TR200103809T2 - Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri - Google Patents
Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleriInfo
- Publication number
- TR200103809T2 TR200103809T2 TR2001/03809T TR200103809T TR200103809T2 TR 200103809 T2 TR200103809 T2 TR 200103809T2 TR 2001/03809 T TR2001/03809 T TR 2001/03809T TR 200103809 T TR200103809 T TR 200103809T TR 200103809 T2 TR200103809 T2 TR 200103809T2
- Authority
- TR
- Turkey
- Prior art keywords
- transition metal
- methods
- metal alkoxide
- made therefrom
- polymerization catalysts
- Prior art date
Links
- -1 transition metal alkoxide Chemical class 0.000 title abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052749 magnesium Inorganic materials 0.000 title abstract 2
- 239000011777 magnesium Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052723 transition metal Inorganic materials 0.000 title abstract 2
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 230000002140 halogenating effect Effects 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Bir olefin polimerizasyon prokatalizörünün olusturulmasi için bir ön maddenin halojenlenmesinin bir yöntemi ifsa edilmistir ve burada bir magnezyum/geçis metali içeren alkoksid bilesigi ön maddesi alkilalüminyum halid, TiX4, SiX4, BX3, ve Br2' den seçilen bir halojenasyon maddesi ile temas ettirilir, burada halid ve X sirasiyla bir halojendir, ve alkilalüminyum halid, TiX4, SiX4, ve Br2 halojenasyon maddesi olarak kullanildiginda çok asamali halojenasyonda ya birlikte ya da kombinasyon olarak kullanilir. Prokatalizör, daha sonra bir kokatalizör ve istege göre bir seçicilik kontrol ajani ile temas ettirilmesi ile bir olefin polimerizasyonuna dönüstürülebilir ve istenen özelliklerde yüksek verimde olefinlerin polimerizasyonu için kullanilir.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14166599P | 1999-06-30 | 1999-06-30 | |
| US39592499A | 1999-09-14 | 1999-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR200103809T2 true TR200103809T2 (tr) | 2002-05-21 |
Family
ID=26839338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2001/03809T TR200103809T2 (tr) | 1999-06-30 | 2000-06-29 | Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6511935B2 (tr) |
| EP (1) | EP1196461B1 (tr) |
| JP (1) | JP2003503562A (tr) |
| KR (1) | KR20020019477A (tr) |
| CN (1) | CN1358202A (tr) |
| AR (1) | AR024606A1 (tr) |
| AT (1) | ATE294823T1 (tr) |
| AU (1) | AU763949B2 (tr) |
| CA (1) | CA2369208A1 (tr) |
| CZ (1) | CZ20014646A3 (tr) |
| DE (1) | DE60019930T2 (tr) |
| ES (1) | ES2238297T3 (tr) |
| NO (1) | NO20016426L (tr) |
| PL (1) | PL352905A1 (tr) |
| TR (1) | TR200103809T2 (tr) |
| WO (1) | WO2001000692A1 (tr) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2369170A1 (en) * | 1999-06-30 | 2001-01-04 | Robert Charles Job | Magnesium/titanium alkoxide complexes and polymerization catalysts made therefrom |
| US6613712B1 (en) * | 1999-11-24 | 2003-09-02 | Phillips Petroleum Company | Organometal catalyst compositions with solid oxide supports treated with fluorine and boron |
| TW200504093A (en) | 2003-05-12 | 2005-02-01 | Dow Global Technologies Inc | Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom |
| MXPA05012158A (es) * | 2003-05-12 | 2006-02-10 | Union Carbide Chem Plastic | Proceso para el control de particulas finas de polimero en una polimerazacion en fase gaseosa. |
| GB0418581D0 (en) | 2004-08-20 | 2004-09-22 | Solvay | Polymer composition |
| EP1805229A1 (en) * | 2004-10-28 | 2007-07-11 | Dow Gloval Technologies Inc. | Method of controlling a polymerization reactor |
| BRPI0517210B1 (pt) | 2004-12-17 | 2017-01-24 | Dow Global Technologies Inc | composição adequada para tubos, composição adequada para películas sopradas, composição adequada para artigos moldados soprados, tubo, película, artigo moldado por sopro e método para melhorar o comportamento de fluxo de fluência de uma resina |
| EP2010603B1 (en) * | 2006-04-07 | 2010-01-13 | Dow Global Technologies Inc. | Polyolefin compositions, articles made therefrom and methods for preparing the same |
