JPH08502469A - ヨウ素化された有機化合物からヨウ素を回収する方法 - Google Patents

ヨウ素化された有機化合物からヨウ素を回収する方法

Info

Publication number: JPH08502469A
Authority: JP; Japan
Prior art keywords: acid; iodine; organic; catalyst; filtered
Prior art date: 1992-10-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP6510620A

Other languages

English (en)

Japanese (ja)

Inventor

ユルゲンヤッケ，

ペーターブラツィキーヴィッツ，

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer Pharma AG

Original Assignee

Schering AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-10-30

Filing date

1993-10-13

Publication date

1996-03-19

1993-10-13 Application filed by Schering AG filed Critical Schering AG

1996-03-19 Publication of JPH08502469A publication Critical patent/JPH08502469A/ja

Status Pending legal-status Critical Current

Links

ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 39
239000011630 iodine Substances 0.000 title claims abstract description 39
229910052740 iodine Inorganic materials 0.000 title claims abstract description 39
150000002894 organic compounds Chemical class 0.000 title claims abstract description 9
238000000034 method Methods 0.000 title claims description 25
239000003054 catalyst Substances 0.000 claims abstract description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
239000000706 filtrate Substances 0.000 claims abstract description 11
150000001875 compounds Chemical class 0.000 claims abstract description 8
239000001257 hydrogen Substances 0.000 claims abstract description 8
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
239000007800 oxidant agent Substances 0.000 claims abstract description 8
150000007524 organic acids Chemical class 0.000 claims abstract description 7
150000007529 inorganic bases Chemical class 0.000 claims abstract description 6
150000007522 mineralic acids Chemical class 0.000 claims abstract description 6
239000000126 substance Substances 0.000 claims abstract description 6
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract description 5
150000007530 organic bases Chemical class 0.000 claims abstract description 5
238000005831 deiodination reaction Methods 0.000 claims abstract description 4
239000011541 reaction mixture Substances 0.000 claims abstract description 4
230000002378 acidificating effect Effects 0.000 claims abstract description 3
238000000926 separation method Methods 0.000 claims abstract 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 10
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
239000002585 base Substances 0.000 claims description 4
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 2
239000000463 material Substances 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
235000006408 oxalic acid Nutrition 0.000 claims description 2
230000001590 oxidative effect Effects 0.000 claims description 2
229910052763 palladium Inorganic materials 0.000 claims description 2
238000011084 recovery Methods 0.000 claims description 2
229910052703 rhodium Inorganic materials 0.000 claims description 2
229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
238000001556 precipitation Methods 0.000 claims 1
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
239000012452 mother liquor Substances 0.000 description 14
239000000243 solution Substances 0.000 description 12
KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
239000002244 precipitate Substances 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 7
238000000605 extraction Methods 0.000 description 5
238000003756 stirring Methods 0.000 description 5
238000004821 distillation Methods 0.000 description 4
238000005984 hydrogenation reaction Methods 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000002351 wastewater Substances 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000001816 cooling Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
KBZFDRWPMZESDI-UHFFFAOYSA-N 5-aminobenzene-1,3-dicarboxylic acid Chemical compound NC1=CC(C(O)=O)=CC(C(O)=O)=C1 KBZFDRWPMZESDI-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
239000003929 acidic solution Substances 0.000 description 2
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
230000006315 carbonylation Effects 0.000 description 2
238000005810 carbonylation reaction Methods 0.000 description 2
239000002872 contrast media Substances 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
238000004128 high performance liquid chromatography Methods 0.000 description 2
150000002497 iodine compounds Chemical class 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
YLJAKJSGUDBOHG-UHFFFAOYSA-N 2,4,6-triiodobenzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=C(I)C(C(O)=O)=C(I)C(C(O)=O)=C1I YLJAKJSGUDBOHG-UHFFFAOYSA-N 0.000 description 1
IPHVGAPABXWWLO-UHFFFAOYSA-N 2,4,6-triiodobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=C(I)C=C(I)C(C(O)=O)=C1I IPHVGAPABXWWLO-UHFFFAOYSA-N 0.000 description 1
CRVYPNHLIAWRNV-UHFFFAOYSA-N 2,4,6-triiodobenzoic acid Chemical compound OC(=O)C1=C(I)C=C(I)C=C1I CRVYPNHLIAWRNV-UHFFFAOYSA-N 0.000 description 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
GOQCZMZLABPEME-UHFFFAOYSA-N 3,5-diamino-2,4,6-triiodobenzoic acid Chemical compound NC1=C(I)C(N)=C(I)C(C(O)=O)=C1I GOQCZMZLABPEME-UHFFFAOYSA-N 0.000 description 1
QMQFFHSJUJDRPG-UHFFFAOYSA-N 3-amino-2,4,6-triiodobenzoic acid Chemical compound NC1=C(I)C=C(I)C(C(O)=O)=C1I QMQFFHSJUJDRPG-UHFFFAOYSA-N 0.000 description 1
JEZJSNULLBSYHV-UHFFFAOYSA-N 5-amino-2,4,6-triiodobenzene-1,3-dicarboxylic acid Chemical compound NC1=C(I)C(C(O)=O)=C(I)C(C(O)=O)=C1I JEZJSNULLBSYHV-UHFFFAOYSA-N 0.000 description 1
239000007983 Tris buffer Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000002144 chemical decomposition reaction Methods 0.000 description 1
239000000539 dimer Substances 0.000 description 1
239000000428 dust Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
ICIWUVCWSCSTAQ-UHFFFAOYSA-N iodic acid Chemical class OI(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-N 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
XQZXYNRDCRIARQ-LURJTMIESA-N iopamidol Chemical compound C[C@H](O)C(=O)NC1=C(I)C(C(=O)NC(CO)CO)=C(I)C(C(=O)NC(CO)CO)=C1I XQZXYNRDCRIARQ-LURJTMIESA-N 0.000 description 1
229960004647 iopamidol Drugs 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000001089 mineralizing effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000005527 organic iodine compounds Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000001256 steam distillation Methods 0.000 description 1
238000000859 sublimation Methods 0.000 description 1
230000008022 sublimation Effects 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/13—Iodine; Hydrogen iodide
- C01B7/14—Iodine
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/06—Decomposition, e.g. elimination of halogens, water or hydrogen halides
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)

