BRPI0417550A - composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas - Google Patents

composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas

Info

Publication number
BRPI0417550A
BRPI0417550A BRPI0417550-6A BRPI0417550A BRPI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A
Authority
BR
Brazil
Prior art keywords
transition metal
metal compound
organometallic transition
bisciclopentadienyl
catalyst system
Prior art date
Application number
BRPI0417550-6A
Other languages
English (en)
Inventor
Yoshikuni Okumura
Iiya Nifant Ev
Michael Elder
Pavel Ivchenko
Vladimir V Bagrov
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34672618&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0417550(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BRPI0417550A publication Critical patent/BRPI0417550A/pt
Publication of BRPI0417550B1 publication Critical patent/BRPI0417550B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
    • C07C13/553—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with an indacene or hydrogenated indacene ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"COMPOSTO DE METAL DE TRANSIçãO ORGANOMETáLICO, SISTEMA DE LIGANTE BISCICLOPENTADIENILA, SISTEMA CATALISADOR E PREPARAçãO DE POLIOLEFINAS". A presente invenção refere-se a compostos de metais de transição organometálicos de fórmula (I), em que M¬ 1¬, X, n, Z, R¬ 1¬ - R¬ 8¬ e A são conforme definidos nas reivindicações, sistemas de ligante bisciclopentadienila com esse padrão de substituição, sistemas catalisadores compreendendo pelo menos um dos compostos de metais de transição organometálicos da presente invenção, um processo para a preparação de poliolefinas por polimerização ou copolimerização de pelo menos uma olefina na presença de um dos sistemas catalisadores da presente invenção, o uso dos sistemas de ligante bisciclopentadienila da presente invenção para a preparação de compostos de metais de transição organometálicos e um processo para a preparação de compostos de metais de transição organometálicos usando os sistemas de ligante bisciclopentadienila.
BRPI0417550A 2003-12-10 2004-12-06 composto de metal de transição organometálico, processo para preparação do mesmo, sistema de ligante bisciclopentadienila, uso do mesmo, sistema catalisador e processo para preparação de poliolefinas BRPI0417550B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10358082A DE10358082A1 (de) 2003-12-10 2003-12-10 Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US54166804P 2004-02-03 2004-02-03
PCT/EP2004/013827 WO2005058916A2 (en) 2003-12-10 2004-12-06 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins

Publications (2)

Publication Number Publication Date
BRPI0417550A true BRPI0417550A (pt) 2007-03-27
BRPI0417550B1 BRPI0417550B1 (pt) 2015-10-27

Family

ID=34672618

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0417550A BRPI0417550B1 (pt) 2003-12-10 2004-12-06 composto de metal de transição organometálico, processo para preparação do mesmo, sistema de ligante bisciclopentadienila, uso do mesmo, sistema catalisador e processo para preparação de poliolefinas

Country Status (10)

Country Link
US (1) US7452949B2 (pt)
EP (1) EP1692144B1 (pt)
JP (1) JP4823071B2 (pt)
CN (1) CN100473669C (pt)
AT (1) ATE464312T1 (pt)
BR (1) BRPI0417550B1 (pt)
DE (1) DE10358082A1 (pt)
ES (1) ES2341453T3 (pt)
RU (1) RU2362779C2 (pt)
WO (1) WO2005058916A2 (pt)

