BG62395B1 - Усъвършенстван метод за получаване на литииран шпинел наосновата на литиев и манганов оксид - Google Patents

Усъвършенстван метод за получаване на литииран шпинел наосновата на литиев и манганов оксид Download PDF

Info

Publication number: BG62395B1
Authority: BG; Bulgaria
Prior art keywords: lithium; spinel; hours; temperature; powder
Prior art date: 1995-06-07

Application number

BG102161A

Other languages

Bulgarian (bg)

English (en)

Other versions

BG102161A (en

Inventor

William L. Bowden

Enoch Wang

Andrew Kallmes

Original Assignee

Duracell Inc.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-06-07

Filing date

1998-01-06

Publication date

1999-10-29

1998-01-06 Application filed by Duracell Inc. filed Critical Duracell Inc.

1998-08-31 Publication of BG102161A publication Critical patent/BG102161A/xx

1999-10-29 Publication of BG62395B1 publication Critical patent/BG62395B1/bg

Links

229910052596 spinel Inorganic materials 0.000 title claims abstract description 79
239000011029 spinel Substances 0.000 title claims abstract description 79
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 47
238000000034 method Methods 0.000 title claims abstract description 29
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title abstract description 24
238000002360 preparation method Methods 0.000 title abstract description 4
229910052744 lithium Inorganic materials 0.000 claims abstract description 57
150000001875 compounds Chemical class 0.000 claims abstract description 10
238000006243 chemical reaction Methods 0.000 claims abstract description 9
150000007942 carboxylates Chemical class 0.000 claims abstract description 3
239000011572 manganese Substances 0.000 claims description 35
XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 claims description 20
229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 17
-1 lithium carboxylates Chemical class 0.000 claims description 13
229940071264 lithium citrate Drugs 0.000 claims description 12
WJSIUCDMWSDDCE-UHFFFAOYSA-K lithium citrate (anhydrous) Chemical compound [Li+].[Li+].[Li+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WJSIUCDMWSDDCE-UHFFFAOYSA-K 0.000 claims description 12
GKQWYZBANWAFMQ-UHFFFAOYSA-M lithium;2-hydroxypropanoate Chemical compound [Li+].CC(O)C([O-])=O GKQWYZBANWAFMQ-UHFFFAOYSA-M 0.000 claims description 12
230000003993 interaction Effects 0.000 claims description 5
230000035484 reaction time Effects 0.000 claims description 5
239000012300 argon atmosphere Substances 0.000 claims description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
239000012298 atmosphere Substances 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims 4
FBDMJGHBCPNRGF-UHFFFAOYSA-M [OH-].[Li+].[O-2].[Mn+2] Chemical compound [OH-].[Li+].[O-2].[Mn+2] FBDMJGHBCPNRGF-UHFFFAOYSA-M 0.000 claims 1
229940125898 compound 5 Drugs 0.000 claims 1
SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 claims 1
229910001947 lithium oxide Inorganic materials 0.000 abstract description 10
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 34
239000000843 powder Substances 0.000 description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
239000003153 chemical reaction reagent Substances 0.000 description 19
229910052786 argon Inorganic materials 0.000 description 18
239000000725 suspension Substances 0.000 description 18
238000000634 powder X-ray diffraction Methods 0.000 description 17
239000000243 solution Substances 0.000 description 16
229910013594 LiOAc Inorganic materials 0.000 description 11
229910052748 manganese Inorganic materials 0.000 description 9
238000010521 absorption reaction Methods 0.000 description 8
239000002002 slurry Substances 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
229910002804 graphite Inorganic materials 0.000 description 5
239000010439 graphite Substances 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
229910015645 LiMn Inorganic materials 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
230000002411 adverse Effects 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
229910021641 deionized water Inorganic materials 0.000 description 3
HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 3
229910001416 lithium ion Inorganic materials 0.000 description 3
229910002102 lithium manganese oxide Inorganic materials 0.000 description 3
VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 3
239000000203 mixture Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
229910052566 spinel group Inorganic materials 0.000 description 3
230000004580 weight loss Effects 0.000 description 3
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
239000008240 homogeneous mixture Substances 0.000 description 2
229940023462 paste product Drugs 0.000 description 2
238000003756 stirring Methods 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
241000219315 Spinacia Species 0.000 description 1
235000009337 Spinacia oleracea Nutrition 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
238000006138 lithiation reaction Methods 0.000 description 1
150000002641 lithium Chemical class 0.000 description 1
150000002642 lithium compounds Chemical class 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
XKPJKVVZOOEMPK-UHFFFAOYSA-M lithium;formate Chemical compound [Li+].[O-]C=O XKPJKVVZOOEMPK-UHFFFAOYSA-M 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052754 neon Inorganic materials 0.000 description 1
229910052756 noble gas Inorganic materials 0.000 description 1
150000002835 noble gases Chemical class 0.000 description 1
239000011255 nonaqueous electrolyte Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229910052704 radon Inorganic materials 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/125—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO3)n-, e.g. CaMnO3
- C01G45/1257—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO3)n-, e.g. CaMnO3 containing lithium, e.g. Li2MnO3 or Li2(MxMn1-x)O3
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Battery Electrode And Active Subsutance (AREA)
Inorganic Compounds Of Heavy Metals (AREA)

