UA46826C2 - Фунгіцидні 2-метоксибензофенони та композиція на їх основі - Google Patents

Фунгіцидні 2-метоксибензофенони та композиція на їх основі Download PDF

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Publication number
UA46826C2
UA46826C2 UA98084467A UA98084467A UA46826C2 UA 46826 C2 UA46826 C2 UA 46826C2 UA 98084467 A UA98084467 A UA 98084467A UA 98084467 A UA98084467 A UA 98084467A UA 46826 C2 UA46826 C2 UA 46826C2
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UA
Ukraine
Prior art keywords
benzophenone
methyl
chloro
trimethoxy
dimethyl
Prior art date
Application number
UA98084467A
Other languages
English (en)
Russian (ru)
Ukrainian (uk)
Inventor
Юрген Куртце
Герд Моршхойзер
Карл-Отто Штумм
Гвідо Альберт
Гвидо Альберт
Гюнтер Райхерт
Вернер Зімон
Андреас Вальдек
Хенрі Ван Туіль Коттер
Аннерозе Едіт Елізе Реніг
Original Assignee
Амерікан Ціанамід Компані
Американ Цианамид Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25435014&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=UA46826(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Амерікан Ціанамід Компані, Американ Цианамид Компани filed Critical Амерікан Ціанамід Компані
Publication of UA46826C2 publication Critical patent/UA46826C2/uk

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/45—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by at least one doubly—bound oxygen atom, not being part of a —CHO group
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C07C45/676—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton by elimination of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
    • C07C65/24—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups polycyclic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
UA98084467A 1997-08-20 1998-08-17 Фунгіцидні 2-метоксибензофенони та композиція на їх основі UA46826C2 (uk)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/914,966 US5945567A (en) 1997-08-20 1997-08-20 Fungicidal 2-methoxybenzophenones

Publications (1)

Publication Number Publication Date
UA46826C2 true UA46826C2 (uk) 2002-06-17

Family

ID=25435014

Family Applications (1)

Application Number Title Priority Date Filing Date
UA98084467A UA46826C2 (uk) 1997-08-20 1998-08-17 Фунгіцидні 2-метоксибензофенони та композиція на їх основі

Country Status (25)

Country Link
US (2) US5945567A (ro)
JP (1) JP4416851B2 (ro)
KR (2) KR100659806B1 (ro)
CN (2) CN1300084C (ro)
AR (1) AR016392A1 (ro)
BG (1) BG64048B1 (ro)
BR (1) BR9803198B1 (ro)
CA (1) CA2245124C (ro)
CO (1) CO5050332A1 (ro)
CZ (1) CZ294488B6 (ro)
EA (1) EA002606B1 (ro)
EE (1) EE03962B1 (ro)
GE (1) GEP20032878B (ro)
HR (1) HRP980439B1 (ro)
HU (1) HU225229B1 (ro)
ID (1) ID20744A (ro)
IL (2) IL169544A (ro)
MY (1) MY126559A (ro)
PL (1) PL193675B1 (ro)
RO (1) RO120905B1 (ro)
SK (1) SK283231B6 (ro)
TR (1) TR199801629A2 (ro)
TW (1) TW382013B (ro)
UA (1) UA46826C2 (ro)
ZA (1) ZA987489B (ro)

