SK286102B6 - Spôsob prípravy polymérov a kopolymérov olefínov a takto získaný polymér alebo kopolymér olefínov - Google Patents

Spôsob prípravy polymérov a kopolymérov olefínov a takto získaný polymér alebo kopolymér olefínov Download PDF

Info

Publication number: SK286102B6
Authority: SK; Slovakia
Prior art keywords: alkyl; carbon atoms; group; aryl; range
Prior art date: 1989-04-28

Application number

SK747-98A

Other languages

English (en)

Slovak (sk)

Other versions

SK74798A3 (en

Inventor

Mario Sacchetti

Gabriele Govoni

Antonio Ciarrocchi

Original Assignee

Himont Incorporated

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-04-28

Filing date

1990-04-26

Publication date

2008-03-05

1990-04-26 Application filed by Himont Incorporated filed Critical Himont Incorporated

2000-02-14 Publication of SK74798A3 publication Critical patent/SK74798A3/sk

2008-03-05 Publication of SK286102B6 publication Critical patent/SK286102B6/sk

Links

238000000034 method Methods 0.000 title claims abstract description 36
229920000642 polymer Polymers 0.000 title claims abstract description 35
238000002360 preparation method Methods 0.000 title claims abstract description 15
229920000089 Cyclic olefin copolymer Polymers 0.000 title abstract description 4
239000003054 catalyst Substances 0.000 claims abstract description 65
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 46
239000012798 spherical particle Substances 0.000 claims abstract description 29
150000001875 compounds Chemical class 0.000 claims abstract description 27
125000000217 alkyl group Chemical group 0.000 claims abstract description 26
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 21
229920001577 copolymer Polymers 0.000 claims abstract description 18
238000002083 X-ray spectrum Methods 0.000 claims abstract description 15
125000003118 aryl group Chemical group 0.000 claims abstract description 14
150000001336 alkenes Chemical class 0.000 claims abstract description 12
229910052736 halogen Inorganic materials 0.000 claims abstract description 11
150000003609 titanium compounds Chemical class 0.000 claims abstract description 10
125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 5
239000007795 chemical reaction product Substances 0.000 claims abstract description 3
229910001629 magnesium chloride Inorganic materials 0.000 claims description 20
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
239000005977 Ethylene Substances 0.000 claims description 17
-1 aryl phthalic acid esters Chemical class 0.000 claims description 17
125000000753 cycloalkyl group Chemical group 0.000 claims description 12
239000002245 particle Substances 0.000 claims description 10
239000011949 solid catalyst Substances 0.000 claims description 8
150000004820 halides Chemical class 0.000 claims description 6
150000005840 aryl radicals Chemical class 0.000 claims description 3
229920005653 propylene-ethylene copolymer Polymers 0.000 claims description 3
150000003377 silicon compounds Chemical class 0.000 claims description 3
229920001384 propylene homopolymer Polymers 0.000 claims description 2
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
239000007787 solid Substances 0.000 abstract description 9
150000002367 halogens Chemical class 0.000 abstract description 6
238000004519 manufacturing process Methods 0.000 abstract description 6
230000003197 catalytic effect Effects 0.000 abstract description 5
229920000098 polyolefin Polymers 0.000 abstract description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
238000006116 polymerization reaction Methods 0.000 description 25
239000000203 mixture Substances 0.000 description 20
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 20
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 20
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 20
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 11
229910052753 mercury Inorganic materials 0.000 description 11
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 9
239000011148 porous material Substances 0.000 description 9
239000010936 titanium Substances 0.000 description 9
239000008096 xylene Substances 0.000 description 9
239000001257 hydrogen Substances 0.000 description 8
229910052739 hydrogen Inorganic materials 0.000 description 8
229910052719 titanium Inorganic materials 0.000 description 8
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 6
239000011777 magnesium Substances 0.000 description 6
238000001228 spectrum Methods 0.000 description 6
238000003756 stirring Methods 0.000 description 6
238000011282 treatment Methods 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
229910052749 magnesium Inorganic materials 0.000 description 5
230000000877 morphologic effect Effects 0.000 description 5
229920001155 polypropylene Polymers 0.000 description 5
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 4
229960002380 dibutyl phthalate Drugs 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000012071 phase Substances 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
239000000243 solution Substances 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
150000002170 ethers Chemical class 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
239000001294 propane Substances 0.000 description 3
239000005060 rubber Substances 0.000 description 3
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
229920002943 EPDM rubber Polymers 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
229910003074 TiCl4 Inorganic materials 0.000 description 2
239000002253 acid Substances 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
229920000092 linear low density polyethylene Polymers 0.000 description 2
239000004707 linear low-density polyethylene Substances 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
239000000047 product Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
ROSQVPGTZCDBOC-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,4-dimethylpentane Chemical compound COCC(C)(COC)CC(C)C ROSQVPGTZCDBOC-UHFFFAOYSA-N 0.000 description 1
BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
QCZVIXQXGWIBHR-UHFFFAOYSA-N ClC(CCCO[Ti])(Cl)Cl Chemical compound ClC(CCCO[Ti])(Cl)Cl QCZVIXQXGWIBHR-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229920000181 Ethylene propylene rubber Polymers 0.000 description 1
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000007860 aryl ester derivatives Chemical class 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000008187 granular material Substances 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
230000002140 halogenating effect Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920001903 high density polyethylene Polymers 0.000 description 1
239000004700 high-density polyethylene Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000002689 maleic acids Chemical class 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
238000011017 operating method Methods 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
150000003022 phthalic acids Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
230000000707 stereoselective effect Effects 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
ZLMGMVJGEULFPP-UHFFFAOYSA-J titanium(4+) trichloride phenoxide Chemical compound Cl[Ti](Cl)(Cl)OC1=CC=CC=C1 ZLMGMVJGEULFPP-UHFFFAOYSA-J 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene

Landscapes

Chemical & Material Sciences (AREA)
Polymers & Plastics (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

SK747-98A 1989-04-28 1990-04-26 Spôsob prípravy polymérov a kopolymérov olefínov a takto získaný polymér alebo kopolymér olefínov SK286102B6 (sk)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT8920329A IT1230134B (it)	1989-04-28	1989-04-28	Componenti e catalizzatori per la polimerizzazione di olefine.

Publications (2)

Publication Number	Publication Date
SK74798A3 SK74798A3 (en)	2000-02-14
SK286102B6 true SK286102B6 (sk)	2008-03-05

Family

ID=11165778

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
SK2109-90A SK279629B6 (sk)	1989-04-28	1990-04-26	Katalytická zložka na polymerizáciu olefínov a kat
SK747-98A SK286102B6 (sk)	1989-04-28	1990-04-26	Spôsob prípravy polymérov a kopolymérov olefínov a takto získaný polymér alebo kopolymér olefínov

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
SK2109-90A SK279629B6 (sk)	1989-04-28	1990-04-26	Katalytická zložka na polymerizáciu olefínov a kat

Country Status (28)

Country	Link
EP (3)	EP1251141B1 (fr)
JP (2)	JP3016816B2 (fr)
KR (1)	KR0177803B1 (fr)
CN (1)	CN1037609C (fr)
AT (3)	ATE160150T1 (fr)
AU (1)	AU636142B2 (fr)
BR (1)	BR9001991A (fr)
CA (1)	CA2015685C (fr)
CZ (1)	CZ288172B6 (fr)
DD (1)	DD298935A5 (fr)
DE (3)	DE69034205T2 (fr)
ES (2)	ES2250553T3 (fr)
FI (1)	FI103124B (fr)
HK (1)	HK1004605A1 (fr)
HU (1)	HU225782B1 (fr)
IL (1)	IL94154A (fr)
IN (2)	IN177689B (fr)
IT (1)	IT1230134B (fr)
MX (1)	MX20477A (fr)
MY (1)	MY106344A (fr)
NO (1)	NO178465C (fr)
PL (3)	PL163548B1 (fr)
PT (1)	PT93923B (fr)
RU (1)	RU2045537C1 (fr)
SK (2)	SK279629B6 (fr)
UA (1)	UA27689C2 (fr)
YU (1)	YU82990A (fr)
ZA (1)	ZA903063B (fr)

