NO863876L - T-alkenylperoksyestere og bruk av dem som initiatorer og herdemidler. - Google Patents

T-alkenylperoksyestere og bruk av dem som initiatorer og herdemidler.

Info

Publication number: NO863876L
Authority: NO; Norway
Prior art keywords: group; methyl; buten; carbon atoms; peroxyester
Prior art date: 1985-09-30

Application number

NO863876A

Other languages

English (en)

Norwegian (no)

Other versions

NO863876D0 (no

Inventor

John Meijer

Hans Westmijze

Eltjo Boelema

Original Assignee

Akzo Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-09-30

Filing date

1986-09-29

Publication date

1987-03-31

1986-09-29 Application filed by Akzo Nv filed Critical Akzo Nv

1986-09-29 Publication of NO863876D0 publication Critical patent/NO863876D0/no

1987-03-31 Publication of NO863876L publication Critical patent/NO863876L/no

Links

239000003999 initiator Substances 0.000 title description 13
-1 2-methyl-3-butene-2-yl Chemical group 0.000 claims abstract description 32
229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 24
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 16
125000000217 alkyl group Chemical group 0.000 claims description 15
238000000034 method Methods 0.000 claims description 9
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
150000001875 compounds Chemical class 0.000 claims description 6
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
125000002947 alkylene group Chemical group 0.000 claims description 5
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
239000005977 Ethylene Substances 0.000 claims description 3
125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 claims description 2
125000004955 1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])C1([H])[*:2] 0.000 claims description 2
125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 2
125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 claims description 2
125000003545 alkoxy group Chemical group 0.000 claims description 2
125000001309 chloro group Chemical group Cl* 0.000 claims description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 claims 1
UZMAEXSJDVBTNL-UHFFFAOYSA-N 2-methylbut-3-en-2-yl 2-[2-(2-methylbut-3-en-2-ylperoxy)-2-oxoethoxy]ethaneperoxoate Chemical compound C=CC(C)(C)OOC(=O)COCC(=O)OOC(C)(C)C=C UZMAEXSJDVBTNL-UHFFFAOYSA-N 0.000 claims 1
HWOSCDHJTMKUOR-UHFFFAOYSA-N bis(2-methylbut-3-en-2-yl) cyclohexane-1,4-dicarboperoxoate Chemical compound C=CC(C)(C)OOC(=O)C1CCC(C(=O)OOC(C)(C)C=C)CC1 HWOSCDHJTMKUOR-UHFFFAOYSA-N 0.000 claims 1
125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 claims 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 1
UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 abstract description 9
239000003795 chemical substances by application Substances 0.000 abstract description 5
238000000354 decomposition reaction Methods 0.000 abstract description 5
125000000864 peroxy group Chemical group O(O*)* 0.000 abstract description 5