JP6510620A 1992-10-30 1993-10-13 ヨウ素化された有機化合物からヨウ素を回収する方法 Pending JPH08502469A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE4236724.7		1992-10-30
DE19924236724 DE4236724A1 (de)	1992-10-30	1992-10-30	Verfahren zur Rückgewinnung von Jod aus jodierten organischen Verbindungen
PCT/EP1993/002822 WO1994010083A1 (de)	1992-10-30	1993-10-13	Verfahren zur rückgewinnung von jod aus jodierten organischen verbindungen

Publications (1)

Publication Number	Publication Date
JPH08502469A true JPH08502469A (ja)	1996-03-19

Family

ID=6471762

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP6510620A Pending JPH08502469A (ja)	1992-10-30	1993-10-13	ヨウ素化された有機化合物からヨウ素を回収する方法

Country Status (5)

Country	Link
EP (1)	EP0666830A1 (de)
JP (1)	JPH08502469A (de)
CA (1)	CA2147373A1 (de)
DE (1)	DE4236724A1 (de)
WO (1)	WO1994010083A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2020522456A (ja) *	2017-06-07	2020-07-30	ブラッコ・イメージング・ソシエタ・ペル・アチオニＢｒａｃｃｏＩｍａｇｉｎｇＳ．Ｐ．Ａ．	水溶液からのヨウ素の回収方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19635531C2 (de) *	1996-08-20	2002-02-28	Schering Ag	Verfahren zum Abbau von Triiodbenzolderivaten in wäßrigen Medien
DE19806001A1 (de) *	1998-02-16	1999-08-19	Berger Johann	Verfahren zur Dehalogenierung von in Wasser gelösten Halogenkohlenwasserstoffen (HKW) mit Hilfe von vernickeltem Zink
CN112919678B (zh) *	2021-01-29	2023-04-18	江苏集萃托普索清洁能源研发有限公司	醋酸生产废水处理工艺
CN113265703B (zh) *	2021-04-28	2022-03-25	中南大学	一种金属砷晶体脱碘方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1152493B (it) *	1982-08-09	1986-12-31	Bracco Ind Chimica Spa	Metodo per il recupero dello iodio da acque madri ed effluenti contenenti iodio organico
JP2569104B2 (ja) *	1988-02-06	1997-01-08	三井東圧化学株式会社	有機沃素化合物を含有する廃液からの沃素回収方法
JP2569111B2 (ja) *	1988-03-03	1997-01-08	三井東圧化学株式会社	有機沃素化合物を含有する廃液から沃素を回収する方法

