LU87394A1 - Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet - Google Patents

Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet Download PDF

Info

Publication number: LU87394A1
Authority: LU; Luxembourg
Prior art keywords: compound; denotes; cosmetic; formula; rays
Prior art date: 1988-11-22

Application number

LU87394A

Other languages

English (en)

French (fr)

Inventor

Lang Gerard

Forestier Serge

Moire Claudine

Lagrange Alain

Original Assignee

Oreal

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-11-22

Filing date

1988-11-22

Publication date

1990-06-12

1988-11-22 Application filed by Oreal filed Critical Oreal

1988-11-22 Priority to LU87394A priority Critical patent/LU87394A1/fr

1989-11-16 Priority to AT89403146T priority patent/ATE84301T1/de

1989-11-16 Priority to DE8989403146T priority patent/DE68904296T2/de

1989-11-16 Priority to FR898915046A priority patent/FR2639347B1/fr

1989-11-16 Priority to EP89403146A priority patent/EP0370867B1/de

1989-11-20 Priority to CH4157/89A priority patent/CH680218A5/fr

1989-11-21 Priority to IT06802989A priority patent/IT1238406B/it

1989-11-21 Priority to GB8926315A priority patent/GB2225013B/en

1989-11-21 Priority to BE8901239A priority patent/BE1002272A3/fr

1989-11-22 Priority to US07/439,977 priority patent/US5064641A/en

1989-11-22 Priority to JP1304562A priority patent/JPH02231463A/ja

1989-11-22 Priority to CA002003597A priority patent/CA2003597C/fr

1990-06-12 Publication of LU87394A1 publication Critical patent/LU87394A1/fr

Links

229910052751 metal Inorganic materials 0.000 title claims abstract description 16
239000002184 metal Substances 0.000 title claims abstract description 16
OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical class CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 title claims abstract description 11
230000005855 radiation Effects 0.000 title description 7
150000002739 metals Chemical class 0.000 title 1
150000001875 compounds Chemical class 0.000 claims abstract description 41
239000000203 mixture Substances 0.000 claims abstract description 29
239000002537 cosmetic Substances 0.000 claims abstract description 18
150000003839 salts Chemical class 0.000 claims abstract description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 13
230000000475 sunscreen effect Effects 0.000 claims abstract description 12
239000000516 sunscreening agent Substances 0.000 claims abstract description 12
150000001768 cations Chemical class 0.000 claims abstract description 3
239000002304 perfume Substances 0.000 claims description 13
239000003755 preservative agent Substances 0.000 claims description 12
238000001914 filtration Methods 0.000 claims description 10
210000003491 skin Anatomy 0.000 claims description 10
-1 benzylidene-camphor sulfone Chemical class 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 7
229910052749 magnesium Inorganic materials 0.000 claims description 6
239000003921 oil Substances 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 5
210000002615 epidermis Anatomy 0.000 claims description 5
239000000049 pigment Substances 0.000 claims description 5
239000004166 Lanolin Substances 0.000 claims description 4
229910052791 calcium Inorganic materials 0.000 claims description 4
239000000839 emulsion Substances 0.000 claims description 4
235000019388 lanolin Nutrition 0.000 claims description 4
229940039717 lanolin Drugs 0.000 claims description 4
229910052725 zinc Inorganic materials 0.000 claims description 4
229910052782 aluminium Inorganic materials 0.000 claims description 3
238000000034 method Methods 0.000 claims description 3
239000002671 adjuvant Substances 0.000 claims description 2
239000000443 aerosol Substances 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
239000000975 dye Substances 0.000 claims description 2
239000003906 humectant Substances 0.000 claims description 2
239000003380 propellant Substances 0.000 claims description 2
239000004094 surface-active agent Substances 0.000 claims description 2
239000000725 suspension Substances 0.000 claims description 2
239000002562 thickening agent Substances 0.000 claims description 2
239000001993 wax Substances 0.000 claims description 2
239000000499 gel Substances 0.000 claims 1
238000012216 screening Methods 0.000 abstract description 3
238000003756 stirring Methods 0.000 description 24
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
239000012071 phase Substances 0.000 description 10
230000002335 preservative effect Effects 0.000 description 10
239000008346 aqueous phase Substances 0.000 description 8
150000003254 radicals Chemical class 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000000047 product Substances 0.000 description 6
239000011541 reaction mixture Substances 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 5
230000004927 fusion Effects 0.000 description 5
235000019198 oils Nutrition 0.000 description 5
239000000843 powder Substances 0.000 description 5
239000011575 calcium Substances 0.000 description 4
235000019441 ethanol Nutrition 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
230000002688 persistence Effects 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
239000011701 zinc Substances 0.000 description 4
DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 3
241000723346 Cinnamomum camphora Species 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
150000001450 anions Chemical class 0.000 description 3
229960000846 camphor Drugs 0.000 description 3
229930008380 camphor Natural products 0.000 description 3
235000011187 glycerol Nutrition 0.000 description 3
239000002609 medium Substances 0.000 description 3
229940099259 vaseline Drugs 0.000 description 3
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
239000006071 cream Substances 0.000 description 2
238000000921 elemental analysis Methods 0.000 description 2
239000008267 milk Substances 0.000 description 2
210000004080 milk Anatomy 0.000 description 2
235000013336 milk Nutrition 0.000 description 2
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
229910002012 Aerosil® Inorganic materials 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
206010015150 Erythema Diseases 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
206010041303 Solar dermatitis Diseases 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
230000004075 alteration Effects 0.000 description 1
150000001449 anionic compounds Chemical class 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
235000013871 bee wax Nutrition 0.000 description 1
239000012166 beeswax Substances 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229960002713 calcium chloride Drugs 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
229940052299 calcium chloride dihydrate Drugs 0.000 description 1
238000004040 coloring Methods 0.000 description 1
DHGWZWRJBUSWOV-UHFFFAOYSA-L dichlorozinc dihydrate Chemical compound O.O.[Cl-].[Cl-].[Zn+2] DHGWZWRJBUSWOV-UHFFFAOYSA-L 0.000 description 1
150000004683 dihydrates Chemical class 0.000 description 1
DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 description 1
231100000321 erythema Toxicity 0.000 description 1
238000009472 formulation Methods 0.000 description 1
YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
229940100242 glycol stearate Drugs 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Substances [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 1
235000019359 magnesium stearate Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
150000002891 organic anions Chemical class 0.000 description 1
DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
231100000760 phototoxic Toxicity 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
230000003389 potentiating effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000037307 sensitive skin Effects 0.000 description 1
231100000075 skin burn Toxicity 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
229960005078 sorbitan sesquioleate Drugs 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
230000009182 swimming Effects 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/23—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing rings other than six-membered aromatic rings
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/24—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of a carbon skeleton containing six-membered aromatic rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Landscapes

