PL407018A1 - Bis (ammonium) herbicidal ionic liquids with 3-oxo pentamethylene-(1.5)-bis (dimethylalkyl ammonium) cations and method for obtaining them - Google Patents
Bis (ammonium) herbicidal ionic liquids with 3-oxo pentamethylene-(1.5)-bis (dimethylalkyl ammonium) cations and method for obtaining themInfo
- Publication number
- PL407018A1 PL407018A1 PL407018A PL40701814A PL407018A1 PL 407018 A1 PL407018 A1 PL 407018A1 PL 407018 A PL407018 A PL 407018A PL 40701814 A PL40701814 A PL 40701814A PL 407018 A1 PL407018 A1 PL 407018A1
- Authority
- PL
- Poland
- Prior art keywords
- bis
- ammonium
- ionic liquids
- obtaining
- methylphenoxy
- Prior art date
Links
- 230000002363 herbicidal effect Effects 0.000 title abstract 4
- 150000001768 cations Chemical class 0.000 title abstract 3
- 239000002608 ionic liquid Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 title 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001450 anions Chemical class 0.000 abstract 2
- SMYMJHWAQXWPDB-UHFFFAOYSA-M (2,4,5-trichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC(Cl)=C(Cl)C=C1Cl SMYMJHWAQXWPDB-UHFFFAOYSA-M 0.000 abstract 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-M (2,4-dichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-M 0.000 abstract 1
- HXOOTKIBIPSPNV-UHFFFAOYSA-N (4-chloro-2-methylphenyl) ethaneperoxoate Chemical compound CC(=O)OOC1=CC=C(Cl)C=C1C HXOOTKIBIPSPNV-UHFFFAOYSA-N 0.000 abstract 1
- XKDNLZWRUACQQA-UHFFFAOYSA-N (4-chloro-2-methylphenyl) propaneperoxoate Chemical compound CCC(=O)OOc1ccc(Cl)cc1C XKDNLZWRUACQQA-UHFFFAOYSA-N 0.000 abstract 1
- IWEDIXLBFLAXBO-UHFFFAOYSA-M 3,6-dichloro-2-methoxybenzoate Chemical compound COC1=C(Cl)C=CC(Cl)=C1C([O-])=O IWEDIXLBFLAXBO-UHFFFAOYSA-M 0.000 abstract 1
- YIVXMZJTEQBPQO-UHFFFAOYSA-M 4-(2,4-dichlorophenoxy)butanoate Chemical compound [O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-M 0.000 abstract 1
- LLWADFLAOKUBDR-UHFFFAOYSA-M 4-(4-chloro-2-methylphenoxy)butanoate Chemical compound CC1=CC(Cl)=CC=C1OCCCC([O-])=O LLWADFLAOKUBDR-UHFFFAOYSA-M 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- WUPZNKGVDMHMBS-UHFFFAOYSA-N azane;dihydrate Chemical compound [NH4+].[NH4+].[OH-].[OH-] WUPZNKGVDMHMBS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 239000004476 plant protection product Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są diamoniowe herbicydowe ciecze jonowe z kationem 3-oksopentametyleno-(1,5)-bis(dimetyloalkiloamoniowym) mające zastosowanie jako środki ochrony roślin oraz sposób ich otrzymywania. Diamoniowe herbicydowe ciecze jonowe z kationem 3-oksopentametyleno-(1,5)-bis(dimetyloalkiloamoniowym) mają wzór ogólny (1), gdzie: R oznacza podstawnik alkilowy o długości węgla od 1 do 16 atomów węgla, A- oznacza anion herbicydowy o wzorze ogólnym (2) lub o wzorze (3). Sposób ich otrzymywania polega na tym, że diamoniowy wodorotlenek rozpuszcza się w metanolu, a następnie poddaje się reakcji zobojętniania w stosunku molowym 1:1 roztworem o stężeniu co najmniej 1%, zawierającym kwas będący źródłem anionów: (4-chloro-2-metylofenoksy)octanowego, lub (2,4-dichlorofenoksy)octanowego, lub (4-chloro-2-metylofenoksy)propionianowego, lub 4-(2,4-dichlorofenoksy)-butanianowego, lub (2,4,5-trichlorofenoksy)octanowego, lub 4-(4-chloro-2-metylofenoksy)butanianowego lub 3,6-dichloro-2-metoksybenzoesowego.The present invention relates to diammonium herbicidal ionic liquids with a 3-oxopentamethylene- (1,5) -bis (dimethylalkylammonium) cation, which are used as plant protection products and the method of obtaining them. Diammonium herbicidal ionic liquids with a 3-oxopentamethylene- (1,5) -bis (dimethylalkylammonium) cation have the general formula (1), where: R is an alkyl substituent with a carbon length of 1 to 16 carbon atoms, A- is a herbicide anion of formula general (2) or formula (3). The method of their preparation consists in the fact that diammonium hydroxide is dissolved in methanol and then subjected to a neutralization reaction in a 1: 1 molar ratio with a solution at least 1%, containing acid which is the source of anions: (4-chloro-2-methylphenoxy) acetate, or (2,4-dichlorophenoxy) acetate, or (4-chloro-2-methylphenoxy) propionate, or 4- (2,4-dichlorophenoxy) butanoate, or (2,4,5-trichlorophenoxy) acetate, or 4- (4-chloro-2-methylphenoxy) butanoate or 3,6-dichloro-2-methoxybenzoate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL407018A PL223414B1 (en) | 2014-01-31 | 2014-01-31 | Bis (ammonium) herbicidal ionic liquids with 3-oxo pentamethylene-(1.5)-bis (dimethylalkyl ammonium) cations and method for obtaining them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL407018A PL223414B1 (en) | 2014-01-31 | 2014-01-31 | Bis (ammonium) herbicidal ionic liquids with 3-oxo pentamethylene-(1.5)-bis (dimethylalkyl ammonium) cations and method for obtaining them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL407018A1 true PL407018A1 (en) | 2015-08-03 |
