JPS6099101A - 酸性多糖類の回収方法 - Google Patents

酸性多糖類の回収方法

Info

Publication number: JPS6099101A
Authority: JP; Japan
Prior art keywords: acid; polysaccharide; aluminum; water; polysaccharides
Prior art date: 1983-11-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP20552483A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0576481B2 (de

Inventor

Hajime Ito

元伊藤

Shiyouji Suzuki

鈴木　晶二

Hirofumi Ninomiya

弘文二宮

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Chemical Corp

Original Assignee

Mitsubishi Rayon Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-11-01

Filing date

1983-11-01

Publication date

1985-06-03

1983-11-01 Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd

1983-11-01 Priority to JP20552483A priority Critical patent/JPS6099101A/ja

1985-06-03 Publication of JPS6099101A publication Critical patent/JPS6099101A/ja

1993-10-22 Publication of JPH0576481B2 publication Critical patent/JPH0576481B2/ja

Status Granted legal-status Critical Current

Links

229920001284 acidic polysaccharide Polymers 0.000 title claims description 30
150000004805 acidic polysaccharides Chemical class 0.000 title claims description 30
238000011084 recovery Methods 0.000 title claims description 7
229920001282 polysaccharide Polymers 0.000 claims description 23
239000005017 polysaccharide Substances 0.000 claims description 23
229910052782 aluminium Inorganic materials 0.000 claims description 22
150000004804 polysaccharides Chemical class 0.000 claims description 22
238000000034 method Methods 0.000 claims description 21
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
239000007864 aqueous solution Substances 0.000 claims description 17
239000002253 acid Substances 0.000 claims description 15
239000003153 chemical reaction reagent Substances 0.000 claims description 14
239000002244 precipitate Substances 0.000 claims description 14
239000003960 organic solvent Substances 0.000 claims description 13
230000003381 solubilizing effect Effects 0.000 claims description 9
235000010418 carrageenan Nutrition 0.000 claims description 8
239000000679 carrageenan Substances 0.000 claims description 8
229920001525 carrageenan Polymers 0.000 claims description 8
229940113118 carrageenan Drugs 0.000 claims description 8
-1 impropatol Natural products 0.000 claims description 8
239000000243 solution Substances 0.000 claims description 8
UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 8
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
229920001277 pectin Polymers 0.000 claims description 6
239000001814 pectin Substances 0.000 claims description 6
235000010987 pectin Nutrition 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
150000003839 salts Chemical class 0.000 claims description 5
IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
229920001817 Agar Polymers 0.000 claims description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
239000008272 agar Substances 0.000 claims description 4
239000001913 cellulose Substances 0.000 claims description 4
229920002678 cellulose Polymers 0.000 claims description 4
235000010413 sodium alginate Nutrition 0.000 claims description 4
239000000661 sodium alginate Substances 0.000 claims description 4
229940005550 sodium alginate Drugs 0.000 claims description 4
229920000388 Polyphosphate Polymers 0.000 claims description 3
229920002472 Starch Polymers 0.000 claims description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
239000001205 polyphosphate Substances 0.000 claims description 3
235000011176 polyphosphates Nutrition 0.000 claims description 3
239000000843 powder Substances 0.000 claims description 3
230000001376 precipitating effect Effects 0.000 claims description 3
239000008107 starch Substances 0.000 claims description 3
235000019698 starch Nutrition 0.000 claims description 3
GIXFALHDORQSOQ-UHFFFAOYSA-N 2,4,6,8-tetrahydroxy-1,3,5,7,2$l^{5},4$l^{5},6$l^{5},8$l^{5}-tetraoxatetraphosphocane 2,4,6,8-tetraoxide Chemical compound OP1(=O)OP(O)(=O)OP(O)(=O)OP(O)(=O)O1 GIXFALHDORQSOQ-UHFFFAOYSA-N 0.000 claims description 2
244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 2
HTTJABKRGRZYRN-UHFFFAOYSA-N Heparin Chemical compound OC1C(NC(=O)C)C(O)OC(COS(O)(=O)=O)C1OC1C(OS(O)(=O)=O)C(O)C(OC2C(C(OS(O)(=O)=O)C(OC3C(C(O)C(O)C(O3)C(O)=O)OS(O)(=O)=O)C(CO)O2)NS(O)(=O)=O)C(C(O)=O)O1 HTTJABKRGRZYRN-UHFFFAOYSA-N 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
229920000669 heparin Polymers 0.000 claims description 2
229960002897 heparin Drugs 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
159000000000 sodium salts Chemical class 0.000 claims description 2
239000011975 tartaric acid Substances 0.000 claims description 2
235000002906 tartaric acid Nutrition 0.000 claims description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
SQDAZGGFXASXDW-UHFFFAOYSA-N 5-bromo-2-(trifluoromethoxy)pyridine Chemical compound FC(F)(F)OC1=CC=C(Br)C=N1 SQDAZGGFXASXDW-UHFFFAOYSA-N 0.000 claims 1
244000215068 Acacia senegal Species 0.000 claims 1
229920001287 Chondroitin sulfate Polymers 0.000 claims 1
SNVFDPHQAOXWJZ-UHFFFAOYSA-N Furcelleran Chemical compound CCOC(=O)C1=C(C)NC(C=2C=CC=CC=2)=C(C(=O)OCC=2C=CC=CC=2)C1C#CC1=CC=CC=C1 SNVFDPHQAOXWJZ-UHFFFAOYSA-N 0.000 claims 1
229920000084 Gum arabic Polymers 0.000 claims 1
229920002201 Oxidized cellulose Polymers 0.000 claims 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
235000010489 acacia gum Nutrition 0.000 claims 1
239000000205 acacia gum Substances 0.000 claims 1
230000001476 alcoholic effect Effects 0.000 claims 1
150000001720 carbohydrates Chemical class 0.000 claims 1
229940059329 chondroitin sulfate Drugs 0.000 claims 1
125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
229940107304 oxidized cellulose Drugs 0.000 claims 1
229960000292 pectin Drugs 0.000 claims 1
239000011574 phosphorus Substances 0.000 claims 1
229910052698 phosphorus Inorganic materials 0.000 claims 1
229920001285 xanthan gum Polymers 0.000 claims 1
239000000230 xanthan gum Substances 0.000 claims 1
235000010493 xanthan gum Nutrition 0.000 claims 1
229940082509 xanthan gum Drugs 0.000 claims 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
238000000605 extraction Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 5
239000000706 filtrate Substances 0.000 description 5
239000003513 alkali Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
238000006386 neutralization reaction Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
150000007513 acids Chemical class 0.000 description 2
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 2
229940009861 aluminum chloride hexahydrate Drugs 0.000 description 2
239000012467 final product Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
238000001226 reprecipitation Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
238000005406 washing Methods 0.000 description 2
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
235000015178 Asplenium bulbiferum subsp bulbiferum Nutrition 0.000 description 1
244000178908 Asplenium bulbiferum subsp bulbiferum Species 0.000 description 1
241000238366 Cephalopoda Species 0.000 description 1
241001672694 Citrus reticulata Species 0.000 description 1
QXKAIJAYHKCRRA-JJYYJPOSSA-N D-arabinonic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C(O)=O QXKAIJAYHKCRRA-JJYYJPOSSA-N 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
229920002683 Glycosaminoglycan Polymers 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241001598113 Laminaria digitata Species 0.000 description 1
LZJOBYGVGAAXFX-UHFFFAOYSA-N O.O.O.O.O.O.[AlH3] Chemical compound O.O.O.O.O.O.[AlH3] LZJOBYGVGAAXFX-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
244000111306 Torreya nucifera Species 0.000 description 1
235000006732 Torreya nucifera Nutrition 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
229940063656 aluminum chloride Drugs 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
235000015165 citric acid Nutrition 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
UZLGHNUASUZUOR-UHFFFAOYSA-L dipotassium;3-carboxy-3-hydroxypentanedioate Chemical compound [K+].[K+].OC(=O)CC(O)(C([O-])=O)CC([O-])=O UZLGHNUASUZUOR-UHFFFAOYSA-L 0.000 description 1
235000019262 disodium citrate Nutrition 0.000 description 1
239000002526 disodium citrate Substances 0.000 description 1
CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000003814 drug Substances 0.000 description 1
238000002036 drum drying Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
235000013399 edible fruits Nutrition 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000000499 gel Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
229940005657 pyrophosphoric acid Drugs 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
235000002639 sodium chloride Nutrition 0.000 description 1
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Landscapes

