BRPI0417550A - composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas - Google Patents
composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinasInfo
- Publication number
- BRPI0417550A BRPI0417550A BRPI0417550-6A BRPI0417550A BRPI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A
- Authority
- BR
- Brazil
- Prior art keywords
- transition metal
- metal compound
- organometallic transition
- bisciclopentadienyl
- catalyst system
- Prior art date
Links
- -1 organometallic transition metal compound Chemical class 0.000 title abstract 7
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- 239000011230 binding agent Substances 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
- C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
- C07C13/553—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with an indacene or hydrogenated indacene ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
"COMPOSTO DE METAL DE TRANSIçãO ORGANOMETáLICO, SISTEMA DE LIGANTE BISCICLOPENTADIENILA, SISTEMA CATALISADOR E PREPARAçãO DE POLIOLEFINAS". A presente invenção refere-se a compostos de metais de transição organometálicos de fórmula (I), em que M¬ 1¬, X, n, Z, R¬ 1¬ - R¬ 8¬ e A são conforme definidos nas reivindicações, sistemas de ligante bisciclopentadienila com esse padrão de substituição, sistemas catalisadores compreendendo pelo menos um dos compostos de metais de transição organometálicos da presente invenção, um processo para a preparação de poliolefinas por polimerização ou copolimerização de pelo menos uma olefina na presença de um dos sistemas catalisadores da presente invenção, o uso dos sistemas de ligante bisciclopentadienila da presente invenção para a preparação de compostos de metais de transição organometálicos e um processo para a preparação de compostos de metais de transição organometálicos usando os sistemas de ligante bisciclopentadienila.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10358082A DE10358082A1 (de) | 2003-12-10 | 2003-12-10 | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| US54166804P | 2004-02-03 | 2004-02-03 | |
| PCT/EP2004/013827 WO2005058916A2 (en) | 2003-12-10 | 2004-12-06 | Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0417550A true BRPI0417550A (pt) | 2007-03-27 |
| BRPI0417550B1 BRPI0417550B1 (pt) | 2015-10-27 |
Family
ID=34672618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0417550A BRPI0417550B1 (pt) | 2003-12-10 | 2004-12-06 | composto de metal de transição organometálico, processo para preparação do mesmo, sistema de ligante bisciclopentadienila, uso do mesmo, sistema catalisador e processo para preparação de poliolefinas |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7452949B2 (pt) |
| EP (1) | EP1692144B1 (pt) |
| JP (1) | JP4823071B2 (pt) |
| CN (1) | CN100473669C (pt) |
| AT (1) | ATE464312T1 (pt) |
| BR (1) | BRPI0417550B1 (pt) |
| DE (1) | DE10358082A1 (pt) |
| ES (1) | ES2341453T3 (pt) |
| RU (1) | RU2362779C2 (pt) |
| WO (1) | WO2005058916A2 (pt) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| US8178636B2 (en) | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
| DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
| JP2008536813A (ja) * | 2005-03-18 | 2008-09-11 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
| BRPI0611557B1 (pt) * | 2005-03-18 | 2017-03-28 | Basell Polyolefine Gmbh | compostos metalocenos bis-indenila em ponte com simetria c2, sistema catalítico dessa classe de compostos e processo de polimerização de a-olefinas com a referida classe de compostos |
| JP2008534705A (ja) * | 2005-03-23 | 2008-08-28 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィン類の重合法 |
| RU2392283C2 (ru) * | 2005-03-23 | 2010-06-20 | Базелль Полиолефине Гмбх | Способ полимеризации олефинов |
| JP2008540714A (ja) | 2005-05-03 | 2008-11-20 | バーゼル・ポリオレフィン・ゲーエムベーハー | α−オレフィンの重合方法 |
| ATE515533T1 (de) | 2005-05-11 | 2011-07-15 | Basell Poliolefine Srl | Polymerisationsverfahren zur herstellung von polyolefinblends |
| WO2006134046A1 (en) * | 2005-06-13 | 2006-12-21 | Basell Polyolefine Gmbh | Process for the copolymerization of propylene |
| WO2007042252A1 (en) * | 2005-10-14 | 2007-04-19 | Basell Polyolefine Gmbh | Hybrid catalyst systems supported on magnesium halide |
| EP1996600B1 (en) * | 2006-03-17 | 2011-09-28 | Basell Polyolefine GmbH | Metallocene compounds |
| US7834205B2 (en) | 2006-04-12 | 2010-11-16 | Basell Polyolifine GmbH | Metallocene compounds |
| EP2010580B1 (en) * | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Process for the preparation of ethylene copolymers |
