JPH0717701B2 - チウラムジスルフィド官能側基を有するポリマー、該ポリマーの製造方法及びグラフトコポリマー製造への該ポリマーの適用 - Google Patents

チウラムジスルフィド官能側基を有するポリマー、該ポリマーの製造方法及びグラフトコポリマー製造への該ポリマーの適用

Info

Publication number: JPH0717701B2
Authority: JP; Japan
Prior art keywords: group; formula; groups; combination; polymer
Prior art date: 1989-10-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP2280536A

Other languages

English (en)

Japanese (ja)

Other versions

JPH03170508A (ja

Inventor

ジルベール・クルエ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arkema France SA

Original Assignee

Atochem SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-10-19

Filing date

1990-10-18

Publication date

1995-03-01

1990-10-18 Application filed by Atochem SA filed Critical Atochem SA

1991-07-24 Publication of JPH03170508A publication Critical patent/JPH03170508A/ja

1995-03-01 Publication of JPH0717701B2 publication Critical patent/JPH0717701B2/ja

2010-03-01 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims description 21
229920000578 graft copolymer Polymers 0.000 title claims description 11
238000000034 method Methods 0.000 title claims description 9
238000004519 manufacturing process Methods 0.000 title claims description 6
125000000524 functional group Chemical group 0.000 title claims description 5
CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 title description 2
125000000217 alkyl group Chemical group 0.000 claims description 26
125000003118 aryl group Chemical group 0.000 claims description 22
239000000178 monomer Substances 0.000 claims description 19
125000000753 cycloalkyl group Chemical group 0.000 claims description 18
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 17
229920002554 vinyl polymer Polymers 0.000 claims description 17
238000006116 polymerization reaction Methods 0.000 claims description 15
-1 polyoxyethylene Polymers 0.000 claims description 13
125000000732 arylene group Chemical group 0.000 claims description 11
125000002947 alkylene group Chemical group 0.000 claims description 10
150000001875 compounds Chemical class 0.000 claims description 10
125000002993 cycloalkylene group Chemical group 0.000 claims description 10
150000001993 dienes Chemical class 0.000 claims description 9
229920001577 copolymer Polymers 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
229920000728 polyester Polymers 0.000 claims description 6
150000003335 secondary amines Chemical group 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000013033 iniferter Substances 0.000 claims description 5
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
238000006243 chemical reaction Methods 0.000 claims description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
125000005843 halogen group Chemical group 0.000 claims description 3
150000003512 tertiary amines Chemical class 0.000 claims description 3
NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 claims description 2
KZUIKPMQAIEBOE-UHFFFAOYSA-N 2-(ethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCNCCOC(=O)C(C)=C KZUIKPMQAIEBOE-UHFFFAOYSA-N 0.000 claims description 2
DEGZUQBZHACZKW-UHFFFAOYSA-N 2-(methylamino)ethyl 2-methylprop-2-enoate Chemical compound CNCCOC(=O)C(C)=C DEGZUQBZHACZKW-UHFFFAOYSA-N 0.000 claims description 2
150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
125000004429 atom Chemical group 0.000 claims description 2
125000002843 carboxylic acid group Chemical group 0.000 claims description 2
125000000962 organic group Chemical group 0.000 claims description 2
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
239000000203 mixture Substances 0.000 description 8
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
238000007334 copolymerization reaction Methods 0.000 description 5
239000002904 solvent Substances 0.000 description 5
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 4
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
229920001519 homopolymer Polymers 0.000 description 3
239000003999 initiator Substances 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000012662 bulk polymerization Methods 0.000 description 2
235000011089 carbon dioxide Nutrition 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 2
238000010528 free radical solution polymerization reaction Methods 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
239000011630 iodine Substances 0.000 description 2
229910052740 iodine Inorganic materials 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 description 2
GVWISOJSERXQBM-UHFFFAOYSA-N n-methylpropan-1-amine Chemical compound CCCNC GVWISOJSERXQBM-UHFFFAOYSA-N 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000010526 radical polymerization reaction Methods 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
239000004912 1,5-cyclooctadiene Substances 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical group COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
AEPWOCLBLLCOGZ-UHFFFAOYSA-N 2-cyanoethyl prop-2-enoate Chemical class C=CC(=O)OCCC#N AEPWOCLBLLCOGZ-UHFFFAOYSA-N 0.000 description 1
WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
UWAQOKCAUJGLQO-UHFFFAOYSA-N 5-hex-5-enylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CCCCC=C)CC1C=C2 UWAQOKCAUJGLQO-UHFFFAOYSA-N 0.000 description 1
WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
UAKPCRIFCXQISY-UHFFFAOYSA-N 5-prop-2-enylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CC=C)CC1C=C2 UAKPCRIFCXQISY-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
MNAGYXVUZKLAEG-UHFFFAOYSA-J [C+4].[O-]S(=O)(=O)OS([O-])(=O)=O.[O-]S(=O)(=O)OS([O-])(=O)=O Chemical compound [C+4].[O-]S(=O)(=O)OS([O-])(=O)=O.[O-]S(=O)(=O)OS([O-])(=O)=O MNAGYXVUZKLAEG-UHFFFAOYSA-J 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000003926 acrylamides Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000004450 alkenylene group Chemical group 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
PPABCIZFQNHUIH-UHFFFAOYSA-N bicyclo[2.2.2]octa-2,5-diene Chemical compound C1=CC2CCC1C=C2 PPABCIZFQNHUIH-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 description 1
NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 1
229940043279 diisopropylamine Drugs 0.000 description 1
WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
239000006060 molten glass Substances 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
AWDBHOZBRXWRKS-UHFFFAOYSA-N tetrapotassium;iron(6+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] AWDBHOZBRXWRKS-UHFFFAOYSA-N 0.000 description 1
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
229960002447 thiram Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/14—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to sulfur-containing macromolecules
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Macromonomer-Based Addition Polymer (AREA)

