BR0101108A - Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes - Google Patents

Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes

Info

Publication number
BR0101108A
BR0101108A BR0101108-1A BR0101108A BR0101108A BR 0101108 A BR0101108 A BR 0101108A BR 0101108 A BR0101108 A BR 0101108A BR 0101108 A BR0101108 A BR 0101108A
Authority
BR
Brazil
Prior art keywords
diethyl
alkoxy
piperidine
dimethyl
derivatives
Prior art date
Application number
BR0101108-1A
Other languages
English (en)
Inventor
Peter Nesvadba
Marie-Odile Zink
Andreas Kramer
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of BR0101108A publication Critical patent/BR0101108A/pt

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94Oxygen atom, e.g. piperidine N-oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Patente de Invenção: "COMPOSTOS DE 2,2,6,6-DIETIL-DIMETIL-1-ALCóXI-PIPERIDINA E SEUS 1-óXIDOS CORRESPONDENTES". A presente invenção refere-se a derivados selecionados de 1-alcóxi-2,2-dietil-6,6-dimetil piperidina e de 1-alcóxi-2,6-dietil-2,3,6-trimetil piperidina que estão substituídos na posição 4 por um átomo de oxigênio ou de nitrogênio; a uma composição polimerizável que compreende a)pelo menos um monómero etilenicamente insaturado e b) os ditos derivados de piperidina. Outros aspectos da presente invenção são um processo para a polimerização de monómeros etilenicamente insaturados e para o uso de derivados de 1-alcóxi-2,2-dietil-6,6-dimetil piperidina e de 1-alcóxi-2,6-dietil-2,3,6-trimetil piperidina que estão substituídos na posição 4 por um átomo de oxigênio ou de nitrogênio para polimerização controlada. Os derivados de N-oxila intermediários, uma composição dos derivados de N-oxila com monómeros etilenicamente insaturados e um iniciador de radical livre, assim como um processo para a polimerização também são assuntos da presente invenção.
BR0101108-1A 2000-03-22 2001-03-21 Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes BR0101108A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22

Publications (1)

Publication Number Publication Date
BR0101108A true BR0101108A (pt) 2001-11-06

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0101108-1A BR0101108A (pt) 2000-03-22 2001-03-21 Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes

Country Status (16)

