JPH07320298A - 相変化型光ディスク - Google Patents
相変化型光ディスクInfo
- Publication number
- JPH07320298A JPH07320298A JP6106997A JP10699794A JPH07320298A JP H07320298 A JPH07320298 A JP H07320298A JP 6106997 A JP6106997 A JP 6106997A JP 10699794 A JP10699794 A JP 10699794A JP H07320298 A JPH07320298 A JP H07320298A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- recording
- protective layer
- optical disk
- upper transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 44
- 239000010410 layer Substances 0.000 claims abstract description 73
- 239000011241 protective layer Substances 0.000 claims abstract description 29
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 230000002441 reversible effect Effects 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 abstract description 9
- 230000008018 melting Effects 0.000 abstract description 9
- 239000003989 dielectric material Substances 0.000 abstract description 2
- 230000007704 transition Effects 0.000 abstract 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 230000031700 light absorption Effects 0.000 description 5
- 229910000618 GeSbTe Inorganic materials 0.000 description 2
- 229910005898 GeSn Inorganic materials 0.000 description 2
- 150000004770 chalcogenides Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 230000005415 magnetization Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018314 SbSeBi Inorganic materials 0.000 description 1
- 229910018321 SbTe Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000005280 amorphization Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000003708 edge detection Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
- G11B7/2578—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
- G11B7/006—Overwriting
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
- G11B7/2548—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers consisting essentially of inorganic materials
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24302—Metals or metalloids
- G11B2007/24312—Metals or metalloids group 14 elements (e.g. Si, Ge, Sn)
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24302—Metals or metalloids
- G11B2007/24314—Metals or metalloids group 15 elements (e.g. Sb, Bi)
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24302—Metals or metalloids
- G11B2007/24316—Metals or metalloids group 16 elements (i.e. chalcogenides, Se, Te)
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
- G11B2007/25705—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
- G11B2007/25706—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing transition metal elements (Zn, Fe, Co, Ni, Pt)
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
- G11B2007/25705—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
- G11B2007/2571—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing group 14 elements except carbon (Si, Ge, Sn, Pb)
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
