šããããåºã§ããå Žåã§ã
ããããäž¡ç«¯å ±äžè¬åŒïŒ»ïŒœã§è¡šãããåºã§ãã
å Žåã奜ãŸããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äž¡ç«¯ã«äžè¬
åŒïŒ»ïŒœã§è¡šããããåºããããšãã¯ããããäž¡
端ã®ïŒã€ã®åºã§R2ïŒR3ïŒR4ïŒïŒ¡ïŒïŒ¢ïŒïœã¯äºã
ã«åãã§ãã€ãŠãç°ãªã€ãŠããŠãããããåãã§
ããå Žåã奜ãŸããã ãŸãæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã¯åèšäž
è¬åŒïŒ»ïŒœã§è¡šããããæ§æåäœã®ä»ã«æ¬¡ã®äžè¬
åŒïŒ»ïŒœã§è¡šããããæ§æåäœãæããŠããŠãã
ããããã«ãŸããæ¬çºæã®ãªã«ã¬ãããªã·ãããµ
ã³ã¯åèšäžè¬åŒïŒ»ïŒœã§è¡šããããåºãæããŠã
ããšãã«ã¯ãäžè¬åŒïŒ»ïŒœã§è¡šããããæ§æåäœ
ã®ã¿ãæããŠããŠãããã äžè¬åŒïŒ»ïŒœ
ãåã
äžè¬åŒïŒ»ïŒœã«ãããŠãR5ããã³R6ã¯äºãã«
åãã§ãã€ãŠãç°ãªã€ãŠããŠããããããããã
æ°ŽçŽ ååãã¢ã«ãã«åºåã¯ã¢ãªãŒã«åºãè¡šããã R5ããã³R6ã§è¡šããããã¢ã«ãã«åºãšããŠå¥œ
ãŸããã®ã¯ãççŽ ååæ°ïŒã12ã®ã¢ã«ãã«åºã§ã
å ·äœçã«ã¯ã¡ãã«åºããšãã«åºãããã«åºãïœâ
ããã·ã«åºããªã¯ãã«åºãããã·ã«åºçãæãã
ããã R5ããã³R6ã§è¡šããããã¢ãªãŒã«åºãšããŠã
å ·äœçã«ã¯ããšãã«åºãããªã«åºãããã·ã«åºç
ãæãããããŸãR6ããã³R7ã§è¡šããããã¢ã«
ãã«åºã¯ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºçïŒçã§
眮æãããŠãããã®ãå«ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåèšäžè¬åŒ
ã§è¡šããããæ§æåäœãæãããšãã«ã¯ã
次ã®äžè¬åŒïŒ»ïŒœã§è¡šããããåºãæããŠããŠã
ããã äžè¬åŒïŒ»ïŒœ
åãã§ãã€ãŠãç°ãªã€ãŠããŠããããããããã
æ°ŽçŽ ååãã¢ã«ãã«åºåã¯ã¢ãªãŒã«åºãè¡šããã R5ããã³R6ã§è¡šããããã¢ã«ãã«åºãšããŠå¥œ
ãŸããã®ã¯ãççŽ ååæ°ïŒã12ã®ã¢ã«ãã«åºã§ã
å ·äœçã«ã¯ã¡ãã«åºããšãã«åºãããã«åºãïœâ
ããã·ã«åºããªã¯ãã«åºãããã·ã«åºçãæãã
ããã R5ããã³R6ã§è¡šããããã¢ãªãŒã«åºãšããŠã
å ·äœçã«ã¯ããšãã«åºãããªã«åºãããã·ã«åºç
ãæãããããŸãR6ããã³R7ã§è¡šããããã¢ã«
ãã«åºã¯ã¢ãªãŒã«åºïŒäŸãã°ããšãã«åºçïŒçã§
眮æãããŠãããã®ãå«ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåèšäžè¬åŒ
ã§è¡šããããæ§æåäœãæãããšãã«ã¯ã
次ã®äžè¬åŒïŒ»ïŒœã§è¡šããããåºãæããŠããŠã
ããã äžè¬åŒïŒ»ïŒœ
ãåã
äžè¬åŒïŒ»ïŒœã«ãããŠãR7ïŒR8ããã³R9ã¯äº
ãã«åãã§ãã€ãŠãç°ãªã€ãåºã§ãã€ãŠããã
ããããããæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒ
ã«åºãè¡šãããR7ïŒR8ããã³R9ã®ã¢ã«ãã«åºãš
ããŠå ·äœçã«ã¯ãã¡ãã«åºããšãã«åºããããã«
åºãïœâãããã«åºãããã«åºãïœâããã«åºç
ãæãããããŸãR7ãR9ã®ã¢ãªãŒã«åºãšããŠå ·
äœçã«ã¯ãããšãã«åºãããªã«åºããã·ãªã«åºç
ãæããããã ãŸããã¢ã«ãã«åºã¯çœ®æåºãäŸãã°ã¢ãªãŒã«åº
ïŒäŸãã°ããšãã«åºçïŒçã§çœ®æãããŠãããã®
ãå«ãã R7ããã³R9ãšããŠå¥œãŸããã®ã¯ãã¡ãã«åºãŸ
ãã¯ããšãã«åºã§ãããR8ãšããŠå¥œãŸããã®ã¯ã
æ°ŽçŽ ååãã¡ãã«åºãããšãã«åºãããªã«åºãã
ã·ãªã«åºããã³ãžã«åºãŸãã¯ããšããã«åºã§ã
ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äž¡ç«¯ã«ãäž
è¬åŒïŒ»ïŒœã§è¡šããããåºãããæã¯ããããäž¡
端ã®ïŒã€ã®åºã§R7ïŒR8ããã³R9ã¯äºãã«åãã§
ãã€ãŠãç°ãªã€ãŠããŠãããããåããŠããå Žå
ã奜ãŸããã 以äžã«æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®ä»£è¡š
çãªå ·äœäŸãæããããæ¬çºæã¯ãããã®ååç©
ã«ããéå®ããããã®ã§ã¯ãªãã
ãã«åãã§ãã€ãŠãç°ãªã€ãåºã§ãã€ãŠããã
ããããããæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒ
ã«åºãè¡šãããR7ïŒR8ããã³R9ã®ã¢ã«ãã«åºãš
ããŠå ·äœçã«ã¯ãã¡ãã«åºããšãã«åºããããã«
åºãïœâãããã«åºãããã«åºãïœâããã«åºç
ãæãããããŸãR7ãR9ã®ã¢ãªãŒã«åºãšããŠå ·
äœçã«ã¯ãããšãã«åºãããªã«åºããã·ãªã«åºç
ãæããããã ãŸããã¢ã«ãã«åºã¯çœ®æåºãäŸãã°ã¢ãªãŒã«åº
ïŒäŸãã°ããšãã«åºçïŒçã§çœ®æãããŠãããã®
ãå«ãã R7ããã³R9ãšããŠå¥œãŸããã®ã¯ãã¡ãã«åºãŸ
ãã¯ããšãã«åºã§ãããR8ãšããŠå¥œãŸããã®ã¯ã
æ°ŽçŽ ååãã¡ãã«åºãããšãã«åºãããªã«åºãã
ã·ãªã«åºããã³ãžã«åºãŸãã¯ããšããã«åºã§ã
ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äž¡ç«¯ã«ãäž
è¬åŒïŒ»ïŒœã§è¡šããããåºãããæã¯ããããäž¡
端ã®ïŒã€ã®åºã§R7ïŒR8ããã³R9ã¯äºãã«åãã§
ãã€ãŠãç°ãªã€ãŠããŠãããããåããŠããå Žå
ã奜ãŸããã 以äžã«æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®ä»£è¡š
çãªå ·äœäŸãæããããæ¬çºæã¯ãããã®ååç©
ã«ããéå®ããããã®ã§ã¯ãªãã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®è£œæ³ã¯ãäŸ
ãã°ã€ãŒã»ãžãŒã»ãã³ãŒïŒE.G.RochouèïŒâã±ã
ã¹ããªãŒ ãªã 㶠ã·ãªã³ãŒã³ïŒãã€ãããã³
ã¢ã³ãããŒã«1951幎çïŒâ66ã70é ãâã·ãªã³ãŒã³
ã®å å·¥ãšå¿çšâïŒé¢è¥¿ãã©ã¹ããã¯æè¡ç 究äŒ
1954幎ïŒ26é ããšãã»ãžãŒã»ãšãŒã»ã¹ããŒã³ïŒF.
G.A.StoneïŒããã³ããã«ãŠãŒã»ãšãŒã»ãžãŒã»ã°
ã©ãã ïŒW.A.G.GrahamïŒèâã€ã³ãªãŒã¬ãã
ã¯ããªããŒãºâïŒã¢ã«ãããã¯ãã¬ã¹1962幎ïŒ230
ã231é ã288ã295é ãªã©ã«èšèŒãããŠããã»ãã
ç¹å ¬æ36â22361å·ã«ç€ºãããŠãããããªåæå
ãªã«ã¬ããããã·ã©ã³ã®å ±å æ°Žå解ã«ããæ¹æ³ã
ç¹å ¬æ35â10771å·ãå43â28694å·ãå45â
14898å·ãªã©ã«ç€ºãããŠãããããªéå±è§Šåªã«ã
ãâ¡SiHãå«ãã·ãããµã³ãžã®ãªã¬ãã€ã³é¡ã®ä»
å åå¿ã«ããæ¹æ³ããæãã¯ãéå±å¡©ã®è§Šåªã«ã
ããâ¡SiHãå«ãã·ãããµã³ãžã®ã¢ã«ã³ãŒã«é¡ã®
è±æ°ŽçŽ åå¿ã«ããæ¹æ³ãæãã¯ããããŠãçªçŽ å
åã«çŽæ¥çµåããŠããªãççŽ ååã«çµåããŠãã
ããããã·åºãã«ã«ããã·åºãããªãŒã«åºãã¢ã
ãåºããšããã·åºçãéåžžã®ææ©åå¿ã«ãã€ãŠä¿®
食ããæ¹æ³ãªã©ãå¿çšããŠåæããããšãã§ã
ãã ãŸããæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äžéš
åã³åæã¯ãç±³åœããã©ãŒã¯ã»ã·ã¹ãã 瀟
ïŒPetrarch SystemsïŒIncïŒãããåžè²©ãããŠã
ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®ééå¹³åå
åéã¯1000ã100000ã®ãã®ã奜ãŸããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåçæ§æå±€
ã«å«æãããã«ã¯ãå¡åžæ¶²ã«ãããããæ·»å ãã
æ¹æ³ãšãæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ããªãŒ
ããŒã³ãŒãåã¯æµžéãããçã®æ¹æ³ããããã補
é ã³ã¹ãã®ç¹ã§ãåè ã®æ¹ã奜ãŸãããå¡åžæ¶²ã«
æ·»å ããæ¹æ³ãšããŠã¯ãåæ£æ¶²ã®ååšäžã«æ¬çºæ
ã®ãªã«ã¬ãããªã·ãããµã³ããæ°Žæãã¯èŠªæ°Žæ§ã³
ãã€ã溶液äžãäŸãã°ãŒã©ãã³æº¶æ¶²äžã«åæ£ãã
ããã«ææã®åççšå¡åžæ¶²ã«æ·»å ããæ¹æ³ããå
ççšã®ãŒã©ãã³æº¶æ¶²äžã«åæ£å€ã®ååšäžã«åæ£
ãããã®ãŸãŸå¡åžããæ¹æ³ãªã©ãããã åæ£å€ãšããŠã¯ãåççšãšããŠéåžžçšããããŠ
ããçé¢æŽ»æ§å€ã䜿çšããããšãã§ããäŸãã°ã
ã¢ããªã³æ§çé¢æŽ»æ§å€ããããªã³æ§çé¢æŽ»æ§å€ã
äž¡æ§çé¢æŽ»æ§å€ãããã¯ã«ããªã³æ§æŽ»æ§å€ããé©
å®éžæããããã®ãçšããè¶ é³æ³¢ãã¢ãžãã€ã¶ãŒ
ãããã¯ãã«ããã¢ãžãã€ã¶ãŒçãçšããŠåæ£ã
ãããšãã§ãããæ¬çºæã®ãªã«ã¬ãããªã·ãããµ
ã³ã®åæ£ç¶æ ã§ã®å¥œãŸããç²åŸãšããŠã¯0.1ã10ÎŒ
ã®ç²åŸã§ãç²åŸãå°ãããããšæ¬çºæã®å¹æãç¹
ã«ãã¹ãæ§ãå£åããç²åŸã倧ãéãããšå€±éã
ãŠæå ææãšããŠå¥œãŸãããªãããŸããåæ£ã«é
ããŠã¯ãåæ£ã容æã«ããããããç²åŸãã³ã³ã
ããŒã«ããããã«ãé ¢é žãšãã«ãã¡ã¿ããŒã«ãã¢
ã»ãã³ãªã©ã®äœæ²žç¹ææ©æº¶åªããããªã¯ã¬ãžã«ã
ãªã¹ããšãŒãçã®éåžžè¯ãçšããããé«æ²žç¹ææ©
溶åªãçšããŠãè¯ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äœ¿çšéã¯ã
å«æãããåçæ§æå±€ã®ãã€ã³ããŒã«å¯ŸããŠ0.3
ã30ééïŒ ã®ç¯å²ã奜ãŸãããïŒã10ééïŒ ã®ç¯
å²ãç¹ã«å¥œãŸããã ãŸããæ¬çºæã«ãããŠã¯ïŒçš®ä»¥äžã®æ¬çºæã®ãª
ã«ã¬ãããªã·ãããµã³ãé©å®äœµçšããããšãã§ã
ãã æ¬çºæã«ãããŠã¯ãããã²ã³åéåçæå ææ
