PL399308A1 - Proton cation ionic liquids (chloroalkyl)dimethyl ammonium and a process for their preparation - Google Patents
Proton cation ionic liquids (chloroalkyl)dimethyl ammonium and a process for their preparationInfo
- Publication number
- PL399308A1 PL399308A1 PL399308A PL39930812A PL399308A1 PL 399308 A1 PL399308 A1 PL 399308A1 PL 399308 A PL399308 A PL 399308A PL 39930812 A PL39930812 A PL 39930812A PL 399308 A1 PL399308 A1 PL 399308A1
- Authority
- PL
- Poland
- Prior art keywords
- chloroalkyl
- dimethylammonium
- ionic liquids
- sulfates
- chain
- Prior art date
Links
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 title abstract 5
- 125000004965 chloroalkyl group Chemical group 0.000 title abstract 5
- 239000002608 ionic liquid Substances 0.000 title abstract 3
- 150000001768 cations Chemical class 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 3
- -1 tetrafluoroborates Chemical class 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 abstract 2
- 150000002823 nitrates Chemical class 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 1
- 239000005648 plant growth regulator Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku sa protonowe ciecze jonowe z kationem (chloroalkilo)dimetyloamoniowym oraz sposób ich otrzymywania, majace zastosowanie jako regulatory wzrostu roslin. Protonowe ciecze jonowe z kationem (chloroalkilo)dimetyloamoniowym o wzorze ogólnym 2, w którym, n oznacza ilosc grup metylenowych, przy czym n = od 1 do 3, natomiast A- oznacza anion organiczny alkilokarboksylowy lancuchowy lub rozgaleziony o dlugosci lancucha alkilowego od 1 do 10 atomów wegla, bis(trifluorometylosulfonylo)imidkowy lub nieorganiczny z grupy: azotanów(III) lub azotanów(V) lub wodorosiarczanów(IV) lub wodorosiarczanów(VI) lub siarczanów(IV), siarczanów(VI) lub tetrafluoroboranów lub heksafluorofosforanów. Sposób polega na tym, ze chlorowodorek (chloroalkilo)dimetyloamoniowy, rozpuszcza sie w krótkolancuchowym alkoholu alifatycznym, korzystnie w metanolu, miesza sie z alkoholanowym roztworem soli sodowej lub potasowej, lub litowej, lub amonowej kwasu alkilokarboksylowego lancuchowego lub rozgalezionego o dlugosci lancucha alkilowego od 1 do 10 atomów wegla, w stosunku molowym chlorowodorku (chloroalkilo)dimetyloamoniowego do soli kwasu organicznego od 1:1 do 1:1,05, korzystnie 1 : 1, w temperaturze od 293 do 363 K, korzystnie 293 K, w czasie co najmniej 2 minut nastepnie odsacza sie nieorganiczny produkt uboczny, po czym z przesaczu usuwa sie rozpuszczalnik.The subject of the invention are proton ionic liquids with a (chloroalkyl) dimethylammonium cation and a method of obtaining them, which are used as plant growth regulators. Proton ionic liquids with a cation (chloroalkyl) dimethylammonium of general formula 2, in which n is the number of methylene groups, where n = from 1 to 3, while A- is the organic chain or branched alkyl carboxylic anion with an alkyl chain length of 1 to 10 carbon, bis (trifluoromethylsulfonyl) imide or inorganic atoms from the group: nitrates (III) or nitrates (V) or hydrogen sulfates (IV) or hydrogen sulfates (VI) or sulfates (IV), sulfates (VI) or tetrafluoroborates or hexafluorophosphates. The method consists in dissolving (chloroalkyl) dimethylammonium hydrochloride in a short-chain aliphatic alcohol, preferably in methanol, mixing with an alcoholate solution of sodium or potassium or lithium or ammonium chain or branched alkyl carboxylic acid with an alkyl chain length of 1 to 1 10 carbon atoms, in a molar ratio of (chloroalkyl) dimethylammonium hydrochloride to organic salt from 1: 1 to 1: 1.05, preferably 1: 1, at a temperature of 293 to 363 K, preferably 293 K, for at least 2 minutes the inorganic by-product is then filtered off, then the solvent is removed from the filtrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL399308A PL221139B1 (en) | 2012-05-25 | 2012-05-25 | Proton cation ionic liquids (chloroalkyl)dimethyl ammonium and a process for their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL399308A PL221139B1 (en) | 2012-05-25 | 2012-05-25 | Proton cation ionic liquids (chloroalkyl)dimethyl ammonium and a process for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL399308A1 true PL399308A1 (en) | 2013-12-09 |
| PL221139B1 PL221139B1 (en) | 2016-02-29 |
Family
ID=49684132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL399308A PL221139B1 (en) | 2012-05-25 | 2012-05-25 | Proton cation ionic liquids (chloroalkyl)dimethyl ammonium and a process for their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL221139B1 (en) |
-
2012
- 2012-05-25 PL PL399308A patent/PL221139B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL221139B1 (en) | 2016-02-29 |
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