- G11B2007/25705—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
- G11B2007/25715—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing oxygen
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
- G11B2007/25705—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
- G11B2007/25716—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing sulfur
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
- G11B7/2534—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins polycarbonates [PC]
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/258—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
- G11B7/2585—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Optical Recording Or Reproduction (AREA)
Abstract
する際に必要な熱エネルギ、すなわち記録時のレーザパ
ワを等価にし、オーバライト時の記録マーク歪を極力小
さく抑えた新規な相変化光ディスクを提供することにあ
る。 【構成】 結晶と非晶質間の可逆的な相変化を用い、レ
ーザ光照射による情報記録膜の相状態変化によって情報
の記録再生消去をおこなう相変化型光ディスクにおい
て、基板上1に下地保護層2、記録層3、上部透明保護
層4、干渉層6、反射層5を順次形成したことを特徴と
する相変化型光ディスクである。干渉層6には、透明の
誘電体材料が用いられ、上部透明保護層4とは光学定数
が異なるものが望ましい。
Description
逆的な相変化を用いて情報を記録する光ディスクに関す
る。
大容量記録が可能であり、非接触で高速アクセスできる
ことから、大容量メモリとして実用化が始まっている。
光ディスクはコンパクトディスクやレーザディスクとし
て知られている再生専用型、ユーザ自身で記録できる追
記型、及びユーザ側で繰り返し記録消去ができる書き替
え型に分類される。追記型・書き替え型の光ディスクは
コンピュータの外部メモリ、あるいは文書・画像ファイ
ルとして使用されようとしている。
化を利用した相変化型光ディスクと垂直磁化膜の磁化方
向の変化を利用した光磁気ディスクがある。このうち、
相変化光ディスクは、外部磁場が不要で、かつ、オーバ
ライトが容易にできることから、今後、書き替え型光デ
ィスクの主流になることが期待されている。
ザ光照射により結晶−非晶質間の相変化を起こす記録膜
を用いた書き換えがおこなわれる。相変化型光ディスク
では記録膜に記録すべき情報に応じた高パワのレーザ光
スポットを照射し、記録膜温度を局部的に上昇させるこ
とにより、結晶−非晶質間の相変化を起こさせて記録
し、これに伴う光学定数の変化を低パワのレーザ光によ
って反射光強度差として読み取ることにより再生をおこ
なっている。例えば、結晶化時間が比較的遅い記録膜を
用いた相変化光ディスクでは、ディスクを回転させ、該
ディスクに形成された記録膜にレーザ光を照射し、該記
録膜の温度を融点以上に上昇させ、レーザ光が通過した
後、急冷することによりその部分を非晶質状態とし、記
録する。消去時には、記録膜温度を結晶化温度以上、融
点以下の結晶化可能温度範囲で結晶化を進行させるため
に十分な時間保持し、記録膜を結晶化させる。このため
の方法としては、レーザ光進行方向に長い長円レーザ光
を照射する方法が知られている。既に記録したデータを
消去しながら新しい情報を記録する2ビームによる疑似
的なオーバライトをおこなう場合には、消去用の長円レ
ーザ光を記録用円形レーザ光に先行させて照射するよう
に配置する。
用いたディスクでは、円形に集光した1本のレーザ光を
使う。従来より知られている方法は、レーザ光のパワを
2つのレベル間で変化させることにより、結晶化あるい
は非晶質化をおこなう。すなわち、記録膜の温度を融点
以上に上昇させることが可能なパワのレーザ光を記録膜
に照射することにより、そのほとんどの部分は冷却時に
非晶質状態となり、一方、記録膜温度が結晶化温度以
上、融点以下の温度となるパワのレーザ光が照射された
部分は結晶状態になる。相変化型光ディスクの記録膜に
は、カルコゲナイド系材料であるGeSbTe系、In
SbTe系、InSe系、InTe系、AsTeGe
系、TeOx−GeSn系、TeSeSn系、SbSe
Bi系、BiSeGe系、などが用いられるが、いずれ
も抵抗加熱真空蒸着法、電子ビーム真空蒸着法、スパッ
タリング法などの成膜法で成膜される。成膜直後の記録
膜の状態は一種の非晶質状態であり、この記録膜に記録
をおこなって非晶質の記録部を形成するために、記録膜
全体を結晶質にしておく初期化処理がおこなわれる。記
録はこの結晶化された状態の中に非晶質部分を形成する
ことにより達成される。
スクでは、主として記録部分と消去部分の反射光量の差
を再生信号として検出していた。しかしながら、一般に
記録部分と消去部分に反射光量に差がある場合、両者で
の吸収率に差が生じ、オーバライト時には、この吸収率
差に起因した記録マーク歪が発生していた。
マーク歪を解消するには、吸収率差を制御して記録レー
ザ照射時の記録マーク部分と消去部分の溶融に必要な熱
エネルギを等価にした相変化光ディスクが非常に有効で
ある。
融する際に必要な熱エネルギ、すなわち記録時のレーザ
パワを等価にし、オーバライト時の記録マーク歪を極力
小さく抑えた新規な構成を有する相変化光ディスクを提
供することにある。
間の可逆的な相変化を用い、レーザ光照射による情報記
録膜の相状態変化によって情報の記録再生消去をおこな
う相変化型光ディスクにおいて、基板上に下地保護層、
記録層、上部透明保護層、干渉層、反射層を順次形成し
たことを特徴とし、さらに、上部透明保護層と干渉層の
光学定数が異なることを特徴とする。
るが、溶融潜熱および熱伝導率は結晶状態のほうが大き
いので、記録時に両者を同一のレーザパワ照射で溶融状
態にするためには、結晶部により多くの熱エネルギが吸
収される状態にしておく必要がある。
