TR200200545T2 - Rodyum/inorganik iyodid katalizör sistemi. - Google Patents
Rodyum/inorganik iyodid katalizör sistemi.Info
- Publication number
- TR200200545T2 TR200200545T2 TR2002/00545T TR200200545T TR200200545T2 TR 200200545 T2 TR200200545 T2 TR 200200545T2 TR 2002/00545 T TR2002/00545 T TR 2002/00545T TR 200200545 T TR200200545 T TR 200200545T TR 200200545 T2 TR200200545 T2 TR 200200545T2
- Authority
- TR
- Turkey
- Prior art keywords
- rhodium
- catalyst system
- iodide catalyst
- inorganic iodide
- production
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title 1
- 229910001505 inorganic iodide Inorganic materials 0.000 title 1
- 229910052703 rhodium Inorganic materials 0.000 title 1
- 239000010948 rhodium Substances 0.000 title 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 238000000034 method Methods 0.000 abstract 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- 238000005810 carbonylation reaction Methods 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 2
- IQGZCSXWIRBTRW-ZZXKWVIFSA-N (2E)-2-ethyl-2-butenal Chemical compound CC\C(=C/C)C=O IQGZCSXWIRBTRW-ZZXKWVIFSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 abstract 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Mevcut bulusa göre olan yöntem, esasen karbonil kirliliklerinin üretimi indirgeyen teknigin bilinen durumu itibari ile bilinen metanol karbonilasyon yöntemlerine bir gelistirme saglamaktadir. Metanol karbonilasyon reaksiyonlarinda karbonil kirliliklerinin, özellikle asetaldehid, krotonaldehid ve 2-etil krotonaldehid üretiminin yaklasik 15 ila yaklasik 40 atmosfer toplam reaksiyon basincindaki 0.1 ila 4 psia arasindaki bir kismi hidrojen basincinda azaldigi bulunmustur.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/386,708 US6303813B1 (en) | 1999-08-31 | 1999-08-31 | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR200200545T2 true TR200200545T2 (tr) | 2002-08-21 |
Family
ID=23526710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2002/00545T TR200200545T2 (tr) | 1999-08-31 | 2000-08-07 | Rodyum/inorganik iyodid katalizör sistemi. |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US6303813B1 (tr) |
| EP (1) | EP1208073B1 (tr) |
| JP (1) | JP4994549B2 (tr) |
| KR (1) | KR100651455B1 (tr) |
| CN (1) | CN1185198C (tr) |
| AR (1) | AR025310A1 (tr) |
| AT (1) | ATE295342T1 (tr) |
| AU (1) | AU775283B2 (tr) |
| BR (1) | BR0013463A (tr) |
| CA (1) | CA2381420C (tr) |
| CZ (1) | CZ2002753A3 (tr) |
| DE (1) | DE60020128T2 (tr) |
| ES (1) | ES2240139T3 (tr) |
| MX (1) | MXPA02002255A (tr) |
| MY (1) | MY131985A (tr) |
| NO (1) | NO327989B1 (tr) |
| NZ (1) | NZ517677A (tr) |
| PL (1) | PL199388B1 (tr) |
| RS (1) | RS50170B (tr) |
| RU (1) | RU2240305C2 (tr) |
| TR (1) | TR200200545T2 (tr) |
| TW (1) | TW506964B (tr) |
| UA (1) | UA70385C2 (tr) |
| WO (1) | WO2001016070A1 (tr) |
| ZA (1) | ZA200200935B (tr) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4526381B2 (ja) * | 2004-12-27 | 2010-08-18 | ダイセル化学工業株式会社 | 酢酸の製造方法 |
| US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| CN103038206B (zh) | 2010-06-14 | 2016-10-05 | 塞拉尼斯国际公司 | 羰基化方法 |
| US8835681B2 (en) | 2010-06-14 | 2014-09-16 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst |
| US8785684B2 (en) | 2010-06-14 | 2014-07-22 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids |
| ES2688801T5 (es) | 2010-12-15 | 2022-03-29 | Daicel Corp | Método de producción de ácido acético |
| WO2012081417A1 (ja) | 2010-12-15 | 2012-06-21 | 株式会社ダイセル | 酢酸の製造方法 |
| BR112014014610A2 (pt) | 2011-12-16 | 2017-06-13 | Celanese Int Corp | produção de ácido acético com estabilidade de catalisador aprimorada |
| TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
| CN105143169B (zh) | 2013-03-15 | 2017-06-23 | 国际人造丝公司 | 使用羰基化方法分离产品气体的方法 |
| US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| US9540304B2 (en) * | 2014-11-14 | 2017-01-10 | Celanese International Corporation | Processes for producing an acetic acid product having low butyl acetate content |
| EP3218347B1 (en) | 2014-11-14 | 2020-04-29 | Celanese International Corporation | Processes for producing acetic acid from a reaction medium having low ethyl iodide content |
| US9260369B1 (en) * | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
| KR102493819B1 (ko) * | 2014-11-14 | 2023-01-30 | 셀라니즈 인터내셔날 코포레이션 | 철을 제거하는 것에 의하여 아세트산 수율을 개선하기 위한 방법 |
| SG11201703442TA (en) * | 2014-11-14 | 2017-05-30 | Celanese Int Corp | Process for producing acetic acid by introducing a lithium compound |
| US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| BR112019017835A2 (pt) * | 2017-03-08 | 2020-04-14 | Daicel Corp | método para produzir ácido acético |
| US10550058B2 (en) | 2017-03-08 | 2020-02-04 | Daicel Corporation | Method for producing acetic acid |
| KR102281510B1 (ko) | 2017-03-22 | 2021-07-26 | 주식회사 다이셀 | 아세트산의 제조 방법 |
| CN107141213A (zh) * | 2017-05-24 | 2017-09-08 | 北京三聚环保新材料股份有限公司 | 一种甲醇羰基化合成醋酸的方法 |
| WO2019229858A1 (ja) * | 2018-05-29 | 2019-12-05 | 株式会社ダイセル | 酢酸の製造方法 |
| CN116217369A (zh) * | 2022-12-30 | 2023-06-06 | 江苏索普化工股份有限公司 | 一种提高甲醇低压羰基合成醋酸中三碘化铑溶解度的方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
| CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
| KR0168207B1 (ko) * | 1993-08-18 | 1999-03-20 | 고지마 아키로 | 무수아세트산 또는 무수아세트산 및 아세트산의 제조방법 |
| FR2711365B1 (fr) * | 1993-10-19 | 1995-12-15 | Rhone Poulenc Chimie | Procédé d'hydroxycarbonylation du butadiène. |
| US5625095A (en) | 1994-06-15 | 1997-04-29 | Daicel Chemical Industries, Ltd. | Process for producing high purity acetic acid |
| GB9503382D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
| IN192600B (tr) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
| JPH10231267A (ja) * | 1997-02-19 | 1998-09-02 | Chiyoda Corp | 有機カルボン酸の製造方法 |
| GB9712601D0 (en) * | 1997-06-16 | 1997-08-20 | Bp Chem Int Ltd | Chemical process |
| GB9816564D0 (en) * | 1998-07-31 | 1998-09-30 | Bp Chem Int Ltd | Process |
-
1999
- 1999-08-31 US US09/386,708 patent/US6303813B1/en not_active Expired - Lifetime
-
2000
- 2000-07-08 UA UA2002021703A patent/UA70385C2/uk unknown
- 2000-08-07 RS YUP-115/02A patent/RS50170B/sr unknown
- 2000-08-07 DE DE60020128T patent/DE60020128T2/de not_active Expired - Lifetime
- 2000-08-07 RU RU2002107997/04A patent/RU2240305C2/ru not_active IP Right Cessation
- 2000-08-07 PL PL353356A patent/PL199388B1/pl not_active IP Right Cessation
- 2000-08-07 KR KR1020027002419A patent/KR100651455B1/ko not_active Expired - Fee Related
- 2000-08-07 WO PCT/US2000/021562 patent/WO2001016070A1/en not_active Ceased
- 2000-08-07 CN CNB008122628A patent/CN1185198C/zh not_active Expired - Fee Related
- 2000-08-07 ES ES00952611T patent/ES2240139T3/es not_active Expired - Lifetime
- 2000-08-07 AT AT00952611T patent/ATE295342T1/de active
- 2000-08-07 CA CA002381420A patent/CA2381420C/en not_active Expired - Fee Related
- 2000-08-07 CZ CZ2002753A patent/CZ2002753A3/cs unknown
- 2000-08-07 AU AU65277/00A patent/AU775283B2/en not_active Ceased
- 2000-08-07 EP EP00952611A patent/EP1208073B1/en not_active Expired - Lifetime
- 2000-08-07 JP JP2001519640A patent/JP4994549B2/ja not_active Expired - Lifetime
- 2000-08-07 MX MXPA02002255A patent/MXPA02002255A/es active IP Right Grant
- 2000-08-07 BR BR0013463-5A patent/BR0013463A/pt not_active Application Discontinuation
- 2000-08-07 TR TR2002/00545T patent/TR200200545T2/tr unknown
- 2000-08-07 NZ NZ517677A patent/NZ517677A/en not_active IP Right Cessation
- 2000-08-17 AR ARP000104257A patent/AR025310A1/es active IP Right Grant
- 2000-08-29 MY MYPI20003980A patent/MY131985A/en unknown
- 2000-08-29 TW TW089117495A patent/TW506964B/zh not_active IP Right Cessation
-
2002
- 2002-02-01 ZA ZA200200935A patent/ZA200200935B/en unknown
- 2002-02-27 NO NO20020961A patent/NO327989B1/no not_active IP Right Cessation
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