230000000875 corresponding effect Effects 0.000 abstract 1
239000003505 polymerization initiator Substances 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 14
239000002253 acid Substances 0.000 description 7
238000006116 polymerization reaction Methods 0.000 description 7
239000000047 product Substances 0.000 description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
230000035484 reaction time Effects 0.000 description 5
DACKWPCRUFMCRC-UHFFFAOYSA-N 3-hydroperoxy-3-methylbut-1-ene Chemical compound OOC(C)(C)C=C DACKWPCRUFMCRC-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
239000000839 emulsion Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
239000012044 organic layer Substances 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
FEMODODLYQTCQA-UHFFFAOYSA-N 2-methylbut-3-en-2-yl benzenecarboperoxoate Chemical compound C=CC(C)(C)OOC(=O)C1=CC=CC=C1 FEMODODLYQTCQA-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000000178 monomer Substances 0.000 description 3
229920005989 resin Polymers 0.000 description 3
239000011347 resin Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
229920006305 unsaturated polyester Polymers 0.000 description 3
JVSFQJZRHXAUGT-UHFFFAOYSA-N 2,2-dimethylpropanoyl chloride Chemical compound CC(C)(C)C(Cl)=O JVSFQJZRHXAUGT-UHFFFAOYSA-N 0.000 description 2
ATCRIUVQKHMXSH-UHFFFAOYSA-N 2,4-dichlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1Cl ATCRIUVQKHMXSH-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
QEVGZEDELICMKH-UHFFFAOYSA-L 2-(carboxylatomethoxy)acetate Chemical compound [O-]C(=O)COCC([O-])=O QEVGZEDELICMKH-UHFFFAOYSA-L 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
YZGQDNOIGFBYKF-UHFFFAOYSA-N Ethoxyacetic acid Chemical compound CCOCC(O)=O YZGQDNOIGFBYKF-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
238000004566 IR spectroscopy Methods 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000007900 aqueous suspension Substances 0.000 description 2
229940067597 azelate Drugs 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
239000012230 colorless oil Substances 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 2
TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
239000003995 emulsifying agent Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000007789 gas Substances 0.000 description 2
MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
LCPDWSOZIOUXRV-UHFFFAOYSA-N phenoxyacetic acid Chemical compound OC(=O)COC1=CC=CC=C1 LCPDWSOZIOUXRV-UHFFFAOYSA-N 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
239000012258 stirred mixture Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 2
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
YEYATOKHYFCMLF-UHFFFAOYSA-N 1-ethenyl-1,2-dihydroperoxycyclohexane Chemical compound OOC1CCCCC1(OO)C=C YEYATOKHYFCMLF-UHFFFAOYSA-N 0.000 description 1
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
VYDBDDDTZMNNMM-UHFFFAOYSA-N 11:0(10Me,10Me) Chemical compound CC(C)(C)CCCCCCCCC(O)=O VYDBDDDTZMNNMM-UHFFFAOYSA-N 0.000 description 1
BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
BZAZNULYLRVMSW-UHFFFAOYSA-N 2-Methyl-2-buten-3-ol Natural products CC(C)=C(C)O BZAZNULYLRVMSW-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
IKCLCGXPQILATA-UHFFFAOYSA-N 2-chlorobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1Cl IKCLCGXPQILATA-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
ZAHGAZCHKBRHPU-UHFFFAOYSA-N 2-methylbut-3-en-2-yl 10,10-dimethylundecaneperoxoate Chemical compound CC(C)(C)CCCCCCCCC(=O)OOC(C)(C)C=C ZAHGAZCHKBRHPU-UHFFFAOYSA-N 0.000 description 1
OMTCPUBEIPYOBL-UHFFFAOYSA-N 2-methylbut-3-en-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)C(=O)OOC(C)(C)C=C OMTCPUBEIPYOBL-UHFFFAOYSA-N 0.000 description 1
NTNGPGZULWEJDR-UHFFFAOYSA-N 2-methylbut-3-en-2-yl 3,3-dimethylbutaneperoxoate Chemical compound CC(C)(C)CC(=O)OOC(C)(C)C=C NTNGPGZULWEJDR-UHFFFAOYSA-N 0.000 description 1
UFCARIRYFLVYHQ-UHFFFAOYSA-N 2-methylbut-3-en-2-yl 6,6-dimethylheptaneperoxoate Chemical compound CC(C)(C)CCCCC(=O)OOC(C)(C)C=C UFCARIRYFLVYHQ-UHFFFAOYSA-N 0.000 description 1
COHZYTGHCHFLOD-UHFFFAOYSA-N 2-methylbut-3-en-2-yl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C=C COHZYTGHCHFLOD-UHFFFAOYSA-N 0.000 description 1
MPBHYBPBBXYZGE-UHFFFAOYSA-N 2-methylbut-3-en-2-yl dodecaneperoxoate Chemical compound CCCCCCCCCCCC(=O)OOC(C)(C)C=C MPBHYBPBBXYZGE-UHFFFAOYSA-N 0.000 description 1
GNCFATVTYPKAJW-UHFFFAOYSA-N 2-methylbut-3-en-2-yl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C=C GNCFATVTYPKAJW-UHFFFAOYSA-N 0.000 description 1
HUHQJVWTZQJWRM-UHFFFAOYSA-N 2-methylbut-3-en-2-yl prop-2-eneperoxoate Chemical compound C=CC(C)(C)OOC(=O)C=C HUHQJVWTZQJWRM-UHFFFAOYSA-N 0.000 description 1
GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
NUVJIDAAKJLVQY-UHFFFAOYSA-N 3-ethyl-3-hydroperoxypent-1-ene Chemical compound CCC(CC)(OO)C=C NUVJIDAAKJLVQY-UHFFFAOYSA-N 0.000 description 1
LUQYSDQMFJDIOI-UHFFFAOYSA-N 3-hydroperoxy-3,4-dimethylpent-1-ene Chemical compound CC(C)C(C)(OO)C=C LUQYSDQMFJDIOI-UHFFFAOYSA-N 0.000 description 1
IXFPAGTVBURROZ-UHFFFAOYSA-N 3-hydroperoxy-3-methylhex-1-ene Chemical compound CCCC(C)(OO)C=C IXFPAGTVBURROZ-UHFFFAOYSA-N 0.000 description 1
UEXZUFJYNCBXAJ-UHFFFAOYSA-N 3-hydroperoxy-3-methylpent-1-ene Chemical compound CCC(C)(OO)C=C UEXZUFJYNCBXAJ-UHFFFAOYSA-N 0.000 description 1
DJMPEKROMMMKOK-UHFFFAOYSA-N 3-hydroperoxy-4-methyl-3-propan-2-ylpent-1-ene Chemical compound CC(C)C(OO)(C=C)C(C)C DJMPEKROMMMKOK-UHFFFAOYSA-N 0.000 description 1
HBTQFOMMZOLPEN-UHFFFAOYSA-N 4-ethenyl-4-hydroperoxyheptane Chemical compound CCCC(C=C)(OO)CCC HBTQFOMMZOLPEN-UHFFFAOYSA-N 0.000 description 1
GCFSGCIYEVPPIL-UHFFFAOYSA-N 4-hydroperoxy-2,3,4-trimethylpent-2-ene Chemical compound CC(C)=C(C)C(C)(C)OO GCFSGCIYEVPPIL-UHFFFAOYSA-N 0.000 description 1
KZPLINHISKOYCK-UHFFFAOYSA-N 4-hydroperoxy-4-methylpent-2-ene Chemical compound CC=CC(C)(C)OO KZPLINHISKOYCK-UHFFFAOYSA-N 0.000 description 1