ãæ§æããåçæ§æå±€ãšã¯ãããã²ã³åéä¹³å€å±€
ãªãã³ã«ä¿è·å±€ãäžéå±€ããã¬ãŒã·ãšã³é²æ¢å±€ã
ãã³ããã¯ã³ãŒãå±€çã®éæå æ§å±€ãããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåçæ§æå±€
ã®ã©ã®å±€ã«çšããŠãè¯ãããç¹ã«ä¿è·å±€ãããã
ã¯ããã¯ã³ãŒãå±€ã«çšããã®ãæ¬çºæã®å¹æãé¡
èã§å¥œãŸããã ãŸããæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãå¥é¢
ã¿ã€ãã®æ¡æ£è»¢ååããã²ã³åéæå ææã®å¥é¢
é¢ãæããå±€ã«çšãããšåªããæ§èœãçºæ®ããã
ãšãã§ããã æ¬çºæã«æå©ã«çšãããã芪氎æ§ã³ãã€ããšã
ãŠã¯ããŒã©ãã³ã®ä»ã«èªå°äœãŒã©ãã³ãã³ãã€ã
ç¶ã¢ã«ããã³ãå¯å€©ãã¢ã©ãã¢ãŽã ãã¢ã«ã®ã³
é žãããšãã°ã¢ã»ãã«å«é19ã26ïŒ ã«ãŸã§å æ°Žå
解ãããã»ã«ããŒãºã¢ã»ããŒãã®åŠãã»ã«ããŒãº
èªå°äœãã¢ã¯ãªã«ã¢ãããã€ããåããªã¢ã¯ãªã«
ã¢ãããã«ãŒã€ã³ãããšãã°ããã«ã¢ã«ã³ãŒã«â
ããã«ã·ã¢ãã¢ã»ããŒãã³ããªããŒã®åŠããŠã¬ã¿
ã³ãã«ã«ãã³é žåºãŸãã¯ã·ã¢ãã¢ã»ãã«åºãå«ã
ããã«ã¢ã«ã³ãŒã«ããªããŒãããªããã«ã¢ã«ã³ãŒ
ã«ãããªããã«ãããªãã³ãå æ°Žå解ããªããã«
ã¢ã»ããŒããèçœè³ªãŸãã¯é£œåã¢ã·ã«åèçœè³ªãš
ããã«åºãæããã¢ãããŒãšã®éåã§åŸãããã
ãªããŒçãå å«ãããã æ¬çºæã«ãããŠã¯ãåèšèŠªæ°Žæ§ã³ãã€ããããª
ãå¡åžèã®ç©æ§ãæ¹è¯ããç®çã§å¿ èŠã«å¿ããŠå
çš®ã®èç©æ§æ¹è¯å€ãäŸãã°ç¡¬èå€ãçšããããšã¯
æãŸããããšã§ãããäŸãã°ç¡¬èå€ã䜵çšãã
ã°ãæ¬çºæã§èšãæŠéå·é²æ¢ã«çžä¹çãªå¹æãåŸ
ãããã®ã¿ãªããã被èã®æ©æ¢°ç匷床ããã³åŠç
液ã«å¯Ÿããè溶解ç¹æ§ãããæ¹åãããã ããã«èŠªæ°Žæ§ã³ãã€ããšããŠãŒã©ãã³ãçšãã
å Žåã代衚çãªç¡¬èå€ã®å ·äœäŸãšããŠã¯ã¢ã«ãã
ãç³»ããšããã·ç³»ããšãã¬ã³ã€ãã³ç³»ã掻æ§ãã
ã²ã³ç³»ãããã«ã¹ã«ãã³ç³»ãã€ãœã·ã¢ããŒãç³»ã
ã¹ã«ãã³é žãšã¹ãã«ç³»ãã«ã«ããžã€ããç³»ãã ã³
ã¯ãã«é žç³»ãã¢ã·ãã€ã«ç³»ãããªãžãŠã å¡©ç³»ãã
ãã«ã¯é«åå系硬èå€çã®å皮硬èå€ãæããã
ãšãã§ããã ãã®æ䜿çšãã硬èå€ã®éã¯ãç®çãšãããŒã©
ãã³èã®çš®é¡ãèŠæ±ãããç©ççæ§è³ªãåçç¹æ§
ã«å¿ããŠæ¬çºæå¹æãæãªããªãä»»æã®ç¯å²ã§ã
ãã°ããã æ¬çºæã«çšãããã芪氎æ§ã³ãã€ãã«ã¯å¿ èŠã«
å¿ããŠåèšç¡¬èå€ä»¥å€ã®åççšæ·»å å€ãšããŠãäŸ
ãã°ãŒã©ãã³å¯å¡å€ãçé¢æŽ»æ§å€ã玫å€ç·åžå
å€ãã«ããªé²æ¢å€ãã¢ã³ãã¹ãã€ã³å€ãPH調ç¯
å€ãé žåé²æ¢å€ã垯é»é²æ¢å€ãå¢ç²å€ãç²ç¶æ§å
äžå€ãææãã¢ã«ãã³ããå¢çœå€ãçŸåé床調æŽ
å€ããããå€çãæ¬çºæã®å¹æãæãªãããªãç¯
å²å ã§äœ¿çšããããšãã§ããã æ¬çºæã«çšããããšã®ã§ãããããå€ãšããŠ
ã¯ãäŸãã°è±åœç¹èš±ç¬¬1221980å·æ现æžãç±³åœç¹
蚱第2992101å·æ现æžãå第2956884å·æ现æžã«èš
èŒãããŠããååç©ãç¹ã«0.5ã20ÎŒmã®ç²åŸãã
ã€ã·ãªã«ã0.5ã20ÎŒmã®ç²åŸããã€ããªã¡ãã«ã¡
ã¿ã¢ã¯ãªã¬ãŒãã®éåäœçãç¹éæ60â126644å·
æ现æžã«èšèŒãããŠããã¢ã«ã«ãªå¯æº¶æ§ãããå€
çãæããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã«çšããã
ãããã²ã³åéä¹³å€ïŒä»¥äžæ¬çºæã®ããã²ã³åé
ä¹³å€ãšãããïŒã«ã¯ãããã²ã³åéãšããŠèåéã
æ²èåéãæ²å¡©åéãå¡©èåéãããã³å¡©åéç
ã®éåžžã®ããã²ã³åéä¹³å€ã«äœ¿çšãããä»»æã®ã
ã®ãçšããäºãã§ããã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãåžžæ³ã«ããååŠ
å¢æããããšãã§ãããå³ã¡ãç¡«é»å¢ææ³ãã»ã¬
ã³å¢ææ³ãéå å¢ææ³ãéãã®ä»ã®è²Žéå±ååç©
ãçšãã貎éå±å¢ææ³ãªã©ãåç¬ã§åã¯çµã¿åã
ããŠçšããããšãã§ããã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãåçæ¥çã«ãã
ãŠå¢æè²çŽ ãšããŠç¥ãããŠããè²çŽ ãçšããŠãæ
æã®æ³¢é·åã«å åŠçã«å¢æã§ãããå¢æè²çŽ ã¯å
ç¬ã§çšããŠãããããïŒçš®ä»¥äžãçµã¿åãããŠçš
ããŠãããå¢æè²çŽ ãšãšãã«ããèªèº«åå å¢æäœ
çšãæããªãè²çŽ ããããã¯å¯èŠå ãå®è³ªçã«åž
åããªãååç©ã§ãã€ãŠãå¢æè²çŽ ã®å¢æäœçšã
匷ãã匷è²å¢æå€ãä¹³å€äžã«å«æãããŠãããã å¢æè²çŽ ãšããŠã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ãè€åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²
çŽ ãããããŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²
çŽ ãã¹ããªã«è²çŽ ããã³ãããªããµããŒã«è²çŽ ã
çšããããã ç¹ã«æçšãªè²çŽ ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ãããã³è€åã¡ãã·ã¢ãã³è²çŽ ã§ãããã
ããã®è²çŽ é¡ã«ã¯ãå¡©åºæ§ç°ç¯ç°æ žãšããŠã·ã¢ã
ã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããããé©çšã§
ãããããªãã¡ããããªã³æ žããªããµãŸãªã³æ žã
ãã¢ãŸãªã³æ žããããŒã«æ žããªããµãŸãŒã«æ žãã
ã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸãŒã«æ žã
ããã©ãŸãŒã«æ žãããªãžã³æ žããã³ãããã®æ žã«
èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³ãããã®
æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãå³ã¡ãã€ã³
ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³æ žãã€ã³ããŒã«
æ žããã³ãºãªããœã¶ãŒã«æ žãããããªããœã¶ãŒã«
æ žããã³ãŸãã¢ãŸãŒã«æ žãããããã¢ãŸãŒã«æ žã
ãã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€ãããŸãŒã«æ žã
ãããªã³æ žãªã©ã§ããããããã®æ žã¯ãççŽ åå
äžã§çœ®æãããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãåºæ¥ãã æçšãªéæå æ§ããã²ã³åéä¹³å€å±€ã«çšããã
ãå¢æè²çŽ ãšããŠã¯ãäŸãã°è¥¿ç¬ç¹èš±929080å·ã
ç±³åœç¹èš±2231658å·ãå2493748å·ãå2503776å·ã
å2519001å·ãå2912329å·ãå3656959å·ãå
3672897å·ãå3694217å·ãå4025349å·ãå
4046572å·ãè±åœç¹èš±1242588å·ãç¹å ¬æ44â
14030å·ãå52â24844å·çã«èšèŒããããã®ãæ
ããããšãã§ããããŸãç·æå æ§ããã²ã³åéä¹³
å€ã«çšããããæçšãªå¢æè²çŽ ãšããŠã¯ãäŸãã°
ç±³åœç¹èš±1939201å·ãå2072908å·ãå2739149å·ã
å2945763å·ãè±åœç¹èš±505979å·çã«èšèŒãããŠ
ããåŠãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãŸãã¯
è€åã·ã¢ãã³è²çŽ ããã®ä»£è¡šçãªãã®ãšããŠæã
ãããšãã§ãããããã«ãèµ€æå æ§ããã²ã³åé
ä¹³å€ã«çšããããæçšãªå¢æè²çŽ ãšããŠã¯ãäŸã
ã°ç±³åœç¹èš±2269234å·ãå2270378å·ãå2442710
å·ãå2454629å·ãå2776280å·çã«èšèŒãããŠã
ãåŠãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€
åã·ã¢ãã³è²çŽ ããã®ä»£è¡šçãªãã®ãšããŠæãã
ããšãã§ãããæŽã«ãŸãç±³åœç¹èš±2213995å·ãå
2493748å·ãå2519001å·ã西ç¬ç¹èš±929080å·çã«
èšèŒãããŠããåŠãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³
è²çŽ ãŸãã¯è€åã·ã¢ãã³è²çŽ ãç·æå æ§ããã²ã³
åéä¹³å€ãŸãã¯èµ€æå æ§ããã²ã³ä¹³å€ã«æå©ã«çš
ããããšãã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãè¯ãããã
ããã®çµã¿åãããçšããŠãè¯ããå¢æè²çŽ ã®çµ
ã¿åããã¯ç¹ã«ã匷è²å¢æã®ç®çã§ãã°ãã°çšã
ãããããã®ä»£è¡šäŸã¯ãç¹å ¬æ43â4932å·ãå43
â4933å·ãå43â4936å·ãå44â32753å·ãå45
â25831å·ãå45â26747å·ãå46â11627å·ãå
46â18107å·ãå47â8741å·ãå47â11114å·ãå
47â25379å·ãå47â37443å·ãå48â28293å·ã
å48â38406å·ãå48â38407å·ãå48â38408å·ã
å48â41203å·ãå48â41204å·ãå49â6207å·ã
å50â40662å·ãå53â12375å·ãå54â34535å·ã
å55â1569å·ãç¹éæ50â33220å·ãå50â33828
å·ãå50â38526å·ãå51â107127å·ãå51â
115820å·ãå51â135528å·ãå51â151527å·ãå
52â23931å·ãå52â51932å·ãå52â104916å·ã
å52â104917å·ãå52â109925å·ãå52â110618
å·ãå54â80118å·ãå56â25728å·ãå57â1483
å·ãå58â10753å·ãå58â91445å·ãå58â
153926å·ãå59â114533å·ãå59â116645å·ãå
59â116647å·ãç±³åœç¹èš±ç¬¬2688545å·ãå2977229
