SE451544B - Forfarande for framstellning av dealuminiserad zeolit y med hog hydrofobicitet - Google Patents
Forfarande for framstellning av dealuminiserad zeolit y med hog hydrofobicitetInfo
- Publication number
- SE451544B SE451544B SE8604873A SE8604873A SE451544B SE 451544 B SE451544 B SE 451544B SE 8604873 A SE8604873 A SE 8604873A SE 8604873 A SE8604873 A SE 8604873A SE 451544 B SE451544 B SE 451544B
- Authority
- SE
- Sweden
- Prior art keywords
- zeolite
- temperature
- water
- treatment
- acid
- Prior art date
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 25
- 239000010457 zeolite Substances 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical class 0.000 claims abstract 2
- 229910000077 silane Inorganic materials 0.000 claims abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 description 4
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000005049 silicon tetrachloride Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 229910018404 Al2 O3 Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- MVMVARHTRUEHCL-UHFFFAOYSA-N [SiH4].[Br] Chemical compound [SiH4].[Br] MVMVARHTRUEHCL-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8604873A SE451544B (sv) | 1986-11-14 | 1986-11-14 | Forfarande for framstellning av dealuminiserad zeolit y med hog hydrofobicitet |
| PCT/SE1987/000483 WO1988003437A1 (fr) | 1986-11-14 | 1987-10-20 | Procede de production de zeolithe y debarrassee de son aluminium et ayant une hydrophobicite elevee |
| EP87907629A EP0332632B1 (fr) | 1986-11-14 | 1987-10-20 | Procede de production de zeolithe y debarrassee de son aluminium et ayant une hydrophobicite elevee |
| JP62507110A JP2514996B2 (ja) | 1986-11-14 | 1987-10-20 | 高疎水性の脱アルミ化ゼオライトyの製造方法 |
| DE3751828T DE3751828T2 (de) | 1986-11-14 | 1987-10-20 | Herstellungsverfahren für stark hydrophoben entaluminierten zeolith y |
| AT87907629T ATE138830T1 (de) | 1986-11-14 | 1987-10-20 | Herstellungsverfahren für stark hydrophoben entaluminierten zeolith y |
| DK384888A DK384888D0 (da) | 1986-11-14 | 1988-07-08 | Fremgangsmaade til fremstilling af dealuminiseret zeolit y med hoej hydrofobicitet |
| NO883067A NO170145C (no) | 1986-11-14 | 1988-07-08 | Fremgangsmaate for aa oeke hydrofobisiteten til dealuminisert zeolitt y |
| US07/353,627 US5013700A (en) | 1986-11-14 | 1989-05-12 | Method of producing dealuminized zeolite Y of high hydrophobicity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8604873A SE451544B (sv) | 1986-11-14 | 1986-11-14 | Forfarande for framstellning av dealuminiserad zeolit y med hog hydrofobicitet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8604873D0 SE8604873D0 (sv) | 1986-11-14 |
| SE451544B true SE451544B (sv) | 1987-10-19 |
Family
ID=20366283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8604873A SE451544B (sv) | 1986-11-14 | 1986-11-14 | Forfarande for framstellning av dealuminiserad zeolit y med hog hydrofobicitet |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5013700A (fr) |
| EP (1) | EP0332632B1 (fr) |
| JP (1) | JP2514996B2 (fr) |
| AT (1) | ATE138830T1 (fr) |
| DE (1) | DE3751828T2 (fr) |
| SE (1) | SE451544B (fr) |
| WO (1) | WO1988003437A1 (fr) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5354452A (en) * | 1990-01-11 | 1994-10-11 | Texaco Inc. | Synthesis of zeolites |
| EP0490037B2 (fr) * | 1990-12-13 | 2001-11-14 | Tosoh Corporation | Méthode de nettoyage de gaz contenant des solvants organiques cétoniques |
| US5256385A (en) * | 1990-12-13 | 1993-10-26 | Tosoh Corporation | Adsorbent and cleaning method of waste gas containing ketonic organic solvents |
| DE4202671A1 (de) * | 1991-05-27 | 1992-12-03 | Degussa | Formkoerper enthaltend dealuminierten zeolith y und das verfahren zu ihrer herstellung |
| US6171568B1 (en) * | 1991-05-27 | 2001-01-09 | Degussa-H{umlaut over (u)}ls Aktiengesellschaft | Method for the purification of exhaust air and/or effluents by contact with moulded bodies containing dealuminated zeolite Y |
| US5242677A (en) * | 1992-06-11 | 1993-09-07 | Pq Corporation | Stable zeolite of low unit cell constant and method of making same |
