JPH058937B2 - - Google Patents

Info

Publication number: JPH058937B2
Authority: JP; Japan
Prior art keywords: rubber; compound; rubbers; reaction; butadiene
Prior art date: 1986-09-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP61214841A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6369849A (ja

Inventor

Toshihiro Fujii

Shizuo Kitahara

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Zeon Corp

Original Assignee

Nippon Zeon Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-09-11

Filing date

1986-09-11

Publication date

1993-02-03

1986-09-11 Application filed by Nippon Zeon Co Ltd filed Critical Nippon Zeon Co Ltd

1986-09-11 Priority to JP61214841A priority Critical patent/JPS6369849A/ja

1988-03-29 Publication of JPS6369849A publication Critical patent/JPS6369849A/ja

1993-02-03 Publication of JPH058937B2 publication Critical patent/JPH058937B2/ja

Status Granted legal-status Critical Current

Links

229920001971 elastomer Polymers 0.000 claims description 109
239000005060 rubber Substances 0.000 claims description 109
239000000203 mixture Substances 0.000 claims description 24
-1 organic acid halide Chemical class 0.000 claims description 8
238000005727 Friedel-Crafts reaction Methods 0.000 claims description 6
239000003054 catalyst Substances 0.000 claims description 6
239000000945 filler Substances 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 3
150000002894 organic compounds Chemical class 0.000 claims description 3
125000005843 halogen group Chemical group 0.000 claims 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
150000001875 compounds Chemical class 0.000 description 23
238000006243 chemical reaction Methods 0.000 description 16
229920001577 copolymer Polymers 0.000 description 12
239000003795 chemical substances by application Substances 0.000 description 10
229910052717 sulfur Inorganic materials 0.000 description 10
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
239000011593 sulfur Substances 0.000 description 9
239000002904 solvent Substances 0.000 description 8
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
229920001195 polyisoprene Polymers 0.000 description 6
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 6
235000012239 silicon dioxide Nutrition 0.000 description 6
238000004073 vulcanization Methods 0.000 description 6
150000001993 dienes Chemical class 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
239000005062 Polybutadiene Substances 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
235000021355 Stearic acid Nutrition 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
230000003712 anti-aging effect Effects 0.000 description 4
150000001555 benzenes Chemical class 0.000 description 4
238000013329 compounding Methods 0.000 description 4
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 4
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 4
238000009472 formulation Methods 0.000 description 4
238000000034 method Methods 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000008117 stearic acid Substances 0.000 description 4
229920003048 styrene butadiene rubber Polymers 0.000 description 4
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 4
229960002447 thiram Drugs 0.000 description 4
LOVYCUYJRWLTSU-UHFFFAOYSA-N 2-(3,4-dichlorophenoxy)-n,n-diethylethanamine Chemical compound CCN(CC)CCOC1=CC=C(Cl)C(Cl)=C1 LOVYCUYJRWLTSU-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
244000043261 Hevea brasiliensis Species 0.000 description 3
241001495453 Parthenium argentatum Species 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
125000002723 alicyclic group Chemical group 0.000 description 3
229910000019 calcium carbonate Inorganic materials 0.000 description 3
239000004927 clay Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
229920003052 natural elastomer Polymers 0.000 description 3
229920001194 natural rubber Polymers 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
PNXDDJPALLQFMY-UHFFFAOYSA-N 5-phenylpent-4-en-1-amine Chemical compound NCCCC=CC1=CC=CC=C1 PNXDDJPALLQFMY-UHFFFAOYSA-N 0.000 description 2
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
229920000459 Nitrile rubber Polymers 0.000 description 2
239000002174 Styrene-butadiene Substances 0.000 description 2
FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 2
239000012346 acetyl chloride Substances 0.000 description 2
239000012190 activator Substances 0.000 description 2
238000007259 addition reaction Methods 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 2
229920005549 butyl rubber Polymers 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
239000003086 colorant Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000007822 coupling agent Substances 0.000 description 2
150000001925 cycloalkenes Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
229920005555 halobutyl Polymers 0.000 description 2
150000002367 halogens Chemical group 0.000 description 2
JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 2
CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 2
229920001084 poly(chloroprene) Polymers 0.000 description 2
229920002857 polybutadiene Polymers 0.000 description 2
239000010734 process oil Substances 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
238000007086 side reaction Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000009864 tensile test Methods 0.000 description 2
150000003613 toluenes Chemical class 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