å·ãå3397060å·ãå3506443å·ãå3578447å·ã
å3672898å·ãå3679428å·ãå3769301å·ãå
3814609å·ãå3837862å·ã«èšèŒãããŠããã æ¬çºæã®ããã²ã³åéåçæå ææã¯é»çœæå
ææãã«ã©ãŒæå ææã®ãããã§ãã€ãŠããã
ããã«ã©ãŒæå ææã®å Žåãä¹³å€å±€ã«ã¯ãçºè²çŸ
ååŠçã«ãããŠãè³éŠæ第ïŒçŽã¢ãã³çŸåå€ïŒäŸ
ãã°ïœâããšãã¬ã³ãžã¢ãã³èªå°äœããã¢ããã
ãšããŒã«èªå°äœãªã©ïŒã®é žåäœãšã«ãããªã³ã°å
å¿ãè¡ãè²çŽ ã圢æããè²çŽ 圢æã«ãã©ãŒãçšã
ãããã該è²çŽ 圢æã«ãã©ãŒã¯åã ã®ä¹³å€å±€ã«å¯Ÿ
ããŠä¹³å€å±€ã®æå ã¹ãã¯ãã«å ãåžåããè²çŽ ã
圢æãããããã«éžæãããã®ãæ®éã§ãããé
ææ§ä¹³å€å±€ã«ã¯ã€ãšããŒè²çŽ 圢æã«ãã©ãŒããç·
ææ§ä¹³å€å±€ã«ã¯ããŒã³ã¿è²çŽ 圢æã«ãã©ãŒããèµ€
ææ§ä¹³å€å±€ã«ã¯ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒãçšãã
ãããããããªããç®çã«å¿ããŠäžèšçµã¿åãã
ãšç°ãªã€ãçšãæ¹ã§ããã²ã³åéã«ã©ãŒåçæå
ææãã€ãã€ãŠãããã ãããè²çŽ 圢æã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåº
ãšåŒã°ããã«ãã©ãŒãéæ¡æ£åãããççŽ æ°ïŒä»¥
äžã®åºãæããããšãæãŸãããåããããè²çŽ
圢æã«ãã©ãŒã¯ïŒååã®è²çŽ ã圢æãããããã«
ïŒååã®éã€ãªã³ãéå ãããå¿ èŠãããïŒçé
æ§ã§ãã€ãŠããïŒååã®éã€ãªã³ãéå ãããã
ãã§è¯ãïŒçéæ§ã®ã©ã¡ãã§ããããè²çŽ 圢æã«
ãã©ãŒã«ã¯çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°ã«
ãã€ãŠçŸåä¿é²å€ãæŒçœä¿é²å€ãçŸåå€ãããã²
ã³åé溶å€ã調è²å€ã硬èå€ã«ããªå€ãã«ããªé²
æ¢å€ãååŠå¢æå€ãåå å¢æå€ãåã³æžæå€ã®ã
ããªåççã«æçšãªãã©ã°ã¡ã³ããæŸåºããåå
ç©ãå«æãããããšãã§ããããããè²çŽ 圢æã«
ãã©ãŒã«è²è£æ£ã®å¹æãæããŠããã«ã©ãŒãã«ã
ã©ãŒããããã¯çŸåã«äŒŽã€ãŠçŸåæå¶å€ãæŸåº
ããç»åã®é®®éæ§ãç»åã®ç²ç¶æ§ãæ¹è¯ããDIR
ã«ãã©ãŒã䜵çšãããŠãããããã®éãDIRã«ã
ã©ãŒã¯è©²ã«ãã©ãŒãã圢æãããè²çŽ ãåãä¹³å€
å±€ã«çšããããè²çŽ 圢æã«ãã©ãŒãã圢æããã
è²çŽ ãšå系統ã§ããæ¹ã奜ãŸããããè²ã®æ¿ãã
ç®ç«ããªãå Žåã¯ç°ãªã€ãçš®é¡ã®è²çŽ ã圢æãã
ãã®ã§ããããDIRã«ãã©ãŒã«æ¿ããŠã該ã«ãã©
ãŒãšåã¯äœµçšããŠçŸåäž»è¬ã®é žåäœãšã«ãããªã³
ã°åå¿ããç¡è²ã®ååç©ãçæãããšåæã«çŸå
æå¶å€ãæŸåºããDIRååç©ãçšããŠãããã çšããããDIRã«ãã©ãŒåã³DIRååç©ã«ã¯ã
ã«ãããªã³ã°äœã«çŽæ¥æå¶å€ãçµåãããã®ãšã
æå¶å€ãïŒäŸ¡åºãä»ããŠã«ãããªã³ã°äœã«çµåã
ãŠãããã«ãããªã³ã°åå¿ã«ããé¢è±ããåºå ã§
ã®ååå æ±æ žåå¿ããååå é»å移ååå¿çã«ã
ãæå¶å€ãæŸåºãããããã«çµåãããã®ïŒã¿ã€
ãã³ã°DIRã«ãã©ãŒãåã³ã¿ã€ãã³ã°DIRååç©
ãšç§°ããïŒãå«ãŸãããåãæå¶å€ãé¢è±åŸæ¡æ£
æ§ã®ãã®ãšããã»ã©æ¡æ£æ§ãæããŠããªããã®
ããçšéã«ããåç¬ã§åã¯äœµçšããŠçšããããšã
ã§ãããè³éŠæ第ïŒçŽã¢ãã³çŸåå€ã®é žåäœãšã«
ãããªã³ã°åå¿ãè¡ãããè²çŽ ã圢æããªãç¡è²
ã«ãã©ãŒãè²çŽ 圢æã«ãã©ãŒãšäœµçšããŠçšããã
ãšãã§ããã ãŸãæ¬çºæã«çšããããæ¯æäœãšããŠã¯ãããš
ãã°ãã©ã€ã¿çŽãããªãšãã¬ã³è¢«èŠçŽãããªãã
ãã¬ã³åæçŽãã¬ã©ã¹çŽãã»ã«ããŒã¹ã¢ã»ããŒ
ããã»ã«ããŒã¹ãã€ãã¬ãŒããããšãã°ããªãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãçã®ããªãšã¹ãã«ãã€ã«ã ã
ããªã¢ãããã€ã«ã ãããªãããã¬ã³ãã€ã«ã ã
ããªã«ãŒãããŒããã€ã«ã ãããªã¹ãã¬ã³ãã€ã«
ã çã代衚çãªãã®ãšããŠå å«ããããããã®æ¯
æäœã¯ããããããã²ã³åéåçæå ææã®äœ¿çš
ç®çã«å¿ããŠé©å®éžæãããã æ¬çºæã®ããã²ã³åéæå ææã®çŸååŠçã«
ã¯ãçš®ã ã®æ¹æ³ãçšããäºãåºæ¥ãããã®çŸååŠ
çã¯ãç®çã«å¿ããŠéç»åã圢æããåŠçïŒé»çœ
çŸååŠçïŒããããã¯è²ç»åã圢æããçŸååŠç
ã®ãããã§ãã€ãŠãè¯ãã é»çœçŸååŠçãšããŠã¯ãçŸååŠçå·¥çšãå®çåŠ
çå·¥çšãæ°ŽæŽåŠçå·¥çšããªããããçŸååŠçå·¥çš
åŸãåæ¢åŠçå·¥çšãè¡ã€ããå®çåŠçå·¥çšåŸãå®
å®ååŠçå·¥çšãæœãå Žåã¯ãæ°ŽæŽåŠçå·¥çšãçç¥
ãããå ŽåãããããŸãçŸåäž»è¬ãŸãã¯ãã®ãã¬
ã«ãŒãµãŒãææäžã«å èããçŸååŠçå·¥çšãã¢ã«
ã«ãªæ¶²ã®ã¿ã§è¡ãªã€ãŠããããçŸå液ãšããŠãªã¹
çŸå液ãçšããçŸååŠçå·¥çšãè¡ãªã€ãŠãããã ã«ã©ãŒçŸååŠçãšããŠãçºè²çŸååŠçå·¥çšãæŒ
çœåŠçå·¥çšãå®çåŠçå·¥çšãå¿ èŠã«å¿ããŠæ°ŽæŽåŠ
çå·¥çšãåã³ïŒãŸãã¯å®å®ååŠçå·¥çšãè¡ããã
æŒçœæ¶²ãçšããåŠçå·¥çšãšå®ç液ãçšããåŠçå·¥
çšã®ä»£ããã«ãïŒæµŽæŒçœå®ç液ãçšããŠãæŒçœå®
çåŠçå·¥çšãè¡ãªãããšãåºæ¥ãããçºè²çŸåã
æŒçœãå®çãïŒæµŽäžã§è¡ãªãããšãåºæ¥ãïŒæµŽçŸ
åæŒçœå®çåŠç液ãçšããã¢ããã¹åŠçå·¥çšãè¡
ãªãããšãåºæ¥ãã ãããã®åŠçå·¥çšã«çµã¿åãããŠå硬èåŠçå·¥
çšããã®äžåå·¥çšãåæ¢å®çåŠçå·¥çšãåŸç¡¬èåŠ
çå·¥çšçãè¡ãªã€ãŠãããããããåŠçã«ãããŠ
çºè²çŸååŠçå·¥çšã®ä»£ããã«çºè²çŸåäž»è¬ããŸã
ã¯ãã®ãã¬ã«ãŒãµãŒãææäžã«å«æãããŠããçŸ
ååŠçãã¢ã¯ãããŒã¿ãŒæ¶²ã§è¡ãªãã¢ã¯ãããŒã¿
ãŒåŠçå·¥çšãè¡ã€ãŠãããããã¢ããã¹åŠçã«ä»£
ããŠã¢ã¯ãããŒã¿ãŒåŠçãšæŒçœãå®çåŠçãšåæ
ã«è¡ãªã€ãŠãããããããã®åŠçäžä»£è¡šçãªåŠç
ã瀺ããïŒãããã®åŠçã¯æçµå·¥çšãšããŠãæ°ŽæŽ
åŠçå·¥çšãå®å®ååŠçå·¥çšãæ°ŽæŽåŠçå·¥çšåã³å®
å®ååŠçå·¥çšã®ãããããè¡ãªããïŒ ã» çºè²çŸååŠçå·¥çšâæŒçœåŠçå·¥çšâå®çåŠç
å·¥çš ã»çºè²çŸååŠçå·¥çšâæŒçœå®çåŠçå·¥çš ã» å硬èåŠçå·¥çšâäžååŠçå·¥çšâçºè²çŸååŠ
çå·¥çšâåæ¢å®çåŠçå·¥çšâæ°ŽæŽåŠçå·¥çšâæŒ
çœåŠçå·¥çšâå®çåŠçå·¥çšâæ°ŽæŽåŠçå·¥çšâåŸ
硬èåŠçå·¥çš ã» çºè²çŸååŠçå·¥çšâæ°ŽæŽåŠçå·¥çšâè£è¶³çºè²
çŸååŠçå·¥çšâåæ¢åŠçå·¥çšâæŒçœåŠçå·¥çšâ
å®çåŠçå·¥çš ã» ã¢ããã¹åŠçå·¥çš ã» ã¢ã¯ãããŒã¿ãŒåŠçå·¥çšâæŒçœå®çåŠçå·¥çš ã» ã¢ã¯ãããŒã¿ãŒåŠçå·¥çšâæŒçœåŠçå·¥çšâå®
çåŠçå·¥çš æ¬çºæã¯èŠªæ°Žæ§ã³ãã€ãå±€ãæããåçš®åçæ
å ææã«é©çšããããšãã§ãããã代衚çã«ã¯æ
å æ§æåãšããŠããã²ã³åéãçšããåã®åçæ
å ææãäŸãã°äžè¬ãã¬æå ææãäžè¬ãªããŒãµ
ã«æå ææãäžè¬çšããžæå ææãçŽæ¥ããžæå
ææãç¹æ®çšïŒäŸãã°å°å·çšãã¬ã€çšãé«è§£å
åçšãèµ€å€çšã玫å€çšçïŒããã²ã³åéåçæå
ææã«çšããããšãã§ããã çºæã®å¹æ æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåçæ§æå±€
ã«çšããããšã«ãããã¹ããªæ§ãè¯å¥œã§ããã€é«
æž©é«æ¹¿ã®æ¡ä»¶ã§ä¿åãããŠããæå ææã©ããã®
æ¥çãé²æ¢ãããããã²ã³åéåçæå ææãåŸ
ãããšãã§ããã å®æœäŸïŒœ 以äžã«æ¬çºæã®å ·äœçå®æœäŸãè¿°ã¹ãããæ¬çº
æã®æ æ§ã¯ãããã«éå®ãããªãã å®æœäŸïŒœ 以äžã®å šãŠã®å®æœäŸã«ãããŠãããã²ã³åéå
çæå ææäžã®æ·»å éã¯ç¹ã«èšèŒã®ãªãéãïŒm2
åœãã®ãã®ã瀺ãããŸããããã²ã³åéãšã³ãã€
ãéã¯éã«æç®ããŠç€ºããã ããªã¢ã»ãã«ã»ã«ããŒã¹ãã€ã«ã æ¯æäœäžã«ã
äžèšã«ç€ºããããªçµæã®åå±€ãé 次æ¯æäœåŽãã
圢æããŠãå€å±€ããã²ã³åéã«ã©ãŒåçæå ææ
ãäœè£œããã 第ïŒå±€ïŒãã¬ãŒã·ãšã³é²æ¢å±€ é»è²ã³ãã€ãéãå«ããŒã©ãã³å±€ã 第ïŒå±€ïŒäžéå±€ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³ã®ä¹³
ååæ£ç©ãå«ããŒã©ãã³å±€ã 第ïŒå±€ïŒäœæ床赀ææ§ããã²ã³åéä¹³å€å±€ å¹³åç²åŸïŒïœïŒ0.30ÎŒmãAgI6ã¢ã«ïŒ ãå«ã
AgBrIãããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé1.8ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ã·ã¢ã³ã«ãã©ãŒïŒïŒ£âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.06ã¢ã« ã«ã©ãŒãã·ã¢ã³ã«ãã©ãŒïŒCCâïŒïŒâŠéïŒã¢
ã«ã«å¯ŸããŠ0.003ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0015ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.002ã¢ã« 第ïŒå±€ïŒé«æ床赀ææ§ããã²ã³åéä¹³å€å±€ å¹³åç²åŸïŒïœïŒ0.5ÎŒmãAgI7.0ã¢ã«ïŒ ãå«ã
AgBrIãããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé1.3ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ã·ã¢ã³ã«ãã©ãŒïŒïŒ£âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.02ã¢ã« ã«ã©ãŒãã·ã¢ã³ã«ãã©ãŒïŒCCâïŒïŒâŠéïŒã¢