BG102161A 1995-06-07 1998-01-06 Усъвършенстван метод за получаване на литииран шпинел наосновата на литиев и манганов оксид BG62395B1 (bg)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US08/474,806 US5693307A (en)	1995-06-07	1995-06-07	Process for making a lithiated lithium manganese oxide spinel
PCT/US1996/009461 WO1996040590A1 (en)	1995-06-07	1996-06-05	An improved process for making a lithiated lithium manganese oxide spinel

Publications (2)

Publication Number	Publication Date
BG102161A BG102161A (en)	1998-08-31
BG62395B1 true BG62395B1 (bg)	1999-10-29

Family

ID=23885010

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BG102161A BG62395B1 (bg)	1995-06-07	1998-01-06	Усъвършенстван метод за получаване на литииран шпинел наосновата на литиев и манганов оксид

Country Status (19)

Country	Link
US (1)	US5693307A (cs)
EP (1)	EP0842120B1 (cs)
JP (1)	JPH11507320A (cs)
KR (1)	KR19990022253A (cs)
CN (1)	CN1084305C (cs)
AT (1)	ATE231823T1 (cs)
AU (1)	AU716975B2 (cs)
BG (1)	BG62395B1 (cs)
BR (1)	BR9609184A (cs)
CA (1)	CA2221738C (cs)
CZ (1)	CZ371797A3 (cs)
DE (1)	DE69626023T2 (cs)
NZ (1)	NZ310242A (cs)
PL (1)	PL324489A1 (cs)
RO (1)	RO115348B1 (cs)
RU (1)	RU2152355C1 (cs)
TW (1)	TW362090B (cs)
WO (1)	WO1996040590A1 (cs)
ZA (1)	ZA963655B (cs)

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EP0797263A2 (en) *	1996-03-19	1997-09-24	Mitsubishi Chemical Corporation	Nonaqueous electrolyte secondary cell
IT1283968B1 (it) *	1996-03-29	1998-05-07	Consiglio Nazionale Ricerche	Batteria ricaricabile al litio o a ioni-litio in grado di sostenere prolungate ciclazioni.
US6869547B2 (en) *	1996-12-09	2005-03-22	Valence Technology, Inc.	Stabilized electrochemical cell active material
US6183718B1 (en) *	1996-12-09	2001-02-06	Valence Technology, Inc.	Method of making stabilized electrochemical cell active material of lithium manganese oxide
US6110442A (en) *	1997-05-30	2000-08-29	Hughes Electronics Corporation	Method of preparing Lix Mn2 O4 for lithium-ion batteries
US6455198B1 (en)	1997-11-10	2002-09-24	Ngk Insulators, Ltd.	Lithium secondary battery with a lithium manganese oxide positive electrode
US5939043A (en) *	1998-06-26	1999-08-17	Ga-Tek Inc.	Process for preparing Lix Mn2 O4 intercalation compounds
US6468695B1 (en)	1999-08-18	2002-10-22	Valence Technology Inc.	Active material having extended cycle life
JP2001266874A (ja) *	2000-03-16	2001-09-28	Toho Titanium Co Ltd	リチウムイオン二次電池
KR101352836B1 (ko) *	2010-10-27	2014-01-20	전남대학교산학협력단	리튬 과잉의 리튬 망간계 산화물의 제조 방법 및 이를 이용한 리튬 이차전지
JP5765179B2 (ja) *	2011-10-14	2015-08-19	日産自動車株式会社	電気化学デバイス用正極材料およびこれを用いた電気化学デバイス
KR101383681B1 (ko) *	2011-11-15	2014-04-10	전남대학교산학협력단	리튬망간산화물 전극재료 제조방법, 그 방법으로 제조된 리튬망간산화물 전극재료, 및 상기 전극재료를 포함하는 2차 전지
RU2591154C1 (ru) *	2015-09-03	2016-07-10	Федеральное государственное бюджетное учреждение науки Институт общей и неорганической химии им. Н.С. Курнакова Российской академии наук (ИОНХ РАН)	Способ получения литированного двойного оксида лития и марганца со структурой шпинели
CN105977471A (zh) *	2016-07-06	2016-09-28	福建师范大学	酸式盐改善尖晶石富锂锰酸锂正极材料性能的方法
CN112960814A (zh) *	2021-02-03	2021-06-15	中环国投(重庆)环保产业开发有限公司	一种电解锰渣的渗滤液无害化处理方法

