JPH1045983A - 塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物 - Google Patents

塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物

Info

Publication number: JPH1045983A
Authority: JP; Japan
Prior art keywords: carbon atoms; group; alkyl; acid; tert
Prior art date: 1996-03-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP9108012A

Other languages

English (en)

Japanese (ja)

Inventor

Horst Zinke

ツィンケホルスト

Wolfgang Wehner

ヴェーナーヴォルフガング

Karl Josef Kuhn

ヨーゼフクーンカール

Valerio Borzatta

ボルツァッタヴァレリオ

Gerhard Rytz

ライツゲルハルト

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novartis AG

BASF Schweiz AG

Original Assignee

Ciba Geigy AG

Ciba Spezialitaetenchemie Holding AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-22

Filing date

1997-03-21

Publication date

1998-02-17

1997-03-21 Application filed by Ciba Geigy AG, Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Geigy AG

1998-02-17 Publication of JPH1045983A publication Critical patent/JPH1045983A/ja

Status Pending legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 56
239000003381 stabilizer Substances 0.000 title claims abstract description 36
150000001875 compounds Chemical class 0.000 title claims description 39
239000000460 chlorine Substances 0.000 title description 17
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title description 14
229910052801 chlorine Inorganic materials 0.000 title description 14
125000000217 alkyl group Chemical group 0.000 claims abstract description 43
229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
125000003342 alkenyl group Chemical group 0.000 claims abstract description 8
229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
230000000087 stabilizing effect Effects 0.000 claims abstract description 4
-1 aluminum compound Chemical class 0.000 claims description 105
239000000203 mixture Substances 0.000 claims description 53
125000004432 carbon atom Chemical group C* 0.000 claims description 52
239000010457 zeolite Substances 0.000 claims description 35
239000011575 calcium Substances 0.000 claims description 13
229910052736 halogen Inorganic materials 0.000 claims description 11
150000002367 halogens Chemical class 0.000 claims description 11
229910052782 aluminium Inorganic materials 0.000 claims description 9
229910052791 calcium Inorganic materials 0.000 claims description 9
238000000034 method Methods 0.000 claims description 9
229910052783 alkali metal Inorganic materials 0.000 claims description 8
150000001340 alkali metals Chemical class 0.000 claims description 8
229910052799 carbon Inorganic materials 0.000 claims description 8
235000014113 dietary fatty acids Nutrition 0.000 claims description 8
229930195729 fatty acid Natural products 0.000 claims description 8
239000000194 fatty acid Substances 0.000 claims description 8
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 8
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 8
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 7
229910001701 hydrotalcite Inorganic materials 0.000 claims description 7
229960001545 hydrotalcite Drugs 0.000 claims description 7
125000000753 cycloalkyl group Chemical group 0.000 claims description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
229920005862 polyol Polymers 0.000 claims description 6
239000003963 antioxidant agent Substances 0.000 claims description 5
125000004925 dihydropyridyl group Chemical group N1(CC=CC=C1)* 0.000 claims description 5
150000002118 epoxides Chemical class 0.000 claims description 5
150000003077 polyols Chemical class 0.000 claims description 5
150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 4
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
150000001721 carbon Chemical group 0.000 claims description 4
HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical class OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims description 4
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000004611 light stabiliser Substances 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
239000006096 absorbing agent Substances 0.000 claims description 3
VCNTUJWBXWAWEJ-UHFFFAOYSA-J aluminum;sodium;dicarbonate Chemical compound [Na+].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O VCNTUJWBXWAWEJ-UHFFFAOYSA-J 0.000 claims description 3
229910001647 dawsonite Inorganic materials 0.000 claims description 3
125000003884 phenylalkyl group Chemical group 0.000 claims description 3
RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims description 2
125000003545 alkoxy group Chemical group 0.000 claims description 2
150000001339 alkali metal compounds Chemical class 0.000 claims 1
239000011701 zinc Substances 0.000 description 26
239000004800 polyvinyl chloride Substances 0.000 description 24
229920000915 polyvinyl chloride Polymers 0.000 description 24
229910021536 Zeolite Inorganic materials 0.000 description 23
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
239000011734 sodium Substances 0.000 description 21
229910052725 zinc Inorganic materials 0.000 description 19
229910052757 nitrogen Inorganic materials 0.000 description 18
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
239000011777 magnesium Substances 0.000 description 14
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
229910052700 potassium Inorganic materials 0.000 description 12
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 11
229920001577 copolymer Polymers 0.000 description 11
239000004014 plasticizer Substances 0.000 description 11
229910018072 Al 2 O 3 Inorganic materials 0.000 description 10
239000000654 additive Substances 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
229910052749 magnesium Inorganic materials 0.000 description 9
239000000049 pigment Substances 0.000 description 9
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
150000002148 esters Chemical class 0.000 description 8
239000000463 material Substances 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 6
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 6
229910052784 alkaline earth metal Inorganic materials 0.000 description 6
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 5