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US6242498B1 (en) * 1997-08-20 2001-06-05 Juergen Curtze Fungicidal 2,6,6′-trimethylbenzophenones
US6277856B1 (en) * 1998-09-25 2001-08-21 American Cynamid Co. Fungicidal mixtures
US6346535B1 (en) * 1999-01-29 2002-02-12 American Cyanamid Company Fungicidal mixtures
US6444618B1 (en) 1999-01-29 2002-09-03 Basf Aktiengesellschaft Crop protection emulsifiable concentrate containing defoaming agents
US6383984B1 (en) 1999-01-29 2002-05-07 Basf Aktiengesellschaft Aqueous suspension concentrate
US6521628B1 (en) 1999-01-29 2003-02-18 Basf Aktiengesellschaft Fungicidal mixtures
US6613806B1 (en) 1999-01-29 2003-09-02 Basf Corporation Enhancement of the efficacy of benzoylbenzenes
GB9912220D0 (en) 1999-05-26 1999-07-28 Novartis Ag Organic compounds
GB9912219D0 (en) 1999-05-26 1999-07-28 Novartis Ag Organic compounds
JP2003501448A (ja) * 1999-06-14 2003-01-14 シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト 併合殺菌剤
US6559336B2 (en) 1999-07-15 2003-05-06 Basf Aktiengesellschaft Process for the preparation of 5- and/or 6-substituted-2-hydroxybenzoic acid esters
KR100651090B1 (ko) 1999-07-15 2006-11-29 바스프 악티엔게젤샤프트 5- 및(또는) 6-치환-2-히드록시벤조산 에스테르의 제조 방법
US6699874B2 (en) 1999-09-24 2004-03-02 Basf Aktiengesellschaft Fungicidal mixtures
GB0010198D0 (en) * 2000-04-26 2000-06-14 Novartis Ag Organic compounds
GB0028702D0 (en) * 2000-11-24 2001-01-10 Novartis Ag Organic compounds
US20040053984A1 (en) * 2001-01-18 2004-03-18 Ptoc K Arne Fungicidal mixtures comprising benzophenone and imidazole derivatives
WO2002072523A1 (de) * 2001-03-13 2002-09-19 Basf Aktiengesellschaft Benzophenone, deren herstellung und verwendung zur bekämpfung von pflanzenpathogenen pilzen
NZ555495A (en) 2002-03-21 2008-07-31 Basf Ag Fungicidal mixtures containing prothioconazole and metrafenone
ES2316819T3 (es) * 2002-07-11 2009-04-16 Basf Se Empleo de fungicidas.
WO2004045288A2 (de) * 2002-11-15 2004-06-03 Basf Aktiengesellschaft Fungizide mischungen zur bekämpfung von reispathogenen
UA79182C2 (en) * 2002-12-13 2007-05-25 Basf Ag Method for the production of benzophenones
DE10349501A1 (de) 2003-10-23 2005-05-25 Bayer Cropscience Ag Synergistische fungizide Wirkstoffkombinationen
EP1744629B1 (de) 2004-04-30 2012-12-05 Basf Se Fungizide mischungen
DE102004049761A1 (de) * 2004-10-12 2006-04-13 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE102005015677A1 (de) 2005-04-06 2006-10-12 Bayer Cropscience Ag Synergistische fungizide Wirkstoffkombinationen
DK1912503T3 (da) 2005-08-05 2014-11-03 Basf Se Fungicide blandinger indeholdende substituerede 1-methyl-pyrazol-4-ylcarboxylsyreanilider
DE102006023263A1 (de) 2006-05-18 2007-11-22 Bayer Cropscience Ag Synergistische Wirkstoffkombinationen
AU2007298999B2 (en) 2006-09-18 2013-11-07 Basf Se Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide
EP2258177A3 (en) 2006-12-15 2011-11-09 Rohm and Haas Company Mixtures comprising 1-methylcyclopropene
EP2109366A2 (en) 2007-02-06 2009-10-21 Basf Se Pesticidal mixtures
US20100093715A1 (en) 2007-04-23 2010-04-15 Basf Se Plant productivity enhancement by combining chemical agents with transgenic modifications
EA020203B1 (ru) 2007-09-20 2014-09-30 Басф Се Композиции и агенты, содержащие фунгицидный штамм и активное соединение
JP2010540495A (ja) 2007-09-26 2010-12-24 ビーエーエスエフ ソシエタス・ヨーロピア ボスカリド及びクロロタロニルを含む三成分殺菌組成物
CN103980109B (zh) * 2009-07-07 2017-05-03 拜尔农作物科学股份公司 制备（2,4‑二甲基联苯‑3‑基）乙酸、其酯及中间体化合物的方法
WO2011026796A1 (en) 2009-09-01 2011-03-10 Basf Se Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi
BR112013014913A2 (pt) 2010-12-20 2016-07-19 Basf Se misturas pesticidas, composição pesticida ou parasiticida, método para proteger os vegetais do ataque ou da infestação por insetos, para o controle dos insetos, para o controle dos fungos fitopatogênicos prejudiciais, para a proteção dos vegetais dos fungos fitopatogênicos prejudiciais, para a proteção do material de propagação dos vegetais, para a proteção dos animais contra a infestação ou infecção por parasitas, para o tratamento dos aminais infectados ou infectados por parasitas e utilização
EP2481284A3 (en) 2011-01-27 2012-10-17 Basf Se Pesticidal mixtures
WO2012127009A1 (en) 2011-03-23 2012-09-27 Basf Se Compositions containing polymeric, ionic compounds comprising imidazolium groups
CN103987261A (zh) 2011-09-02 2014-08-13 巴斯夫欧洲公司 包含芳基喹唑啉酮化合物的农业混合物
EP3646731A1 (en) 2012-06-20 2020-05-06 Basf Se Pesticidal mixtures comprising a pyrazole compound
CN102823597A (zh) * 2012-09-13 2012-12-19 陕西上格之路生物科学有限公司 一种含苯菌酮和苯氧喹啉的杀菌组合物
US20150257383A1 (en) 2012-10-12 2015-09-17 Basf Se Method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material
EA030875B1 (ru) 2012-12-20 2018-10-31 Басф Агро Б.В. Композиции, содержащие триазольное соединение
EP2783569A1 (en) 2013-03-28 2014-10-01 Basf Se Compositions comprising a triazole compound
EP2835052A1 (en) 2013-08-07 2015-02-11 Basf Se Fungicidal mixtures comprising pyrimidine fungicides
CA2923101A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
WO2015036059A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
CN103858872B (zh) * 2014-03-15 2017-06-30 海南正业中农高科股份有限公司 含苯菌酮的农药组合物
EP2979549A1 (en) 2014-07-31 2016-02-03 Basf Se Method for improving the health of a plant
CA2963446A1 (en) 2014-10-24 2016-04-28 Basf Se Nonampholytic, quaternizable and water-soluble polymers for modifying the surface charge of solid particles
CN107033006B (zh) * 2016-02-04 2018-12-18 长沙理工大学 一种二芳基酮的制备方法
EP3443842A4 (en) * 2016-04-15 2019-09-11 Ishihara Sangyo Kaisha, Ltd. METHOD FOR POTENTIATING THE PLANT-DISEASING EFFECT OF AN ARYLPHENYLKETONE FUNGICIDE AND METHOD FOR CONTROLLING PLANT DISEASES
IL257535B (en) 2018-02-14 2020-01-30 N3 Coat Ltd Benzophenone compounds as light catalysts for polyolefins
GB2592668B (en) * 2020-03-06 2024-08-14 Rotam Agrochem Int Co Ltd A novel form of metrafenone, a process for its preparation and use of the same
CN113060808A (zh) * 2021-03-19 2021-07-02 衡阳市建衡实业有限公司 一种含聚氯化铝的水处理剂及其制备方法

