PL416320A1 - New ionic liquids with alkyl [2(2-hydroxyethoxy)ethyl]dimethylammonium cation and formate anion and method for obtaining them - Google Patents
New ionic liquids with alkyl [2(2-hydroxyethoxy)ethyl]dimethylammonium cation and formate anion and method for obtaining themInfo
- Publication number
- PL416320A1 PL416320A1 PL416320A PL41632016A PL416320A1 PL 416320 A1 PL416320 A1 PL 416320A1 PL 416320 A PL416320 A PL 416320A PL 41632016 A PL41632016 A PL 41632016A PL 416320 A1 PL416320 A1 PL 416320A1
- Authority
- PL
- Poland
- Prior art keywords
- ethyl
- hydroxyethoxy
- ionic liquids
- alkyl
- obtaining
- Prior art date
Links
- -1 alkyl [2(2-hydroxyethoxy)ethyl]dimethylammonium Chemical compound 0.000 title abstract 3
- 239000002608 ionic liquid Substances 0.000 title abstract 3
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 title abstract 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 238000005349 anion exchange Methods 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Przedmiotem zgłoszenia są nowe ciecze jonowe z kationem alkilo[2-(2-hydroksyetoksy)etylo]dimetyloamoniowym i anionem mrówczanowym, o wzorze ogólnym 1, gdzie R oznacza podstawnik alkilowy prostołańcuchowy zawierający od czterech do szesnastu atomów węgla. Zgłoszenie obejmuje też sposób ich otrzymywania polega na tym, że czwartorzędowy bromek alkilo[2-(2-hydroksyetoksy)etylo]dimetyloamoniowy o wzorze ogólnym 2, w którym R oznacza podstawnik alkilowy prostołańcuchowy zawierający od czterech do szesnastu atomów węgla, poddaje się reakcji wymiany anionu z solą sodową lub potasową, lub litową, lub amonową kwasu mrówkowego w stosunku molowym czwartorzędowej soli amoniowej do soli kwasu w stosunku molowym 1:1, w temperaturze poniżej 100°C, w środowisku wodnym, po czym produkt reakcji wydziela się metodą ekstrakcji dwufazowej za pomocą rozpuszczalnika organicznego z grupy: chloroform, albo dichlorometan, albo toluen, albo octan etylu, po czym oddziela się fazę organiczną, dalej rozpuszczalnik usuwa się, a otrzymany produkt suszy. Przedmiotowe ciecze jonowe mają zastosowanie jako bakteriobójcze środki powierzchniowo czynne.The subject of the application are new ionic liquids with an alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium cation and a formate anion of the general formula 1, where R is a straight chain alkyl substituent containing from four to sixteen carbon atoms. The application also includes a method for their preparation in which the quaternary alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium bromide of general formula 2, wherein R is a straight chain alkyl substituent containing from four to sixteen carbon atoms, is subjected to an anion exchange reaction with a sodium or potassium or lithium or ammonium salt of formic acid in a molar ratio of quaternary ammonium salt to the acid salt in a molar ratio of 1: 1, at a temperature below 100 ° C, in an aqueous medium, after which the reaction product is isolated by two-phase extraction by by means of an organic solvent from the group: chloroform or dichloromethane or toluene or ethyl acetate, the organic phase is separated off, the solvent is removed and the product obtained is dried. The ionic liquids concerned are used as bactericidal surfactants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL416320A PL230039B1 (en) | 2016-02-29 | 2016-02-29 | New ionic liquids with alkyl [2(2-hydroxyethoxy)ethyl]dimethylammonium cation and formate anion and method for obtaining them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL416320A PL230039B1 (en) | 2016-02-29 | 2016-02-29 | New ionic liquids with alkyl [2(2-hydroxyethoxy)ethyl]dimethylammonium cation and formate anion and method for obtaining them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL416320A1 true PL416320A1 (en) | 2017-09-11 |
| PL230039B1 PL230039B1 (en) | 2018-09-28 |
Family
ID=59771913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL416320A PL230039B1 (en) | 2016-02-29 | 2016-02-29 | New ionic liquids with alkyl [2(2-hydroxyethoxy)ethyl]dimethylammonium cation and formate anion and method for obtaining them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL230039B1 (en) |
-
2016
- 2016-02-29 PL PL416320A patent/PL230039B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL230039B1 (en) | 2018-09-28 |
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