BQAVEYARUMDLOG-UHFFFAOYSA-N 1,1-dimethyl-2-phenyl-2-(5-phenylpent-4-enyl)hydrazine Chemical compound C=1C=CC=CC=1N(N(C)C)CCCC=CC1=CC=CC=C1 BQAVEYARUMDLOG-UHFFFAOYSA-N 0.000 description 1
MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
HAZJTCQWIDBCCE-UHFFFAOYSA-N 1h-triazine-6-thione Chemical compound SC1=CC=NN=N1 HAZJTCQWIDBCCE-UHFFFAOYSA-N 0.000 description 1
FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical group CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
VJQJFYCKFCMMFF-UHFFFAOYSA-N 4-(5-anilinopent-1-enyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C=CCCCNC1=CC=CC=C1 VJQJFYCKFCMMFF-UHFFFAOYSA-N 0.000 description 1
ANTUKSPNJZPWAA-UHFFFAOYSA-N 4-(benzylideneamino)benzonitrile Chemical compound C1=CC(C#N)=CC=C1N=CC1=CC=CC=C1 ANTUKSPNJZPWAA-UHFFFAOYSA-N 0.000 description 1
BMZZGIWIRFMFOU-UHFFFAOYSA-N 4-cyclohexylidenebutan-1-amine Chemical compound NCCCC=C1CCCCC1 BMZZGIWIRFMFOU-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
229910000003 Lead carbonate Inorganic materials 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
WZWRHKQSYZLFDM-UHFFFAOYSA-N N-ethoxy-N-(5-phenylpent-4-enyl)aniline Chemical compound C(C)ON(C1=CC=CC=C1)CCCC=CC1=CC=CC=C1 WZWRHKQSYZLFDM-UHFFFAOYSA-N 0.000 description 1
CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
239000006087 Silane Coupling Agent Substances 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
FXXACINHVKSMDR-UHFFFAOYSA-N acetyl bromide Chemical compound CC(Br)=O FXXACINHVKSMDR-UHFFFAOYSA-N 0.000 description 1
HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
229920005603 alternating copolymer Polymers 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000010692 aromatic oil Substances 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
AQIHMSVIAGNIDM-UHFFFAOYSA-N benzoyl bromide Chemical compound BrC(=O)C1=CC=CC=C1 AQIHMSVIAGNIDM-UHFFFAOYSA-N 0.000 description 1
PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000001273 butane Substances 0.000 description 1
235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
239000000378 calcium silicate Substances 0.000 description 1
229910052918 calcium silicate Inorganic materials 0.000 description 1
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000004568 cement Substances 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
239000002131 composite material Substances 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
125000004663 dialkyl amino group Chemical group 0.000 description 1
AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
125000004997 halocarbonyl group Chemical group 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229920006270 hydrocarbon resin Polymers 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000001023 inorganic pigment Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
238000004898 kneading Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
239000000391 magnesium silicate Substances 0.000 description 1
229910052919 magnesium silicate Inorganic materials 0.000 description 1
235000019792 magnesium silicate Nutrition 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052752 metalloid Inorganic materials 0.000 description 1
VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
GNBWUEAMCSHHMO-UHFFFAOYSA-N methyl 2-carbonochloridoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(Cl)=O GNBWUEAMCSHHMO-UHFFFAOYSA-N 0.000 description 1
PFSNVPBPVQOJCQ-UHFFFAOYSA-N methyl 4-(5-aminopent-1-enyl)benzoate Chemical compound COC(=O)C1=CC=C(C=CCCCN)C=C1 PFSNVPBPVQOJCQ-UHFFFAOYSA-N 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000006011 modification reaction Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000000178 monomer Substances 0.000 description 1
UVEWQKMPXAHFST-UHFFFAOYSA-N n,1-diphenylmethanimine Chemical compound C=1C=CC=CC=1C=NC1=CC=CC=C1 UVEWQKMPXAHFST-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
BXFLCAZUAUSMSQ-UHFFFAOYSA-N n-butylpropan-1-imine Chemical compound CCCCN=CCC BXFLCAZUAUSMSQ-UHFFFAOYSA-N 0.000 description 1
QKSQEJXIILKPDX-UHFFFAOYSA-N n-cyclohexyl-1-phenylmethanimine Chemical compound C1CCCCC1N=CC1=CC=CC=C1 QKSQEJXIILKPDX-UHFFFAOYSA-N 0.000 description 1
HXTGGPKOEKKUQO-UHFFFAOYSA-N n-methyl-1-phenylmethanimine Chemical compound CN=CC1=CC=CC=C1 HXTGGPKOEKKUQO-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
RPFGCUFAJAQNLJ-UHFFFAOYSA-N n-phenylcyclohexanimine Chemical compound C1CCCCC1=NC1=CC=CC=C1 RPFGCUFAJAQNLJ-UHFFFAOYSA-N 0.000 description 1
WGTZFOHCKYJBMK-UHFFFAOYSA-N n-phenylpropan-1-imine Chemical compound CCC=NC1=CC=CC=C1 WGTZFOHCKYJBMK-UHFFFAOYSA-N 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
235000021313 oleic acid Nutrition 0.000 description 1
239000012860 organic pigment Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
PWXJULSLLONQHY-UHFFFAOYSA-N phenylcarbamic acid Chemical compound OC(=O)NC1=CC=CC=C1 PWXJULSLLONQHY-UHFFFAOYSA-N 0.000 description 1
RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920006124 polyolefin elastomer Polymers 0.000 description 1
229920003246 polypentenamer Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000007142 ring opening reaction Methods 0.000 description 1
238000010058 rubber compounding Methods 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229920006132 styrene block copolymer Polymers 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
238000005987 sulfurization reaction Methods 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000013585 weight reducing agent Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Landscapes