Families Citing this family (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE102004056104A1 (de) * 2004-11-19 2006-05-24 Basell Polyolefine Gmbh Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme
RU2410388C2 (ru) * 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
CN101146836B (zh) 2005-03-23 2011-06-08 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
AU2006259143A1 (en) * 2005-06-13 2006-12-21 Basell Polyolefine Gmbh Process for the copolymerization of propylene
US7723448B2 (en) * 2005-10-14 2010-05-25 Basell Polyolefine Gmbh Hybrid catalyst systems supported on magnesium halide
WO2007107448A1 (en) * 2006-03-17 2007-09-27 Basell Polyolefine Gmbh Metallocene compounds
US7834205B2 (en) * 2006-04-12 2010-11-16 Basell Polyolifine GmbH Metallocene compounds
EP2010580B1 (en) * 2006-04-21 2016-07-13 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers
US8785575B2 (en) 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
WO2009043867A1 (en) * 2007-10-04 2009-04-09 Basell Polyolefine Gmbh Process for the preparation of catalyst paste and products thereof
ATE547439T1 (de) * 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere
JP5409294B2 (ja) * 2008-12-17 2014-02-05 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2676972A1 (en) 2012-06-19 2013-12-25 Basell Polyolefine GmbH Process for the obtainment of a polyolefin composition
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
EP2722344B1 (en) 2012-10-18 2017-03-22 Borealis AG Polymerisation process
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
US9321914B2 (en) 2012-10-31 2016-04-26 Exxonmobil Chemical Patents Inc. Propylene copolymer compositions and processes to produce them
EP2746301B1 (en) 2012-12-21 2018-05-30 Borealis AG Catalyst
WO2014096282A1 (en) 2012-12-21 2014-06-26 Borealis Ag Catalyst
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
EP3539993A1 (en) 2013-07-17 2019-09-18 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN103980395B (zh) * 2014-04-30 2016-08-24 中国科学院化学研究所 一种可用于3d打印的超高分子量无规聚丙烯树脂及其制备方法和应用
KR101580591B1 (ko) 2014-06-10 2015-12-28 주식회사 엘지화학 프로필렌계 엘라스토머
EP2995629B1 (en) 2014-09-12 2018-03-07 Borealis AG Process for producing propylene copolymers in gas phase
WO2016038211A1 (en) 2014-09-12 2016-03-17 Borealis Ag Process for the preparation of copolymers of propylene
JP6604334B2 (ja) * 2014-11-26 2019-11-13 住友化学株式会社 化合物の製造方法
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR101846412B1 (ko) * 2016-12-06 2018-05-18 한화케미칼 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
JP6984128B2 (ja) * 2016-12-29 2021-12-17 日本ポリエチレン株式会社 ポリエチレン樹脂の製造方法並びに当該方法により製造されたポリエチレン樹脂を用いた太陽電池封止材および太陽電池モジュール
EP3562831B1 (en) 2016-12-29 2021-10-20 Borealis AG Catalysts
KR102065719B1 (ko) 2017-01-25 2020-01-13 주식회사 엘지화학 혼성 담지 촉매
US11518824B2 (en) 2017-10-11 2022-12-06 Basell Polyolefine Gmbh Supported catalyst system
US11001657B2 (en) 2017-10-25 2021-05-11 Exxonmobil Chemical Patents Inc. Unbridged indacenyl metallocenes
WO2019099250A1 (en) * 2017-11-14 2019-05-23 Exxonmobil Chemical Patents Inc. (di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US11214631B2 (en) 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
KR102530448B1 (ko) * 2019-03-13 2023-05-08 주식회사 엘지화학 전이 금속 화합물 및 이를 포함하는 촉매 조성물
US12065560B2 (en) 2019-06-11 2024-08-20 Lg Chem, Ltd. Propylene-ethylene random copolymer
KR102524952B1 (ko) * 2019-06-13 2023-04-24 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
EP3925987B1 (en) 2019-06-13 2026-01-28 Lg Chem, Ltd. Hybrid supported metallocene catalyst and method of preparing polypropylene using same
EP4017887A4 (en) 2019-08-22 2023-01-18 ExxonMobil Chemical Patents Inc. ISOTACTIC PROPYLENE HOMOPOLYMERS AND COPOLYMERS MADE WITH C1-SYMMETRIC METALLOCENE CATALYSTS
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
CN114401977B (zh) * 2020-07-16 2024-08-02 株式会社Lg化学 过渡金属化合物和包含该化合物的催化剂组合物
CN116670146A (zh) 2020-11-23 2023-08-29 埃克森美孚化学专利公司 使用不含芳族溶剂的载体制备的茂金属聚丙烯
EP4396246A1 (en) 2021-09-02 2024-07-10 ExxonMobil Chemical Patents Inc. C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
CN115160470B (zh) * 2022-07-18 2023-06-30 宁夏清研高分子新材料有限公司 一种tpx聚合物的制备方法、催化剂及其制备方法
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025051400A1 (en) 2023-09-07 2025-03-13 Borealis Ag Methods of producing metallocene catalyst components
WO2025016566A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2026041323A1 (en) 2024-08-19 2026-02-26 Basell Poliolefine Italia S.R.L. Polypropylene composition having good thermal and optical properties