を高反射率に設定して、信号再生をおこなう場合、従来
例の媒体構成として、図4に示すように、基板上に下地
保護層、記録層、上部透明保護層、反射層を順次形成し
た媒体構成では、非晶質状態の吸収率が結晶状態の吸収
率を上回るため、結晶の吸収率が非晶質の吸収率を上回
る状態を実現できない。
層及び反射層を形成することでこれら層間における光学
干渉をおこし、非晶質である記録マーク部分と結晶であ
る消去部分を溶融する際の熱エネルギを等しくしたもの
である。
録層上に上部透明保護層、干渉層、および反射層を設け
た場合、記録層を透過する光は、上部透明保護層、干渉
層を経て反射層より反射され、再び記録層に戻る。この
時の戻り光の位相は各層の膜厚を制御することによって
調整でき、これにより、記録層での光吸収量を制御でき
る。記録層の光学定数は非晶質と結晶状態で異なるが、
膜厚の設定によって両状態における記録層での昇温量を
等価にできる。
収率をAa、結晶状態における記録層での吸収率をA
c、非晶質状態におけるディスクの反射率をRa、結晶
状態におけるディスクの反射率をRc、非晶質状態にお
ける反射層での吸収率をARa、結晶状態における反射
層での吸収率をARcとすると、本発明におけるディス
クでは、 Aa+ARa+Ra=100% Ac+ARc+Rc=100% Rc>Ra の条件のもとで、 Ac≧Aa が容易に実現できる。
(260nm厚)、Ge2 Sb2 Te5記録層3(15nm
厚)、ZnS−SiO2 上部透明保護層4、Si干渉層
6(20nm厚)、Al反射層5(60nm厚)の条件で、
上部透明保護層の膜厚を変えた時のRa、Rc、Aa、
Acの変化を示した図である。上部透明保護層膜厚10
−40nmおよび150−220nm近傍で、所望の条件が
実現できる。
(260nm厚)、Ge2 Sb2 Te5記録層3(15nm
厚)、ZnS−SiO2 上部透明保護層4(20nm
厚)、Si干渉層6、Al反射層5(60nm厚)の条件
で、Si干渉層の膜厚を変えた時のRa、Rc、Aa、
Acの変化を示した図である。干渉層膜厚20−30nm
および110−120nm近傍で、所望の条件が実現でき
る。
上に記録膜を形成し、さらに記録膜に隣接して光吸収膜
を設けた溶融消去可能な相変化光ディスクが示されてい
る。この技術においては光吸収層が熱吸収層の働きをし
ており、加熱時の熱吸収を記録層と光吸収層に分担させ
て相変化による吸収率の違いを抑えようとしたものであ
る。しかし、記録層と接したところに金属等よりなる光
吸収層を備えているため本願発明のような干渉層と反射
層による干渉を利用して光吸収制御を行うことはできな
い。また、非晶質状態の吸収率が結晶状態の吸収率を上
回るため、本発明にかかる吸収率の条件を実現できな
い。又、この手法は、溶融消去可能な相変化光ディスク
に限って適用できる方法であるため、適用できる記録層
材料には制限がある。しかし、本発明によれば、消去時
に溶融しないモード、溶融させるモードにかかわらず適
用可能である。
成としては、たとえば、特開平2−3119号公報に、
基板上に媒体層、保護層を形成した光記録媒体が示され
ている。特にこの発明では光学的に消去時の吸収率を最
大になるように膜厚を設定することで、少ない照射光エ
ネルギを用いて情報の消去を行うことができるとしてい
る。しかし、この公報に開示された構成は光学的に消去
時の吸収率を最大になるように膜厚を設定して記録感度
を良くしているに過ぎず、本発明のような所望の熱エネ
ルギの吸収率制御をおこなうことはできない。
て説明する。図1は本発明にかかる光ディスクの構成を
示した図である。基板1上に下地保護層2、記録層3、
上部透明保護層4、干渉層6、反射層5が順次形成され
たものである。基板1には、円盤状のガラスもしくはプ
ラスチックが用いられる。下地保護層2と上部透明保護
層4にはSiO2 、Si3 N4 、AlN、TiO2 、Z
nS、ZnS−SiO2 、Ta2 O5 などの材料が用い
られる。記録層3としてはカルコゲナイド系材料である
GeSbTe系、InSbTe系、InSe系、InT
e系、AsTeGe系、TeOx−GeSn系、TeS
eSn系、SbSeBi系、BiSeGe系、などが用
いられる。干渉層6には、透明性の誘電体材料が用いら
れ、上部透明保護層とは光学定数が異なるものが望まし
い。例えば、SiO、Si、Ge、MgF2 、Al2 O
3 、In2 O3 、ZrO2 などが使用できる。反射膜6
にはAl、Au、Cu、Ag、Tiなどの金属が用いら
れる。この構成では、干渉層6と反射層5での光学干渉
を利用して記録層3の結晶部により多くの熱エネルギが
吸収される状態が実現できる。
録層3、上部透明保護層4、干渉層6、反射層5を順次
成膜した。基板1には、直径130mmのポリカーボネー
ト基板(板厚1.2mm、トラックピッチ1.6μm )を
用いた。この基板上に順次スパッタ法により、ZnS−
SiO2 から成る下地保護層2(260nm厚)、Ge2
Sb2 Te5 記録層3(15nm厚)、ZnS−SiO2
上部透明保護層4(20nm厚)、Si干渉層6(20nm
厚)、Al反射層5(60nm厚)を形成した。
ない、再生信号特性を評価した。測定には、波長830
nmの半導体レーザを搭載した光ヘッドを用いた。初期化
処理後のディスクを回転数3600rpmにて回転さ
せ、半径30mmのトラックに8.4MHz(Duty5
0%)の信号を記録した後、同じトラックに2.2MH
z(Duty50%)の信号をオーバライトした。再生
信号の2次高調波歪が最小となるように、記録パワと消
去パワをそれぞれ12mW、6mWに設定した。次に、
このトラックを再生し、記録ビットエッジでみた再生信
号ジッタを測定した。オーバライト後の2.2MHz信
号のジッタは、オーバライトをおこなわない初記録時と
ほとんど変わらなかった。
れていない干渉層を有しない図4と同等の構成を持つ従
来のディスクのオーバライト後ジッタを測定した。波長
830nmの半導体レーザが搭載された光ヘッドにより、
記録消去再生をおこなった。8.4MHz信号記録後に
2.2MHz信号をオーバライトしたときのジッタは、
初記録時の約2倍に増加した。
バライト時の記録マークと消去部分間の昇温量の差を解
消できるため、マークエッジで発生する歪を抑制でき、
良好なエッジ検出が可能となり、高密度記録が可能とな
るという効果がある。
す図である。
保護層膜厚と光学特性の関係を示す図である。
厚と光学特性の関係を示す図である。
る。
Claims (2)
- 【請求項1】結晶と非晶質間の可逆的な相変化を用い、
レーザ光照射による情報記録膜の相状態変化によって情
報の記録再生消去をおこなう相変化型光ディスクにおい
