BR0101108A - Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes - Google Patents
Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentesInfo
- Publication number
- BR0101108A BR0101108A BR0101108-1A BR0101108A BR0101108A BR 0101108 A BR0101108 A BR 0101108A BR 0101108 A BR0101108 A BR 0101108A BR 0101108 A BR0101108 A BR 0101108A
- Authority
- BR
- Brazil
- Prior art keywords
- diethyl
- alkoxy
- piperidine
- dimethyl
- derivatives
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Hydrogenated Pyridines (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Polymerization Catalysts (AREA)
Abstract
Patente de Invenção: "COMPOSTOS DE 2,2,6,6-DIETIL-DIMETIL-1-ALCóXI-PIPERIDINA E SEUS 1-óXIDOS CORRESPONDENTES". A presente invenção refere-se a derivados selecionados de 1-alcóxi-2,2-dietil-6,6-dimetil piperidina e de 1-alcóxi-2,6-dietil-2,3,6-trimetil piperidina que estão substituídos na posição 4 por um átomo de oxigênio ou de nitrogênio; a uma composição polimerizável que compreende a)pelo menos um monómero etilenicamente insaturado e b) os ditos derivados de piperidina. Outros aspectos da presente invenção são um processo para a polimerização de monómeros etilenicamente insaturados e para o uso de derivados de 1-alcóxi-2,2-dietil-6,6-dimetil piperidina e de 1-alcóxi-2,6-dietil-2,3,6-trimetil piperidina que estão substituídos na posição 4 por um átomo de oxigênio ou de nitrogênio para polimerização controlada. Os derivados de N-oxila intermediários, uma composição dos derivados de N-oxila com monómeros etilenicamente insaturados e um iniciador de radical livre, assim como um processo para a polimerização também são assuntos da presente invenção.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00810246 | 2000-03-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0101108A true BR0101108A (pt) | 2001-11-06 |
Family
ID=8174612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0101108-1A BR0101108A (pt) | 2000-03-22 | 2001-03-21 | Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes |
Country Status (16)
| Country | Link |
|---|---|
| US (3) | US6624306B2 (pt) |
| JP (1) | JP2001316365A (pt) |
| KR (1) | KR100743975B1 (pt) |
| CN (1) | CN1319590A (pt) |
| AU (1) | AU784894B2 (pt) |
| BE (1) | BE1014058A5 (pt) |
| BR (1) | BR0101108A (pt) |
| CA (1) | CA2341791C (pt) |
| DE (1) | DE10113209A1 (pt) |
| ES (1) | ES2173046B1 (pt) |
| FR (1) | FR2806720B1 (pt) |
| GB (1) | GB2361235B (pt) |
| IT (1) | ITMI20010546A1 (pt) |
| NL (1) | NL1017635C2 (pt) |
| NO (1) | NO20011436L (pt) |
| TW (1) | TW541303B (pt) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG82601A1 (en) * | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
| TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
| TWI274053B (en) * | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
| TW557305B (en) * | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
| JP4389247B2 (ja) * | 2001-06-13 | 2009-12-24 | チバ ホールディング インコーポレーテッド | 4−イミノ−n−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用 |
| US7868171B2 (en) * | 2001-11-12 | 2011-01-11 | Ciba Specialty Chemicals Corp. | N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators |
| CA2467119C (en) * | 2001-12-21 | 2012-02-07 | Ciba Specialty Chemicals Holding Inc. | Novel flame retarding compounds |
| US8013062B2 (en) * | 2002-01-22 | 2011-09-06 | Arkema France | Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerization in the presence of nitroxides |
| US7297819B2 (en) * | 2002-03-05 | 2007-11-20 | Ciba Specialty Chemicals Corp. | Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization |
| WO2005032479A2 (en) * | 2003-10-01 | 2005-04-14 | Unviversity Of Florida Research Foundation, Inc. | Compositions and methods for selective inhibition of nicotine acetylcholine receptors |
| EP1675629A1 (en) * | 2003-10-07 | 2006-07-05 | Coloplast A/S | An adhesive composition and use of such composition |
| WO2005118651A1 (en) * | 2004-05-27 | 2005-12-15 | Ciba Specialty Chemicals Holding Inc. | Alkoxyamines containing a radically polymerizable group |
| CN100577692C (zh) | 2005-01-11 | 2010-01-06 | 西巴特殊化学品控股有限公司 | 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法 |
| BRPI0807571A2 (pt) * | 2007-02-22 | 2014-07-01 | Othera Holding Inc | Compostos de hidroxilamina e métodos de seu uso |
| KR20090127193A (ko) * | 2007-04-05 | 2009-12-09 | 바스프 에스이 | 선택 공중합체를 포함하는 선스크린 및 개인 위생 조성물 |
| WO2008145595A1 (en) * | 2007-06-01 | 2008-12-04 | Basf Se | Modified printable surfaces |
| WO2009156277A1 (en) | 2008-06-23 | 2009-12-30 | Basf Se | Pigment dispersants with modified copolymers |
| CN102137889B (zh) * | 2008-08-28 | 2013-11-13 | 巴斯夫欧洲公司 | 用于无生命有机材料的稳定剂 |
| KR101524342B1 (ko) | 2010-03-30 | 2015-07-06 | 바스프 에스이 | 말단-관능화 중합체 |
| JP4821916B1 (ja) | 2010-05-07 | 2011-11-24 | 横浜ゴム株式会社 | 変性ポリマーの製造法 |
| WO2012000992A1 (en) | 2010-06-29 | 2012-01-05 | Basf Se | Process for improving the flow properties of polymer melts |
| WO2013060708A1 (en) | 2011-10-25 | 2013-05-02 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| CN104125984B9 (zh) | 2012-02-23 | 2017-09-22 | 巴斯夫欧洲公司 | 具有低动态表面张力的氟代丙烯酸酯嵌段共聚物 |
| US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
| CN111278934B (zh) | 2017-10-23 | 2022-04-12 | 巴斯夫欧洲公司 | 硅氧烷聚合物水乳液 |
| EP4314155B1 (en) | 2021-03-26 | 2025-04-09 | Basf Se | Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant |
| CN120271495B (zh) * | 2025-06-12 | 2025-09-19 | 成都道合尔医药技术有限公司 | 一种(3r,4r)-n-pg-4-氨基-3-甲基哌啶的合成方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5848580B2 (ja) * | 1975-05-28 | 1983-10-29 | 三共株式会社 | ゴウセイコウブンシザイリヨウヨウアンテイザイ |
| GB1492494A (en) * | 1975-05-28 | 1977-11-23 | Sankyo Co | Derivatives of 4-aminopiperidine |
| US4191683A (en) | 1975-05-28 | 1980-03-04 | Ciba-Geigy Corporation | Derivatives of 4-aminopiperidine as stabilizers for polymers |
| US4141883A (en) * | 1975-05-28 | 1979-02-27 | Sankyo Company, Limited | Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives |
| JPS6089452A (ja) * | 1983-07-11 | 1985-05-20 | コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン | 遊離基重合開始用化合物 |
| DE3486145T2 (de) | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
| DE69708896T2 (de) | 1996-09-25 | 2002-06-20 | Akzo Nobel N.V., Arnheim/Arnhem | Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation |
| DE69829588T2 (de) | 1997-01-10 | 2006-01-19 | E.I. Du Pont De Nemours And Co., Wilmington | Farblose wässrige Ammoniumsulfidlösung |