JP2280536A 1989-10-19 1990-10-18 チウラムジスルフィド官能側基を有するポリマー、該ポリマーの製造方法及びグラフトコポリマー製造への該ポリマーの適用 Expired - Lifetime JPH0717701B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR8913706A FR2653434A1 (fr)	1989-10-19	1989-10-19	Polymeres a fonctions disulfure de thiurame pendantes, leur fabrication, et leur application a la fabrication de copolymere greffes.
FR8913706		1989-10-19

Publications (2)

Publication Number	Publication Date
JPH03170508A JPH03170508A (ja)	1991-07-24
JPH0717701B2 true JPH0717701B2 (ja)	1995-03-01

Family

ID=9386571

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2280536A Expired - Lifetime JPH0717701B2 (ja)	1989-10-19	1990-10-18	チウラムジスルフィド官能側基を有するポリマー、該ポリマーの製造方法及びグラフトコポリマー製造への該ポリマーの適用

Country Status (5)

Country	Link
JP (1)	JPH0717701B2 (fr)
KR (1)	KR910008026A (fr)
CA (2)	CA2042015A1 (fr)
FR (1)	FR2653434A1 (fr)
IE (1)	IE903693A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2690266A1 (fr) *	1992-04-17	1993-10-22	Cray Valley Sa	Polymères comportant des séquences vyniliques et leur procédé de fabrication.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1091317A (fr) *	1953-01-16	1955-04-12	Basf Ag	Procédé de préparation de poly-(bis-thiurame-disulfures)

1989
- 1989-10-19 FR FR8913706A patent/FR2653434A1/fr not_active Withdrawn
1990
- 1990-10-15 CA CA002042015A patent/CA2042015A1/fr not_active Abandoned
- 1990-10-15 IE IE369390A patent/IE903693A1/en unknown
- 1990-10-15 CA CA002027612A patent/CA2027612A1/fr not_active Abandoned
- 1990-10-18 KR KR1019900016833A patent/KR910008026A/ko not_active Ceased
- 1990-10-18 JP JP2280536A patent/JPH0717701B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2042015A1 (fr)	1991-04-20
KR910008026A (ko)	1991-05-30
IE903693A1 (en)	1991-04-24
JPH03170508A (ja)	1991-07-24
CA2027612A1 (fr)	1991-04-20
FR2653434A1 (fr)	1991-04-26

Publication	Publication Date	Title
EP0229481B1 (fr)	1991-02-20	Pentacyanocobaltate (II) comme agent de transfert de chaîne catalytique pour le contrôle du poids moléculaire dans la polymérisation à radical libre
KR100483088B1 (ko)	2005-09-12	분지중합체의합성방법
US4656233A (en)	1987-04-07	"Living" polymers and chain transfer-regulated polymerization process
CA1232998A (fr)	1988-02-16	Polymeres vivants et procede de preparation
JPH0662700B2 (ja)	1994-08-17	二硫化チウラム基を有するポリマー及びその製造方法
KR20010093181A (ko)	2001-10-27	치환 및 비치환 α-메틸렌-γ-부티로락톤의 올리고머화,중합 및 공중합과 그의 생성물
US5189112A (en)	1993-02-23	Polymers having pendant thiuram disulphide functions
JPH0717701B2 (ja)	1995-03-01	チウラムジスルフィド官能側基を有するポリマー、該ポリマーの製造方法及びグラフトコポリマー製造への該ポリマーの適用
KR20010040881A (ko)	2001-05-15	알파-메틸스티렌 이합체 유도체
JP3489893B2 (ja)	2004-01-26	片末端に官能基を有するポリメタクリレートおよびその製造法
JPH04320408A (ja)	1992-11-11	チウラムジスルフィド官能基を有するポリマー、該ポリマーの製造方法、及び該ポリマーを用いるグラフトコポリマーの製造
JP2000281718A (ja)	2000-10-10	重合体、該重合体の製造方法、ならびに該重合体を用いた硬化性組成物
US5847060A (en)	1998-12-08	Functionalized diene oligomers
US4906713A (en)	1990-03-06	"Acrylic" ladder polymers
US6262213B1 (en)	2001-07-17	Anionic polymerization of acrylates and methacrylates
Zeldin et al.	1985	Synthesis of isotactic, syndiotactic, and heterotactic poly (tributyltin methacrylate) and poly (tributyltin methacrylate‐co‐styrene)
JPH0617420B2 (ja)	1994-03-09	ビニル樹脂エマルション
JP4079804B2 (ja)	2008-04-23	ポリオレフィン側鎖含有グラフトポリマーセグメントを有するブロックポリマー
JPH0616756A (ja)	1994-01-25	ブロック共重合体
JPH06199938A (ja)	1994-07-19	グルタルイミドコポリマーの製造方法と、その中間化合物
JPH027325B2 (fr)	1990-02-16
EP0507036A1 (fr)	1992-10-07	Polymères à fonctions disulfure de thiurame pendantes, leur fabrication, et leur application à la fabrication de copolymères greffés
JPS6296507A (ja)	1987-05-06	自己架橋型アクリル酸エステル系ランダム共重合体及びそれを用いた繊維処理剤
JPH10245407A (ja)	1998-09-14	ラジカル重合方法
JP2007297526A (ja)	2007-11-15	重合体の製造方法