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US5248817A (en) * 1991-07-15 1993-09-28 Merck & Co., Inc. Process for aromatic bromination
CZ294096B6 (cs) * 1995-01-20 2004-10-13 Americanácyanamidácompany Benzofenonové sloučeninyŹ způsob jejich výrobyŹ fungicidní prostředky s jejich obsahem a způsob ochrany rostlin

Also Published As

Publication number Publication date
HRP980439A2 (en) 1999-06-30
TR199801629A3 (tr) 1999-10-21
JP4416851B2 (ja) 2010-02-17
HU225229B1 (en) 2006-08-28
SK113198A3 (en) 2000-02-14
HRP980439B1 (en) 2003-08-31
KR100659806B1 (ko) 2007-05-17
GEP20032878B (en) 2003-02-25
CZ294488B6 (cs) 2005-01-12
CA2245124A1 (en) 1999-02-20
EA199800645A1 (ru) 1999-02-25
IL169544A (en) 2009-08-03
CZ256898A3 (cs) 1999-03-17
ZA987489B (en) 2000-02-21
SK283231B6 (sk) 2003-04-01
BG64048B1 (bg) 2003-11-28
TR199801629A2 (xx) 1999-10-21
CN1147456C (zh) 2004-04-28
EA002606B1 (ru) 2002-06-27
KR19990023639A (ko) 1999-03-25
AR016392A1 (es) 2001-07-04
CN1300084C (zh) 2007-02-14
HU9801900D0 (en) 1998-10-28
CA2245124C (en) 2008-08-05
US5945567A (en) 1999-08-31
BR9803198B1 (pt) 2008-11-18
PL328112A1 (en) 1999-03-01
RO120905B1 (ro) 2006-09-29
TW382013B (en) 2000-02-11
CN1495153A (zh) 2004-05-12
JPH11171818A (ja) 1999-06-29
KR20060014458A (ko) 2006-02-15
BR9803198A (pt) 2000-03-28
US5922905A (en) 1999-07-13
EE9800301A (et) 1999-04-15
EE03962B1 (et) 2003-02-17
CN1217317A (zh) 1999-05-26
HUP9801900A2 (hu) 1999-06-28
PL193675B1 (pl) 2007-03-30
BG102704A (en) 1999-10-29
IL125788A0 (en) 1999-04-11
CO5050332A1 (es) 2001-06-27
MY126559A (en) 2006-10-31
ID20744A (id) 1999-02-25
KR100693645B1 (ko) 2007-03-14
HUP9801900A3 (en) 2001-02-28
IL125788A (en) 2005-11-20

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