Families Citing this family (300)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU648534B2 (en) *	1989-12-28	1994-04-28	Idemitsu Petrochemical Co., Ltd.	Carrier for olefin polymerization catalyst and process for producing olefins
IT1245250B (it) *	1991-03-27	1994-09-13	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine
IT1245249B (it) *	1991-03-27	1994-09-13	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine
IT1252129B (it) *	1991-11-22	1995-06-05	Himont Inc	Componenti a catalizzatori sferici per la polimerizzazione di olefine
IT1262935B (it) *	1992-01-31	1996-07-22	Montecatini Tecnologie Srl	Componenti e catalizzatori per la polimerizzazione di olefine
IT1262934B (it) *	1992-01-31	1996-07-22	Montecatini Tecnologie Srl	Componenti e catalizzatori per la polimerizzazione di olefine
IT1260495B (it) *	1992-05-29	1996-04-09	Himont Inc	Concentrati adatti alla preparazione di poliolefine funzionalizzate e processo di funzionalizzazione mediante detti concentrati
IT1256403B (it) *	1992-08-18	1995-12-05	Montecatini Tecnologie Srl	Componenti e catalizzatori a base di vanadio per la polimerizzazione di olefine,e processi di polimerizzazione impieganti gli stessi
IT1256647B (it) *	1992-12-11	1995-12-12	Montecatini Tecnologie Srl	Procedimento per la preparazione di (co) polimeri a larga distribuzione di pesi molecolari dell'etilene.
IT1256648B (it)	1992-12-11	1995-12-12	Montecatini Tecnologie Srl	Componenti e catalizzatori per la polimerizzazione delle olefine
ITMI922919A1 (it) *	1992-12-21	1994-06-22	Montecatini Tecnologie Srl	Componenti e catalizzatori per la polimerizzazione di olefine
IT1264679B1 (it)	1993-07-07	1996-10-04	Spherilene Srl	Catalizzatori per la (co)polimerizzazione di etilene
IT1269194B (it) *	1994-01-21	1997-03-21	Spherilene Srl	Composizioni polimeriche ad elevata processabilita' basate su lldpe
CN1039234C (zh) *	1994-03-22	1998-07-22	中国石油化工总公司	聚丙烯球形催化剂及其制备
IT1269931B (it) *	1994-03-29	1997-04-16	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
IT1269841B (it) *	1994-05-27	1997-04-15	Himont Inc	Procedimento e dispositivo per la classificazione di particelle solide
IT1270070B (it)	1994-07-08	1997-04-28	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
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1989
- 1989-04-28 IT IT8920329A patent/IT1230134B/it active
1990
- 1990-04-18 MY MYPI90000639A patent/MY106344A/en unknown
- 1990-04-20 IL IL9415490A patent/IL94154A/en not_active IP Right Cessation
- 1990-04-23 IN IN817CA1993 patent/IN177689B/en unknown
- 1990-04-23 ZA ZA903063A patent/ZA903063B/xx unknown
- 1990-04-23 IN IN330CA1990 patent/IN174661B/en unknown
- 1990-04-25 YU YU00829/90A patent/YU82990A/xx unknown
- 1990-04-26 FI FI902107A patent/FI103124B/fi active IP Right Grant
- 1990-04-26 SK SK2109-90A patent/SK279629B6/sk not_active IP Right Cessation
- 1990-04-26 MX MX2047790A patent/MX20477A/es unknown
- 1990-04-26 SK SK747-98A patent/SK286102B6/sk not_active IP Right Cessation
- 1990-04-27 HU HU9002616A patent/HU225782B1/hu not_active IP Right Cessation
- 1990-04-27 NO NO901912A patent/NO178465C/no unknown
- 1990-04-27 AT AT90108049T patent/ATE160150T1/de not_active IP Right Cessation
- 1990-04-27 AT AT02016309T patent/ATE307147T1/de not_active IP Right Cessation
- 1990-04-27 RU SU4743803/05A patent/RU2045537C1/ru not_active IP Right Cessation
- 1990-04-27 DD DD90340236A patent/DD298935A5/de unknown
- 1990-04-27 PL PL90284968A patent/PL163548B1/pl unknown
- 1990-04-27 PL PL90299950A patent/PL165373B1/pl unknown
- 1990-04-27 DE DE69034205T patent/DE69034205T2/de not_active Expired - Fee Related
- 1990-04-27 PT PT93923A patent/PT93923B/pt not_active IP Right Cessation
- 1990-04-27 DE DE69034255T patent/DE69034255D1/de not_active Expired - Fee Related
- 1990-04-27 UA UA4743803A patent/UA27689C2/uk unknown
- 1990-04-27 PL PL90299951A patent/PL165028B1/pl unknown
- 1990-04-27 EP EP02016309A patent/EP1251141B1/fr not_active Expired - Lifetime
- 1990-04-27 AT AT97107180T patent/ATE400590T1/de not_active IP Right Cessation
- 1990-04-27 ES ES02016309T patent/ES2250553T3/es not_active Expired - Lifetime
- 1990-04-27 EP EP97107180A patent/EP0789037B1/fr not_active Expired - Lifetime
- 1990-04-27 DE DE69031693T patent/DE69031693T2/de not_active Expired - Fee Related
- 1990-04-27 EP EP90108049A patent/EP0395083B1/fr not_active Expired - Lifetime
- 1990-04-27 CA CA002015685A patent/CA2015685C/fr not_active Expired - Lifetime
- 1990-04-27 BR BR909001991A patent/BR9001991A/pt not_active IP Right Cessation
- 1990-04-27 ES ES90108049T patent/ES2110399T3/es not_active Expired - Lifetime
- 1990-04-27 AU AU54569/90A patent/AU636142B2/en not_active Ceased
- 1990-04-28 CN CN90104123A patent/CN1037609C/zh not_active Expired - Lifetime
- 1990-04-28 KR KR1019900006053A patent/KR0177803B1/ko not_active Expired - Fee Related
- 1990-05-01 JP JP2115719A patent/JP3016816B2/ja not_active Expired - Fee Related
1998
- 1998-05-01 HK HK98103720A patent/HK1004605A1/en not_active IP Right Cessation
1999
- 1999-02-11 CZ CZ1999469A patent/CZ288172B6/cs not_active IP Right Cessation
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Also Published As