Polysaccharides And Polysaccharide Derivatives (AREA)

JP20552483A 1983-11-01 1983-11-01 酸性多糖類の回収方法 Granted JPS6099101A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP20552483A JPS6099101A (ja)	1983-11-01	1983-11-01	酸性多糖類の回収方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP20552483A JPS6099101A (ja)	1983-11-01	1983-11-01	酸性多糖類の回収方法

Publications (2)

Publication Number	Publication Date
JPS6099101A true JPS6099101A (ja)	1985-06-03
JPH0576481B2 JPH0576481B2 (de)	1993-10-22

Family

ID=16508304

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP20552483A Granted JPS6099101A (ja)	1983-11-01	1983-11-01	酸性多糖類の回収方法

Country Status (1)

Country	Link
JP (1)	JPS6099101A (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0557734U (ja) *	1992-01-10	1993-07-30	株式会社ゼクセル	多連式押釦

1983
- 1983-11-01 JP JP20552483A patent/JPS6099101A/ja active Granted

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0557734U (ja) *	1992-01-10	1993-07-30	株式会社ゼクセル	多連式押釦

Also Published As

Publication number	Publication date
JPH0576481B2 (de)	1993-10-22

Legal Events

Date	Code	Title	Description
2003-10-22	LAPS	Cancellation because of no payment of annual fees

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JPS6099101A - 酸性多糖類の回収方法 - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=16508304

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

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