PL401266A1 - Oxisalt in two component system tungstate (VI) metal molybdate (VI) a rare earth element and a method for producing a two component oxisalts a two component tungstate (VI) metal molybdate (VI) a rare earth element - Google Patents
Oxisalt in two component system tungstate (VI) metal molybdate (VI) a rare earth element and a method for producing a two component oxisalts a two component tungstate (VI) metal molybdate (VI) a rare earth elementInfo
- Publication number
- PL401266A1 PL401266A1 PL401266A PL40126612A PL401266A1 PL 401266 A1 PL401266 A1 PL 401266A1 PL 401266 A PL401266 A PL 401266A PL 40126612 A PL40126612 A PL 40126612A PL 401266 A1 PL401266 A1 PL 401266A1
- Authority
- PL
- Poland
- Prior art keywords
- molybdate
- iii
- component
- tungstate
- rare earth
- Prior art date
Links
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 title abstract 28
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052761 rare earth metal Inorganic materials 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title 2
- 239000002184 metal Substances 0.000 title 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052692 Dysprosium Inorganic materials 0.000 abstract 3
- 229910052693 Europium Inorganic materials 0.000 abstract 3
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 abstract 3
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 abstract 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract 3
- 229910052688 Gadolinium Inorganic materials 0.000 abstract 2
- 229910052779 Neodymium Inorganic materials 0.000 abstract 2
- 229910052777 Praseodymium Inorganic materials 0.000 abstract 2
- 229910052772 Samarium Inorganic materials 0.000 abstract 2
- 229910052771 Terbium Inorganic materials 0.000 abstract 2
- KLNIPFWTZXANST-UHFFFAOYSA-N cobalt(2+) dioxido(dioxo)tungsten Chemical group [Co+2].[O-][W]([O-])(=O)=O KLNIPFWTZXANST-UHFFFAOYSA-N 0.000 abstract 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 abstract 2
- RJOJUSXNYCILHH-UHFFFAOYSA-N gadolinium(3+) Chemical compound [Gd+3] RJOJUSXNYCILHH-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical group [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 abstract 2
- WCWKKSOQLQEJTE-UHFFFAOYSA-N praseodymium(3+) Chemical compound [Pr+3] WCWKKSOQLQEJTE-UHFFFAOYSA-N 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 abstract 2
- DOSGOCSVHPUUIA-UHFFFAOYSA-N samarium(3+) Chemical compound [Sm+3] DOSGOCSVHPUUIA-UHFFFAOYSA-N 0.000 abstract 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 abstract 2
- HKCRVXUAKWXBLE-UHFFFAOYSA-N terbium(3+) Chemical compound [Tb+3] HKCRVXUAKWXBLE-UHFFFAOYSA-N 0.000 abstract 2
- 238000000137 annealing Methods 0.000 abstract 1
- IOIFRTZBJMZZFO-UHFFFAOYSA-N dysprosium(3+) Chemical compound [Dy+3] IOIFRTZBJMZZFO-UHFFFAOYSA-N 0.000 abstract 1
- LNBHUCHAFZUEGJ-UHFFFAOYSA-N europium(3+) Chemical compound [Eu+3] LNBHUCHAFZUEGJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- -1 neodymium (VI) Chemical compound 0.000 abstract 1
Landscapes
- Luminescent Compositions (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Oksysól w dwuskładnikowym układzie wolframianu(VI) metalu-molibdenianu(VI) pierwiastka ziem rzadkich, charakteryzuje się tym, że układ dwuskładnikowy oznacza wolframian(VI) kobaltu(II)-molibdenian(VI) prazeodymu(III) lub molibdenian(VI) neodymu(III) lub molibdenian(VI) samaru(III) lub molibdenian(VI) europu(III) lub molibdenian(VI) gadolinu(III) lub molibdenian(VI) terbu(III) lub molibdenian(VI) dysprozu(III), a oksysól ma ogólny wzór CoRE2MoWO10 gdzie RE oznacza prazeodym lub neodym lub samar lub europ lub gadolin lub terb lub dysproz. Sposób wytwarzania oksysoli w dwuskładnikowym układzie wolframianu(VI) metalu-molibdenianu(VI) pierwiastka ziem rzadkich, polegający na mieszaniu, ujednoradnianiu i wygrzewaniu otrzymanych mieszanin, charakteryzuje się tym, że wolframian(VI) kobaltu(II) miesza się z molibdenianem(VI) prazeodymu(III) lub molibdenianem(VI) neodymu(III) lub molibdenianem(VI) samaru(III) lub molibdenianem(VI) europu(III) lub molibdenianem(VI) gadolinu(III) lub molibdenianem(VI) terbu(III) lub molibdenianem(VI) dysprozu(III) w stosunkach molowych w % jak 50:50. Mieszaniny ogrzewa się w temperaturze 800-1000°C, najlepiej w 8 etapach po 12 godzin każdy. Po każdym etapie próbki schładza się wolno do temperatury otoczenia, otrzymując produkt o wzorze CoRE2MoWO10 gdzie RE oznacza prazeodym lub neodym lub samar lub europ lub gadolin lub terb lub dysproz.Oxysol in the two-component rare-earth metal-molybdate (VI) tungstate system is characterized in that the two-component system is cobalt (II) tungstate (VI) molybdate (VI) praseodymium (III) or neodymium (VI) molybdate (VI) III) or samarium (III) molybdate or VI (europium III) molybdate or gadolinium (III) molybdate or terbium (III) molybdate or dysprosium molybdate (VI), and oxysole has the general formula CoRE2MoWO10 where RE is praseodymium or neodymium or samarium or europium or gadolinium or terbium or dysprosium. The method of producing oxysols in a two-component rare-earth metal-molybdate (VI) tungstate system, consisting of mixing, homogenizing and annealing of obtained mixtures, characterized by the fact that cobalt (II) tungstate is mixed with molybdate (VI) praseodymium (III) or molybdate (VI) neodymium (III) or molybdate (VI) samarium (III) or molybdate (VI) europium (III) or molybdate (VI) gadolinium (III) or molybdate (VI) terbium (III) or molybdate (VI) dysprosium (III) in molar ratios in% as 50:50. The mixtures are heated at 800-1000 ° C, preferably in 8 stages of 12 hours each. After each step, the samples are slowly cooled to ambient temperature to give a product of the formula CoRE2MoWO10 where RE is praseodymium or neodymium or samarium or europium or gadolinium or terbium or dysprosium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL401266A PL222186B1 (en) | 2012-10-17 | 2012-10-17 | Oxisalt in two component system tungstate (VI) metal molybdate (VI) a rare earth element and a method for producing a two component oxisalts a two component tungstate (VI) metal molybdate (VI) a rare earth element |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL401266A PL222186B1 (en) | 2012-10-17 | 2012-10-17 | Oxisalt in two component system tungstate (VI) metal molybdate (VI) a rare earth element and a method for producing a two component oxisalts a two component tungstate (VI) metal molybdate (VI) a rare earth element |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL401266A1 true PL401266A1 (en) | 2014-04-28 |
| PL222186B1 PL222186B1 (en) | 2016-07-29 |
Family
ID=50514927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL401266A PL222186B1 (en) | 2012-10-17 | 2012-10-17 | Oxisalt in two component system tungstate (VI) metal molybdate (VI) a rare earth element and a method for producing a two component oxisalts a two component tungstate (VI) metal molybdate (VI) a rare earth element |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL222186B1 (en) |
-
2012
- 2012-10-17 PL PL401266A patent/PL222186B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL222186B1 (en) | 2016-07-29 |
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