JPH0635483B2 - 架橋コポリマーの製造方法 - Google Patents

架橋コポリマーの製造方法

Info

Publication number: JPH0635483B2
Authority: JP; Japan
Prior art keywords: monomer; seed; weight; particles; seed particles
Prior art date: 1982-06-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP58117180A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5918705A (ja

Inventor

ジエ−ムス・ヘンリ−・バレツト

ト−マス・ジエイムス・ホウエル

ジヨ−ジ・マクス・レイン・ジユニア

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rohm and Haas Co

Original Assignee

Rohm and Haas Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-06-30

Filing date

1983-06-30

Publication date

1994-05-11

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23556919&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JPH0635483(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1983-06-30 Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co

1984-01-31 Publication of JPS5918705A publication Critical patent/JPS5918705A/ja

1994-05-11 Publication of JPH0635483B2 publication Critical patent/JPH0635483B2/ja

2009-05-11 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

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239000000725 suspension Substances 0.000 claims abstract description 30
239000003456 ion exchange resin Substances 0.000 claims abstract description 20
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238000004132 cross linking Methods 0.000 claims abstract description 13
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239000003431 cross linking reagent Substances 0.000 claims description 15
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KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 4
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125000006615 aromatic heterocyclic group Chemical group 0.000 claims description 2
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 claims description 2
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HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
238000000926 separation method Methods 0.000 claims description 2
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239000004094 surface-active agent Substances 0.000 description 9
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OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 8
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OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 5
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QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
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229910000391 tricalcium phosphate Inorganic materials 0.000 description 4
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WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
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WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 2
KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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239000002253 acid Substances 0.000 description 2
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
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XJUZRXYOEPSWMB-UHFFFAOYSA-N Chloromethyl methyl ether Chemical compound COCCl XJUZRXYOEPSWMB-UHFFFAOYSA-N 0.000 description 1
244000147058 Derris elliptica Species 0.000 description 1
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SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
HJWBBBADPXPUPA-UHFFFAOYSA-N ethyl 3-(4-chlorophenyl)-5-methyl-1,2-oxazole-4-carboxylate Chemical compound CCOC(=O)C1=C(C)ON=C1C1=CC=C(Cl)C=C1 HJWBBBADPXPUPA-UHFFFAOYSA-N 0.000 description 1
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000005189 flocculation Methods 0.000 description 1
230000016615 flocculation Effects 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
238000007429 general method Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
150000002688 maleic acid derivatives Chemical class 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
239000011859 microparticle Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000003204 osmotic effect Effects 0.000 description 1
KSOCVFUBQIXVDC-FMQUCBEESA-N p-azophenyltrimethylammonium Chemical compound C1=CC([N+](C)(C)C)=CC=C1\N=N\C1=CC=C([N+](C)(C)C)C=C1 KSOCVFUBQIXVDC-FMQUCBEESA-N 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
230000035515 penetration Effects 0.000 description 1
UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical compound C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920001289 polyvinyl ether Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
238000005956 quaternization reaction Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000012492 regenerant Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
230000035939 shock Effects 0.000 description 1
238000002791 soaking Methods 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000012258 stirred mixture Substances 0.000 description 1
229920006249 styrenic copolymer Polymers 0.000 description 1
239000000758 substrate Substances 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
239000003760 tallow Substances 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 1
NZHHDFRSEQSGLN-ZRDIBKRKSA-N tris(prop-2-enyl) (e)-prop-1-ene-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)C\C(C(=O)OCC=C)=C/C(=O)OCC=C NZHHDFRSEQSGLN-ZRDIBKRKSA-N 0.000 description 1
PLCFYBDYBCOLSP-UHFFFAOYSA-N tris(prop-2-enyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)CC(O)(CC(=O)OCC=C)C(=O)OCC=C PLCFYBDYBCOLSP-UHFFFAOYSA-N 0.000 description 1
XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F271/00—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00
- C08F271/02—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00 on to polymers of monomers containing heterocyclic nitrogen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Analytical Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)
Polymerisation Methods In General (AREA)
Inks, Pencil-Leads, Or Crayons (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Materials For Medical Uses (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Macromonomer-Based Addition Polymer (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

JP58117180A 1982-06-30 1983-06-30 架橋コポリマーの製造方法 Expired - Lifetime JPH0635483B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/393,953 US4419245A (en)	1982-06-30	1982-06-30	Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer
US393953		1995-02-24

Publications (2)

Publication Number	Publication Date
JPS5918705A JPS5918705A (ja)	1984-01-31
JPH0635483B2 true JPH0635483B2 (ja)	1994-05-11

Family

ID=23556919

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58117180A Expired - Lifetime JPH0635483B2 (ja)	1982-06-30	1983-06-30	架橋コポリマーの製造方法