Organic Chemistry (AREA)
Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Public Health (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Veterinary Medicine (AREA)
Epidemiology (AREA)
Birds (AREA)
Dermatology (AREA)
Cosmetics (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Hydrogenated Pyridines (AREA)
Nitrogen Condensed Heterocyclic Rings (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

LU87394A 1988-11-22 1988-11-22 Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet LU87394A1 (fr)

Priority Applications (12)

Application Number	Priority Date	Filing Date	Title
LU87394A LU87394A1 (fr)	1988-11-22	1988-11-22	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet
AT89403146T ATE84301T1 (de)	1988-11-22	1989-11-16	Polyvalente metallsalze von sulfonierten derivaten von benzylidenkampfer und deren verwendung als ultravioletstrahlungsschutzmittel.
DE8989403146T DE68904296T2 (de)	1988-11-22	1989-11-16	Polyvalente metallsalze von sulfonierten derivaten von benzylidenkampfer und deren verwendung als ultravioletstrahlungsschutzmittel.
FR898915046A FR2639347B1 (fr)	1988-11-22	1989-11-16	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet
EP89403146A EP0370867B1 (de)	1988-11-22	1989-11-16	Polyvalente Metallsalze von sulfonierten Derivaten von Benzylidenkampfer und deren Verwendung als Ultravioletstrahlungsschutzmittel
CH4157/89A CH680218A5 (de)	1988-11-22	1989-11-20
IT06802989A IT1238406B (it)	1988-11-22	1989-11-21	Sali di metalli polivalenti di derivati solfonici di benzilidene- canfora, composizioni che li contengono e loro utilizzazione per la protezione della pelle contro la radiazione ultravioletta
GB8926315A GB2225013B (en)	1988-11-22	1989-11-21	Compounds for protecting the skin against ultraviolet radiation
BE8901239A BE1002272A3 (fr)	1988-11-22	1989-11-21	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet.
US07/439,977 US5064641A (en)	1988-11-22	1989-11-22	Polyvalent metal salts of sulphonted derivatives of benzylidenecamphor and their use for protecting the skin against ultraviolet radiation
JP1304562A JPH02231463A (ja)	1988-11-22	1989-11-22	ベンジリデン―カンファースルホン化誘導体および紫外線防止剤
CA002003597A CA2003597C (fr)	1988-11-22	1989-11-22	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
LU87394A LU87394A1 (fr)	1988-11-22	1988-11-22	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet
LU87394		1988-11-22