| PL223414B1 PL223414B1 (en) | 2016-10-31 |
Family
ID=53723626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL407018A PL223414B1 (en) | 2014-01-31 | 2014-01-31 | Bis (ammonium) herbicidal ionic liquids with 3-oxo pentamethylene-(1.5)-bis (dimethylalkyl ammonium) cations and method for obtaining them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL223414B1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109180505B (en) * | 2018-09-19 | 2021-07-16 | 中国日用化学研究院有限公司 | Preparation method of diethyl ether-alpha, omega-double-long-chain alkyl dimethyl ammonium chloride surfactant |
-
2014
- 2014-01-31 PL PL407018A patent/PL223414B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL223414B1 (en) | 2016-10-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| UA118549C2 (en) | 2,3-disubstituted 1 -acyl-4-amino-1,2,3,4-tetrahydroquinoline derivatives and their use as bromodomain inhibitors | |
| MX2018007418A (en) | Benzamide compounds and their use as herbicides. | |
| IN2014MN02343A (en) | ||
| HK1249504A1 (en) | Pyridinone dicarboxamide for use as bromodomain inhibitors | |
| MY171414A (en) | Compositions and methods for improving the compatibility of water soluble herbicide salts | |
| PH12019500822A1 (en) | Crystalline forms of eravacycline | |
| UY34943A (en) | HERBICIDE COMPOSITIONS THAT INCLUDE ACID 4-AMINO-3-CHLORO-5-FLUORO-6- (4-CHLORO-2-FLUORO-3-METOXIFENILO) PIRIDINA-2-CARBOXÍLICO OR A DERIVATIVE OF THE SAME AND A SULPHONYLAMINOCARBON. | |
| PL407017A1 (en) | Bis (ammonium) herbicidal ionic liquids with alkyldiyl-bis (dimethylalkyl ammonium) cations and method for producing them | |
| EP2828236A4 (en) | PROCESS FOR THE PREPARATION OF BIOCIDAL AQUEOUS COMPOSITIONS | |
| PL410423A1 (en) | Alkoxymethyl bis(2-hydroxyethyl)methylammonium 4-chloro-2-methylphenoxyacetates, method for obtaining them and application as plant pesticides | |
| PL416323A1 (en) | Methyl alkyl betaine 3,6-dichloro-2-methoxybenzoate, method for obtaining it and application as a herbicide | |
| MX2015012211A (en) | Ionic liquids and uses thereof. | |
| PL407019A1 (en) | Bis (ammonium) herbicidal ionic liquids with 3.6-dioxooctamethylene-(1.8)-bis (dimethylalkyl ammonium) cations and method for obtaining them | |
| PL399057A1 (en) | New herbicidal esterquats with the anion having herbicidal effect and a process for their preparation | |
| PL402382A1 (en) | Ionic liquids with a diallilodimethylammonium cation and herbicide anion, process for their preparation and the use as a herbicide | |
| PL402385A1 (en) | New monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides | |
| PL410422A1 (en) | New alkoxymethyl (2-hydroxyethyl)diethylammonium 4-chloro-2-methylphenoxyacetates and method for producing them and application as a herbicide | |
| PL415210A1 (en) | Method for obtaining ammonium ionic liquids with cation derivative of betaine and nonenoate anion and their application as herbicides | |
| EP2822899A4 (en) | PROCESS FOR THE PREPARATION OF BIOCIDAL AND ANTIFOULING AQUEOUS COMPOSITIONS COMPRISING BROMHYDRIC ACID, UREA AND SODIUM HYPOCHLORITE | |
| PL411286A1 (en) | New alkoxymethyl di(2-hydroxyethyl)ethylammonium ionic liquids with sweet anions and method for producing them and application as a medium for the protection of surface against accumulation of electrostatic charges | |
| PL399974A1 (en) | Ionic liquids with tetramethylene-1,4-bis (alkyldimethylammonium) cation and (4-chloro-2-methylphenoxy) acetate anion and the method of obtaining them | |
| PL412742A1 (en) | New di[2-(2,4-dichlorophenoxy)propionates] alkano-1,X-bis(decyl dimethylammonium) bis-ammonium ionic liquids, method for obtaining them and applications as plant protection products | |
| PL413284A1 (en) | Ionic liquids with N-[2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)ethyl]-N,N,N alkyl dimethylammonium cation and (4-chloro-2-methylphenoxy)acetate anion and method for obtaining them | |
| PL410064A1 (en) | Piperidinium ionic liquids with 4-(4-chloro-2-methylphenoxy)butanoate anion and method for producing them and their application as herbicides | |
| PL402384A1 (en) | New bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |