JPS61213267A - モノクロロトリアジニル基を含むホルマザン化合物の混合物，それらの製造および使用 - Google Patents

モノクロロトリアジニル基を含むホルマザン化合物の混合物，それらの製造および使用

Info

Publication number: JPS61213267A
Authority: JP; Japan
Prior art keywords: compound; alkyl; formula; hydrogen; substituted
Prior art date: 1985-03-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP61055155A

Other languages

English (en)

Japanese (ja)

Inventor

ユルグ　シユタイガー

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sandoz AG

Original Assignee

Sandoz AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-03-16

Filing date

1986-03-14

Publication date

1986-09-22

1986-03-14 Application filed by Sandoz AG filed Critical Sandoz AG

1986-09-22 Publication of JPS61213267A publication Critical patent/JPS61213267A/ja

Status Pending legal-status Critical Current

Links

150000001875 compounds Chemical class 0.000 title claims description 184
239000000203 mixture Substances 0.000 title claims description 63
-1 monochlorotriazinyl group Chemical group 0.000 title claims description 32
238000004519 manufacturing process Methods 0.000 title description 3
125000000217 alkyl group Chemical group 0.000 claims description 59
229910052739 hydrogen Inorganic materials 0.000 claims description 52
239000001257 hydrogen Substances 0.000 claims description 52
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 47
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 41
150000002431 hydrogen Chemical class 0.000 claims description 32
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 24
229910052736 halogen Inorganic materials 0.000 claims description 23
150000002367 halogens Chemical group 0.000 claims description 23
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 21
238000004043 dyeing Methods 0.000 claims description 21
238000000034 method Methods 0.000 claims description 21
229910052801 chlorine Inorganic materials 0.000 claims description 18
239000000460 chlorine Substances 0.000 claims description 18
150000003839 salts Chemical group 0.000 claims description 17
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 16
GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 16
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 16
125000004433 nitrogen atom Chemical group N* 0.000 claims description 16
125000004093 cyano group Chemical group *C#N 0.000 claims description 14
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
229920000742 Cotton Polymers 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 10
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 9
125000003545 alkoxy group Chemical group 0.000 claims description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
125000001188 haloalkyl group Chemical group 0.000 claims description 7
125000005842 heteroatom Chemical group 0.000 claims description 7
PVOAHINGSUIXLS-UHFFFAOYSA-N 1-Methylpiperazine Chemical group CN1CCNCC1 PVOAHINGSUIXLS-UHFFFAOYSA-N 0.000 claims description 6
125000001309 chloro group Chemical group Cl* 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
239000007858 starting material Substances 0.000 claims description 6
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 5
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
239000000758 substrate Substances 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 4
239000002657 fibrous material Substances 0.000 claims description 4
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
239000000463 material Substances 0.000 claims description 2
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
125000000896 monocarboxylic acid group Chemical group 0.000 claims 7
239000000126 substance Substances 0.000 claims 6
JGLMVXWAHNTPRF-CMDGGOBGSA-N CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O Chemical compound CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O JGLMVXWAHNTPRF-CMDGGOBGSA-N 0.000 claims 1
238000003419 tautomerization reaction Methods 0.000 claims 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
239000000975 dye Substances 0.000 description 8
150000001412 amines Chemical class 0.000 description 7
150000001768 cations Chemical class 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
239000000985 reactive dye Substances 0.000 description 5
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
239000000243 solution Substances 0.000 description 4
MEKOFIRRDATTAG-UHFFFAOYSA-N 2,2,5,8-tetramethyl-3,4-dihydrochromen-6-ol Chemical compound C1CC(C)(C)OC2=C1C(C)=C(O)C=C2C MEKOFIRRDATTAG-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
239000004744 fabric Substances 0.000 description 3
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
229920000297 Rayon Polymers 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000010016 exhaust dyeing Methods 0.000 description 2
239000010446 mirabilite Substances 0.000 description 2
VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical class N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
125000000229 (C1-C4)alkoxy group Chemical group 0.000 description 1
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
229920003043 Cellulose fiber Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
235000014676 Phragmites communis Nutrition 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000010933 acylation Effects 0.000 description 1
238000005917 acylation reaction Methods 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000001045 blue dye Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
235000010980 cellulose Nutrition 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
108010011222 cyclo(Arg-Pro) Proteins 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000010985 leather Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000002964 rayon Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000005185 salting out Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
239000013535 sea water Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
210000004243 sweat Anatomy 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
230000002747 voluntary effect Effects 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
- C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
- C09B62/046—Specific dyes not provided for in group C09B62/06 - C09B62/10

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Coloring (AREA)

JP61055155A 1985-03-16 1986-03-14 モノクロロトリアジニル基を含むホルマザン化合物の混合物，それらの製造および使用 Pending JPS61213267A (ja)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
DE3509559		1985-03-16
DE3509559.8		1985-03-16
DE3541561.4		1985-11-25
DE3541561		1985-11-25

Publications (1)

Publication Number	Publication Date
JPS61213267A true JPS61213267A (ja)	1986-09-22

Family

ID=25830402

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP61055155A Pending JPS61213267A (ja)	1985-03-16	1986-03-14	モノクロロトリアジニル基を含むホルマザン化合物の混合物，それらの製造および使用

Country Status (5)

Country	Link
JP (1)	JPS61213267A (it)
CH (1)	CH667278A5 (it)
FR (1)	FR2578852B1 (it)
GB (1)	GB2172896B (it)
IT (1)	IT1203749B (it)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4880434A (en) *	1987-07-23	1989-11-14	Sumitomo Chemical Company, Limited	Method of obtaining dyed and finished cellulose fiber materials using reactive metallized formazan dye with no color change
DE3737536A1 (de) *	1987-11-05	1989-05-18	Basf Ag	Kupfer-formazanreaktivfarbstoffe und ihre verwendung
DE58904174D1 (de) *	1988-03-17	1993-06-03	Ciba Geigy Ag	Reaktivfarbstoffe, verfahren zu deren herstellung und deren verwendung.
EP0352222B1 (de) *	1988-06-29	1994-05-25	Ciba-Geigy Ag	Faserreaktive Formazanfarbstoffe, Verfahren zu deren Herstellung und deren Verwendung
DE59010337D1 (de) *	1989-11-01	1996-06-27	Ciba Geigy Ag	Faserreaktive Formazanfarbstoffe, Verfahren zu deren Herstellung und deren Verwendung

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH441571A (de) *	1959-11-13	1967-08-15	Geigy Ag J R	Verfahren zur Herstellung von metallhaltigen reaktiven Formazanfarbstoffen
CH577544A5 (it) *	1972-12-29	1976-07-15	Ciba Geigy Ag
JPS6067562A (ja) *	1983-09-24	1985-04-17	Nippon Kayaku Co Ltd	ホルマザン化合物及びこれを用いるセルロ−ス系繊維の染色法

1986
- 1986-03-10 CH CH969/86A patent/CH667278A5/de not_active IP Right Cessation
- 1986-03-10 FR FR8603474A patent/FR2578852B1/fr not_active Expired
- 1986-03-12 GB GB08606059A patent/GB2172896B/en not_active Expired
- 1986-03-13 IT IT47762/86A patent/IT1203749B/it active
- 1986-03-14 JP JP61055155A patent/JPS61213267A/ja active Pending

Also Published As

Publication number	Publication date
IT8647762A0 (it)	1986-03-13
FR2578852B1 (fr)	1988-09-09
GB8606059D0 (en)	1986-04-16
FR2578852A1 (fr)	1986-09-19
CH667278A5 (de)	1988-09-30
IT1203749B (it)	1989-02-23
GB2172896B (en)	1988-11-02
GB2172896A (en)	1986-10-01

Publication	Publication Date	Title
JPH04258674A (ja)	1992-09-14	染料混合物およびその使用
JPS61213267A (ja)	1986-09-22	モノクロロトリアジニル基を含むホルマザン化合物の混合物，それらの製造および使用
JPH0234667A (ja)	1990-02-05	繊維反応性染料
JPH01221460A (ja)	1989-09-04	繊維反応性フタロシアニンモノアゾ化合物
US4578457A (en)	1986-03-25	Reactive mono-azo dyes and the preparation and use thereof
JPS6025064B2 (ja)	1985-06-15	ジスアゾ染料
US4338092A (en)	1982-07-06	Disazo compounds having a 4,6,8-trisulfonaphthyl diazo components radical and a 2-amino or substituted amino-4-chloro-1,3,5-triazin-6-yl-amino substituent
JPS5943500B2 (ja)	1984-10-22	非対称型１：２クロム錯塩染料
JPS5975950A (ja)	1984-04-28	モノクロロトリアジニル基含有モノアゾ化合物
JP2002517539A (ja)	2002-06-18	モノアゾ反応染料
JPH0860012A (ja)	1996-03-05	アルミニウム−フタロシアニン反応性染料およびそれによる染色および捺染法
JPS63182373A (ja)	1988-07-27	モノアゾ化合物
US5693765A (en)	1997-12-02	Substituted 5- 5'- (5"- Chloro-2", 4"-difluoropyrimid-6"-ylamino) phenylcarbonylamino!-2'-sulfophenyl-azo!-6-hydroxy-4-methyl-3-sulfomethylpyrid-2-ones
JPH09104826A (ja)	1997-04-22	反応性染料及びその製造方法
JPS63280768A (ja)	1988-11-17	アニオンジスアゾ染料
JPS61213269A (ja)	1986-09-22	金属化されたクロロトリアジニル基含有ジスアゾ化合物ならびにそれらの製造および使用
US5373094A (en)	1994-12-13	Reactive dyes containing a 2,6-difluoro-3,5-dichloropyridine group
KR0181491B1 (ko)	1999-04-01	반응성 염료 및 이의 염료제제
JPS62127354A (ja)	1987-06-09	モノアゾ化合物
KR960001065B1 (ko)	1996-01-18	수용성 모노아조 착색제 및 이들을 사용한 염색방법
US5698681A (en)	1997-12-16	Reactive disazo dyestuff compounds containing halo-substituted triazinyl rings
US5359043A (en)	1994-10-25	Reactive dyes having a sulphonamido group
JPH0416503B2 (it)	1992-03-24
JPS62172063A (ja)	1987-07-29	水溶性アゾ化合物、その製法及び該化合物を染料として使用する方法
JPS5925825B2 (ja)	1984-06-21	繊維反応性モノアゾ染料