| EP0600483A1 (fr) * | 1992-12-03 | 1994-06-08 | Tosoh Corporation | Procédé d'élimination d'oxides d'azote de gaz d'échappement à teneur élevée en oxygène |
| US5534135A (en) * | 1994-03-07 | 1996-07-09 | Abb Lummus Global Inc. | Synthesis of zeolites |
| US5549813A (en) * | 1994-03-07 | 1996-08-27 | Dai; Pei-Shing E. | FCC process employing low unit cell size y-zeolites |
| FR2735764B1 (fr) * | 1995-06-21 | 1997-08-22 | Irma | Zeolithe y desaluminee, son procede de fabrication et son application a l'adsorption des composes organiques volatils en presence de vapeur d'eau |
| DE19532500A1 (de) * | 1995-09-02 | 1997-03-06 | Degussa | Verfahren zur Herstellung von Zeolith Y |
| CA2240612A1 (fr) * | 1997-07-29 | 1999-01-29 | Vladimir Borisovich Kazansky | Preparation du phenol et de ses derives |
| US6180549B1 (en) * | 1998-09-10 | 2001-01-30 | The B. F. Goodrich Company | Modified zeolites and methods of making thereof |
| RU2213055C2 (ru) | 1999-03-03 | 2003-09-27 | Пи Кью ХОЛДИНГ, ИНК. | Способ получения модифицированного цеолита |
| CN1230496C (zh) * | 2002-10-28 | 2005-12-07 | 中国石油化工股份有限公司 | 一种含稀土y型沸石的石油烃裂化催化剂及其制备方法 |
| JP5504446B2 (ja) * | 2010-05-14 | 2014-05-28 | 国立大学法人大阪大学 | 疎水性ゼオライトの製造方法及びその方法で得られた疎水性ゼオライト |
| US20130172649A1 (en) * | 2011-12-30 | 2013-07-04 | Sivadinarayana Chinta | Supported nano sized zeolite catalyst for alkylation reactions |
| EP3083045A1 (fr) * | 2013-12-20 | 2016-10-26 | Basf Se | Catalyseur et procédé de conversion de composés oxygénés en oléfines |
| FR3064624A1 (fr) * | 2017-04-04 | 2018-10-05 | IFP Energies Nouvelles | Procede de preparation de cristaux de zeolithe y se presentant sous forme de boites creuses |
| CN110902691B (zh) * | 2019-11-25 | 2021-07-20 | 北京化工大学 | 一种y型分子筛疏水改性的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644220A (en) * | 1969-11-13 | 1972-02-22 | Exxon Research Engineering Co | Metal halide containing zeolites and method for their preparation |
| US4093560A (en) * | 1976-05-20 | 1978-06-06 | Mobil Oil Corporation | Ultra high silicon-content zeolites and preparation thereof |
| EP0068817B1 (fr) * | 1981-07-01 | 1984-10-03 | ENGLISH CLAYS LOVERING POCHIN & COMPANY LIMITED | Procédé pour la préparation de zéolithes du type ZSM |
| DE3132380C1 (de) * | 1981-08-17 | 1983-02-24 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von ultrastabilen Zeolithen |
| CA1190206A (fr) * | 1982-03-30 | 1985-07-09 | Brent M. Lok | Modification de zeolites par traitement au chlore gazeux |
| US4840930A (en) * | 1982-05-18 | 1989-06-20 | Mobil Oil Corporation | Method for preparing acid stable zeolites and high silica zeolites prepared by it |
| DE3377414D1 (en) * | 1982-05-27 | 1988-08-25 | Ici Plc | Preparation of modified zeolites |
| CA1220771A (fr) * | 1982-08-02 | 1987-04-21 | Frank P. Gortsema | Modification des tamis moleculaires pour traitement avec un melange gazeux de tetrafluorure de silicium |
| US4632749A (en) * | 1983-03-14 | 1986-12-30 | Uop Inc. | Fluid catalytic cracking hydrocarbon conversion process |
| US4663025A (en) * | 1986-08-14 | 1987-05-05 | Phillips Petroleum Company | Catalytic cracking processes |
-
1986
- 1986-11-14 SE SE8604873A patent/SE451544B/sv not_active IP Right Cessation
-
1987
- 1987-10-20 JP JP62507110A patent/JP2514996B2/ja not_active Expired - Lifetime
- 1987-10-20 EP EP87907629A patent/EP0332632B1/fr not_active Revoked
- 1987-10-20 DE DE3751828T patent/DE3751828T2/de not_active Revoked
- 1987-10-20 WO PCT/SE1987/000483 patent/WO1988003437A1/fr not_active Ceased
- 1987-10-20 AT AT87907629T patent/ATE138830T1/de not_active IP Right Cessation
-
1989
- 1989-05-12 US US07/353,627 patent/US5013700A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| SE8604873D0 (sv) | 1986-11-14 |
| JP2514996B2 (ja) | 1996-07-10 |
| DE3751828D1 (de) | 1996-07-11 |
| DE3751828T2 (de) | 1997-01-23 |
| JPH02502627A (ja) | 1990-08-23 |
| EP0332632B1 (fr) | 1996-06-05 |
| WO1988003437A1 (fr) | 1988-05-19 |
| EP0332632A1 (fr) | 1989-09-20 |
| US5013700A (en) | 1991-05-07 |
| ATE138830T1 (de) | 1996-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
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