VBHRLSQLJDHSCO-UHFFFAOYSA-N 5,5-dimethylhexanoic acid Chemical compound CC(C)(C)CCCC(O)=O VBHRLSQLJDHSCO-UHFFFAOYSA-N 0.000 description 1
AAOISIQFPPAFQO-UHFFFAOYSA-N 7:0(6Me,6Me) Chemical compound CC(C)(C)CCCCC(O)=O AAOISIQFPPAFQO-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
239000008351 acetate buffer Substances 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
229920000180 alkyd Polymers 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000003708 ampul Substances 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
239000007798 antifreeze agent Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
VJFJOXWSCNWKMY-UHFFFAOYSA-N bis(2-methylbut-3-en-2-yl) benzene-1,3-dicarboperoxoate Chemical compound C=CC(C)(C)OOC(=O)C1=CC=CC(C(=O)OOC(C)(C)C=C)=C1 VJFJOXWSCNWKMY-UHFFFAOYSA-N 0.000 description 1
FMAJPFWWDGLWPI-UHFFFAOYSA-N bis(2-methylbut-3-en-2-yl) decanediperoxoate Chemical compound C=CC(C)(C)OOC(=O)CCCCCCCCC(=O)OOC(C)(C)C=C FMAJPFWWDGLWPI-UHFFFAOYSA-N 0.000 description 1
IGZPOVNXNBLAFM-UHFFFAOYSA-N bis(2-methylbut-3-en-2-yl) dodecanediperoxoate Chemical compound C=CC(C)(C)OOC(=O)CCCCCCCCCCC(=O)OOC(C)(C)C=C IGZPOVNXNBLAFM-UHFFFAOYSA-N 0.000 description 1
MEIHZZXDYPNCPP-UHFFFAOYSA-N bis(2-methylbut-3-en-2-yl) pentanediperoxoate Chemical compound C=CC(C)(C)OOC(=O)CCCC(=O)OOC(C)(C)C=C MEIHZZXDYPNCPP-UHFFFAOYSA-N 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000012320 chlorinating reagent Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
YVWBQGFBSVLPIK-UHFFFAOYSA-N cyclohex-2-ene-1-carboxylic acid Chemical compound OC(=O)C1CCCC=C1 YVWBQGFBSVLPIK-UHFFFAOYSA-N 0.000 description 1
QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
125000004956 cyclohexylene group Chemical group 0.000 description 1
239000003975 dentin desensitizing agent Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000000586 desensitisation Methods 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
FPIQZBQZKBKLEI-UHFFFAOYSA-N ethyl 1-[[2-chloroethyl(nitroso)carbamoyl]amino]cyclohexane-1-carboxylate Chemical compound ClCCN(N=O)C(=O)NC1(C(=O)OCC)CCCCC1 FPIQZBQZKBKLEI-UHFFFAOYSA-N 0.000 description 1
239000000945 filler Substances 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 1
RMIODHQZRUFFFF-UHFFFAOYSA-N methoxyacetic acid Chemical compound COCC(O)=O RMIODHQZRUFFFF-UHFFFAOYSA-N 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000006072 paste Substances 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000002990 reinforced plastic Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/38—Peroxy compounds the —O—O— group being bound between a >C=O group and a carbon atom, not further substituted by oxygen atoms, i.e. esters of peroxy acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Medicinal Chemistry (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Polymers & Plastics (AREA)
Polymerization Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Macromonomer-Based Addition Polymer (AREA)
Adhesives Or Adhesive Processes (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

NO863876A 1985-09-30 1986-09-29 T-alkenylperoksyestere og bruk av dem som initiatorer og herdemidler. NO863876L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
NL8502661		1985-09-30

Publications (2)

Publication Number	Publication Date
NO863876D0 NO863876D0 (no)	1986-09-29
NO863876L true NO863876L (no)	1987-03-31

Family

ID=19846639

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO863876A NO863876L (no)	1985-09-30	1986-09-29	T-alkenylperoksyestere og bruk av dem som initiatorer og herdemidler.

Country Status (9)

Country	Link
US (2)	US4705888A (ja)
EP (1)	EP0219900B1 (ja)
JP (1)	JPS6281366A (ja)
AT (1)	ATE56431T1 (ja)
AU (1)	AU586285B2 (ja)
CA (1)	CA1256118A (ja)
DE (1)	DE3674135D1 (ja)
FI (1)	FI863916A7 (ja)
NO (1)	NO863876L (ja)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3631815A1 (de) *	1986-09-19	1988-03-31	Basf Ag	Verfahren zur herstellung von polymaleinsaeure
US5202386A (en) *	1987-12-14	1993-04-13	Akzo Nv	Modification of (co)polymers employing organic peroxides
NL8703014A (nl) *	1987-12-14	1989-07-03	Akzo Nv	Bereiding van epoxidegroepen-bevattende (co)polymeren onder toepassing van organische peroxiden.
US5051531A (en) *	1988-05-31	1991-09-24	Atochem North America, Inc.	Antioxidant-peroxides
JP2762109B2 (ja) *	1989-04-11	1998-06-04	日本メクトロン株式会社	アクリルエラストマー組成物の製造法
JPH0372505A (ja) *	1989-05-24	1991-03-27	Sanyo Chem Ind Ltd	電子写真用トナーバインダー
AU672298B2 (en) *	1989-11-01	1996-09-26	Commonwealth Scientific And Industrial Research Organisation	Control of molecular weight and end group functionality in polymers
ATE154343T1 (de) *	1989-11-01	1997-06-15	Commw Scient Ind Res Org	Kontrolle des molekulargewichts und der endgruppenfunktionalität in polymeren unter verwendung ungesättigter peroxide als kettenübertragungsmittel
JPH05501573A (ja) *	1989-11-15	1993-03-25	アクゾ　ナムローゼ　フェンノートシャップ	アリルヒドロペルオキシド連鎖移動剤
US5470945A (en) *	1990-02-05	1995-11-28	Battelle Memorial Institute	Thermally reversible isocyanate-based polymers
JPH0433924A (ja) *	1990-05-29	1992-02-05	Nippon Oil & Fats Co Ltd	ポリメリックペルオキシド重合開始剤及びブロック共重合体の製造方法
US5292839A (en) *	1990-10-16	1994-03-08	Akzo N.V.	Allyl peroxyketal chain transfer agents
TW426707B (en) *	1997-07-24	2001-03-21	Akzo Nobel Nv	Emulsions of peroxyesters
DE60011469T2 (de) *	1999-12-22	2005-06-09	Akzo Nobel N.V.	Verwendung von ungesättigten diacyl oder acylkarbonatgruppen-enthaltenden peroxiden in vernetzungsverfahren
UA77245C2 (uk)	2001-12-21	2006-11-15	Акцо Нобель Н.В.	Спосіб полімеризації суміші, яка містить вінілхлоридний мономер
CN109628184A (zh) *	2018-12-29	2019-04-16	中润油新能源股份有限公司	一种改变甲醇汽油冷启动性的添加活性剂及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3451989A (en) *	1965-07-09	1969-06-24	Nat Distillers Chem Corp	Peroxy compounds,and polymerization of ethylenically unsaturated hydrocarbons using same as catalysts
BE693035A (ja) *	1966-03-03	1967-07-03
US3451981A (en) *	1966-06-29	1969-06-24	Nat Distillers Chem Corp	Polymerization of vinyl chloride and mixtures of vinyl acetate and ethylene using tertiary alkyl per-3-alkenoates as catalysts
US3624123A (en) *	1968-05-01	1971-11-30	Argus Chem	t-ALKYL PERESTERS OF t-HYDROPEROXIDES
US3726847A (en) *	1968-05-01	1973-04-10	Argus Chem	Polymerization method employing t-alkyl peresters of t-hydroperoxides
US4057567A (en) *	1968-05-01	1977-11-08	Argus Chemical Corporation	Polymerization method and t-alkyl peresters of t-hydroperoxides for use therein
BE754577A (ja) *	1969-08-08	1971-02-08	Wacker Chemie Gmbh
US3687867A (en) *	1970-04-08	1972-08-29	Argus Chem	Novel co-initiator systems
US3988261A (en) *	1975-07-28	1976-10-26	Ppg Industries, Inc.	Frozen organic peroxide emulsion
US4079074A (en) *	1977-01-06	1978-03-14	Pennwalt Corporation	Unsymmetrical diperoxides and processes of use in polymerizing unsaturated monomers
US4219675A (en) *	1979-02-06	1980-08-26	Pennwalt Corporation	Batch process for manufacturing and purifying liquid organic peroxide by distillation

1986
- 1986-09-04 US US06/903,955 patent/US4705888A/en not_active Expired - Fee Related
- 1986-09-26 DE DE8686201699T patent/DE3674135D1/de not_active Expired - Lifetime
- 1986-09-26 EP EP86201699A patent/EP0219900B1/en not_active Expired - Lifetime
- 1986-09-26 AT AT86201699T patent/ATE56431T1/de not_active IP Right Cessation
- 1986-09-26 JP JP61226377A patent/JPS6281366A/ja active Pending
- 1986-09-29 CA CA000519313A patent/CA1256118A/en not_active Expired
- 1986-09-29 NO NO863876A patent/NO863876L/no unknown
- 1986-09-29 AU AU63215/86A patent/AU586285B2/en not_active Ceased
- 1986-09-29 FI FI863916A patent/FI863916A7/fi not_active Application Discontinuation
1987
- 1987-06-24 US US07/066,002 patent/US4837287A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
NO863876D0 (no)	1986-09-29
US4837287A (en)	1989-06-06
EP0219900A1 (en)	1987-04-29
FI863916L (fi)	1987-03-31
AU586285B2 (en)	1989-07-06
DE3674135D1 (de)	1990-10-18
FI863916A0 (fi)	1986-09-29
US4705888A (en)	1987-11-10
JPS6281366A (ja)	1987-04-14
CA1256118A (en)	1989-06-20
EP0219900B1 (en)	1990-09-12
FI863916A7 (fi)	1987-03-31
ATE56431T1 (de)	1990-09-15
AU6321586A (en)	1987-04-02

Publication	Publication Date	Title
NO863876L (no)	1987-03-31	T-alkenylperoksyestere og bruk av dem som initiatorer og herdemidler.
AU5143496A (en)	1996-09-23	Cyclic ketone peroxides as polymer initiators
EP0186215A2 (en)	1986-07-02	Fluorine-containing diacylperoxides and use thereof
US4008175A (en)	1977-02-15	Organic acid anhydride-peroxydicarbonate composition
US3660468A (en)	1972-05-02	Carboxy-peresters
US3446831A (en)	1969-05-27	Esters of 1,1,3,3-tetramethylbutyl hydroperoxide
US3222327A (en)	1965-12-07	Peroxide catalysts and polymerization processes employing the same
US3528956A (en)	1970-09-15	Process for the polymerization of unsaturated monomers using 4-substituted dicyclohexyl peroxydicarbonates as initiators
KR960004116B1 (ko)	1996-03-26	고분자 과산화물 중합개시제, 및 블럭 공중합체의 제조방법
US4455412A (en)	1984-06-19	Process for polymerization using monoperoxyoxalic acid diesters
CA1159816A (en)	1984-01-03	Peroxygen compound-6-o-alkanoyl-l-ascorbic acid redox catalyst system for vinyl monomer polymerization
US4269958A (en)	1981-05-26	Peroxygen compound-stannous chloride redox catalyst system for suspension polymerization of vinyl chloride
EP0384660B1 (en)	1994-06-29	Ester-type polymeric peroxides
US5012010A (en)	1991-04-30	T-ethyl-1,5-dimethylhexylperoxy acid esters
JP2550644B2 (ja)	1996-11-06	環式モノペルオキシケタール
JPS6332068B2 (ja)	1988-06-28
US4543401A (en)	1985-09-24	Peroxygen compound-isoascorbic acid redox catalyst system for suspension polymerization of vinyl chloride
CA2189557A1 (en)	1995-11-16	Use of peroxyacids as molecular weight regulators
US5783647A (en)	1998-07-21	1,1,2,2-tetramethylpropylperoxy esters and method for preparing vinyl polymers
US4370459A (en)	1983-01-25	Polymerizing unsaturated monomers with gem-diperoxyester catalyst
US3316228A (en)	1967-04-25	Diperoxycarbonic acid anhydrides and polymerization processes employing same
JP2743487B2 (ja)	1998-04-22	塩化ビニルの重合方法および重合開始剤
EP0049966A1 (en)	1982-04-21	Use of diperesters in the polymerisation of vinyl chloride monomer
US4075199A (en)	1978-02-21	Tertiary aliphatic alpha-peroxyazo compounds
JP3165525B2 (ja)	2001-05-14	ビニル系単量体の重合方法