| KR20090014329A (ko) * | 2006-05-02 | 2009-02-10 | 다우 글로벌 테크놀로지스 인크. | 고밀도 폴리에틸렌 조성물, 이의 제조 방법, 이로부터제조된 물품, 및 이러한 물품의 제조 방법 |
| US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
| WO2008051824A2 (en) | 2006-10-23 | 2008-05-02 | Dow Global Technologies Inc. | Polyethylene compositions, methods of making the same, and articles prepared therefrom |
| WO2008136849A1 (en) * | 2007-05-02 | 2008-11-13 | Dow Global Technologies Inc. | High-density polyethylene compositions, method of making the same, injection molded articles made therefrom, and method of making such articles |
| CN101970508B (zh) | 2008-03-14 | 2013-03-27 | 沙特基础工业公司 | 催化剂体系及在该催化剂体系的存在下制备聚乙烯的方法 |
| JP2011522060A (ja) * | 2008-04-17 | 2011-07-28 | サウディ ベーシック インダストリーズ コーポレイション | 超高分子量ポリエチレンの製造プロセス |
| WO2010006756A1 (en) * | 2008-07-18 | 2010-01-21 | Saudi Basic Industries Corporation | Process for the production of polyethylene |
| ES2605277T3 (es) | 2008-08-06 | 2017-03-13 | Union Carbide Chemicals & Plastics Technology Llc | Métodos de obtención de composiciones de catalizador de ziegler-natta para producir polietilenos con una cola de alto peso molecular |
| MX2011008053A (es) | 2009-01-30 | 2012-01-12 | Dow Global Technologies Llc | Composiciones de polietileno de alta densidad, metodo para producir las mismas, dispositivos de cierre elaborados de las mismas, y metodo para elaborar dichos dispositivos de cierre. |
| EP2284199A1 (en) | 2009-08-14 | 2011-02-16 | Saudi Basic Industries Corporation | A catalyst system and a process for the production of polyethylene |
| WO2011062961A1 (en) | 2009-11-23 | 2011-05-26 | Dow Global Technologies Inc. | Compositions, films and methods of preparing the same |
| US20130075409A1 (en) | 2010-04-14 | 2013-03-28 | Mridula Kapur | Fuel containers made from polyethylene compositions with improved creep resistance |
| JP6146589B2 (ja) * | 2011-12-12 | 2017-06-14 | サウディ ベーシック インダストリーズ コーポレイション | 超高分子量ポリエチレンを製造するための触媒系 |
| EP3107942A4 (en) * | 2014-02-17 | 2017-07-12 | Reliance Industries Limited | Heterogeneous ziegler-natta catalyst composition, a process for its preparation and a process for polymerizing olefin using the same |
| US10030121B2 (en) * | 2015-04-01 | 2018-07-24 | Reliance Industries Limited | Catalyst composition and process for obtaining a colored olefin polymer |
| ES2877475T3 (es) * | 2016-03-01 | 2021-11-16 | Univation Tech Llc | Método para mejorar la actividad del catalizador ziegler-natta |
| WO2018026331A1 (en) * | 2016-08-04 | 2018-02-08 | Irpc Public Company Limited | Olefin polymerization catalyst and process for preparing the same |
| JP7157049B2 (ja) | 2016-09-29 | 2022-10-19 | ダウ グローバル テクノロジーズ エルエルシー | ハロゲン化マグネシウム担持チタン(前駆)触媒 |
| EP3830140A1 (en) | 2018-08-02 | 2021-06-09 | Borealis AG | Process for polymerizing ethylene in a multi-stage polymerization process |
| CN112778528A (zh) * | 2020-12-31 | 2021-05-11 | 南京跃贝新材料科技有限公司 | 一种长碳链聚酰胺弹性体的制备方法 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5082907A (en) * | 1990-10-18 | 1992-01-21 | Shell Oil Company | Olefin polymerization catalyst |
| BE791676A (fr) | 1971-12-08 | 1973-05-21 | Solvay | Procédé pour la polymérisation des oléfines |
| US4105846A (en) | 1977-08-25 | 1978-08-08 | Standard Oil Company (Indiana) | Increasing the particle size of as formed polyethylene or ethylene copolymer |
| DE2752577A1 (de) | 1977-11-25 | 1979-06-07 | Hoechst Ag | Verfahren zur herstellung eines mischkatalysators |
| US4199476A (en) | 1978-08-23 | 1980-04-22 | Standard Oil Company (Indiana) | Olefin polymerization catalyst |
| US4525554A (en) * | 1981-03-04 | 1985-06-25 | Mitsubishi Chemical Industries Ltd. | Process for polymerizing olefin |
| US4518751A (en) | 1981-06-05 | 1985-05-21 | Idemitsu Kosan Company Limited | Process for the production of polyethylene |
| US4525468A (en) | 1982-09-30 | 1985-06-25 | E. I. Du Pont De Nemours And Company | Olefin polymerization catalyst |
| FR2546522B1 (fr) | 1983-05-25 | 1985-07-26 | Ato Chimie | Procede de preparation d'une composante de metal de transition pour un systeme catalytique de polymerisation d'olefines |