ã«ã«å¯ŸããŠ0.0015ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.001ã¢ã« 第ïŒå±€ïŒäžéå±€ 第ïŒå±€ãšåãããŒã©ãã³å±€ã 第ïŒå±€ïŒäœæ床ç·ææ§ããã²ã³åéä¹³å€å±€ ä¹³å€ââŠå¡åžéé1.5ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ2.5Ã10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.2Ã10-5ã¢ã« ããŒã³ã¿ã«ãã©ãŒïŒïŒâïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.050ã¢ã« ã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒïŒCMâïŒïŒâŠéïŒ
ã¢ã«ã«å¯ŸããŠ0.009ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0010ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0030ã¢ã« 第ïŒå±€ïŒé«æ床ç·ææ§ããã²ã³åéä¹³å€å±€ ä¹³å€ââŠå¡åžéé1.4ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.5Ã10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ããŒã³ã¿ã«ãã©ãŒïŒïŒâïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.020ã¢ã« ã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒïŒCMâïŒïŒâŠéïŒ
ã¢ã«ã«å¯ŸããŠ0.002ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0010ã¢ã« 第ïŒå±€ïŒã€ãšããŒãã€ã«ã¿ãŒå±€ é»è²ã³ãã€ãéãšïŒïŒïŒâãžâïœâãªã¯ãã«ã
ã€ããããã³ã®ä¹³ååæ£ç©ãšãå«ããŒã©ãã³
å±€ã 第ïŒå±€ïŒäœæ床éææ§ããã²ã³åéä¹³å€å±€ å¹³åç²åŸ0.48ÎŒmãAgI6ã¢ã«ïŒ ãå«ãAgBrIã
ããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé0.9ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.3Ã10-5ã¢ã« ã€ãšããŒã«ãã©ãŒïŒïŒ¹âïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.29ã¢ã« 第10å±€ïŒé«æ床éææ§ä¹³å€å±€ å¹³åç²åŸ0.8ÎŒmãAgI15ã¢ã«ïŒ ãå«ãAgBrIã
ããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé0.5ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ã€ãšããŒã«ãã©ãŒïŒïŒ¹âïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.08ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0015ã¢ã« 第11å±€ïŒçŽ«å€ç·åžåå€å«æå±€ æ²èåéïŒAgI1ã¢ã«ïŒ å¹³åç²åŸ0.07ÎŒmïŒéå¡
åžé0.5ïœïŒm2 玫å€ç·åžåå€ UVâïŒïŒUVâïŒåã³ãã«ã
ãªã³ã¹ã«ãã³ãžã€ãŒHSâïŒãå«ããŒã©ãã³å±€ã 第12å±€ïŒç¬¬ïŒä¿è·å±€ 以äžã®ä¿è·å±€å¡åžæ¶²ããŒã©ãã³0.6ïœïŒm2ãšãª
ãããã«å¡åžããã ãªã«ã¬ãããªã·ãããµã³åæ£æ¶²ã®èª¿æŽïŒœ 液 ãªã«ã¬ãããªã·ãããµã³ïŒäŸç€ºååç©OS
âïŒïŒ 2.0ïœ é ¢é žãšãã« 1.5ïœ ïŒ¢æ¶² ãŒã©ãã³æ°Žæº¶æ¶²ïŒïŒ 20ml ããªã€ãœãããã«ããã¿ã¬ã³ã¹ã«ãã³é žãœ
ãŒã 2.0ïœ ïŒ£æ¶² ãŒã©ãã³æ°Žæº¶æ¶²ïŒïŒ 50ml 液ãšïŒ¢æ¶²ãæ··åããŠããã³ããŽãŒãªã³ç€Ÿè£œã
ã«ãåãã¢ãžãã€ã¶ãŒãçšããŠãåæ£ç©ã®ç²åŸã
0.8ÎŒäœã«ãªãããã«ã³ã³ãããŒã«ããŠãåæ£æ¶²ã
åŸããåŸãããåæ£æ¶²ã«ïŒ£æ¶²ãæ·»å ããæ°Žãå ã
ãŠ80mlã«ä»äžããŠããªã«ã¬ãããªã·ãããµã³åæ£
液ãšããã ä¿è·å±€å¡åžæ¶²ïŒœ ãªã«ã¬ãããªã·ãããµã³åæ£æ¶² 70ml ãŒã©ãã³ 40ïœ ãœãžãŠã âã¢ãã«âãã·ã«ã¹ã«ããµã¯ã·ããŒã
1.0ïœ ãšãã«ã¡ã¿ã¯ãªã¬ãŒã30ã¢ã«ïŒ ãã¡ãã«ã¡ã¿ã¯
ãªã¬ãŒã30ã¢ã«ïŒ ãã¡ã¿ã¯ãªã«é ž40ã¢ã«ïŒ ã®ã³
ããªããŒç²åïŒïŒå¹³åç²åŸ2.2ÎŒmïŒ 4.0ïœ ïŒïŒïŒâãã¹ããã«ã¹ã«ããã«ãšã¿ã³ 2.0ïœ æ°Žã§1000mlã«ä»äžããã ïŒå¹³åç²åŸã¯ãå å ŽåŒèªåç²åºŠååžæž¬å®æ©
CAPAâ500ãçšããã å°ãåå±€ã«ã¯äžèšçµæç©ã®ä»ã«ããŒã©ãã³ç¡¬å
å€ïŒïŒšâïŒïŒãçé¢æŽ»æ§å€ãæ·»å ããã åå±€ã«å«ãŸããååç©ã¯äžèšã®éãã§ããã å¢æè²çŽ ïŒã¢ã³ãããïŒïŒ5â²âãžã¯ããâïŒâ
ãšãã«âïŒïŒ3â²âãžâïŒïŒâã¹ã«ããããã«ïŒ
ãã¢ã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒâãšãã«âïŒïŒ3â²âãž
âïŒïŒâã¹ã«ããããã«ïŒâïŒïŒïŒïŒ4â²ïŒ5â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒïŒ5â²âãžããšãã«âïŒ
âãšãã«âïŒïŒ3â²âãžâïŒïŒâã¹ã«ãããã
ã«ïŒãªããµã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒâãšãã«âïŒïŒ3â²âãž
âïŒïŒâã¹ã«ããããã«ïŒâïŒïŒïŒïŒ5â²ïŒ6â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒïŒ3â²âãžâïŒïŒâã¹ã«
ããããã«ïŒâïŒïŒïŒâãã³ãŸâ5â²âã¡ãã
ã·ãã¢ã·ã¢ãã³
ãã°ã€ãŒã»ãžãŒã»ãã³ãŒïŒE.G.RochouèïŒâã±ã
ã¹ããªãŒ ãªã 㶠ã·ãªã³ãŒã³ïŒãã€ãããã³
ã¢ã³ãããŒã«1951幎çïŒâ66ã70é ãâã·ãªã³ãŒã³
ã®å å·¥ãšå¿çšâïŒé¢è¥¿ãã©ã¹ããã¯æè¡ç 究äŒ
1954幎ïŒ26é ããšãã»ãžãŒã»ãšãŒã»ã¹ããŒã³ïŒF.
G.A.StoneïŒããã³ããã«ãŠãŒã»ãšãŒã»ãžãŒã»ã°
ã©ãã ïŒW.A.G.GrahamïŒèâã€ã³ãªãŒã¬ãã
ã¯ããªããŒãºâïŒã¢ã«ãããã¯ãã¬ã¹1962幎ïŒ230
ã231é ã288ã295é ãªã©ã«èšèŒãããŠããã»ãã
ç¹å ¬æ36â22361å·ã«ç€ºãããŠãããããªåæå
ãªã«ã¬ããããã·ã©ã³ã®å ±å æ°Žå解ã«ããæ¹æ³ã
ç¹å ¬æ35â10771å·ãå43â28694å·ãå45â
14898å·ãªã©ã«ç€ºãããŠãããããªéå±è§Šåªã«ã
ãâ¡SiHãå«ãã·ãããµã³ãžã®ãªã¬ãã€ã³é¡ã®ä»
å åå¿ã«ããæ¹æ³ããæãã¯ãéå±å¡©ã®è§Šåªã«ã
ããâ¡SiHãå«ãã·ãããµã³ãžã®ã¢ã«ã³ãŒã«é¡ã®
è±æ°ŽçŽ åå¿ã«ããæ¹æ³ãæãã¯ããããŠãçªçŽ å
åã«çŽæ¥çµåããŠããªãççŽ ååã«çµåããŠãã
ããããã·åºãã«ã«ããã·åºãããªãŒã«åºãã¢ã
ãåºããšããã·åºçãéåžžã®ææ©åå¿ã«ãã€ãŠä¿®
食ããæ¹æ³ãªã©ãå¿çšããŠåæããããšãã§ã
ãã ãŸããæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äžéš
åã³åæã¯ãç±³åœããã©ãŒã¯ã»ã·ã¹ãã 瀟
ïŒPetrarch SystemsïŒIncïŒãããåžè²©ãããŠã
ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®ééå¹³åå
åéã¯1000ã100000ã®ãã®ã奜ãŸããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåçæ§æå±€
ã«å«æãããã«ã¯ãå¡åžæ¶²ã«ãããããæ·»å ãã
æ¹æ³ãšãæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ããªãŒ
ããŒã³ãŒãåã¯æµžéãããçã®æ¹æ³ããããã補
é ã³ã¹ãã®ç¹ã§ãåè ã®æ¹ã奜ãŸãããå¡åžæ¶²ã«
æ·»å ããæ¹æ³ãšããŠã¯ãåæ£æ¶²ã®ååšäžã«æ¬çºæ
ã®ãªã«ã¬ãããªã·ãããµã³ããæ°Žæãã¯èŠªæ°Žæ§ã³
ãã€ã溶液äžãäŸãã°ãŒã©ãã³æº¶æ¶²äžã«åæ£ãã
ããã«ææã®åççšå¡åžæ¶²ã«æ·»å ããæ¹æ³ããå
ççšã®ãŒã©ãã³æº¶æ¶²äžã«åæ£å€ã®ååšäžã«åæ£
ãããã®ãŸãŸå¡åžããæ¹æ³ãªã©ãããã åæ£å€ãšããŠã¯ãåççšãšããŠéåžžçšããããŠ
ããçé¢æŽ»æ§å€ã䜿çšããããšãã§ããäŸãã°ã
ã¢ããªã³æ§çé¢æŽ»æ§å€ããããªã³æ§çé¢æŽ»æ§å€ã
äž¡æ§çé¢æŽ»æ§å€ãããã¯ã«ããªã³æ§æŽ»æ§å€ããé©
å®éžæããããã®ãçšããè¶ é³æ³¢ãã¢ãžãã€ã¶ãŒ
ãããã¯ãã«ããã¢ãžãã€ã¶ãŒçãçšããŠåæ£ã
ãããšãã§ãããæ¬çºæã®ãªã«ã¬ãããªã·ãããµ
ã³ã®åæ£ç¶æ ã§ã®å¥œãŸããç²åŸãšããŠã¯0.1ã10ÎŒ
ã®ç²åŸã§ãç²åŸãå°ãããããšæ¬çºæã®å¹æãç¹
ã«ãã¹ãæ§ãå£åããç²åŸã倧ãéãããšå€±éã
ãŠæå ææãšããŠå¥œãŸãããªãããŸããåæ£ã«é
ããŠã¯ãåæ£ã容æã«ããããããç²åŸãã³ã³ã
ããŒã«ããããã«ãé ¢é žãšãã«ãã¡ã¿ããŒã«ãã¢
ã»ãã³ãªã©ã®äœæ²žç¹ææ©æº¶åªããããªã¯ã¬ãžã«ã
ãªã¹ããšãŒãçã®éåžžè¯ãçšããããé«æ²žç¹ææ©
溶åªãçšããŠãè¯ãã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ã®äœ¿çšéã¯ã
å«æãããåçæ§æå±€ã®ãã€ã³ããŒã«å¯ŸããŠ0.3
ã30ééïŒ ã®ç¯å²ã奜ãŸãããïŒã10ééïŒ ã®ç¯
å²ãç¹ã«å¥œãŸããã ãŸããæ¬çºæã«ãããŠã¯ïŒçš®ä»¥äžã®æ¬çºæã®ãª
ã«ã¬ãããªã·ãããµã³ãé©å®äœµçšããããšãã§ã
ãã æ¬çºæã«ãããŠã¯ãããã²ã³åéåçæå ææ