Publication number	Publication date
CZ9900469A3 (cs)	2001-01-17
NO901912L (no)	1990-10-29
BR9001991A (pt)	1991-08-13
IL94154A0 (en)	1991-01-31
EP0395083A3 (fr)	1991-06-05
KR0177803B1 (ko)	1999-05-15
JP3016816B2 (ja)	2000-03-06
JP3193360B2 (ja)	2001-07-30
ATE307147T1 (de)	2005-11-15
EP0789037B1 (fr)	2008-07-09
JPH0362805A (ja)	1991-03-18
IN177689B (fr)	1997-02-15
EP0789037A3 (fr)	1998-11-04
PL165373B1 (pl)	1994-12-30
IL94154A (en)	1994-01-25
AU5456990A (en)	1990-11-01
MY106344A (en)	1995-05-30
ES2250553T3 (es)	2006-04-16
DE69031693T2 (de)	1998-05-14
HK1004605A1 (en)	1998-11-27
PL163548B1 (en)	1994-04-29
DE69031693D1 (de)	1997-12-18
EP1251141A2 (fr)	2002-10-23
DD298935A5 (de)	1992-03-19
CA2015685A1 (fr)	1990-10-28
EP0395083B1 (fr)	1997-11-12
FI103124B1 (fi)	1999-04-30
IT8920329A0 (it)	1989-04-28
YU82990A (en)	1991-10-31
NO901912D0 (no)	1990-04-27
EP0789037A2 (fr)	1997-08-13
EP1251141A3 (fr)	2003-10-29
RU2045537C1 (ru)	1995-10-10
UA27689C2 (uk)	2000-10-16
PT93923A (pt)	1990-11-20
FI103124B (fi)	1999-04-30
CZ288172B6 (en)	2001-05-16
IT1230134B (it)	1991-10-14
ES2110399T3 (es)	1998-02-16
DE69034255D1 (de)	2008-08-21
HU225782B1 (en)	2007-09-28
MX20477A (es)	1993-12-01
CN1047302A (zh)	1990-11-28
CN1037609C (zh)	1998-03-04
DE69034205T2 (de)	2007-06-28
CA2015685C (fr)	1999-12-21
HU902616D0 (en)	1990-09-28
KR900016272A (ko)	1990-11-13
HUT62609A (en)	1993-05-28
IN174661B (fr)	1995-02-04
SK210990A3 (en)	1999-01-11
ZA903063B (en)	1991-01-30
ATE400590T1 (de)	2008-07-15
SK74798A3 (en)	2000-02-14
FI902107A0 (fi)	1990-04-26
PL165028B1 (pl)	1994-11-30
DE69034205D1 (de)	2006-03-02
PL284968A1 (en)	1992-01-13
NO178465C (no)	1996-04-03
EP0395083A2 (fr)	1990-10-31
NO178465B (no)	1995-12-27
EP1251141B1 (fr)	2005-10-19
SK279629B6 (sk)	1999-01-11
PT93923B (pt)	1996-11-29
ATE160150T1 (de)	1997-11-15
AU636142B2 (en)	1993-04-22
JP2000080121A (ja)	2000-03-21