Publications (1)

Publication Number	Publication Date
LU87394A1 true LU87394A1 (fr)	1990-06-12

Family

ID=19731116

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LU87394A LU87394A1 (fr)	1988-11-22	1988-11-22	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet

Country Status (12)

Country	Link
US (1)	US5064641A (de)
EP (1)	EP0370867B1 (de)
JP (1)	JPH02231463A (de)
AT (1)	ATE84301T1 (de)
BE (1)	BE1002272A3 (de)
CA (1)	CA2003597C (de)
CH (1)	CH680218A5 (de)
DE (1)	DE68904296T2 (de)
FR (1)	FR2639347B1 (de)
GB (1)	GB2225013B (de)
IT (1)	IT1238406B (de)
LU (1)	LU87394A1 (de)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2677543B1 (fr) *	1991-06-13	1993-09-24	Oreal	Composition cosmetique filtrante a base d'acide benzene 1,4-di(3-methylidene-10-camphosulfonique) et de nanopigments d'oxydes metalliques.
FR2680685B1 (fr) *	1991-08-30	1995-04-21	Oreal	Gel cosmetique solaire contenant en suspension des spherouides hydrates d'une substance lipidique hydrophile et, en solution dans la phase aqueuse, un filtre u.v. de type sulfonique.
DE59406277D1 (de) *	1993-02-11	1998-07-23	Beiersdorf Ag	Wasserfeste kosmetische oder dermatologische lichtschutzzubereitungen
FR2718638B1 (fr) *	1994-04-19	1996-05-24	Oreal	Compositions cosmétiques filtrantes contenant un agent hydrophile acide et utilisation.
FR2733148B1 (fr) *	1995-04-20	1997-05-30	Oreal	Composition pour lutter contre les taches et/ou le vieillissement de la peau, ses utilisations
US6535268B1 (en) *	1995-10-30	2003-03-18	Reveo, Inc.	Multilayer non metallic reflecting flakes for cosmetics and sunscreens
EP1117638B1 (de) *	1998-10-02	2004-03-17	Ciba SC Holding AG	Durch camphor- oder hydantoin-derivate substituierte diphenylverbindungen als lichtschutzmittel
FR2799645B1 (fr)	1999-10-13	2004-04-30	Oreal	Utilisation de la dhea ou de ses precurseurs ou derives metaboliques comme depigmentant
FR2801212A1 (fr) *	1999-11-19	2001-05-25	Oreal	Compositions filtrantes contenant l'association d'un compose naphtalenique et de l'acide benzene 1,4-di(3-methylidene-10-camphosulfonique)
FR2818130A1 (fr) *	2000-12-18	2002-06-21	Oreal	Compositions cosmetiques antisolaires a base d'un melange synergetique de filtres et utilisations
FR2833170B1 (fr) *	2001-12-07	2004-07-16	Oreal	Compositions cosmetiques antisolaires a base d'un melange synergique de filtres et utilisations
FR2833164B1 (fr)	2001-12-07	2004-07-16	Oreal	Compositions cosmetiques antisolaires a base d'un melange synergique de filtres et utilisations
US20040096406A1 (en) *	2002-09-30	2004-05-20	L'oreal	Composition containing ascorbic acid compound and screening agent, method of use
FR2908660B1 (fr) *	2006-11-17	2013-02-08	Gombert Bernard Lucien	Composition terpenique anti-microorganisme
US20120148647A1 (en) *	2009-08-21	2012-06-14	Blueshift Pharma Gmbh	Photoresponsive Sunscreen Composition
FR2949342B1 (fr) *	2009-08-28	2011-10-21	Oreal	Composition contenant une s-triazine siliciee substituee par au moins deux groupes alkylaminobenzoates et un filtre uva hydrophile
ES2548147T3 (es)	2009-11-19	2015-10-14	L'oréal	Composición perfumante coloreada sin difenilacrilato de alquilo que contiene un filtro UVA hidrófilo
FR2993176B1 (fr)	2012-07-13	2014-06-27	Oreal	Composition cosmetique contenant des particules composites filtrantes de taille moyenne superieure a 0,1 micron et des particules de filtre inorganique et une phase aqueuse
ES2822151T5 (es)	2012-07-13	2024-03-18	Oreal	Pigmento compuesto y procedimiento para prepararlo
JP6100896B2 (ja)	2012-07-13	2017-03-22	ロレアル	複合顔料及びその調製方法
JP6096897B2 (ja)	2012-07-13	2017-03-15	ロレアル	化粧料組成物
US11266584B2 (en)	2012-07-13	2022-03-08	L'oreal	Cosmetic composition comprising composite sunscreen particles