ãæ§æããåçæ§æå±€ãšã¯ãããã²ã³åéä¹³å€å±€
ãªãã³ã«ä¿è·å±€ãäžéå±€ããã¬ãŒã·ãšã³é²æ¢å±€ã
ãã³ããã¯ã³ãŒãå±€çã®éæå æ§å±€ãããã æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåçæ§æå±€
ã®ã©ã®å±€ã«çšããŠãè¯ãããç¹ã«ä¿è·å±€ãããã
ã¯ããã¯ã³ãŒãå±€ã«çšããã®ãæ¬çºæã®å¹æãé¡
èã§å¥œãŸããã ãŸããæ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãå¥é¢
ã¿ã€ãã®æ¡æ£è»¢ååããã²ã³åéæå ææã®å¥é¢
é¢ãæããå±€ã«çšãããšåªããæ§èœãçºæ®ããã
ãšãã§ããã æ¬çºæã«æå©ã«çšãããã芪氎æ§ã³ãã€ããšã
ãŠã¯ããŒã©ãã³ã®ä»ã«èªå°äœãŒã©ãã³ãã³ãã€ã
ç¶ã¢ã«ããã³ãå¯å€©ãã¢ã©ãã¢ãŽã ãã¢ã«ã®ã³
é žãããšãã°ã¢ã»ãã«å«é19ã26ïŒ ã«ãŸã§å æ°Žå
解ãããã»ã«ããŒãºã¢ã»ããŒãã®åŠãã»ã«ããŒãº
èªå°äœãã¢ã¯ãªã«ã¢ãããã€ããåããªã¢ã¯ãªã«
ã¢ãããã«ãŒã€ã³ãããšãã°ããã«ã¢ã«ã³ãŒã«â
ããã«ã·ã¢ãã¢ã»ããŒãã³ããªããŒã®åŠããŠã¬ã¿
ã³ãã«ã«ãã³é žåºãŸãã¯ã·ã¢ãã¢ã»ãã«åºãå«ã
ããã«ã¢ã«ã³ãŒã«ããªããŒãããªããã«ã¢ã«ã³ãŒ
ã«ãããªããã«ãããªãã³ãå æ°Žå解ããªããã«
ã¢ã»ããŒããèçœè³ªãŸãã¯é£œåã¢ã·ã«åèçœè³ªãš
ããã«åºãæããã¢ãããŒãšã®éåã§åŸãããã
ãªããŒçãå å«ãããã æ¬çºæã«ãããŠã¯ãåèšèŠªæ°Žæ§ã³ãã€ããããª
ãå¡åžèã®ç©æ§ãæ¹è¯ããç®çã§å¿ èŠã«å¿ããŠå
çš®ã®èç©æ§æ¹è¯å€ãäŸãã°ç¡¬èå€ãçšããããšã¯
æãŸããããšã§ãããäŸãã°ç¡¬èå€ã䜵çšãã
ã°ãæ¬çºæã§èšãæŠéå·é²æ¢ã«çžä¹çãªå¹æãåŸ
ãããã®ã¿ãªããã被èã®æ©æ¢°ç匷床ããã³åŠç
液ã«å¯Ÿããè溶解ç¹æ§ãããæ¹åãããã ããã«èŠªæ°Žæ§ã³ãã€ããšããŠãŒã©ãã³ãçšãã
å Žåã代衚çãªç¡¬èå€ã®å ·äœäŸãšããŠã¯ã¢ã«ãã
ãç³»ããšããã·ç³»ããšãã¬ã³ã€ãã³ç³»ã掻æ§ãã
ã²ã³ç³»ãããã«ã¹ã«ãã³ç³»ãã€ãœã·ã¢ããŒãç³»ã
ã¹ã«ãã³é žãšã¹ãã«ç³»ãã«ã«ããžã€ããç³»ãã ã³
ã¯ãã«é žç³»ãã¢ã·ãã€ã«ç³»ãããªãžãŠã å¡©ç³»ãã
ãã«ã¯é«åå系硬èå€çã®å皮硬èå€ãæããã
ãšãã§ããã ãã®æ䜿çšãã硬èå€ã®éã¯ãç®çãšãããŒã©
ãã³èã®çš®é¡ãèŠæ±ãããç©ççæ§è³ªãåçç¹æ§
ã«å¿ããŠæ¬çºæå¹æãæãªããªãä»»æã®ç¯å²ã§ã
ãã°ããã æ¬çºæã«çšãããã芪氎æ§ã³ãã€ãã«ã¯å¿ èŠã«
å¿ããŠåèšç¡¬èå€ä»¥å€ã®åççšæ·»å å€ãšããŠãäŸ
ãã°ãŒã©ãã³å¯å¡å€ãçé¢æŽ»æ§å€ã玫å€ç·åžå
å€ãã«ããªé²æ¢å€ãã¢ã³ãã¹ãã€ã³å€ãPH調ç¯
å€ãé žåé²æ¢å€ã垯é»é²æ¢å€ãå¢ç²å€ãç²ç¶æ§å
äžå€ãææãã¢ã«ãã³ããå¢çœå€ãçŸåé床調æŽ
å€ããããå€çãæ¬çºæã®å¹æãæãªãããªãç¯
å²å ã§äœ¿çšããããšãã§ããã æ¬çºæã«çšããããšã®ã§ãããããå€ãšããŠ
ã¯ãäŸãã°è±åœç¹èš±ç¬¬1221980å·æ现æžãç±³åœç¹
蚱第2992101å·æ现æžãå第2956884å·æ现æžã«èš
èŒãããŠããååç©ãç¹ã«0.5ã20ÎŒmã®ç²åŸãã
ã€ã·ãªã«ã0.5ã20ÎŒmã®ç²åŸããã€ããªã¡ãã«ã¡
ã¿ã¢ã¯ãªã¬ãŒãã®éåäœçãç¹éæ60â126644å·
æ现æžã«èšèŒãããŠããã¢ã«ã«ãªå¯æº¶æ§ãããå€
çãæããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã«çšããã
ãããã²ã³åéä¹³å€ïŒä»¥äžæ¬çºæã®ããã²ã³åé
ä¹³å€ãšãããïŒã«ã¯ãããã²ã³åéãšããŠèåéã
æ²èåéãæ²å¡©åéãå¡©èåéãããã³å¡©åéç
ã®éåžžã®ããã²ã³åéä¹³å€ã«äœ¿çšãããä»»æã®ã
ã®ãçšããäºãã§ããã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãåžžæ³ã«ããååŠ
å¢æããããšãã§ãããå³ã¡ãç¡«é»å¢ææ³ãã»ã¬
ã³å¢ææ³ãéå å¢ææ³ãéãã®ä»ã®è²Žéå±ååç©
ãçšãã貎éå±å¢ææ³ãªã©ãåç¬ã§åã¯çµã¿åã
ããŠçšããããšãã§ããã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãåçæ¥çã«ãã
ãŠå¢æè²çŽ ãšããŠç¥ãããŠããè²çŽ ãçšããŠãæ
æã®æ³¢é·åã«å åŠçã«å¢æã§ãããå¢æè²çŽ ã¯å
ç¬ã§çšããŠãããããïŒçš®ä»¥äžãçµã¿åãããŠçš
ããŠãããå¢æè²çŽ ãšãšãã«ããèªèº«åå å¢æäœ
çšãæããªãè²çŽ ããããã¯å¯èŠå ãå®è³ªçã«åž
åããªãååç©ã§ãã€ãŠãå¢æè²çŽ ã®å¢æäœçšã
匷ãã匷è²å¢æå€ãä¹³å€äžã«å«æãããŠãããã å¢æè²çŽ ãšããŠã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ãè€åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²
çŽ ãããããŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²
çŽ ãã¹ããªã«è²çŽ ããã³ãããªããµããŒã«è²çŽ ã
çšããããã ç¹ã«æçšãªè²çŽ ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ãããã³è€åã¡ãã·ã¢ãã³è²çŽ ã§ãããã
ããã®è²çŽ é¡ã«ã¯ãå¡©åºæ§ç°ç¯ç°æ žãšããŠã·ã¢ã
ã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããããé©çšã§
ãããããªãã¡ããããªã³æ žããªããµãŸãªã³æ žã
ãã¢ãŸãªã³æ žããããŒã«æ žããªããµãŸãŒã«æ žãã
ã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸãŒã«æ žã
ããã©ãŸãŒã«æ žãããªãžã³æ žããã³ãããã®æ žã«
èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³ãããã®
æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãå³ã¡ãã€ã³
ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³æ žãã€ã³ããŒã«
æ žããã³ãºãªããœã¶ãŒã«æ žãããããªããœã¶ãŒã«
æ žããã³ãŸãã¢ãŸãŒã«æ žãããããã¢ãŸãŒã«æ žã
ãã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€ãããŸãŒã«æ žã
ãããªã³æ žãªã©ã§ããããããã®æ žã¯ãççŽ åå
äžã§çœ®æãããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãåºæ¥ãã æçšãªéæå æ§ããã²ã³åéä¹³å€å±€ã«çšããã
ãå¢æè²çŽ ãšããŠã¯ãäŸãã°è¥¿ç¬ç¹èš±929080å·ã
ç±³åœç¹èš±2231658å·ãå2493748å·ãå2503776å·ã
å2519001å·ãå2912329å·ãå3656959å·ãå
3672897å·ãå3694217å·ãå4025349å·ãå
4046572å·ãè±åœç¹èš±1242588å·ãç¹å ¬æ44â
14030å·ãå52â24844å·çã«èšèŒããããã®ãæ
ããããšãã§ããããŸãç·æå æ§ããã²ã³åéä¹³
å€ã«çšããããæçšãªå¢æè²çŽ ãšããŠã¯ãäŸãã°
ç±³åœç¹èš±1939201å·ãå2072908å·ãå2739149å·ã
å2945763å·ãè±åœç¹èš±505979å·çã«èšèŒãããŠ
ããåŠãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãŸãã¯
è€åã·ã¢ãã³è²çŽ ããã®ä»£è¡šçãªãã®ãšããŠæã
ãããšãã§ãããããã«ãèµ€æå æ§ããã²ã³åé
ä¹³å€ã«çšããããæçšãªå¢æè²çŽ ãšããŠã¯ãäŸã
ã°ç±³åœç¹èš±2269234å·ãå2270378å·ãå2442710
å·ãå2454629å·ãå2776280å·çã«èšèŒãããŠã
ãåŠãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€
åã·ã¢ãã³è²çŽ ããã®ä»£è¡šçãªãã®ãšããŠæãã
ããšãã§ãããæŽã«ãŸãç±³åœç¹èš±2213995å·ãå
2493748å·ãå2519001å·ã西ç¬ç¹èš±929080å·çã«
èšèŒãããŠããåŠãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³
è²çŽ ãŸãã¯è€åã·ã¢ãã³è²çŽ ãç·æå æ§ããã²ã³
åéä¹³å€ãŸãã¯èµ€æå æ§ããã²ã³ä¹³å€ã«æå©ã«çš
ããããšãã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãè¯ãããã
ããã®çµã¿åãããçšããŠãè¯ããå¢æè²çŽ ã®çµ
ã¿åããã¯ç¹ã«ã匷è²å¢æã®ç®çã§ãã°ãã°çšã
ãããããã®ä»£è¡šäŸã¯ãç¹å ¬æ43â4932å·ãå43
â4933å·ãå43â4936å·ãå44â32753å·ãå45
â25831å·ãå45â26747å·ãå46â11627å·ãå
46â18107å·ãå47â8741å·ãå47â11114å·ãå
47â25379å·ãå47â37443å·ãå48â28293å·ã
å48â38406å·ãå48â38407å·ãå48â38408å·ã
å48â41203å·ãå48â41204å·ãå49â6207å·ã
å50â40662å·ãå53â12375å·ãå54â34535å·ã
å55â1569å·ãç¹éæ50â33220å·ãå50â33828
å·ãå50â38526å·ãå51â107127å·ãå51â
115820å·ãå51â135528å·ãå51â151527å·ãå
52â23931å·ãå52â51932å·ãå52â104916å·ã
å52â104917å·ãå52â109925å·ãå52â110618
å·ãå54â80118å·ãå56â25728å·ãå57â1483
å·ãå58â10753å·ãå58â91445å·ãå58â
153926å·ãå59â114533å·ãå59â116645å·ãå
59â116647å·ãç±³åœç¹èš±ç¬¬2688545å·ãå2977229