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US4070529A (en) *	1976-07-07	1978-01-24	Agence Nationale De Valorisation De La Recherche (Anvar)	Solid electrolyte
US4246253A (en) *	1978-09-29	1981-01-20	Union Carbide Corporation	MnO2 derived from LiMn2 O4
US4312930A (en) *	1978-09-29	1982-01-26	Union Carbide Corporation	MnO2 Derived from LiMn2 O4
AU532635B2 (en) *	1979-11-06	1983-10-06	South African Inventions Development Corporation	Metal oxide cathode
US4507371A (en) *	1982-06-02	1985-03-26	South African Inventions Development Corporation	Solid state cell wherein an anode, solid electrolyte and cathode each comprise a cubic-close-packed framework structure
US4959282A (en) *	1988-07-11	1990-09-25	Moli Energy Limited	Cathode active materials, methods of making same and electrochemical cells incorporating the same
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US5478672A (en) *	1993-12-24	1995-12-26	Sharp Kabushiki Kaisha	Nonaqueous secondary battery, positive-electrode active material

1995
- 1995-06-07 US US08/474,806 patent/US5693307A/en not_active Expired - Lifetime
1996
- 1996-05-08 ZA ZA963655A patent/ZA963655B/xx unknown
- 1996-05-24 TW TW085106148A patent/TW362090B/zh active
- 1996-06-05 CN CN96195030A patent/CN1084305C/zh not_active Expired - Fee Related
- 1996-06-05 CA CA002221738A patent/CA2221738C/en not_active Expired - Fee Related
- 1996-06-05 BR BR9609184A patent/BR9609184A/pt not_active Application Discontinuation
- 1996-06-05 KR KR1019970708732A patent/KR19990022253A/ko not_active Ceased
- 1996-06-05 NZ NZ310242A patent/NZ310242A/en unknown
- 1996-06-05 PL PL96324489A patent/PL324489A1/xx unknown
- 1996-06-05 AU AU61004/96A patent/AU716975B2/en not_active Ceased
- 1996-06-05 DE DE69626023T patent/DE69626023T2/de not_active Expired - Fee Related
- 1996-06-05 CZ CZ973717A patent/CZ371797A3/cs unknown
- 1996-06-05 EP EP96918315A patent/EP0842120B1/en not_active Expired - Lifetime
- 1996-06-05 RU RU98100422/12A patent/RU2152355C1/ru not_active IP Right Cessation
- 1996-06-05 RO RO97-02251A patent/RO115348B1/ro unknown
- 1996-06-05 WO PCT/US1996/009461 patent/WO1996040590A1/en not_active Ceased
- 1996-06-05 AT AT96918315T patent/ATE231823T1/de not_active IP Right Cessation
- 1996-06-05 JP JP9501775A patent/JPH11507320A/ja active Pending
1998
- 1998-01-06 BG BG102161A patent/BG62395B1/bg unknown

Also Published As

Publication number	Publication date
RO115348B1 (ro)	2000-01-28
CN1084305C (zh)	2002-05-08
KR19990022253A (ko)	1999-03-25
BR9609184A (pt)	1999-05-11
CA2221738A1 (en)	1996-12-19
RU2152355C1 (ru)	2000-07-10
JPH11507320A (ja)	1999-06-29
EP0842120A4 (en)	1998-12-09
TW362090B (en)	1999-06-21
CZ371797A3 (cs)	1998-06-17
WO1996040590A1 (en)	1996-12-19
AU6100496A (en)	1996-12-30
DE69626023D1 (de)	2003-03-06
US5693307A (en)	1997-12-02
NZ310242A (en)	1998-11-25
AU716975B2 (en)	2000-03-09
HK1010866A1 (en)	1999-07-02
CN1189143A (zh)	1998-07-29
BG102161A (en)	1998-08-31
EP0842120B1 (en)	2003-01-29
EP0842120A1 (en)	1998-05-20
ATE231823T1 (de)	2003-02-15
ZA963655B (en)	1996-11-21
PL324489A1 (en)	1998-05-25
CA2221738C (en)	2001-02-27
DE69626023T2 (de)	2003-10-16

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