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
239000007983 Tris buffer Substances 0.000 description 5
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 5
150000007942 carboxylates Chemical class 0.000 description 5
239000007859 condensation product Substances 0.000 description 5
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
229910052744 lithium Inorganic materials 0.000 description 5
239000000314 lubricant Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
235000013772 propylene glycol Nutrition 0.000 description 5
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 5
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 4
KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 4
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 4
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
150000001342 alkaline earth metals Chemical class 0.000 description 4
235000006708 antioxidants Nutrition 0.000 description 4
238000000576 coating method Methods 0.000 description 4
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
239000002184 metal Substances 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
229960004063 propylene glycol Drugs 0.000 description 4
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
229910052712 strontium Inorganic materials 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
150000003752 zinc compounds Chemical class 0.000 description 4
SQHKJSPPFSVNDF-UHFFFAOYSA-N 1,2,2,3-tetrakis(hydroxymethyl)cyclohexan-1-ol Chemical compound OCC1CCCC(O)(CO)C1(CO)CO SQHKJSPPFSVNDF-UHFFFAOYSA-N 0.000 description 3
KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 3
WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000001361 adipic acid Substances 0.000 description 3
235000011037 adipic acid Nutrition 0.000 description 3
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 3
229910052788 barium Inorganic materials 0.000 description 3
FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical group CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 3
USIOOCIPICIXLX-UHFFFAOYSA-N ethylsulfanyl-hydroxy-sulfanyl-sulfanylidene-lambda5-phosphane Chemical compound CCSP(O)(S)=S USIOOCIPICIXLX-UHFFFAOYSA-N 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
239000000945 filler Substances 0.000 description 3
239000006260 foam Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000000395 magnesium oxide Substances 0.000 description 3
229940049964 oleate Drugs 0.000 description 3
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
239000004597 plastic additive Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
235000019260 propionic acid Nutrition 0.000 description 3
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000003549 soybean oil Substances 0.000 description 3
235000012424 soybean oil Nutrition 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 3
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
125000005591 trimellitate group Chemical group 0.000 description 3
239000008096 xylene Substances 0.000 description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 2
LIKQHVGPOUBDTG-UHFFFAOYSA-N 1,4-diphenylbutane-1,3-dione Chemical compound C=1C=CC=CC=1CC(=O)CC(=O)C1=CC=CC=C1 LIKQHVGPOUBDTG-UHFFFAOYSA-N 0.000 description 2
CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 description 2
ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 2
BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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229960001147 triclofos Drugs 0.000 description 1
FICPQAZLPKLOLH-UHFFFAOYSA-N tricyclohexyl phosphite Chemical group C1CCCCC1OP(OC1CCCCC1)OC1CCCCC1 FICPQAZLPKLOLH-UHFFFAOYSA-N 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
WDRCVXGINNJWPH-UHFFFAOYSA-N tris(6-methylheptyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCOC(=O)C1=CC=C(C(=O)OCCCCCC(C)C)C(C(=O)OCCCCCC(C)C)=C1 WDRCVXGINNJWPH-UHFFFAOYSA-N 0.000 description 1
235000013799 ultramarine blue Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
239000003981 vehicle Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000011709 vitamin E Substances 0.000 description 1
235000019165 vitamin E Nutrition 0.000 description 1
229940046009 vitamin E Drugs 0.000 description 1
239000010456 wollastonite Substances 0.000 description 1
229910052882 wollastonite Inorganic materials 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
239000011667 zinc carbonate Substances 0.000 description 1
235000004416 zinc carbonate Nutrition 0.000 description 1
229910000010 zinc carbonate Inorganic materials 0.000 description 1
BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
229910052984 zinc sulfide Inorganic materials 0.000 description 1
RBEYUVZBFYVXEX-UHFFFAOYSA-L zinc;2-sulfanylacetate Chemical compound [Zn+2].[O-]C(=O)CS.[O-]C(=O)CS RBEYUVZBFYVXEX-UHFFFAOYSA-L 0.000 description 1
JIXJDKNPPOUBJH-UHFFFAOYSA-L zinc;2-sulfanylbenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1S.[O-]C(=O)C1=CC=CC=C1S JIXJDKNPPOUBJH-UHFFFAOYSA-L 0.000 description 1
YCFZZALTCSESPA-UHFFFAOYSA-L zinc;2-sulfanylbutanedioate Chemical compound [Zn+2].[O-]C(=O)CC(S)C([O-])=O YCFZZALTCSESPA-UHFFFAOYSA-L 0.000 description 1
WLVAUUBKRRARBW-UHFFFAOYSA-L zinc;2-sulfanylpropanoate Chemical compound [Zn+2].CC(S)C([O-])=O.CC(S)C([O-])=O WLVAUUBKRRARBW-UHFFFAOYSA-L 0.000 description 1
YMTQMTSQMKJKPX-UHFFFAOYSA-L zinc;diphenoxide Chemical compound [Zn+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 YMTQMTSQMKJKPX-UHFFFAOYSA-L 0.000 description 1
PCHQDTOLHOFHHK-UHFFFAOYSA-L zinc;hydrogen carbonate Chemical compound [Zn+2].OC([O-])=O.OC([O-])=O PCHQDTOLHOFHHK-UHFFFAOYSA-L 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
239000002076 α-tocopherol Substances 0.000 description 1
235000004835 α-tocopherol Nutrition 0.000 description 1
239000011590 β-tocopherol Substances 0.000 description 1
235000007680 β-tocopherol Nutrition 0.000 description 1
239000002478 γ-tocopherol Substances 0.000 description 1
QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
239000002446 δ-tocopherol Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/138—Phenolates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