Country Link
US (3) US6624306B2 (pt)
JP (1) JP2001316365A (pt)
KR (1) KR100743975B1 (pt)
CN (1) CN1319590A (pt)
AU (1) AU784894B2 (pt)
BE (1) BE1014058A5 (pt)
BR (1) BR0101108A (pt)
CA (1) CA2341791C (pt)
DE (1) DE10113209A1 (pt)
ES (1) ES2173046B1 (pt)
FR (1) FR2806720B1 (pt)
GB (1) GB2361235B (pt)
IT (1) ITMI20010546A1 (pt)
NL (1) NL1017635C2 (pt)
NO (1) NO20011436L (pt)
TW (1) TW541303B (pt)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
JP4389247B2 (ja) * 2001-06-13 2009-12-24 チバ ホールディング インコーポレーテッド 4−イミノ−n−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
CA2467119C (en) * 2001-12-21 2012-02-07 Ciba Specialty Chemicals Holding Inc. Novel flame retarding compounds
US8013062B2 (en) * 2002-01-22 2011-09-06 Arkema France Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerization in the presence of nitroxides
US7297819B2 (en) * 2002-03-05 2007-11-20 Ciba Specialty Chemicals Corp. Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
WO2005032479A2 (en) * 2003-10-01 2005-04-14 Unviversity Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
EP1675629A1 (en) * 2003-10-07 2006-07-05 Coloplast A/S An adhesive composition and use of such composition
WO2005118651A1 (en) * 2004-05-27 2005-12-15 Ciba Specialty Chemicals Holding Inc. Alkoxyamines containing a radically polymerizable group
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
BRPI0807571A2 (pt) * 2007-02-22 2014-07-01 Othera Holding Inc Compostos de hidroxilamina e métodos de seu uso
KR20090127193A (ko) * 2007-04-05 2009-12-09 바스프 에스이 선택 공중합체를 포함하는 선스크린 및 개인 위생 조성물
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
WO2009156277A1 (en) 2008-06-23 2009-12-30 Basf Se Pigment dispersants with modified copolymers
CN102137889B (zh) * 2008-08-28 2013-11-13 巴斯夫欧洲公司 用于无生命有机材料的稳定剂
KR101524342B1 (ko) 2010-03-30 2015-07-06 바스프 에스이 말단-관능화 중합체
JP4821916B1 (ja) 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
WO2012000992A1 (en) 2010-06-29 2012-01-05 Basf Se Process for improving the flow properties of polymer melts
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
CN104125984B9 (zh) 2012-02-23 2017-09-22 巴斯夫欧洲公司 具有低动态表面张力的氟代丙烯酸酯嵌段共聚物
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
CN111278934B (zh) 2017-10-23 2022-04-12 巴斯夫欧洲公司 硅氧烷聚合物水乳液
EP4314155B1 (en) 2021-03-26 2025-04-09 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant
CN120271495B (zh) * 2025-06-12 2025-09-19 成都道合尔医药技术有限公司 一种(3r,4r)-n-pg-4-氨基-3-甲基哌啶的合成方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5848580B2 (ja) * 1975-05-28 1983-10-29 三共株式会社 ゴウセイコウブンシザイリヨウヨウアンテイザイ
GB1492494A (en) * 1975-05-28 1977-11-23 Sankyo Co Derivatives of 4-aminopiperidine
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
US4141883A (en) * 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン 遊離基重合開始用化合物
DE3486145T2 (de) 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
DE69708896T2 (de) 1996-09-25 2002-06-20 Akzo Nobel N.V., Arnheim/Arnhem Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation
DE69829588T2 (de) 1997-01-10 2006-01-19 E.I. Du Pont De Nemours And Co., Wilmington Farblose wässrige Ammoniumsulfidlösung
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
WO1999003894A1 (en) 1997-07-15 1999-01-28 Ciba Specialty Chemicals Holding Inc. Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI246519B (en) * 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd (メタ)アクリル酸ピペリジン−1−オキシルエステル誘導体からなる(メタ)アクリル酸エステル用重合防止剤およびその製造方法
AU759408B2 (en) 1998-09-03 2003-04-17 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
ATE272610T1 (de) 1999-07-02 2004-08-15 Ciba Sc Holding Ag Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren

Also Published As

Publication number Publication date
GB2361235B (en) 2002-06-12
KR100743975B1 (ko) 2007-07-30
AU784894B2 (en) 2006-07-20
ES2173046A1 (es) 2002-10-01
CA2341791C (en) 2010-02-23
CA2341791A1 (en) 2001-09-22
CN1319590A (zh) 2001-10-31
US6891008B2 (en) 2005-05-10
FR2806720B1 (fr) 2006-12-08
BE1014058A5 (fr) 2003-03-04
KR20010092697A (ko) 2001-10-26
FR2806720A1 (fr) 2001-09-28
GB2361235A (en) 2001-10-17
GB0105678D0 (en) 2001-04-25
JP2001316365A (ja) 2001-11-13
US20050143539A1 (en) 2005-06-30
DE10113209A1 (de) 2001-09-27
NL1017635C2 (nl) 2001-09-25
US7160966B2 (en) 2007-01-09
US20030166939A1 (en) 2003-09-04
US20030065184A1 (en) 2003-04-03
TW541303B (en) 2003-07-11
NO20011436D0 (no) 2001-03-21
NO20011436L (no) 2001-09-24
ITMI20010546A1 (it) 2002-09-15
US6624306B2 (en) 2003-09-23
ES2173046B1 (es) 2004-06-16
AU2804901A (en) 2001-09-27

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A, 6A E 7A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1962 DE 12/08/2008.