å·ãå3397060å·ãå3506443å·ãå3578447å·ã
å3672898å·ãå3679428å·ãå3769301å·ãå
3814609å·ãå3837862å·ã«èšèŒãããŠããã æ¬çºæã®ããã²ã³åéåçæå ææã¯é»çœæå
ææãã«ã©ãŒæå ææã®ãããã§ãã€ãŠããã
ããã«ã©ãŒæå ææã®å Žåãä¹³å€å±€ã«ã¯ãçºè²çŸ
ååŠçã«ãããŠãè³éŠæ第ïŒçŽã¢ãã³çŸåå€ïŒäŸ
ãã°ïœâããšãã¬ã³ãžã¢ãã³èªå°äœããã¢ããã
ãšããŒã«èªå°äœãªã©ïŒã®é žåäœãšã«ãããªã³ã°å
å¿ãè¡ãè²çŽ ã圢æããè²çŽ 圢æã«ãã©ãŒãçšã
ãããã該è²çŽ 圢æã«ãã©ãŒã¯åã ã®ä¹³å€å±€ã«å¯Ÿ
ããŠä¹³å€å±€ã®æå ã¹ãã¯ãã«å ãåžåããè²çŽ ã
圢æãããããã«éžæãããã®ãæ®éã§ãããé
ææ§ä¹³å€å±€ã«ã¯ã€ãšããŒè²çŽ 圢æã«ãã©ãŒããç·
ææ§ä¹³å€å±€ã«ã¯ããŒã³ã¿è²çŽ 圢æã«ãã©ãŒããèµ€
ææ§ä¹³å€å±€ã«ã¯ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒãçšãã
ãããããããªããç®çã«å¿ããŠäžèšçµã¿åãã
ãšç°ãªã€ãçšãæ¹ã§ããã²ã³åéã«ã©ãŒåçæå
ææãã€ãã€ãŠãããã ãããè²çŽ 圢æã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåº
ãšåŒã°ããã«ãã©ãŒãéæ¡æ£åãããççŽ æ°ïŒä»¥
äžã®åºãæããããšãæãŸãããåããããè²çŽ
圢æã«ãã©ãŒã¯ïŒååã®è²çŽ ã圢æãããããã«
ïŒååã®éã€ãªã³ãéå ãããå¿ èŠãããïŒçé
æ§ã§ãã€ãŠããïŒååã®éã€ãªã³ãéå ãããã
ãã§è¯ãïŒçéæ§ã®ã©ã¡ãã§ããããè²çŽ 圢æã«
ãã©ãŒã«ã¯çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°ã«
ãã€ãŠçŸåä¿é²å€ãæŒçœä¿é²å€ãçŸåå€ãããã²
ã³åé溶å€ã調è²å€ã硬èå€ã«ããªå€ãã«ããªé²
æ¢å€ãååŠå¢æå€ãåå å¢æå€ãåã³æžæå€ã®ã
ããªåççã«æçšãªãã©ã°ã¡ã³ããæŸåºããåå
ç©ãå«æãããããšãã§ããããããè²çŽ 圢æã«
ãã©ãŒã«è²è£æ£ã®å¹æãæããŠããã«ã©ãŒãã«ã
ã©ãŒããããã¯çŸåã«äŒŽã€ãŠçŸåæå¶å€ãæŸåº
ããç»åã®é®®éæ§ãç»åã®ç²ç¶æ§ãæ¹è¯ããDIR
ã«ãã©ãŒã䜵çšãããŠãããããã®éãDIRã«ã
ã©ãŒã¯è©²ã«ãã©ãŒãã圢æãããè²çŽ ãåãä¹³å€
å±€ã«çšããããè²çŽ 圢æã«ãã©ãŒãã圢æããã
è²çŽ ãšå系統ã§ããæ¹ã奜ãŸããããè²ã®æ¿ãã
ç®ç«ããªãå Žåã¯ç°ãªã€ãçš®é¡ã®è²çŽ ã圢æãã
ãã®ã§ããããDIRã«ãã©ãŒã«æ¿ããŠã該ã«ãã©
ãŒãšåã¯äœµçšããŠçŸåäž»è¬ã®é žåäœãšã«ãããªã³
ã°åå¿ããç¡è²ã®ååç©ãçæãããšåæã«çŸå
æå¶å€ãæŸåºããDIRååç©ãçšããŠãããã çšããããDIRã«ãã©ãŒåã³DIRååç©ã«ã¯ã
ã«ãããªã³ã°äœã«çŽæ¥æå¶å€ãçµåãããã®ãšã
æå¶å€ãïŒäŸ¡åºãä»ããŠã«ãããªã³ã°äœã«çµåã
ãŠãããã«ãããªã³ã°åå¿ã«ããé¢è±ããåºå ã§
ã®ååå æ±æ žåå¿ããååå é»å移ååå¿çã«ã
ãæå¶å€ãæŸåºãããããã«çµåãããã®ïŒã¿ã€
ãã³ã°DIRã«ãã©ãŒãåã³ã¿ã€ãã³ã°DIRååç©
ãšç§°ããïŒãå«ãŸãããåãæå¶å€ãé¢è±åŸæ¡æ£
æ§ã®ãã®ãšããã»ã©æ¡æ£æ§ãæããŠããªããã®
ããçšéã«ããåç¬ã§åã¯äœµçšããŠçšããããšã
ã§ãããè³éŠæ第ïŒçŽã¢ãã³çŸåå€ã®é žåäœãšã«
ãããªã³ã°åå¿ãè¡ãããè²çŽ ã圢æããªãç¡è²
ã«ãã©ãŒãè²çŽ 圢æã«ãã©ãŒãšäœµçšããŠçšããã
ãšãã§ããã ãŸãæ¬çºæã«çšããããæ¯æäœãšããŠã¯ãããš
ãã°ãã©ã€ã¿çŽãããªãšãã¬ã³è¢«èŠçŽãããªãã
ãã¬ã³åæçŽãã¬ã©ã¹çŽãã»ã«ããŒã¹ã¢ã»ããŒ
ããã»ã«ããŒã¹ãã€ãã¬ãŒããããšãã°ããªãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãçã®ããªãšã¹ãã«ãã€ã«ã ã
ããªã¢ãããã€ã«ã ãããªãããã¬ã³ãã€ã«ã ã
ããªã«ãŒãããŒããã€ã«ã ãããªã¹ãã¬ã³ãã€ã«
ã çã代衚çãªãã®ãšããŠå å«ããããããã®æ¯
æäœã¯ããããããã²ã³åéåçæå ææã®äœ¿çš
ç®çã«å¿ããŠé©å®éžæãããã æ¬çºæã®ããã²ã³åéæå ææã®çŸååŠçã«
ã¯ãçš®ã ã®æ¹æ³ãçšããäºãåºæ¥ãããã®çŸååŠ
çã¯ãç®çã«å¿ããŠéç»åã圢æããåŠçïŒé»çœ
çŸååŠçïŒããããã¯è²ç»åã圢æããçŸååŠç
ã®ãããã§ãã€ãŠãè¯ãã é»çœçŸååŠçãšããŠã¯ãçŸååŠçå·¥çšãå®çåŠ
çå·¥çšãæ°ŽæŽåŠçå·¥çšããªããããçŸååŠçå·¥çš
åŸãåæ¢åŠçå·¥çšãè¡ã€ããå®çåŠçå·¥çšåŸãå®
å®ååŠçå·¥çšãæœãå Žåã¯ãæ°ŽæŽåŠçå·¥çšãçç¥
ãããå ŽåãããããŸãçŸåäž»è¬ãŸãã¯ãã®ãã¬
ã«ãŒãµãŒãææäžã«å èããçŸååŠçå·¥çšãã¢ã«
ã«ãªæ¶²ã®ã¿ã§è¡ãªã€ãŠããããçŸå液ãšããŠãªã¹
çŸå液ãçšããçŸååŠçå·¥çšãè¡ãªã€ãŠãããã ã«ã©ãŒçŸååŠçãšããŠãçºè²çŸååŠçå·¥çšãæŒ
çœåŠçå·¥çšãå®çåŠçå·¥çšãå¿ èŠã«å¿ããŠæ°ŽæŽåŠ
çå·¥çšãåã³ïŒãŸãã¯å®å®ååŠçå·¥çšãè¡ããã
æŒçœæ¶²ãçšããåŠçå·¥çšãšå®ç液ãçšããåŠçå·¥
çšã®ä»£ããã«ãïŒæµŽæŒçœå®ç液ãçšããŠãæŒçœå®
çåŠçå·¥çšãè¡ãªãããšãåºæ¥ãããçºè²çŸåã
æŒçœãå®çãïŒæµŽäžã§è¡ãªãããšãåºæ¥ãïŒæµŽçŸ
åæŒçœå®çåŠç液ãçšããã¢ããã¹åŠçå·¥çšãè¡
ãªãããšãåºæ¥ãã ãããã®åŠçå·¥çšã«çµã¿åãããŠå硬èåŠçå·¥
çšããã®äžåå·¥çšãåæ¢å®çåŠçå·¥çšãåŸç¡¬èåŠ
çå·¥çšçãè¡ãªã€ãŠãããããããåŠçã«ãããŠ
çºè²çŸååŠçå·¥çšã®ä»£ããã«çºè²çŸåäž»è¬ããŸã
ã¯ãã®ãã¬ã«ãŒãµãŒãææäžã«å«æãããŠããçŸ
ååŠçãã¢ã¯ãããŒã¿ãŒæ¶²ã§è¡ãªãã¢ã¯ãããŒã¿
ãŒåŠçå·¥çšãè¡ã€ãŠãããããã¢ããã¹åŠçã«ä»£
ããŠã¢ã¯ãããŒã¿ãŒåŠçãšæŒçœãå®çåŠçãšåæ
ã«è¡ãªã€ãŠãããããããã®åŠçäžä»£è¡šçãªåŠç
ã瀺ããïŒãããã®åŠçã¯æçµå·¥çšãšããŠãæ°ŽæŽ
åŠçå·¥çšãå®å®ååŠçå·¥çšãæ°ŽæŽåŠçå·¥çšåã³å®
å®ååŠçå·¥çšã®ãããããè¡ãªããïŒ ã» çºè²çŸååŠçå·¥çšâæŒçœåŠçå·¥çšâå®çåŠç
å·¥çš ã»çºè²çŸååŠçå·¥çšâæŒçœå®çåŠçå·¥çš ã» å硬èåŠçå·¥çšâäžååŠçå·¥çšâçºè²çŸååŠ
çå·¥çšâåæ¢å®çåŠçå·¥çšâæ°ŽæŽåŠçå·¥çšâæŒ
çœåŠçå·¥çšâå®çåŠçå·¥çšâæ°ŽæŽåŠçå·¥çšâåŸ
硬èåŠçå·¥çš ã» çºè²çŸååŠçå·¥çšâæ°ŽæŽåŠçå·¥çšâè£è¶³çºè²
çŸååŠçå·¥çšâåæ¢åŠçå·¥çšâæŒçœåŠçå·¥çšâ
å®çåŠçå·¥çš ã» ã¢ããã¹åŠçå·¥çš ã» ã¢ã¯ãããŒã¿ãŒåŠçå·¥çšâæŒçœå®çåŠçå·¥çš ã» ã¢ã¯ãããŒã¿ãŒåŠçå·¥çšâæŒçœåŠçå·¥çšâå®
çåŠçå·¥çš æ¬çºæã¯èŠªæ°Žæ§ã³ãã€ãå±€ãæããåçš®åçæ
å ææã«é©çšããããšãã§ãããã代衚çã«ã¯æ
å æ§æåãšããŠããã²ã³åéãçšããåã®åçæ
å ææãäŸãã°äžè¬ãã¬æå ææãäžè¬ãªããŒãµ
ã«æå ææãäžè¬çšããžæå ææãçŽæ¥ããžæå
ææãç¹æ®çšïŒäŸãã°å°å·çšãã¬ã€çšãé«è§£å
åçšãèµ€å€çšã玫å€çšçïŒããã²ã³åéåçæå
ææã«çšããããšãã§ããã çºæã®å¹æ æ¬çºæã®ãªã«ã¬ãããªã·ãããµã³ãåçæ§æå±€
ã«çšããããšã«ãããã¹ããªæ§ãè¯å¥œã§ããã€é«
æž©é«æ¹¿ã®æ¡ä»¶ã§ä¿åãããŠããæå ææã©ããã®
æ¥çãé²æ¢ãããããã²ã³åéåçæå ææãåŸ
ãããšãã§ããã å®æœäŸïŒœ 以äžã«æ¬çºæã®å ·äœçå®æœäŸãè¿°ã¹ãããæ¬çº
æã®æ æ§ã¯ãããã«éå®ãããªãã å®æœäŸïŒœ 以äžã®å šãŠã®å®æœäŸã«ãããŠãããã²ã³åéå
çæå ææäžã®æ·»å éã¯ç¹ã«èšèŒã®ãªãéãïŒm2
åœãã®ãã®ã瀺ãããŸããããã²ã³åéãšã³ãã€
ãéã¯éã«æç®ããŠç€ºããã ããªã¢ã»ãã«ã»ã«ããŒã¹ãã€ã«ã æ¯æäœäžã«ã
äžèšã«ç€ºããããªçµæã®åå±€ãé 次æ¯æäœåŽãã
圢æããŠãå€å±€ããã²ã³åéã«ã©ãŒåçæå ææ
ãäœè£œããã 第ïŒå±€ïŒãã¬ãŒã·ãšã³é²æ¢å±€ é»è²ã³ãã€ãéãå«ããŒã©ãã³å±€ã 第ïŒå±€ïŒäžéå±€ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³ã®ä¹³
ååæ£ç©ãå«ããŒã©ãã³å±€ã 第ïŒå±€ïŒäœæ床赀ææ§ããã²ã³åéä¹³å€å±€ å¹³åç²åŸïŒïœïŒ0.30ÎŒmãAgI6ã¢ã«ïŒ ãå«ã
AgBrIãããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé1.8ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ã·ã¢ã³ã«ãã©ãŒïŒïŒ£âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.06ã¢ã« ã«ã©ãŒãã·ã¢ã³ã«ãã©ãŒïŒCCâïŒïŒâŠéïŒã¢
ã«ã«å¯ŸããŠ0.003ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0015ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.002ã¢ã« 第ïŒå±€ïŒé«æ床赀ææ§ããã²ã³åéä¹³å€å±€ å¹³åç²åŸïŒïœïŒ0.5ÎŒmãAgI7.0ã¢ã«ïŒ ãå«ã
AgBrIãããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé1.3ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ã·ã¢ã³ã«ãã©ãŒïŒïŒ£âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.02ã¢ã« ã«ã©ãŒãã·ã¢ã³ã«ãã©ãŒïŒCCâïŒïŒâŠéïŒã¢