| US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| WO1999003894A1 (en) | 1997-07-15 | 1999-01-28 | Ciba Specialty Chemicals Holding Inc. | Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds |
| SG82601A1 (en) * | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
| TWI246519B (en) * | 1998-06-25 | 2006-01-01 | Ciba Sc Holding Ag | Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators |
| JP2000072718A (ja) * | 1998-09-01 | 2000-03-07 | Mitsubishi Rayon Co Ltd | (メタ)アクリル酸ピペリジン−1−オキシルエステル誘導体からなる(メタ)アクリル酸エステル用重合防止剤およびその製造方法 |
| AU759408B2 (en) | 1998-09-03 | 2003-04-17 | Ciba Specialty Chemicals Holding Inc. | Grafting of ethylenically unsaturated monomers onto polymers |
| ATE272610T1 (de) | 1999-07-02 | 2004-08-15 | Ciba Sc Holding Ag | Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren |
-
2001
- 2001-03-02 TW TW090104959A patent/TW541303B/zh active
- 2001-03-08 GB GB0105678A patent/GB2361235B/en not_active Expired - Fee Related
- 2001-03-15 IT IT2001MI000546A patent/ITMI20010546A1/it unknown
- 2001-03-16 AU AU28049/01A patent/AU784894B2/en not_active Ceased
- 2001-03-19 DE DE10113209A patent/DE10113209A1/de not_active Withdrawn
- 2001-03-19 US US09/811,959 patent/US6624306B2/en not_active Expired - Fee Related
- 2001-03-19 NL NL1017635A patent/NL1017635C2/nl not_active IP Right Cessation
- 2001-03-20 BE BE2001/0181A patent/BE1014058A5/fr not_active IP Right Cessation
- 2001-03-20 KR KR1020010014312A patent/KR100743975B1/ko not_active Expired - Fee Related
- 2001-03-20 CA CA2341791A patent/CA2341791C/en not_active Expired - Fee Related
- 2001-03-21 FR FR0103797A patent/FR2806720B1/fr not_active Expired - Fee Related
- 2001-03-21 BR BR0101108-1A patent/BR0101108A/pt not_active IP Right Cessation
- 2001-03-21 CN CN01111693A patent/CN1319590A/zh active Pending
- 2001-03-21 ES ES200100650A patent/ES2173046B1/es not_active Expired - Fee Related
- 2001-03-21 NO NO20011436A patent/NO20011436L/no not_active Application Discontinuation
- 2001-03-22 JP JP2001083293A patent/JP2001316365A/ja active Pending
-
2003
- 2003-01-21 US US10/348,088 patent/US6891008B2/en not_active Expired - Fee Related
-
2005
- 2005-02-01 US US11/048,677 patent/US7160966B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB2361235B (en) | 2002-06-12 |
| KR100743975B1 (ko) | 2007-07-30 |
| AU784894B2 (en) | 2006-07-20 |
| ES2173046A1 (es) | 2002-10-01 |
| CA2341791C (en) | 2010-02-23 |
| CA2341791A1 (en) | 2001-09-22 |
| CN1319590A (zh) | 2001-10-31 |
| US6891008B2 (en) | 2005-05-10 |
| FR2806720B1 (fr) | 2006-12-08 |
| BE1014058A5 (fr) | 2003-03-04 |
| KR20010092697A (ko) | 2001-10-26 |
| FR2806720A1 (fr) | 2001-09-28 |
| GB2361235A (en) | 2001-10-17 |
| GB0105678D0 (en) | 2001-04-25 |
| JP2001316365A (ja) | 2001-11-13 |
| US20050143539A1 (en) | 2005-06-30 |
| DE10113209A1 (de) | 2001-09-27 |
| NL1017635C2 (nl) | 2001-09-25 |
| US7160966B2 (en) | 2007-01-09 |
| US20030166939A1 (en) | 2003-09-04 |
| US20030065184A1 (en) | 2003-04-03 |
| TW541303B (en) | 2003-07-11 |
| NO20011436D0 (no) | 2001-03-21 |
| NO20011436L (no) | 2001-09-24 |
| ITMI20010546A1 (it) | 2002-09-15 |
| US6624306B2 (en) | 2003-09-23 |
| ES2173046B1 (es) | 2004-06-16 |
| AU2804901A (en) | 2001-09-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A, 6A E 7A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1962 DE 12/08/2008. |