BE1014058A5 - Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants. - Google Patents

Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants. Download PDF

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Publication number
BE1014058A5
BE1014058A5 BE2001/0181A BE200100181A BE1014058A5 BE 1014058 A5 BE1014058 A5 BE 1014058A5 BE 2001/0181 A BE2001/0181 A BE 2001/0181A BE 200100181 A BE200100181 A BE 200100181A BE 1014058 A5 BE1014058 A5 BE 1014058A5
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BE
Belgium
Prior art keywords
diethyl
derivatives
alkoxy
alcoxypiperidines
oxides
Prior art date
Application number
BE2001/0181A
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English (en)
Inventor
Peter Nesvadba
Andreas Kramer
Marie-Odile Zink
Original Assignee
Ciba Sc Holding Ag
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Publication date
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Publication of BE1014058A5 publication Critical patent/BE1014058A5/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)

Abstract

La présente invention concerne certains dérivés de 1-alcoxy-2,2-diéthyle-6,6-diméthylpipéridines et de 1-alcoxy-2,6-diéthyl-2,3,6-triméthylpipéridines substituées en position 4 par un atome d'oxygène ou d'azote; une composition polymérisable comprenant a) au moins un monomère à insaturation éthylénique et b) lesdits dérivés de pipéridine. D'autres aspects de la présente invention concernent un procédé de polymérisation de monomères à insaturation éthylénique et l'utilisation éthylénique et l'utilisation de dérivés de 1-alcoxy-2,2-diéthyl-6,6-diméthylpipéridines et de 1-alcoxy-2,6-diéthyl-2,3,6-triméthylpipéridines substituées en position 4 par un atome d'oxygéne ou d'azote pour une polymérisation contrôlée...
BE2001/0181A 2000-03-22 2001-03-20 Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants. BE1014058A5 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22

Publications (1)

Publication Number Publication Date
BE1014058A5 true BE1014058A5 (fr) 2003-03-04

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
BE2001/0181A BE1014058A5 (fr) 2000-03-22 2001-03-20 Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants.

Country Status (16)

Country Link
US (3) US6624306B2 (fr)
JP (1) JP2001316365A (fr)
KR (1) KR100743975B1 (fr)
CN (1) CN1319590A (fr)
AU (1) AU784894B2 (fr)
BE (1) BE1014058A5 (fr)
BR (1) BR0101108A (fr)
CA (1) CA2341791C (fr)
DE (1) DE10113209A1 (fr)
ES (1) ES2173046B1 (fr)
FR (1) FR2806720B1 (fr)
GB (1) GB2361235B (fr)
IT (1) ITMI20010546A1 (fr)
NL (1) NL1017635C2 (fr)
NO (1) NO20011436L (fr)
TW (1) TW541303B (fr)

Families Citing this family (27)

