PL428342A1 - Method of producing a modified FAME biofuel for automotive compression ignition engines and the modified FAME biofuel for automotive compression ignition engines - Google Patents
Method of producing a modified FAME biofuel for automotive compression ignition engines and the modified FAME biofuel for automotive compression ignition enginesInfo
- Publication number
- PL428342A1 PL428342A1 PL428342A PL42834218A PL428342A1 PL 428342 A1 PL428342 A1 PL 428342A1 PL 428342 A PL428342 A PL 428342A PL 42834218 A PL42834218 A PL 42834218A PL 428342 A1 PL428342 A1 PL 428342A1
- Authority
- PL
- Poland
- Prior art keywords
- solvent
- fame
- raw material
- biofuel
- modified
- Prior art date
Links
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical class CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 title abstract 7
- 239000002551 biofuel Substances 0.000 title abstract 6
- 230000006835 compression Effects 0.000 title abstract 4
- 238000007906 compression Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 239000002904 solvent Substances 0.000 abstract 11
- 239000002994 raw material Substances 0.000 abstract 6
- 235000019387 fatty acid methyl ester Nutrition 0.000 abstract 5
- 208000016444 Benign adult familial myoclonic epilepsy Diseases 0.000 abstract 4
- 208000016427 familial adult myoclonic epilepsy Diseases 0.000 abstract 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- 238000002425 crystallisation Methods 0.000 abstract 3
- 230000008025 crystallization Effects 0.000 abstract 3
- 239000000706 filtrate Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000013049 sediment Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób wytwarzania zmodyfikowanego biopaliwa FAME przeznaczonego do silników samochodowych o zapłonie samoczynnym polega, na tym, że surowiec, to jest mieszaninę estrów metylowych kwasów tłuszczowych - FAME o temperaturze mętnienia nie niższej niż -8°C, temperaturze płynięcia nie niższej niż -15°C i temperaturze zablokowania zimnego filtra nie niższej niż -15°C poddaje się procesowi rozdzielania rozpuszczalnikowego na filtrat będący zmodyfikowanym biopaliwem FAME i osad obejmującemu etap krystalizacji i etap filtracji przy czym w etapie krystalizacji surowiec poddaje się pierwszemu rozcieńczeniu rozpuszczalnikiem zawierającym 10% - 85% (m/m) dwuchloroetanu i odpowiednio 85% - 15% (m/m) chlorku metylenu, uzyskując mieszaninę surowca i rozpuszczalnika, którą następnie oziębia się z kontrolowaną prędkością z równoczesnym doprowadzeniem oziębionego rozpuszczalnika w 1 - 6 porcjach przy szybkości schładzania w zakresie 0,2 - 8,0°C/min, aż do osiągnięcia temperatury od -20 do -30°C, przy czym stosunek sumarycznej ilości rozpuszczalnika do surowca zawiera się w przedziale od 1: 1 do 7: 1 (m/m), a wielkość rozcieńczeń wyrażona stosunkiem masowym rozpuszczalnika do surowca wynosi od 0,4: 1 do 4: 1 (m/m), po czym w zakresie temperatur od -20 do -30°C, odfiltrowuje się wydzielony osad, który przemywa się zimnym rozpuszczalnikiem o takim samym składzie jak rozpuszczalnik używany w etapie krystalizacji, stosowanym w ilości od 0,1: 1 do 2: 1 (m/m) wyrażonej stosunkiem masowym rozpuszczalnika do surowca, a następnie z filtratu oddestylowuje się rozpuszczalnik uzyskując produkt końcowy o obniżonych: temperaturze mętnienia o 3 do 10°C, temperaturze płynięcia o 1 do 9°C i temperaturze zablokowania zimnego filtra o 1 do 10°C, w stosunku do wartości tych temperatur przed poddaniem FAME procesowi rozdzielania rozpuszczalnikowego na filtrat i osad. Ponadto przedmiotem zgłoszenia jest również zmodyfikowane biopaliwo FAME przeznaczone do silników samochodowych o zapłonie samoczynnym, ma obniżoną poniżej -7°C temperaturę poniżej -8°C temperaturę płynięcia i poniżej 9°C temperaturę zablokowania zimnego filtra. Zmodyfikowane biopaliwo FAME przeznaczone do silników samochodowych o zapłonie samoczynnym wytworzone jest sposobem, według którejkolwiek jego odmiany.The subject of the application is a method of producing a modified biofuel FAME intended for compression ignition car engines consists in the fact that the raw material is a mixture of fatty acid methyl esters - FAME with a cloud point not lower than -8 ° C, a pour point not lower than -15 ° C and a cold filter blocking temperature not lower than -15 ° C is subjected to a solvent separation process into a filtrate which is a modified biofuel FAME and a sediment including a crystallization step and a filtration step, while in the crystallization step the raw material is first diluted with a solvent containing 10% - 85% (m / m) of dichloroethane and 85% - 15% (m / m) of methylene chloride, respectively, to obtain a mixture of raw material and solvent, which is then cooled at a controlled rate with the simultaneous introduction of cooled solvent in 1 - 6 portions at a cooling rate in the range of 0 , 2 - 8.0 ° C / min, until the temperature is reached ranging from -20 to -30 ° C, the ratio of the total amount of solvent to the raw material is in the range from 1: 1 to 7: 1 (m / m), and the amount of dilution expressed by the mass ratio of the solvent to the raw material is from 0.4 : 1 to 4: 1 (m / m), then in the temperature range from -20 to -30 ° C, the separated precipitate is filtered off, which is washed with a cold solvent of the same composition as the solvent used in the crystallization stage, used in the amount of from 0.1: 1 to 2: 1 (m / m) expressed as the mass ratio of the solvent to the raw material, and then the solvent is distilled off the filtrate, obtaining the final product with reduced: cloud point by 3 to 10 ° C, pour point by 1 to 9 ° C and a cold filter plugging point of 1 to 10 ° C, compared to the values of these temperatures before subjecting the FAME to the solvent separation process into the filtrate and sediment. In addition, the subject of the application is also a modified FAME biofuel for compression ignition automotive engines, which has a temperature below -7 ° C, a pour point below -8 ° C and a cold filter plugging point below 9 ° C. Modified FAME biofuel for compression-ignition automotive engines is produced by a process according to any variant thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL428342A PL236706B1 (en) | 2018-12-27 | 2018-12-27 | Method of producing a modified FAME biofuel for automotive compression ignition engines and the modified FAME biofuel for automotive compression ignition engines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL428342A PL236706B1 (en) | 2018-12-27 | 2018-12-27 | Method of producing a modified FAME biofuel for automotive compression ignition engines and the modified FAME biofuel for automotive compression ignition engines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL428342A1 true PL428342A1 (en) | 2020-06-29 |
| PL236706B1 PL236706B1 (en) | 2021-02-08 |
Family
ID=71124938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL428342A PL236706B1 (en) | 2018-12-27 | 2018-12-27 | Method of producing a modified FAME biofuel for automotive compression ignition engines and the modified FAME biofuel for automotive compression ignition engines |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL236706B1 (en) |
-
2018
- 2018-12-27 PL PL428342A patent/PL236706B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL236706B1 (en) | 2021-02-08 |
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