FR3001142B1 (fr) *	2013-01-21	2015-06-19	Oreal	Composition cosmetique ou dermatologique comprenant un filtre uva organique hydrophile et au moins une merocyanine
WO2014111567A2 (en) *	2013-01-21	2014-07-24	L'oreal	Cosmetic or dermatological composition comprising a merocyanine and a uva-screening agent of the amino-substituted 2-hydroxybenzophenone type and/or a hydrophilic organic uva-screening agent
CN105705131B (zh)	2013-01-21	2019-12-17	莱雅公司	包含部花青和uv-遮蔽剂的化妆品或皮肤病学组合物
EP3185843B2 (de)	2014-08-28	2025-07-02	L'oreal	Gelzusammensetzung und gel mit einem uv-filter
WO2016083404A1 (fr)	2014-11-24	2016-06-02	L'oreal	Composition cosmetique comprenant un phyllosilicate synthetique et un polyol et/ou un filtre uv
MY182398A (en) *	2015-01-12	2021-01-25	Lg Household & Health Care Ltd	Cosmetic product comprising water-insoluble sponge impregnated with cosmetic composition having ultraviolet ray blocking function
SG11201705650VA (en) *	2015-01-12	2017-08-30	Lg Household & Health Care Ltd	Cosmetic product comprising water-insoluble sponge impregnated with cosmetic composition having ultraviolet ray blocking function
FR3037243B1 (fr)	2015-06-11	2018-11-16	L'oreal	Composition comprenant un filtre uv, un polymere hydrophile reticule anionique, un tensioactif ayant une hlb inferieure ou egale a 5 et un copolymere silicone
US11395794B2 (en)	2015-12-14	2022-07-26	L'oreal	Process for treating keratin fibres using an aqueous composition comprising a combination of particular alkoxysilanes
WO2017102857A1 (en)	2015-12-14	2017-06-22	L'oreal	Composition comprising a combination of particular alkoxysilanes and a fatty substance
FR3045319B1 (fr)	2015-12-18	2019-12-20	L'oreal	Procede de realisation d'une composition cosmetique
FR3045322B1 (fr)	2015-12-18	2019-12-20	L'oreal	Procede de coloration d'une composition cosmetique de base
CN106831503A (zh) *	2016-12-28	2017-06-13	广州星业科技股份有限公司	一种对苯二亚甲基二樟脑磺酸防晒剂的制备方法
FR3068242B1 (fr)	2017-06-30	2019-07-19	L'oreal	Utilisation d'une composition lavante comprenant des tensioactifs et des polymeres cationiques et/ou amphoteres en association avec une composition comprenant des agents benefiques anioniques
FR3073408B1 (fr)	2017-11-15	2019-10-11	L'oreal	Compositions comprenant au moins un polymere acrylique et au moins un filtre organique insoluble
FR3075618B1 (fr)	2017-12-22	2020-02-14	L'oreal	Procede de traitement des fibres keratiniques comprenant l’application d’une composition lavante, d’une compositon de soin puis d’une composition benefique
JP7188945B2 (ja) *	2018-01-30	2022-12-13	株式会社資生堂	日焼け止め化粧料
WO2019151004A1 (ja) *	2018-01-30	2019-08-08	株式会社資生堂	日焼け止め化粧料
FR3083093A1 (fr)	2018-06-28	2020-01-03	L'oreal	Composition photoprotectrice comprenant des particules de silice colloidale
FR3090329B1 (fr)	2018-12-21	2020-12-04	Oreal	Composition comprenant un filtre UV, un polymère hydrophile réticulé anionique, un tensioactif ayant une HLB inférieure ou égale à 5 et un alcane non volatil
FR3103704B1 (fr)	2019-11-29	2022-07-08	Oreal	Composition comprenant un filtre UV, un polymère éthylénique à groupe acide phosphonique et une huile hydrocarbonée
FR3103705B1 (fr)	2019-11-29	2021-12-17	Oreal	Composition comprenant un filtre UV, un polymère séquencé à groupe acide phosphonique et une huile hydrocarbonée
FR3104422B1 (fr)	2019-12-17	2022-03-18	Oreal	Composition cosmétique comprenant des filtres UV hydrosolubles ou hydrodispersibles, des épaississants hydrophiles et des tensioactifs hydrophiles
FR3121044B1 (fr)	2021-03-26	2024-04-19	Oreal	Emulsion avec filtre hydrosoluble neutralisé, huile siliconée non volatile non phénylée, polymère filmogène et émulsionnant polydiméthylméthylsiloxane polyoxyalkyléné linéaire
FR3129598B1 (fr)	2021-11-26	2025-03-14	Oreal	Emulsion eau-dans-huile cosmétique comprenant un filtre UV hydrosoluble particulier, une base, une huile volatile, un polymère filmogène hydrophobe, une polydiméthylméthylsiloxane linéaire polyoxyalkyléné et une vitamine B3.
FR3141062A1 (fr)	2022-10-21	2024-04-26	L'oreal	Composition comprenant un filtre organique lipophile, un filtre organique hydrophile, avec une quantité en poids de phase grasse entre 20 et 70 % et un ratio massique filtres organiques hydrophiles / filtres organiques lipophiles supérieur à 0,3
FR3141061B1 (fr)	2022-10-21	2026-02-06	Oreal	Composition comprenant un filtre organique lipophile, un filtre organique hydrophile, des particules sphériques de silice poreuse, des particules sphériques de cellulose, et une poudre d’acide aminé N-acylé
WO2024083567A1 (en)	2022-10-21	2024-04-25	L'oreal	Composition comprising a lipophilic organic screening agent, a hydrophilic organic screening agent, with an amount by weight of fatty phase between 20 and 70%
FR3141060A1 (fr)	2022-10-21	2024-04-26	L'oreal	Composition comprenant un filtre UV organique lipophile, un filtre UV organique hydrophile et un polymère gélifiant hydrophile spécifique
FR3142897A1 (fr)	2022-12-09	2024-06-14	L'oreal	Composition comprenant un filtre organique hydrodispersible et au moins un complexe polyionique contenant un polysaccharide cationique et un acide non polymérique ayant au moins 3 valeurs de pKa et/ou l’un de ses sels
FR3143344A1 (fr)	2022-12-16	2024-06-21	L'oreal	Composition comprenant un filtre UV, un polymère lipophile convenablement sélectionné, et un carraghénane
FR3149778A1 (fr)	2023-06-16	2024-12-20	L'oreal	Composition comprenant au moins 1 % en poids d’acide ascorbique et un polymère lipophile convenablement sélectionné
FR3149777A1 (fr)	2023-06-16	2024-12-20	L'oreal	Composition cosmétique ou dermatologique aqueuse comprenant une mérocyanine et un filtre UV hydrosoluble
FR3149779A1 (fr)	2023-06-16	2024-12-20	L'oreal	Composition comprenant un filtre UV, au moins 1 % en poids d’acide ascorbique et une gomme de scléroglucane
FR3149780A1 (fr)	2023-06-16	2024-12-20	L'oreal	Composition comprenant au moins 1 % en poids d’acide ascorbique, un filtre UV organique hydrosoluble et des filtres UV addditionnels
FR3156035A1 (fr)	2023-12-01	2025-06-06	L'oreal	Composition comprenant un filtre UV organique lipophile, un tensioactif géminé et un tensioactif anionique dérivé d’un acide aminé
FR3156037A1 (fr)	2023-12-01	2025-06-06	L'oreal	Composition comprenant un filtre UV organique lipophile, un tensioactif géminé et au moins 8 % en poids d’un mono-alcool en C1-C4
FR3156034A1 (fr)	2023-12-01	2025-06-06	L'oreal	Composition comprenant un filtre UV organique lipophile, un tensioactif géminé, un polymère semi-cristallin contenant au moins une chaine d’alkyl acrylate et un polyol
WO2025114438A1 (en)	2023-12-01	2025-06-05	L'oreal	Composition comprising a lipophilic organic uv-screening agent, a gemini surfactant and at least 8% by weight of a c1-c4 monoalcohol
FR3161116A1 (fr)	2024-04-11	2025-10-17	L'oreal	Composition comprenant un filtre UV organique, un polymère gélifiant hydrophile spécifique et un ester d’acide gras et de sucre
FR3161108A1 (fr)	2024-04-11	2025-10-17	L'oreal	Composition comprenant le Drometrizole Trisiloxane, un filtre organique hydrophile, avec un ratio massique filtres organiques hydrophiles / filtres organiques lipophiles supérieur à 0,3, sans alcool
FR3162628A1 (fr)	2024-05-31	2025-12-05	L'oreal	Composition comprenant un filtre UV organique lipophile solide et au moins un phospholipide
FR3167293A1 (fr)	2024-10-10	2026-04-17	L'oreal	Composition photoprotectrice comprenant au moins un monoester d’acide gras linéaire et des filtres liposolubles

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US4165336A (en) *	1973-02-19	1979-08-21	L'oreal	(2-Oxo-3-bornylidene methyl)-benzene sulfonates and derivatives thereof
LU67061A1 (de) *	1973-02-19	1974-09-25
FR2282426A2 (fr) *	1974-08-19	1976-03-19	Oreal	Nouveaux agents sulfones, pour la protection contre les rayons actiniques et compositions cosmetiques les contenant
FR2383904A1 (fr) *	1977-03-15	1978-10-13	Oreal	Nouveaux benzylidene camphres, leur procede de preparation et compositions cosmetiques les contenant
JPS53116360A (en) *	1977-03-15	1978-10-11	Oreal	Novel benzylidene camphor process for preparing same and cosmetic composition containig sae
US4654434A (en) *	1982-06-15	1987-03-31	L'oreal	3-benzylidene-camphors, process for their preparation and their use in protection against UV rays
FR2528420A1 (fr) *	1982-06-15	1983-12-16	Oreal	Nouveaux 3-benzylidene camphres, leur procede de preparation et leur utilisation pour la protection contre les rayons uv
US4663088A (en) *	1982-06-15	1987-05-05	L'oreal	3-benzylidene-camphors, process for their preparation and their use in protection against UV rays

1988
- 1988-11-22 LU LU87394A patent/LU87394A1/fr unknown
1989
- 1989-11-16 EP EP89403146A patent/EP0370867B1/de not_active Expired - Lifetime
- 1989-11-16 AT AT89403146T patent/ATE84301T1/de not_active IP Right Cessation
- 1989-11-16 FR FR898915046A patent/FR2639347B1/fr not_active Expired - Lifetime
- 1989-11-16 DE DE8989403146T patent/DE68904296T2/de not_active Expired - Lifetime
- 1989-11-20 CH CH4157/89A patent/CH680218A5/fr not_active IP Right Cessation
- 1989-11-21 GB GB8926315A patent/GB2225013B/en not_active Expired - Lifetime
- 1989-11-21 BE BE8901239A patent/BE1002272A3/fr not_active IP Right Cessation
- 1989-11-21 IT IT06802989A patent/IT1238406B/it active IP Right Grant
- 1989-11-22 JP JP1304562A patent/JPH02231463A/ja active Pending
- 1989-11-22 US US07/439,977 patent/US5064641A/en not_active Expired - Lifetime
- 1989-11-22 CA CA002003597A patent/CA2003597C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE68904296D1 (de)	1993-02-18
ATE84301T1 (de)	1993-01-15
DE68904296T2 (de)	1993-05-06
EP0370867A1 (de)	1990-05-30
CA2003597A1 (fr)	1990-05-22
CA2003597C (fr)	1999-11-09
BE1002272A3 (fr)	1990-11-13
IT8968029A1 (it)	1991-05-21
CH680218A5 (de)	1992-07-15
GB2225013A (en)	1990-05-23
IT1238406B (it)	1993-07-26
GB8926315D0 (en)	1990-01-10
GB2225013B (en)	1992-06-03
JPH02231463A (ja)	1990-09-13
US5064641A (en)	1991-11-12
FR2639347A1 (fr)	1990-05-25
FR2639347B1 (fr)	1991-04-05
EP0370867B1 (de)	1993-01-07
IT8968029A0 (it)	1989-11-21