Country Status (11)

Country	Link
US (1)	US4419245A (de)
EP (1)	EP0098130B1 (de)
JP (1)	JPH0635483B2 (de)
AT (1)	ATE48004T1 (de)
BR (1)	BR8303410A (de)
CA (1)	CA1228695A (de)
DE (1)	DE3380847D1 (de)
FI (1)	FI72986C (de)
MX (1)	MX167035B (de)
NO (1)	NO165444C (de)
ZA (1)	ZA834584B (de)

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1982
- 1982-06-30 US US06/393,953 patent/US4419245A/en not_active Expired - Lifetime
1983
- 1983-06-16 CA CA000430497A patent/CA1228695A/en not_active Expired
- 1983-06-23 ZA ZA834584A patent/ZA834584B/xx unknown
- 1983-06-23 MX MX197776A patent/MX167035B/es unknown
- 1983-06-27 AT AT83303681T patent/ATE48004T1/de not_active IP Right Cessation
- 1983-06-27 BR BR8303410A patent/BR8303410A/pt not_active IP Right Cessation
- 1983-06-27 EP EP83303681A patent/EP0098130B1/de not_active Expired
- 1983-06-27 DE DE8383303681T patent/DE3380847D1/de not_active Expired
- 1983-06-29 FI FI832391A patent/FI72986C/fi not_active IP Right Cessation
- 1983-06-30 NO NO832379A patent/NO165444C/no unknown
- 1983-06-30 JP JP58117180A patent/JPH0635483B2/ja not_active Expired - Lifetime

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Publication number	Publication date
NO832379L (no)	1984-01-02
FI72986B (fi)	1987-04-30
ZA834584B (en)	1984-08-29
EP0098130B1 (de)	1989-11-15
ATE48004T1 (de)	1989-12-15
MX167035B (es)	1993-02-24
FI832391L (fi)	1983-12-31
NO165444B (no)	1990-11-05
EP0098130A2 (de)	1984-01-11
US4419245A (en)	1983-12-06
FI72986C (fi)	1987-08-10
DE3380847D1 (en)	1989-12-21
NO165444C (no)	1991-02-13
BR8303410A (pt)	1984-02-07
EP0098130A3 (en)	1985-09-18
JPS5918705A (ja)	1984-01-31
FI832391A0 (fi)	1983-06-29
CA1228695A (en)	1987-10-27

Publication	Publication Date	Title
JPH0635483B2 (ja)	1994-05-11	架橋コポリマーの製造方法
US4582859A (en)	1986-04-15	Process for producing an expanded seed copolymer and product therefrom
US4486313A (en)	1984-12-04	Polymerication processes and products therefrom
US4382124A (en)	1983-05-03	Process for preparing macroreticular resins, copolymers and products of said process
US4221871A (en)	1980-09-09	Reticular crosslinked monovinylidene N-heterocyclic copolymer
EP0101943B1 (de)	1990-08-29	Ionenaustauscherharze
EP0604109B1 (de)	1996-10-02	Suspensions Polymerisationsverfahren für wasserlösliche Monomere
KR100441367B1 (ko)	2004-09-18	가교결합된중합체의제조방법
EP0617714A1 (de)	1994-10-05	Poroes geimpfte copolymere und daraus hersgestellte ionenaustauscherharzen.
WO1993025592A1 (en)	1993-12-23	An adiabatic process for the preparation of ion exchange and adsorbent copolymers
US4745134A (en)	1988-05-17	Inert separator beads for regeneration of mixed bed-ion exchange resins
KR100621945B1 (ko)	2006-09-13	겔형 공중합체 비드 및 이로부터 제조된 이온 교환 수지
MXPA02004644A (es)	2002-11-20	Procedimiento para la obtencion de intercambiadores de cationes en forma de gel, monodispersados.
KR100579675B1 (ko)	2006-05-15	단분산 젤라틴상 양이온 교환체의 제조방법
KR20110129595A (ko)	2011-12-02	미세 기공구조를 갖는 마이크론 크기의 단분산 초가교 고분자 입자의 제조 공정
CN1231509C (zh)	2005-12-14	凝胶状阳离子交换剂的制备方法
CN1856511A (zh)	2006-11-01	改进的交换树脂无溶剂磺化
JP2005068421A (ja)	2005-03-17	マイクロカプセル化されていない単分散性の粒状ポリマーの製造方法
JPH04285610A (ja)	1992-10-09	塩化ビニリデン系樹脂粒子の製造方法
JPH0545604B2 (de)	1993-07-09

JPH0635483B2 - 架橋コポリマーの製造方法 - Google Patents

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