JP9108012A 1996-03-22 1997-03-21 塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物 Pending JPH1045983A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH75196		1996-03-22
CH751/96		1996-03-22

Publications (1)

Publication Number	Publication Date
JPH1045983A true JPH1045983A (ja)	1998-02-17

Family

ID=4194353

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP9108012A Pending JPH1045983A (ja)	1996-03-22	1997-03-21	塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物

Country Status (16)

Country	Link
JP (1)	JPH1045983A (da)
AT (1)	AT413210B (da)
BE (1)	BE1012198A5 (da)
BR (1)	BR9701422A (da)
CA (1)	CA2200536A1 (da)
DE (1)	DE19711690A1 (da)
DK (1)	DK29697A (da)
ES (1)	ES2147078B1 (da)
FR (1)	FR2746405A1 (da)
GB (1)	GB2311292B (da)
IT (1)	IT1290431B1 (da)
NL (1)	NL1005608C2 (da)
NO (1)	NO971335L (da)
SE (1)	SE9701011L (da)
TW (1)	TW354800B (da)
ZA (1)	ZA972426B (da)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2000273254A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法
JP2000273248A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19752481A1 (de) *	1997-11-27	1999-06-02	Cit Alcatel	Isoliermaterial auf der Basis von Polyvinylchlorid
GB0219260D0 (en) *	2002-08-19	2002-09-25	Clariant Gmbh	Improvements in or relating to organic compounds
ATE493467T1 (de)	2007-08-28	2011-01-15	Basf Se	Stabilisatormischung
CN103554009B (zh) *	2013-10-22	2016-05-04	山西省化工研究所（有限公司）	一种尼龙多功能稳定剂的制备方法
CN118812417A (zh) *	2024-06-21	2024-10-22	福建帝盛科技股份有限公司	N,n-双(2,2,6,6-四甲基哌啶基)-1,4-乙二酰胺的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3684765A (en) *	1970-01-08	1972-08-15	Sankyo Co	Stabilization of synthetic polymers
EP0421933B1 (de) *	1989-10-06	1996-06-12	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen
EP0432096A1 (de) *	1989-12-06	1991-06-12	Ciba-Geigy Ag	Stabilisierte chlorhaltige Zusammensetzung
EP0446171A3 (en) *	1990-03-08	1992-05-20	Ciba-Geigy Ag	Stabilised chlorinated polymer compositions
DE59108223D1 (de) *	1990-11-30	1996-10-31	Ciba Geigy Ag	Stabilisierte chlorhaltige Polymere
US5283273A (en) *	1990-11-30	1994-02-01	Ciba-Geigy Corporation	Stabilized chlorine-containing polymers
EP0488950B1 (de) *	1990-11-30	1995-09-20	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymere
EP0570337B1 (de) *	1992-05-13	1998-03-18	Ciba SC Holding AG	Stabilisierte chlorhaltige Polymerzusammensetzungen
ATE312874T1 (de) *	1996-03-22	2005-12-15	Wolfgang Wehner	Stabilisatorkombination für chlorhaltige polymere