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SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
JP4389247B2 (ja) * 2001-06-13 2009-12-24 チバ ホールディング インコーポレーテッド ４−イミノ−ｎ−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
CA2467119C (fr) * 2001-12-21 2012-02-07 Ciba Specialty Chemicals Holding Inc. Nouveaux composes ignifuges
US8013062B2 (en) * 2002-01-22 2011-09-06 Arkema France Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerization in the presence of nitroxides
US7297819B2 (en) * 2002-03-05 2007-11-20 Ciba Specialty Chemicals Corp. Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
WO2005032479A2 (fr) * 2003-10-01 2005-04-14 Unviversity Of Florida Research Foundation, Inc. Compositions et methodes d'inhibition selective des recepteurs nicotiniques de l'acetylcholine
EP1675629A1 (fr) * 2003-10-07 2006-07-05 Coloplast A/S Composition adhesive et utilisation de cette composition
WO2005118651A1 (fr) * 2004-05-27 2005-12-15 Ciba Specialty Chemicals Holding Inc. Alcoxyamines contenant un groupe polymerisable par voie radicalaire
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
BRPI0807571A2 (pt) * 2007-02-22 2014-07-01 Othera Holding Inc Compostos de hidroxilamina e métodos de seu uso
KR20090127193A (ko) * 2007-04-05 2009-12-09 바스프 에스이 선택 공중합체를 포함하는 선스크린 및 개인 위생 조성물
WO2008145595A1 (fr) * 2007-06-01 2008-12-04 Basf Se Surfaces imprimables modifiées
WO2009156277A1 (fr) 2008-06-23 2009-12-30 Basf Se Dispersants pour pigments à base de copolymères modifiés
CN102137889B (zh) * 2008-08-28 2013-11-13 巴斯夫欧洲公司 用于无生命有机材料的稳定剂
KR101524342B1 (ko) 2010-03-30 2015-07-06 바스프 에스이 말단-관능화 중합체
JP4821916B1 (ja) 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
WO2012000992A1 (fr) 2010-06-29 2012-01-05 Basf Se Procédé pour améliorer les propriétés d'écoulement de polymères en fusion
WO2013060708A1 (fr) 2011-10-25 2013-05-02 Basf Se Utilisation de copolymères en peigne ou séquencés comme agents anti-redéposition de la saleté et agents de libération de la saleté dans des processus de blanchisserie
CN104125984B9 (zh) 2012-02-23 2017-09-22 巴斯夫欧洲公司 具有低动态表面张力的氟代丙烯酸酯嵌段共聚物
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
CN111278934B (zh) 2017-10-23 2022-04-12 巴斯夫欧洲公司 硅氧烷聚合物水乳液
EP4314155B1 (fr) 2021-03-26 2025-04-09 Basf Se Composition polymère comprenant un copolymère à blocs polyacryliques et un polyalkylnéoxyde à base aromatique comme dispersant
CN120271495B (zh) * 2025-06-12 2025-09-19 成都道合尔医药技术有限公司 一种(3r,4r)-n-pg-4-氨基-3-甲基哌啶的合成方法

Citations (2)

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DE2621870A1 (de) * 1975-05-28 1976-12-16 Ciba Geigy Ag Neue derivate von 4-aminopiperidin
DE19909767A1 (de) * 1998-03-09 1999-09-16 Ciba Geigy Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler

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Publication number Priority date Publication date Assignee Title
DE2621870A1 (de) * 1975-05-28 1976-12-16 Ciba Geigy Ag Neue derivate von 4-aminopiperidin
DE19909767A1 (de) * 1998-03-09 1999-09-16 Ciba Geigy Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler

Also Published As

Publication number Publication date
GB2361235B (en) 2002-06-12
KR100743975B1 (ko) 2007-07-30
AU784894B2 (en) 2006-07-20
ES2173046A1 (es) 2002-10-01
CA2341791C (fr) 2010-02-23
CA2341791A1 (fr) 2001-09-22
CN1319590A (zh) 2001-10-31
US6891008B2 (en) 2005-05-10
FR2806720B1 (fr) 2006-12-08
KR20010092697A (ko) 2001-10-26
FR2806720A1 (fr) 2001-09-28
GB2361235A (en) 2001-10-17
GB0105678D0 (en) 2001-04-25
JP2001316365A (ja) 2001-11-13
US20050143539A1 (en) 2005-06-30
DE10113209A1 (de) 2001-09-27
NL1017635C2 (nl) 2001-09-25
BR0101108A (pt) 2001-11-06
US7160966B2 (en) 2007-01-09
US20030166939A1 (en) 2003-09-04
US20030065184A1 (en) 2003-04-03
TW541303B (en) 2003-07-11
NO20011436D0 (no) 2001-03-21
NO20011436L (no) 2001-09-24
ITMI20010546A1 (it) 2002-09-15
US6624306B2 (en) 2003-09-23
ES2173046B1 (es) 2004-06-16
AU2804901A (en) 2001-09-27

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