Publication	Publication Date	Title
CA2003597C (fr)	1999-11-09	Sels de metaux polyvalents de derives sulfones du benzylidene-camphre et leur utilisation pour la protection de la peau contre le rayonnement ultraviolet
EP0457687B1 (de)	1993-12-15	Filtrierende kosmetische Emulsion, die einen UV-A-Filter und einen UV-B-Filter enthält
US6440401B1 (en)	2002-08-27	2-phenyl-benzimidazolesulfonic acids as UV-B filters
CA2065117C (fr)	2002-12-24	Derives s-triaziniques portant des substituants benzalmalonates, leur procede de preparation, compositions cosmetiques filtrantes les contenant et leur utilisation pour proteger la peau et les cheveux du rayonnement ultraviolet
CA1211451A (fr)	1986-09-16	Sulfonamides derives du 3-benzylidene camphre et leur application en tant que filtres u.v., notamment dans des compositions cosmetiques
BE1000652A4 (fr)	1989-02-28	Composition cosmetique contenant des derives hydroxyles de chalcone et son utilisation pour la protection de la peau et des cheveux contre les radiations lumineuses, nouveaux derives hydroxyles de chalcone utilises et leur procede de preparation.
CH658451A5 (fr)	1986-11-14	Derives du 3-benzylidene camphre, leur procede de preparation et leur utilisation pour la protection contre les rayons uv.
CA1298789C (fr)	1992-04-14	Composition cosmetique photostable contenant un derive d'ethylrutine a titre d'agent de protection contre la lumiere solaire et son utilisation pourla protection de la peau et descheveux
CA2071277A1 (fr)	1992-12-14	Composition cosmetique filtrante contenant un melange d'acide benzene 1,4-di(3-methylidene-10-camphosulfonique) partiellement ou totalement neutralise et de nanopigments d'oxydes metalliques
FR2540380A1 (fr)	1984-08-10	Composition cosmetique pour la protection contre le rayonnement ultraviolet et son utilisation a cet effet
FR2645148A1 (fr)	1990-10-05	Compositions cosmetiques et pharmaceutiques contenant des derives hydrophiles du benzylidene camphre et nouveaux derives sulfones hydrophiles du benzylidene camphre
EP0293579B1 (de)	1991-04-10	Kosmetisches Mittel zum Schutz gegen UV-Strahlung, das einen Kupferkomplex des 3,5-Diisopropyl-salicylsäure enthält sowie dessen Verwendung in Kosmetika
FR2717808A1 (fr)	1995-09-29	Composition cosmétique stable à la lumière.
LU85139A1 (fr)	1985-09-12	Nouveaux derives du 3-benzylidene camphre,leur procede de preparation et leur utilisation en tant qu'agents de protection contre les rayons uv et en tant que medicaments
LU87089A1 (fr)	1989-07-07	Nouveaux sulfonamides du benzylidene camphre derivant d'aminoacides et leur application en cosmetique,notamment en tant que filtres solaires
FR2854157A1 (fr)	2004-10-29	Derives de s-triazine possedant 3 groupements para-aminobenzalmalonates particuliers; compositions cosmetiques photoprotectrices contenant ces derives; utilisations desdits derives de s-triazine
FR2801206A1 (fr)	2001-05-25	Compositions filtrantes contenant l'association d'un derive d'acide naphtalene mono-ou polycarboxylique et d'un filtre uv derive d'hydroxyphenylbenzotriazole
EP1278718B1 (de)	2003-12-17	Neue aminsäure-derivate, verfahren zur ihrer herstellung, ihre zusammensetzungen und ihre verwendung als sonnenfilter
EP1454896A1 (de)	2004-09-08	Amine-, Amid-, Sulfonamid- oder Karbamatderivate von Benzylmalonsäuresalzen und diese enthaltende kosmetische Lichtschutzzusammensetzungen
WO2002049598A2 (fr)	2002-06-27	Compositions cosmetiques antisolaires a base d'un melange synergique de filtres et utilisations