Legal Events

Date	Code	Title	Description
2010-01-07	MM4A	Patent lapsed due to non-payment of maintenance fees	Effective date: 20090426

Publication	Publication Date	Title
SK286102B6 (sk)	2008-03-05	Spôsob prípravy polymérov a kopolymérov olefínov a takto získaný polymér alebo kopolymér olefínov
US5221651A (en)	1993-06-22	Component and catalysts for the polymerization of olefins
EP0685497B1 (fr)	1999-11-03	Système catalytique stéréospécifique pour la polymérisation d'oléfines
CN103476806B (zh)	2016-12-07	用于烯烃聚合的催化剂组分
US6365685B1 (en)	2002-04-02	Process for the preparation of random propylene copolymers and products obtained therefrom
HK1004605B (en)	1998-11-27	Components and catalysts for the polymerization of olefins
US5869418A (en)	1999-02-09	Stereospecific catalyst system for polymerization of olefins
IL107958A (en)	1998-09-24	Spherical catalyst components for the polymerization of olefins their preparation and catalysts comprising them
KR20040018238A (ko)	2004-03-02	올레핀 중합용 성분 및 촉매
US5236962A (en)	1993-08-17	Crystalline propylene polymers and copolymers in the form of spherical particles at high porosity
EP1483301B1 (fr)	2009-02-18	Procede de preparation d'un composant catalytique a base de diether
US5275993A (en)	1994-01-04	Olefin polymerization catalyst
EP1483302B1 (fr)	2008-01-02	Procede de polymerisation d'olefines
CZ288057B6 (cs)	2001-04-11	Katalytická složka a katalyzátor pro polymeraci olefinů
FI104632B (fi)	2000-03-15	Menetelmä olefiinien polymeroimiseksi ja näin saadut polymeerit ja kopolymeerit
CN114729068A (zh)	2022-07-08	用于烯烃的聚合的催化剂组合物