| JPS6096609A (ja) | 1983-11-01 | 1985-05-30 | Showa Denko Kk | 熱可塑性エラストマ−の製造法 |
| JPS60262802A (ja) * | 1984-06-11 | 1985-12-26 | Toyo Soda Mfg Co Ltd | ポリオレフインの製造方法 |
| US4814314A (en) * | 1986-09-26 | 1989-03-21 | Mitsubishi Petrochemical Company Limited | Catalyst for olefin polymerization |
| DE3780260T2 (de) * | 1986-11-20 | 1993-02-11 | Mitsubishi Chem Ind | Verfahren zur herstellung von olefinpolymeren. |
| JP2536530B2 (ja) * | 1987-06-17 | 1996-09-18 | 東ソー株式会社 | 立体規則性ポリオレフィンの製造方法 |
| FR2624122B1 (fr) * | 1987-12-03 | 1991-11-08 | Solvay | Procede pour la polymerisation des alpha-olefines, complexes catalytiques solides utilisables pour cette polymerisation et procede pour leur preparation |
| JPH0791332B2 (ja) * | 1988-06-09 | 1995-10-04 | チッソ株式会社 | オレフィン重合用チタン触媒成分の製法 |
| JP2757206B2 (ja) * | 1989-05-15 | 1998-05-25 | 東ソー株式会社 | ポリオレフィンの製造方法 |
| US5232998A (en) | 1990-05-09 | 1993-08-03 | Quantum Chemical Corporation | Olefin polymerization using silica supported catalyst |
| US5034361A (en) * | 1990-05-24 | 1991-07-23 | Shell Oil Company | Catalyst precursor production |
| IT1246265B (it) * | 1990-09-07 | 1994-11-17 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
| US5124298A (en) | 1990-10-22 | 1992-06-23 | Shell Oil Company | Olefin polymerization catalyst |
| US5122494A (en) | 1991-02-19 | 1992-06-16 | Shell Oil Company | Olefin polymerization catalyst |
| DE4126093A1 (de) * | 1991-08-07 | 1993-02-11 | Hoechst Ag | Verfahren zur herstellung von ethylen(co)polymeren |
| WO1994015977A1 (en) | 1992-12-31 | 1994-07-21 | Shell Polypropylene Company | Olefin polymerization catalyst |
| WO1995006672A1 (en) | 1993-09-03 | 1995-03-09 | Occidental Chemical Corporation | Improved catalysts for polymerizing olefins |
| JPH07145210A (ja) | 1993-11-19 | 1995-06-06 | Mitsubishi Chem Corp | エチレン重合体の製造法 |
| BE1008702A3 (fr) | 1994-09-22 | 1996-07-02 | Solvay | Procede de polymerisation d'olefines. |
| JPH0952910A (ja) * | 1995-06-07 | 1997-02-25 | Tokuyama Corp | ポリオレフィンの製造方法 |
| CA2369170A1 (en) * | 1999-06-30 | 2001-01-04 | Robert Charles Job | Magnesium/titanium alkoxide complexes and polymerization catalysts made therefrom |
-
2000
- 2000-06-29 KR KR1020017016855A patent/KR20020019477A/ko not_active Withdrawn
- 2000-06-29 AT AT00946917T patent/ATE294823T1/de not_active IP Right Cessation
- 2000-06-29 JP JP2001506700A patent/JP2003503562A/ja active Pending
- 2000-06-29 WO PCT/US2000/018011 patent/WO2001000692A1/en not_active Ceased
- 2000-06-29 CA CA002369208A patent/CA2369208A1/en not_active Abandoned
- 2000-06-29 DE DE60019930T patent/DE60019930T2/de not_active Expired - Fee Related
- 2000-06-29 CZ CZ20014646A patent/CZ20014646A3/cs unknown
- 2000-06-29 CN CN00809579A patent/CN1358202A/zh active Pending
- 2000-06-29 AR ARP000103287A patent/AR024606A1/es unknown
- 2000-06-29 PL PL00352905A patent/PL352905A1/xx unknown
- 2000-06-29 AU AU60602/00A patent/AU763949B2/en not_active Ceased
- 2000-06-29 EP EP00946917A patent/EP1196461B1/en not_active Expired - Lifetime
- 2000-06-29 TR TR2001/03809T patent/TR200103809T2/tr unknown
- 2000-06-29 ES ES00946917T patent/ES2238297T3/es not_active Expired - Lifetime
-
2001
- 2001-06-08 US US09/877,295 patent/US6511935B2/en not_active Expired - Fee Related
- 2001-12-28 NO NO20016426A patent/NO20016426L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1358202A (zh) | 2002-07-10 |
| DE60019930D1 (de) | 2005-06-09 |
| PL352905A1 (en) | 2003-09-22 |
| AU6060200A (en) | 2001-01-31 |
| US6511935B2 (en) | 2003-01-28 |
| ATE294823T1 (de) | 2005-05-15 |
| CZ20014646A3 (cs) | 2002-09-11 |
| EP1196461B1 (en) | 2005-05-04 |
| NO20016426L (no) | 2002-02-26 |
| AR024606A1 (es) | 2002-10-16 |
| CA2369208A1 (en) | 2001-01-04 |
| KR20020019477A (ko) | 2002-03-12 |
| US20010051586A1 (en) | 2001-12-13 |
| EP1196461A1 (en) | 2002-04-17 |
| JP2003503562A (ja) | 2003-01-28 |
| WO2001000692A1 (en) | 2001-01-04 |
| DE60019930T2 (de) | 2006-02-16 |
| NO20016426D0 (no) | 2001-12-28 |
| AU763949B2 (en) | 2003-08-07 |
| ES2238297T3 (es) | 2005-09-01 |
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