1992
- 1992-10-30 DE DE19924236724 patent/DE4236724A1/de not_active Ceased
1993
- 1993-10-13 JP JP6510620A patent/JPH08502469A/ja active Pending
- 1993-10-13 WO PCT/EP1993/002822 patent/WO1994010083A1/de not_active Ceased
- 1993-10-13 EP EP93922560A patent/EP0666830A1/de not_active Withdrawn
- 1993-10-13 CA CA002147373A patent/CA2147373A1/en not_active Abandoned

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2020522456A (ja) *	2017-06-07	2020-07-30	ブラッコ・イメージング・ソシエタ・ペル・アチオニＢｒａｃｃｏＩｍａｇｉｎｇＳ．Ｐ．Ａ．	水溶液からのヨウ素の回収方法

Also Published As

Publication number	Publication date
EP0666830A1 (de)	1995-08-16
WO1994010083A1 (de)	1994-05-11
DE4236724A1 (de)	1994-05-05
CA2147373A1 (en)	1994-05-11

Publication	Publication Date	Title
AU753991B2 (en)	2002-10-31	A process for the recovery of iodine from aqueous solutions containing iodinated organic compounds
JP3421057B2 (ja)	2003-06-30	触媒の回収
JPH10503530A (ja)	1998-03-31	ハロ置換芳香族酸の製造方法
JP2001253720A (ja)	2001-09-18	塩を含有する反応混合物から触媒−遷移金属を回収する方法
US4857295A (en)	1989-08-15	Process for the manufacture of iodine
JPH07300316A (ja)	1995-11-14	反応液からのコバルトとタングステンの回収と再使用方法
JPH07118201A (ja)	1995-05-09	２，６−ナフタレンジカルボン酸の精製方法
CA2147373A1 (en)	1994-05-11	Method of recovering iodine from iodated organic compounds
JP2569104B2 (ja)	1997-01-08	有機沃素化合物を含有する廃液からの沃素回収方法
JP3263401B2 (ja)	2002-03-04	結晶化によりアジピン酸を精製する方法
CN101336228B (zh)	2013-06-12	碘海醇的制备方法
JPH06144802A (ja)	1994-05-24	有機沃素化合物を含有する廃液から沃素を回収する方法
JPS6017780B2 (ja)	1985-05-07	４−アミノメチル安息香酸の製造方法
JP2569111B2 (ja)	1997-01-08	有機沃素化合物を含有する廃液から沃素を回収する方法
JP2664467B2 (ja)	1997-10-15	ビフェニルジカルボン酸の精製法
JPS643143B2 (de)	1989-01-19
JPH02129143A (ja)	1990-05-17	４−クロロフタル酸の製法
JP2917462B2 (ja)	1999-07-12	４，４’―ジフェニルジカルボン酸の精製方法
JPS626537B2 (de)	1987-02-12
JP4080012B2 (ja)	2008-04-23	ナフタレンカルボン酸類の精製方法
JP2821564B2 (ja)	1998-11-05	キナゾリノン誘導体の製造方法
JPH0657670B2 (ja)	1994-08-03	粗イブプロフエンの精製方法
JPS583977B2 (ja)	1983-01-24	ロジウムの分離回収方法
JPH06157007A (ja)	1994-06-03	有機沃素化合物を含有する廃液から沃素を回収する方法
JPS63208548A (ja)	1988-08-30	２，３，５，６−テトラフルオロ安息香酸の製法

JPH08502469A - ヨウ素化された有機化合物からヨウ素を回収する方法 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (3)

Publications (1)

Family

ID=6471762

Family Applications (1)

Country Status (5)

Cited By (1)

Families Citing this family (4)

Family Cites Families (3)

Cited By (1)

Also Published As

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