て、基板上に下地保護層、記録層、上部透明保護層、干
渉層、反射層を順次形成したことを特徴とする相変化型
光ディスク。 - 【請求項2】上部透明保護層と干渉層の光学定数が異な
ることを特徴とする請求項1記載の相変化光ディスク。
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6106997A JP2850754B2 (ja) | 1994-05-20 | 1994-05-20 | 相変化型光ディスク |
| EP95107697A EP0683485B1 (en) | 1994-05-20 | 1995-05-19 | Phase change type optical disk |
| DE69518355T DE69518355T2 (de) | 1994-05-20 | 1995-05-19 | Optische Platte vom Phasenwechseltyp |
| KR1019950012539A KR0160363B1 (ko) | 1994-05-20 | 1995-05-19 | 위상 변화형 광 디스크 |
| US08/445,501 US5521901A (en) | 1994-05-20 | 1995-05-22 | Re-writable phase change type optical disk with suppressed recording mark distortion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6106997A JP2850754B2 (ja) | 1994-05-20 | 1994-05-20 | 相変化型光ディスク |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07320298A true JPH07320298A (ja) | 1995-12-08 |
| JP2850754B2 JP2850754B2 (ja) | 1999-01-27 |
Family
ID=14447866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6106997A Expired - Lifetime JP2850754B2 (ja) | 1994-05-20 | 1994-05-20 | 相変化型光ディスク |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5521901A (ja) |
| EP (1) | EP0683485B1 (ja) |
| JP (1) | JP2850754B2 (ja) |
| KR (1) | KR0160363B1 (ja) |
| DE (1) | DE69518355T2 (ja) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996006431A1 (en) * | 1994-08-25 | 1996-02-29 | Sony Corporation | Substrate for optical disk |
| JP2737666B2 (ja) * | 1994-10-18 | 1998-04-08 | 日本電気株式会社 | 光学的情報記録媒体 |
| US5958649A (en) * | 1995-03-27 | 1999-09-28 | Hitachi, Ltd. | Information recording medium and information memory apparatus |
| JP2785763B2 (ja) * | 1995-09-27 | 1998-08-13 | 日本電気株式会社 | 相変化光ディスク |
| US6821707B2 (en) | 1996-03-11 | 2004-11-23 | Matsushita Electric Industrial Co., Ltd. | Optical information recording medium, producing method thereof and method of recording/erasing/reproducing information |
| JP3434419B2 (ja) * | 1996-08-09 | 2003-08-11 | パイオニア株式会社 | 記録媒体とその読み出し装置 |
| US6503690B1 (en) | 1997-08-12 | 2003-01-07 | Matsushita Electric Industrial Co., Ltd. | Optical information recording medium, method for producing the same, and method for recording and reproducing optical information |
| JPH11134720A (ja) | 1997-08-28 | 1999-05-21 | Matsushita Electric Ind Co Ltd | 光学的情報記録媒体及びその記録再生方法 |
| US6343062B1 (en) | 1997-09-26 | 2002-01-29 | Matsushita Electric Industrial Co., Ltd | Optical disk device and optical disk for recording and reproducing high-density signals |
| EP1628296B1 (en) * | 1997-11-17 | 2013-03-06 | Mitsubishi Kagaku Media Co., Ltd. | Optical information recording medium |
| TW448443B (en) | 1998-08-05 | 2001-08-01 | Matsushita Electric Industrial Co Ltd | Optical information storage media and production method as well as the storage reproducing method and device |
| JP3698905B2 (ja) * | 1999-01-11 | 2005-09-21 | 日本電気株式会社 | 光学的情報記録媒体、その情報記録方法、その情報消去方法 |
| JP2000235732A (ja) * | 1999-02-12 | 2000-08-29 | Sony Corp | 多層光ディスク |