1997
- 1997-03-17 DK DK029697A patent/DK29697A/da not_active Application Discontinuation
- 1997-03-19 SE SE9701011A patent/SE9701011L/xx not_active Application Discontinuation
- 1997-03-20 ZA ZA9702426A patent/ZA972426B/xx unknown
- 1997-03-20 DE DE19711690A patent/DE19711690A1/de not_active Withdrawn
- 1997-03-20 CA CA002200536A patent/CA2200536A1/en not_active Abandoned
- 1997-03-20 FR FR9703402A patent/FR2746405A1/fr not_active Withdrawn
- 1997-03-21 IT IT97MI000662A patent/IT1290431B1/it active IP Right Grant
- 1997-03-21 AT AT0050297A patent/AT413210B/de not_active IP Right Cessation
- 1997-03-21 NO NO971335A patent/NO971335L/no not_active Application Discontinuation
- 1997-03-21 ES ES009700618A patent/ES2147078B1/es not_active Expired - Fee Related
- 1997-03-21 TW TW086103573A patent/TW354800B/zh active
- 1997-03-21 BE BE9700251A patent/BE1012198A5/fr not_active IP Right Cessation
- 1997-03-21 JP JP9108012A patent/JPH1045983A/ja active Pending
- 1997-03-21 GB GB9705846A patent/GB2311292B/en not_active Expired - Fee Related
- 1997-03-21 BR BR9701422A patent/BR9701422A/pt not_active Application Discontinuation
- 1997-03-21 NL NL1005608A patent/NL1005608C2/nl not_active IP Right Cessation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2000273254A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法
JP2000273248A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法

Also Published As

Publication number	Publication date
IT1290431B1 (it)	1998-12-03
DE19711690A1 (de)	1997-11-06
ATA50297A (de)	2005-05-15
SE9701011L (sv)	1997-09-23
SE9701011D0 (sv)	1997-03-19
TW354800B (en)	1999-03-21
ES2147078B1 (es)	2001-04-01
DK29697A (da)	1997-09-23
NL1005608C2 (nl)	2000-05-22
GB9705846D0 (en)	1997-05-07
GB2311292B (en)	2000-10-04
GB2311292A (en)	1997-09-24
FR2746405A1 (fr)	1997-09-26
AT413210B (de)	2005-12-15
CA2200536A1 (en)	1997-09-22
NO971335L (no)	1997-09-23
ES2147078A1 (es)	2000-08-16
NL1005608A1 (nl)	1997-09-23
NO971335D0 (no)	1997-03-21
ITMI970662A1 (it)	1998-09-21
BR9701422A (pt)	1998-11-10
BE1012198A5 (fr)	2000-07-04
ZA972426B (en)	1997-09-22

Publication	Publication Date	Title
EP1046668B2 (de)	2010-03-03	Stabilisatorkombinationen für chlorhaltige Polymere
US6013703A (en)	2000-01-11	Stabilizer combination for chlorine-containing polymers
KR19980024864A (ko)	1998-07-06	Ｎ,ｎ-디메틸-6-아미노우라실로써 안정화된 경질 ｐｖｃ
JPH0711084A (ja)	1995-01-13	ポリ塩化ビニルの安定化
JPH10120855A (ja)	1998-05-12	ポリ塩化ビニルのための安定剤としてのモノマー性およびオリゴマー性ビスホスフィット
JPH07292196A (ja)	1995-11-07	安定化されたポリ塩化ビニル
JPH09208780A (ja)	1997-08-12	安定化されたハロゲン含有ポリマー
JP4243382B2 (ja)	2009-03-25	塩素含有ポリマーと少なくとも１種のシアノアセチル尿素とを含有する組成物、塩素含有組成物の安定化方法およびシアノアセチル尿素の使用
EP1569994B1 (de)	2008-01-09	Monosubstituierte 6-aminouracile zum stabilisieren von halogenhaltigen polymeren
JPH0912815A (ja)	1997-01-14	帯電防止剤を含有するハロゲン含有ポリマー
JP4886519B2 (ja)	2012-02-29	ハロゲン含有ポリマーのための安定剤組成物
US6232375B1 (en)	2001-05-15	4-aminopyrimidinones and oxazolidino-4-aminopyrimidinones, process for their preparation and their use for stabilizing halogen-containing polymers
JPH1045983A (ja)	1998-02-17	塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物
US5804622A (en)	1998-09-08	Monomeric N-piperidinylmelamines as stabilizers for chlorine-containing polymers
JPH1053571A (ja)	1998-02-24	塩素含有ポリマーのための安定剤
JPH07300544A (ja)	1995-11-14	安定化ハロゲン含有ポリマー
GB2345695A (en)	2000-07-19	Stabilizer combinations for halogen-containing polymers
DE29924285U1 (de)	2002-09-12	Cyanacetylharnstoffe zum Stabilisieren von halogenhaltigen Polymeren

JPH1045983A - 塩素含有ポリマーのための安定剤の組合せにおける４−アシルアミド−ピペリジン化合物 - Google Patents

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Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=4194353

Family Applications (1)

Country Status (16)

Cited By (2)

Families Citing this family (5)

Family Cites Families (9)

Cited By (2)

Also Published As

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