ã«ã«å¯ŸããŠ0.0015ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.001ã¢ã« 第ïŒå±€ïŒäžéå±€ 第ïŒå±€ãšåãããŒã©ãã³å±€ã 第ïŒå±€ïŒäœæ床ç·ææ§ããã²ã³åéä¹³å€å±€ ä¹³å€ââŠå¡åžéé1.5ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ2.5Ã10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.2Ã10-5ã¢ã« ããŒã³ã¿ã«ãã©ãŒïŒïŒâïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.050ã¢ã« ã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒïŒCMâïŒïŒâŠéïŒ
ã¢ã«ã«å¯ŸããŠ0.009ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0010ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0030ã¢ã« 第ïŒå±€ïŒé«æ床ç·ææ§ããã²ã³åéä¹³å€å±€ ä¹³å€ââŠå¡åžéé1.4ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.5Ã10-5ã¢ã« å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ããŒã³ã¿ã«ãã©ãŒïŒïŒâïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.020ã¢ã« ã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒïŒCMâïŒïŒâŠéïŒ
ã¢ã«ã«å¯ŸããŠ0.002ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0010ã¢ã« 第ïŒå±€ïŒã€ãšããŒãã€ã«ã¿ãŒå±€ é»è²ã³ãã€ãéãšïŒïŒïŒâãžâïœâãªã¯ãã«ã
ã€ããããã³ã®ä¹³ååæ£ç©ãšãå«ããŒã©ãã³
å±€ã 第ïŒå±€ïŒäœæ床éææ§ããã²ã³åéä¹³å€å±€ å¹³åç²åŸ0.48ÎŒmãAgI6ã¢ã«ïŒ ãå«ãAgBrIã
ããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé0.9ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.3Ã10-5ã¢ã« ã€ãšããŒã«ãã©ãŒïŒïŒ¹âïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.29ã¢ã« 第10å±€ïŒé«æ床éææ§ä¹³å€å±€ å¹³åç²åŸ0.8ÎŒmãAgI15ã¢ã«ïŒ ãå«ãAgBrIã
ããªã ååæ£ä¹³å€ïŒä¹³å€ïŒâŠéå¡åžé0.5ïœïŒm2 å¢æè²çŽ âŠéïŒã¢ã«ã«å¯ŸããŠ1.0Ã10-5ã¢ã« ã€ãšããŒã«ãã©ãŒïŒïŒ¹âïŒïŒâŠéïŒã¢ã«ã«å¯Ÿã
ãŠ0.08ã¢ã« DIRååç©ïŒïŒ€âïŒïŒâŠéïŒã¢ã«ã«å¯ŸããŠ
0.0015ã¢ã« 第11å±€ïŒçŽ«å€ç·åžåå€å«æå±€ æ²èåéïŒAgI1ã¢ã«ïŒ å¹³åç²åŸ0.07ÎŒmïŒéå¡
åžé0.5ïœïŒm2 玫å€ç·åžåå€ UVâïŒïŒUVâïŒåã³ãã«ã
ãªã³ã¹ã«ãã³ãžã€ãŒHSâïŒãå«ããŒã©ãã³å±€ã 第12å±€ïŒç¬¬ïŒä¿è·å±€ 以äžã®ä¿è·å±€å¡åžæ¶²ããŒã©ãã³0.6ïœïŒm2ãšãª
ãããã«å¡åžããã ãªã«ã¬ãããªã·ãããµã³åæ£æ¶²ã®èª¿æŽïŒœ 液 ãªã«ã¬ãããªã·ãããµã³ïŒäŸç€ºååç©OS
âïŒïŒ 2.0ïœ é ¢é žãšãã« 1.5ïœ ïŒ¢æ¶² ãŒã©ãã³æ°Žæº¶æ¶²ïŒïŒ 20ml ããªã€ãœãããã«ããã¿ã¬ã³ã¹ã«ãã³é žãœ
ãŒã 2.0ïœ ïŒ£æ¶² ãŒã©ãã³æ°Žæº¶æ¶²ïŒïŒ 50ml 液ãšïŒ¢æ¶²ãæ··åããŠããã³ããŽãŒãªã³ç€Ÿè£œã
ã«ãåãã¢ãžãã€ã¶ãŒãçšããŠãåæ£ç©ã®ç²åŸã
0.8ÎŒäœã«ãªãããã«ã³ã³ãããŒã«ããŠãåæ£æ¶²ã
åŸããåŸãããåæ£æ¶²ã«ïŒ£æ¶²ãæ·»å ããæ°Žãå ã
ãŠ80mlã«ä»äžããŠããªã«ã¬ãããªã·ãããµã³åæ£
液ãšããã ä¿è·å±€å¡åžæ¶²ïŒœ ãªã«ã¬ãããªã·ãããµã³åæ£æ¶² 70ml ãŒã©ãã³ 40ïœ ãœãžãŠã âã¢ãã«âãã·ã«ã¹ã«ããµã¯ã·ããŒã
1.0ïœ ãšãã«ã¡ã¿ã¯ãªã¬ãŒã30ã¢ã«ïŒ ãã¡ãã«ã¡ã¿ã¯
ãªã¬ãŒã30ã¢ã«ïŒ ãã¡ã¿ã¯ãªã«é ž40ã¢ã«ïŒ ã®ã³
ããªããŒç²åïŒïŒå¹³åç²åŸ2.2ÎŒmïŒ 4.0ïœ ïŒïŒïŒâãã¹ããã«ã¹ã«ããã«ãšã¿ã³ 2.0ïœ æ°Žã§1000mlã«ä»äžããã ïŒå¹³åç²åŸã¯ãå å ŽåŒèªåç²åºŠååžæž¬å®æ©
CAPAâ500ãçšããã å°ãåå±€ã«ã¯äžèšçµæç©ã®ä»ã«ããŒã©ãã³ç¡¬å
å€ïŒïŒšâïŒïŒãçé¢æŽ»æ§å€ãæ·»å ããã åå±€ã«å«ãŸããååç©ã¯äžèšã®éãã§ããã å¢æè²çŽ ïŒã¢ã³ãããïŒïŒ5â²âãžã¯ããâïŒâ
ãšãã«âïŒïŒ3â²âãžâïŒïŒâã¹ã«ããããã«ïŒ
ãã¢ã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒâãšãã«âïŒïŒ3â²âãž
âïŒïŒâã¹ã«ããããã«ïŒâïŒïŒïŒïŒ4â²ïŒ5â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒïŒ5â²âãžããšãã«âïŒ
âãšãã«âïŒïŒ3â²âãžâïŒïŒâã¹ã«ãããã
ã«ïŒãªããµã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒâãšãã«âïŒïŒ3â²âãž
âïŒïŒâã¹ã«ããããã«ïŒâïŒïŒïŒïŒ5â²ïŒ6â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ããããã·ã å¢æè²çŽ ïŒã¢ã³ãããïŒïŒ3â²âãžâïŒïŒâã¹ã«
ããããã«ïŒâïŒïŒïŒâãã³ãŸâ5â²âã¡ãã
ã·ãã¢ã·ã¢ãã³
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ããããŠåŸãããè©Šæãè©ŠæãšããããŸã
OSâïŒã®ãããã«ãè¡šâïŒã«ç€ºããããªãªã«ã¬
ãããªã·ãããµã³ãçšãã以å€ã¯è©Šæãšåäžã®
è©Šæããäœæããã ãŸãæ¯èŒçšãšããŠãäžèšæ§é ã®ãªã«ã¬ãããªã·
ãããµã³ããã³ãçšããè©Šæãè©Šæã€ããã³
ããšããã
OSâïŒã®ãããã«ãè¡šâïŒã«ç€ºããããªãªã«ã¬
ãããªã·ãããµã³ãçšãã以å€ã¯è©Šæãšåäžã®
è©Šæããäœæããã ãŸãæ¯èŒçšãšããŠãäžèšæ§é ã®ãªã«ã¬ãããªã·
ãããµã³ããã³ãçšããè©Šæãè©Šæã€ããã³
ããšããã
ãåã
ãåã
ãããã®è©Šæã«ã€ããŠãä¹³å€å±€åŽè¡šé¢ã®æ©æŠä¿
æ°ããã³é«æž©é«æ¹¿äžã«ãããä¹³å€é¢ãšããªã¢ã»ã
ãŒãè£é¢ãšã®èæ¥çæ§ã以äžã®ãããªæ¹æ³ã§èª¿ã¹
ãã çµæãè¡šâïŒã«ç€ºãã æ©æŠä¿æ°ïŒœ ã» ç±³åœASTMDâ1814ã®æ¹æ³ã«æºããŠæž¬å® è©Šæã¯23â 55ïŒ RHïŒçžå¯Ÿæ¹¿åºŠïŒ23â 80ïŒ
RHãããã24æé調湿åŸæž¬å®ããã ã» åçãã€ã«ã çšé®å çŽã«å¯Ÿããåæ©æŠä¿æ°ã§
衚瀺 èæ¥çæ§è©Šéšæ³ïŒœ è©ŠæãïŒÃïŒcmã®å€§ããã«è£æããŠïŒæãïŒçµ
ãšãã23â 80ïŒ RHïŒçžå¯Ÿæ¹¿åºŠïŒã®é°å²æ°äžã§
24æé調湿ããåŸãããããåè©Šæã®ä¿è·å±€ãšè£
é¢å±€ãšãæ¥è§Šãã800ïœã®è·éããã40â 80ïŒ
RHäžã§24æéä¿ååŸè·éãåãé€ãè©Šæãã¯ã
ããŠæ¥çéšåã®é¢ç©ã枬å®ãèæ¥çæ§ãè©äŸ¡ã
ããè©äŸ¡åºæºã¯æ¬¡ã«ç€ºãæ¹æ³ã«ãã€ãã ã©ã³ã¯ïŒ¡ æ¥çéšåã®é¢ç© ïŒã20ïŒ ïŒ¢ æ¥çéšåã®é¢ç© 21ã40ïŒ ïŒ£ æ¥çéšåã®é¢ç© 41ã60ïŒ ïŒ€ æ¥çéšåã®é¢ç© 61ã80ïŒ ïŒ¥ æ¥çéšåã®é¢ç© 81ïŒ ä»¥äž
æ°ããã³é«æž©é«æ¹¿äžã«ãããä¹³å€é¢ãšããªã¢ã»ã
ãŒãè£é¢ãšã®èæ¥çæ§ã以äžã®ãããªæ¹æ³ã§èª¿ã¹
ãã çµæãè¡šâïŒã«ç€ºãã æ©æŠä¿æ°ïŒœ ã» ç±³åœASTMDâ1814ã®æ¹æ³ã«æºããŠæž¬å® è©Šæã¯23â 55ïŒ RHïŒçžå¯Ÿæ¹¿åºŠïŒ23â 80ïŒ
RHãããã24æé調湿åŸæž¬å®ããã ã» åçãã€ã«ã çšé®å çŽã«å¯Ÿããåæ©æŠä¿æ°ã§
衚瀺 èæ¥çæ§è©Šéšæ³ïŒœ è©ŠæãïŒÃïŒcmã®å€§ããã«è£æããŠïŒæãïŒçµ
ãšãã23â 80ïŒ RHïŒçžå¯Ÿæ¹¿åºŠïŒã®é°å²æ°äžã§
24æé調湿ããåŸãããããåè©Šæã®ä¿è·å±€ãšè£
é¢å±€ãšãæ¥è§Šãã800ïœã®è·éããã40â 80ïŒ
RHäžã§24æéä¿ååŸè·éãåãé€ãè©Šæãã¯ã
ããŠæ¥çéšåã®é¢ç©ã枬å®ãèæ¥çæ§ãè©äŸ¡ã
ããè©äŸ¡åºæºã¯æ¬¡ã«ç€ºãæ¹æ³ã«ãã€ãã ã©ã³ã¯ïŒ¡ æ¥çéšåã®é¢ç© ïŒã20ïŒ ïŒ¢ æ¥çéšåã®é¢ç© 21ã40ïŒ ïŒ£ æ¥çéšåã®é¢ç© 41ã60ïŒ ïŒ€ æ¥çéšåã®é¢ç© 61ã80ïŒ ïŒ¥ æ¥çéšåã®é¢ç© 81ïŒ ä»¥äž
ãè¡šã
è¡šïŒããæãããªããã«æ¬çºæäŸã®è©Šæã¯ãã
ã¹ãæ§ãè¯ãããã€ãã€ã«ã ããŒã¹è£é¢ãšã®æ¥ç
æ§ãå°ãªããåªããè¡šé¢ç©æ§ãæããŠããã å®æœäŸ ïŒ äžåŒããã»ã©ãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãæ¯æäœã®äž¡é¢ã«ãèåé98.5moïŒ ãæ²åé
1.5moïŒ ãããªãå¹³åç²åŸ1.2ÎŒã®é«æ床ããã²
ã³åéç²åãå«ãããã²ã³åéä¹³å€å±€ãšä¿è·å±€ãš
ãå¡èšããç·çšããã²ã³åéåçæå ææãåŸ
ãã ããã²ã³åéä¹³å€ã«ã¯ãããã²ã³åéïŒã¢ã«ã
ãã次ã®æ·»å å€ãæ·»å ããã ïŒâããããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒ
ïŒâããã©ã¶ã€ã³ãã³ 1.2ïœ ãžãšãã¬ã³ã³ã°ãªã³ãŒã« 11.0ïœ ã¯ãªãªãã¶ãŒã« 1.2ïœ ãžãšãã«ããã·ã«ãµã¯ã·ããŒãã¹ã«ãã³é žãã