| JP3548929B2 (ja) * | 1999-03-23 | 2004-08-04 | 太陽誘電株式会社 | 光情報記録媒体 |
| TW484126B (en) * | 1999-03-26 | 2002-04-21 | Matsushita Electric Industrial Co Ltd | Manufacturing and recording regeneration method for information record medium |
| KR20010047949A (ko) | 1999-11-24 | 2001-06-15 | 윤종용 | 상변화 광디스크 |
| JP4091262B2 (ja) * | 2001-03-21 | 2008-05-28 | 日立マクセル株式会社 | 情報記録媒体および情報記録媒体の製造方法 |
| KR100788646B1 (ko) * | 2001-08-09 | 2007-12-26 | 삼성전자주식회사 | 광디스크의 bca 코드 기록방법 |
| US7123569B2 (en) * | 2001-09-04 | 2006-10-17 | Imation Corp. | Optical data storage medium |
| US7241549B2 (en) * | 2001-09-18 | 2007-07-10 | Ricoh Company, Ltd. | Information recording medium |
| US7280297B2 (en) * | 2002-10-31 | 2007-10-09 | International Business Machines Corporation | Optical storage system using an antenna for recording information data to a phase-change type medium |
| AT523060B1 (de) * | 2020-05-12 | 2021-05-15 | Hueck Folien Gmbh | Sicherheitselement |
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| JPH01149238A (ja) * | 1987-12-04 | 1989-06-12 | Matsushita Electric Ind Co Ltd | 光学的情報記録媒体 |
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| US5368986A (en) * | 1991-05-02 | 1994-11-29 | Hitachi, Ltd. | Information recording media, manufacturing method for the same, and information recording method |
| JPH05174433A (ja) * | 1991-11-30 | 1993-07-13 | Sony Corp | 光磁気記録媒体 |
| US5424106A (en) * | 1992-04-17 | 1995-06-13 | Matsushita Electric Industrial Co., Ltd. | Optical information recording medium and method of designing its structure |
-
1994
- 1994-05-20 JP JP6106997A patent/JP2850754B2/ja not_active Expired - Lifetime
-
1995
- 1995-05-19 KR KR1019950012539A patent/KR0160363B1/ko not_active Expired - Fee Related
- 1995-05-19 EP EP95107697A patent/EP0683485B1/en not_active Expired - Lifetime
- 1995-05-19 DE DE69518355T patent/DE69518355T2/de not_active Expired - Lifetime
- 1995-05-22 US US08/445,501 patent/US5521901A/en not_active Expired - Lifetime
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|---|---|---|---|---|
| JPH01149238A (ja) * | 1987-12-04 | 1989-06-12 | Matsushita Electric Ind Co Ltd | 光学的情報記録媒体 |
| JPH02128330A (ja) * | 1988-11-08 | 1990-05-16 | Fuji Electric Co Ltd | 光記録媒体 |
| JPH02240842A (ja) * | 1989-03-15 | 1990-09-25 | Hitachi Ltd | 溶融消去可能な相変化光ディスク |
| JPH05298747A (ja) * | 1992-04-17 | 1993-11-12 | Matsushita Electric Ind Co Ltd | 光学的情報記録媒体及びその構造設計方法 |
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| JPH07262612A (ja) * | 1994-03-24 | 1995-10-13 | Toshiba Corp | 相変化形光情報記録媒体 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0683485A1 (en) | 1995-11-22 |
| KR950034140A (ko) | 1995-12-26 |
| DE69518355T2 (de) | 2001-04-12 |
| KR0160363B1 (ko) | 1999-01-15 |
| DE69518355D1 (de) | 2000-09-21 |
| JP2850754B2 (ja) | 1999-01-27 |
| US5521901A (en) | 1996-05-28 |
| EP0683485B1 (en) | 2000-08-16 |
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