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03181920A (ja) * 1989-12-12 1991-08-07 Matsushita Electric Ind Co Ltd 光電子集積回路
IL96810A0 (en) 1990-01-02 1991-09-16 Exxon Chemical Patents Inc Supported ionic metallocene catalysts for olefin polymerization and methods for the preparation thereof
DE69412954T2 (de) * 1993-01-11 1999-03-11 Mitsui Chemicals, Inc., Tokio/Tokyo Propylenpolymer zusammensetzung
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
ES2143636T3 (es) 1994-06-24 2000-05-16 Exxon Chemical Patents Inc Sistemas de catalizadores de polimerizacion, su produccion y uso.
EP0728773B1 (en) * 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Catalysts for olefin polymerization and a process for preparing olefin polymers therewith
DE69528635T2 (de) 1995-05-01 2003-06-26 Agfa-Gevaert, Mortsel Verfahren zur Wiedergabe eines Strahlungsbildes
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
DE69710838T2 (de) 1996-04-22 2002-10-31 Japan Polyolefins Co. Ltd., Tokio/Tokyo Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren
JPH10265588A (ja) * 1997-01-24 1998-10-06 Mitsui Chem Inc オレフィン系共重合体製収縮フィルム
US5789634A (en) 1997-02-05 1998-08-04 Boulder Scientific Company Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst intermediates
EP0931099A1 (de) 1997-03-07 1999-07-28 Basell Polyolefine GmbH Verfahren zur herstellung von olefinpolymerisaten mit erhöhtem schmelzpunkt
KR100624632B1 (ko) 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
DE19733017A1 (de) 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
CN1184256C (zh) * 1997-08-19 2005-01-12 出光石油化学株式会社 丙烯聚合物组合物及由其制备的薄膜
DE19808253A1 (de) * 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
ES2182494T3 (es) 1998-03-11 2003-03-01 Dow Chemical Co Procedimiento integrado para la preparacion de complejos de dienos.
DE19816154A1 (de) * 1998-04-09 1999-10-21 Bernhard Rieger Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
AU1272100A (en) 1998-11-25 2000-06-13 Targor Gmbh Metallocene monohalogenides
BRPI0016723B1 (pt) 1999-12-23 2018-02-27 Basell Polyolefine Gmbh. Metaloceno, sistema catalisador, e, processo para a copolimerização de propileno com etileno
MXPA03000364A (es) 2000-07-13 2004-09-13 Promotional Notions Pty Ltd Sistema promocional.
WO2003045964A1 (en) 2001-11-30 2003-06-05 Basell Polyolefine Gmbh Metallocene compounds and process for the preparation of propylene polymers
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE60318616T2 (de) * 2002-12-04 2009-01-08 Basell Polyolefine Gmbh Verfahren zur herstellung von1-buten-polymeren
ATE423784T1 (de) * 2003-05-28 2009-03-15 Basell Polyolefine Gmbh Bisindenyl-zirconium-komplexe zur olefinpolymerisation

Also Published As

Publication number Publication date
WO2005058916A2 (en) 2005-06-30
RU2006124537A (ru) 2008-01-20
WO2005058916A3 (en) 2005-11-03
JP4823071B2 (ja) 2011-11-24
BRPI0417550B1 (pt) 2015-10-27
RU2362779C2 (ru) 2009-07-27
ES2341453T3 (es) 2010-06-21
US7452949B2 (en) 2008-11-18
EP1692144B1 (en) 2010-04-14
JP2007513906A (ja) 2007-05-31
ATE464312T1 (de) 2010-04-15
CN1890272A (zh) 2007-01-03
DE10358082A1 (de) 2005-07-14
EP1692144A2 (en) 2006-08-23
CN100473669C (zh) 2009-04-01
US20070155919A1 (en) 2007-07-05

Similar Documents

Publication Publication Date Title
BRPI0417550A (pt) composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas
DE602004019647D1 (de) Bisindenyl-zirconium-komplexe zur olefinpolymerisation
MXPA04001348A (es) NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS.
TR200003273A2 (tr) Olefinler'den katalitik olarak aldehit imalatına yönelik usul
ATE355308T1 (de) Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
DE69919755D1 (de) Katalysator zur ethylen homo und copolymerisation
MY133984A (en) Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
WO2003016321A3 (de) Neue phosphitverbindungen und neue phosphitmetallkomplexe
ATE344268T1 (de) Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen
AU2003293320A1 (en) Catalyst systems for ethylene oligomerisation to linear alpha olefins
NO20000120L (no) Fremstilling av <alfa>-olefiner
RU2008147886A (ru) Усовершенствованные комплексы гафния с гетероциклическими органическими лигандами
TR200103809T2 (tr) Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri
WO2005005496A3 (en) Process for the production of a polymer comprising monomeric units of ethylene, an a-olefin and a vinyl norbornene
ATE251635T1 (de) Heteroligand
RU94035670A (ru) Способ полимеризации олефинов
MY140496A (en) System suitable for the hydrocyanation of olefinically unsaturated compounds
AU2003211480A1 (en) Transition metal complexes, ligands, polymerization catalysts for olefins, and process for production of olefin polymers
TW200619182A (en) The magnesium compounds, the solid catalyst components, the olefin polymerization catalyst, and the method for producing polyolefin
MY134869A (en) Bridged metallocene compounds, process for their preparation and their use as catalysts for the polymerization of olefins
DE69920746D1 (de) Olefinpolymerisation
AU2003250043A1 (en) Preparation of catalyst systems
WO2001068724A3 (en) Polymerization of olefins
MXPA02007951A (es) Complejos de vanadio-imido-fosforanoiminato para la polimerizacion de olefinas.
EP1586589A4 (en) CATALYSTS FOR THE POLYMERIZATION OF OLEFINES AND METHOD FOR THE PRODUCTION OF OLEFIN POLYMER

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 27/10/2015, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 20A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2804 DE 01-10-2024 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.