| US8785575B2 (en) | 2006-04-21 | 2014-07-22 | Basell Polyolefine Gmbh | Process for the preparation of ethylene propylene copolymers |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| US8076259B2 (en) * | 2007-10-04 | 2011-12-13 | Basell Polyolefine Gmbh | Process for the preparation of catalyst paste and products thereof |
| JP5578473B2 (ja) * | 2007-10-25 | 2014-08-27 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー |
| JP5409294B2 (ja) | 2008-12-17 | 2014-02-05 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| EP2402354B1 (en) | 2010-07-01 | 2016-03-02 | Borealis AG | Process for olefin polymerisation using group 4 metallocene as catalysts |
| EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
| JP5966321B2 (ja) * | 2010-11-19 | 2016-08-10 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
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| JP6604334B2 (ja) * | 2014-11-26 | 2019-11-13 | 住友化学株式会社 | 化合物の製造方法 |
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| JPH03181920A (ja) * | 1989-12-12 | 1991-08-07 | Matsushita Electric Ind Co Ltd | 光電子集積回路 |
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| WO1994016009A1 (fr) * | 1993-01-11 | 1994-07-21 | Mitsui Petrochemical Industries, Ltd. | Composition polymere de propylene |
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| JPH10265588A (ja) * | 1997-01-24 | 1998-10-06 | Mitsui Chem Inc | オレフィン系共重合体製収縮フィルム |
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| AU7332398A (en) | 1997-03-07 | 1998-09-29 | Targor Gmbh | Method for producing olefin polymers with a higher melting point |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| EP1006149B1 (en) * | 1997-08-19 | 2009-09-30 | Idemitsu Kosan Co., Ltd. | Films made of nucleated propylene polymer compositions |
| DE19808253A1 (de) * | 1998-02-27 | 1999-09-02 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| DE69902638T2 (de) | 1998-03-11 | 2003-04-24 | The Dow Chemical Co., Midland | Integriertes verfahren zur herstellung von dien-komplexen |
| DE19816154A1 (de) * | 1998-04-09 | 1999-10-21 | Bernhard Rieger | Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| DE59914158D1 (de) | 1998-11-25 | 2007-03-08 | Basell Polyolefine Gmbh | Metallocenmonohalogenide |
| CN1590422A (zh) | 1999-12-23 | 2005-03-09 | 巴塞尔聚烯烃有限公司 | 过渡金属化合物,配体体系,催化剂体系及其在烯烃的聚合反应和共聚反应中的用途 |
| EP1312067A4 (en) | 2000-07-13 | 2004-06-09 | Promotional Notions Pty Ltd | Promotional system |
| DE10158656A1 (de) | 2001-11-30 | 2003-06-26 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| EP1448578B1 (en) | 2001-11-30 | 2006-07-26 | Basell Polyolefine GmbH | Metallocene compounds and process for the preparation of propylene polymers |
| DE60318616T2 (de) * | 2002-12-04 | 2009-01-08 | Basell Polyolefine Gmbh | Verfahren zur herstellung von1-buten-polymeren |
| JP2007505947A (ja) * | 2003-05-28 | 2007-03-15 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 特定の置換パターンを有する有機遷移金属化合物、ビスシクロペンタジエニル配位子組成物、触媒組成物、及ポリオレフィンの製造法 |
-
2003
- 2003-12-10 DE DE10358082A patent/DE10358082A1/de not_active Withdrawn
-
2004
- 2004-12-06 JP JP2006543449A patent/JP4823071B2/ja not_active Expired - Lifetime
- 2004-12-06 CN CNB2004800363141A patent/CN100473669C/zh not_active Expired - Fee Related
- 2004-12-06 RU RU2006124537/04A patent/RU2362779C2/ru active
- 2004-12-06 WO PCT/EP2004/013827 patent/WO2005058916A2/en not_active Ceased
- 2004-12-06 ES ES04803537T patent/ES2341453T3/es not_active Expired - Lifetime
- 2004-12-06 BR BRPI0417550A patent/BRPI0417550B1/pt not_active IP Right Cessation
- 2004-12-06 AT AT04803537T patent/ATE464312T1/de not_active IP Right Cessation
- 2004-12-06 US US10/581,985 patent/US7452949B2/en not_active Expired - Lifetime
- 2004-12-06 EP EP04803537A patent/EP1692144B1/en not_active Revoked
Also Published As
| Publication number | Publication date |
|---|---|
| JP4823071B2 (ja) | 2011-11-24 |
| EP1692144B1 (en) | 2010-04-14 |
| JP2007513906A (ja) | 2007-05-31 |
| ES2341453T3 (es) | 2010-06-21 |
| US7452949B2 (en) | 2008-11-18 |
| BRPI0417550B1 (pt) | 2015-10-27 |
| CN1890272A (zh) | 2007-01-03 |
| EP1692144A2 (en) | 2006-08-23 |
| WO2005058916A2 (en) | 2005-06-30 |
| ATE464312T1 (de) | 2010-04-15 |
| RU2006124537A (ru) | 2008-01-20 |
| US20070155919A1 (en) | 2007-07-05 |
| RU2362779C2 (ru) | 2009-07-27 |
| WO2005058916A3 (en) | 2005-11-03 |
| DE10358082A1 (de) | 2005-07-14 |
| CN100473669C (zh) | 2009-04-01 |
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