ãªãŠã 1.5ïœ ãã©ãããããšãã«ããªããšãã«ããªã¹ãã¢ã€
ãã¯ãã©ã€ã 0.2ïœ ããããŠèª¿æŽããå¡åžæ¶²ãéïŒïœïŒm2ããŒã©ã
ã³1.7ïœïŒm2ã«ãªãããã«å¡åžããã ãŸãä¿è·å±€ã¯ããŒã©ãã³éã1.2ïœïŒm2ã«ãªã
ããã«äžèšçµæã®å¡åžæ¶²ãå¡åžããã ä¿è·å±€çµæ ãŒã©ãã³ 80ïœ ãžãšãã«ããã·ã«ãµã¯ã·ããŒãã¹ã«ãã³é žãã
ãªãŠã ïŒïœ ã ã³ã¯ãã«é ž ïŒïœ å¹³åç²åŸãïŒã4ÎŒã®ããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒ
ã ïŒïœ ãã©ããã«ããšãã«ãªãã·ãšãã¬ã³ãšãŒã©ã«ã»
ãã«ã ã¢ã«ãããéçž®åç© ïŒïœ ããªãªãã·ãšãã¬ã³âãžâããã«ããšããŒã«ãš
ãŒãã«ç¡«é žãããªãŠã ïŒïœ å®æœäŸïŒã®æ¹æ³ã§äœããããªã«ã¬ãããªã·ãã
ãµã³OSâïŒåæ£æ¶² 120ml ããããŠåŸãããè©Šæãè©Šæãšããã ãŸããOSâïŒã®ãããã«ãè¡šâïŒã«ç€ºããã
ãªãªã«ã¬ãããªã·ãããµã³ãçšãã以å€ã¯ãè©Šæ
ãšåäžã®è©ŠæããïŒãäœæããã ãããã®è©Šæã«ã€ããŠãå®æœäŸïŒãšåæ§ã«ä¹³å€
å±€åŽè¡šé¢ã®æ©æŠä¿æ°ããã³ãé«æž©é«æ¹¿äžã«ããã
ä¹³å€é¢ã©ãããšã®èæ¥çæ§ã調ã¹ãã çµæãè¡šâïŒã«ç€ºãã
ã¹ãæ§ãè¯ãããã€ãã€ã«ã ããŒã¹è£é¢ãšã®æ¥ç
æ§ãå°ãªããåªããè¡šé¢ç©æ§ãæããŠããã å®æœäŸ ïŒ äžåŒããã»ã©ãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ãæ¯æäœã®äž¡é¢ã«ãèåé98.5moïŒ ãæ²åé
1.5moïŒ ãããªãå¹³åç²åŸ1.2ÎŒã®é«æ床ããã²
ã³åéç²åãå«ãããã²ã³åéä¹³å€å±€ãšä¿è·å±€ãš
ãå¡èšããç·çšããã²ã³åéåçæå ææãåŸ
ãã ããã²ã³åéä¹³å€ã«ã¯ãããã²ã³åéïŒã¢ã«ã
ãã次ã®æ·»å å€ãæ·»å ããã ïŒâããããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒ
ïŒâããã©ã¶ã€ã³ãã³ 1.2ïœ ãžãšãã¬ã³ã³ã°ãªã³ãŒã« 11.0ïœ ã¯ãªãªãã¶ãŒã« 1.2ïœ ãžãšãã«ããã·ã«ãµã¯ã·ããŒãã¹ã«ãã³é žãã
ãªãŠã 1.5ïœ ãã©ãããããšãã«ããªããšãã«ããªã¹ãã¢ã€
ãã¯ãã©ã€ã 0.2ïœ ããããŠèª¿æŽããå¡åžæ¶²ãéïŒïœïŒm2ããŒã©ã
ã³1.7ïœïŒm2ã«ãªãããã«å¡åžããã ãŸãä¿è·å±€ã¯ããŒã©ãã³éã1.2ïœïŒm2ã«ãªã
ããã«äžèšçµæã®å¡åžæ¶²ãå¡åžããã ä¿è·å±€çµæ ãŒã©ãã³ 80ïœ ãžãšãã«ããã·ã«ãµã¯ã·ããŒãã¹ã«ãã³é žãã
ãªãŠã ïŒïœ ã ã³ã¯ãã«é ž ïŒïœ å¹³åç²åŸãïŒã4ÎŒã®ããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒ
ã ïŒïœ ãã©ããã«ããšãã«ãªãã·ãšãã¬ã³ãšãŒã©ã«ã»
ãã«ã ã¢ã«ãããéçž®åç© ïŒïœ ããªãªãã·ãšãã¬ã³âãžâããã«ããšããŒã«ãš
ãŒãã«ç¡«é žãããªãŠã ïŒïœ å®æœäŸïŒã®æ¹æ³ã§äœããããªã«ã¬ãããªã·ãã
ãµã³OSâïŒåæ£æ¶² 120ml ããããŠåŸãããè©Šæãè©Šæãšããã ãŸããOSâïŒã®ãããã«ãè¡šâïŒã«ç€ºããã
ãªãªã«ã¬ãããªã·ãããµã³ãçšãã以å€ã¯ãè©Šæ
ãšåäžã®è©ŠæããïŒãäœæããã ãããã®è©Šæã«ã€ããŠãå®æœäŸïŒãšåæ§ã«ä¹³å€
å±€åŽè¡šé¢ã®æ©æŠä¿æ°ããã³ãé«æž©é«æ¹¿äžã«ããã
ä¹³å€é¢ã©ãããšã®èæ¥çæ§ã調ã¹ãã çµæãè¡šâïŒã«ç€ºãã
ãè¡šã
ãè¡šã
è¡šïŒããæãããªããã«ãçœé»æå
ææã«ã€ã
ãŠããæ¬çºæäŸã®è©Šæã¯ããã¹ãæ§ãè¯ãããã€
é«æž©é«æ¹¿äžã§ã®ä¹³å€é¢ã©ããã®èæ¥çæ§ãåªãã
è¡šé¢ç©æ§ãæããŠããã
ãŠããæ¬çºæäŸã®è©Šæã¯ããã¹ãæ§ãè¯ãããã€
é«æž©é«æ¹¿äžã§ã®ä¹³å€é¢ã©ããã®èæ¥çæ§ãåªãã
è¡šé¢ç©æ§ãæããŠããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«ãå°ãªããšãäžå±€ã®ããã²ã³åé
ä¹³å€å±€ãæããããã²ã³åéåçæå ææã«ãã
ãŠãåèšæ¯æäœäžã«èšããããããã²ã³åéåç
æå ææãæ§æããåçæ§æå±€ã®å°ãªããšãäžå±€
ã«ã¯ãäžèšäžè¬åŒïŒ»ïŒœã§è¡šããããæ§æåäœã
ãã³ïŒãŸãã¯äžèšäžè¬åŒïŒ»ïŒœã§è¡šããããåºã
æãããªã«ã¬ãããªã·ãããµã³ãå«æãããŠãã
ããšãç¹åŸŽãšããããã²ã³åéåçæå ææã äžè¬åŒïŒ»ïŒœ ãåã åŒäžãR1ã¯æ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ã¢
ãªãŒã«åºãè¡šãããR2ã¯ççŽ ååæ°ïŒä»¥äžã®ã¢
ã«ãã«åºãè¡šãããã¯ã¢ã«ãã¬ã³åºãè¡šããã
ïœã¯ïŒãŸãã¯ïŒãè¡šããããŸããã¯ââïŒâ
COOâïŒâOCOâïŒâNHCOâïŒâCONHâïŒâ
âïŒâSO2âïŒâSO2NHâãŸãã¯âNHSO2âãè¡š
ããã äžè¬åŒïŒ»ïŒœ ãåã åŒäžãR2ïŒïŒ¡ïŒïŒ¢ããã³ïœã¯äžè¬åŒïŒ»ïŒœ
ã«ãããR2ïŒïŒ¡ïŒïŒ¢ïŒïœãšå矩ã§ãããR3ãã
ã³R4ã¯ãããããæ°ŽçŽ ååãã¢ã«ãã«åºãã¢ãª
ãŒã«åºãŸãã¯ïŒâïŒnâââR2ãè¡šããã ïŒ åèšãªã«ã¬ãããªã·ãããµã³ããåçæ§æå±€
ã®ãã¡ã®æå€å±€ã®å°ãªããšãäžå±€ã«å«æãããŠã
ãããšãç¹åŸŽãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
ããã²ã³åéåçæå ææã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5626386A JPS62212649A (ja) | 1986-03-14 | 1986-03-14 | ã¹ããªæ§åã³èæ¥çæ§ã®æ¹è¯ãããããã²ã³åéåçæå ææ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5626386A JPS62212649A (ja) | 1986-03-14 | 1986-03-14 | ã¹ããªæ§åã³èæ¥çæ§ã®æ¹è¯ãããããã²ã³åéåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62212649A JPS62212649A (ja) | 1987-09-18 |
| JPH0575100B2 true JPH0575100B2 (ja) | 1993-10-19 |
Family
ID=13022190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5626386A Granted JPS62212649A (ja) | 1986-03-14 | 1986-03-14 | ã¹ããªæ§åã³èæ¥çæ§ã®æ¹è¯ãããããã²ã³åéåçæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62212649A (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2823064B1 (fr) * | 2001-04-04 | 2004-05-28 | Biogemma Fr | Procede d'obtention de plantes c4 a metabolisme carbone modifie |
-
1986
- 1986-03-14 JP JP5626386A patent/JPS62212649A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62212649A (ja) | 1987-09-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5834821B2 (ja) | åçæå ææ | |
| JPS62168156A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0233139B2 (ja) | Harogenkaginshashinkankozairyo | |
| JPS59149357A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0575100B2 (ja) | ||
| JPH0575099B2 (ja) | ||
| JPS62253170A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0575098B2 (ja) | ||
| JPH0621924B2 (ja) | èæ¥çæ§åã³ã¹ããªæ§ã®æ¹è¯ãããããã²ã³åéåçæå ææ | |
| JP3010391B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS62166334A (ja) | ããã²ã³åéã«ã©âæå ææ | |
| US5561031A (en) | Color reversal elements with incorporated bleach accelerator | |
| EP0849624B1 (en) | Silver halide photographic material containing a polymer with a phographically useful group which is rendered non-diffusive by cross-linking | |
| JP2678233B2 (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPH01102461A (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JP2000330242A (ja) | æ¥çä¿é²å±€ãæããæ¯æåºå€ãå«ãåçèŠçŽ | |
| JPS62168145A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPS62286038A (ja) | è¯å¥œãªåž¯é»é²æ¢æ§ãæããããã²ã³åéåçæå ææ | |
| JPH09171230A (ja) | åçèŠçŽ | |
| JPH0555029B2 (ja) | ||
| JPS5833541B2 (ja) | ã·ã€ã·ã³ã¶ã€ãªãšãŠããµãã«ã·ãšãŠããŠã·ããŠã㊠| |
| JPS62195655A (ja) | æ°èŠãªã«ãã©âãå«æããããã²ã³åéåçæå ææ | |
| JPS62170958A (ja) | ããã²ã³åéåçæå ææ | |
| JPS62244043A (ja) | åçèŠçŽ | |
| JPS6285240A (ja) | ããã²ã³åéåçæå ææ |