Tires In General (AREA)
Compositions Of Macromolecular Compounds (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP61214841A 1986-09-11 1986-09-11 明色ゴム組成物 Granted JPS6369849A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP61214841A JPS6369849A (ja)	1986-09-11	1986-09-11	明色ゴム組成物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP61214841A JPS6369849A (ja)	1986-09-11	1986-09-11	明色ゴム組成物

Publications (2)

Publication Number	Publication Date
JPS6369849A JPS6369849A (ja)	1988-03-29
JPH058937B2 true JPH058937B2 (2)	1993-02-03

Family

ID=16662427

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP61214841A Granted JPS6369849A (ja)	1986-09-11	1986-09-11	明色ゴム組成物

Country Status (1)

Country	Link
JP (1)	JPS6369849A (2)

1986
- 1986-09-11 JP JP61214841A patent/JPS6369849A/ja active Granted

Also Published As

Publication number	Publication date
JPS6369849A (ja)	1988-03-29

Publication	Publication Date	Title
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JPS61225202A (ja)	1986-10-07	ゴムの変性方法
JPH023802B2 (2)	1990-01-25
US4525541A (en)	1985-06-25	Method for modifying rubbers
JPH01234443A (ja)	1989-09-19	ゴム配合組成物
JPH08511049A (ja)	1996-11-19	硫黄加硫ゴム組成物中の亜鉛錯体
EP0328291B1 (en)	1992-04-29	Halogenated polybutadiene series elastomers, method of producing the same, and rubber compositions for tires containing the elastomer
JPH058937B2 (2)	1993-02-03
JPH0249040A (ja)	1990-02-19	加硫性ゴム組成物
JPH05412B2 (2)	1993-01-05
JP2511367B2 (ja)	1996-06-26	変性ポリイソプレンゴム組成物
JPS60127301A (ja)	1985-07-08	ゴムの変性方法
JPS6032839A (ja)	1985-02-20	ゴム組成物
JPS59131641A (ja)	1984-07-28	ブレンドゴム組成物
JPS6377954A (ja)	1988-04-08	変性ゴム組成物
JPH0442402B2 (2)	1992-07-13
JPH0562122B2 (2)	1993-09-07
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JPS59223701A (ja)	1984-12-15	ゴムの変性方法
JPS60141701A (ja)	1985-07-26	ゴムの変性方法
JPH0447704B2 (2)	1992-08-04
CN114829460A (zh)	2022-07-29	橡胶组合物的制备方法、以该方法制备的橡胶组合物及利用其制造的轮胎
JPS60130602A (ja)	1985-07-12	ポリイソプレンゴムの改質方法
JPS6032840A (ja)	1985-02-20	ゴム組成物
JPH01234440A (ja)	1989-09-19	ゴム組成物