CA2065927C - Compositions de detergent en poudre concentre - Google Patents

Compositions de detergent en poudre concentre

Info

Publication number: CA2065927C
Authority: CA; Canada
Prior art keywords: composition according; weight; sodium; alkyl; bleach
Prior art date: 1991-04-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002065927A

Other languages

English (en)

Other versions

CA2065927A1 (fr

Inventor

Rudolf Johan Martens

Ton Swarthoff

Marten Robert P. Van Vliet

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-04-17

Filing date

1992-04-13

Publication date

1996-12-17

1992-04-13 Application filed by Unilever PLC filed Critical Unilever PLC

1992-10-18 Publication of CA2065927A1 publication Critical patent/CA2065927A1/fr

1996-12-17 Application granted granted Critical

1996-12-17 Publication of CA2065927C publication Critical patent/CA2065927C/fr

2012-04-13 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 87
239000000843 powder Substances 0.000 title claims abstract description 44
239000003599 detergent Substances 0.000 title claims abstract description 36
239000007844 bleaching agent Substances 0.000 claims abstract description 42
239000003054 catalyst Substances 0.000 claims abstract description 31
150000001875 compounds Chemical class 0.000 claims abstract description 25
239000011572 manganese Substances 0.000 claims abstract description 24
229910052748 manganese Inorganic materials 0.000 claims abstract description 19
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 17
102000004190 Enzymes Human genes 0.000 claims abstract description 12
108090000790 Enzymes Proteins 0.000 claims abstract description 12
239000004094 surface-active agent Substances 0.000 claims abstract description 7
150000002696 manganese Chemical class 0.000 claims abstract description 5
-1 inorganic persalts Chemical class 0.000 claims description 19
239000002243 precursor Substances 0.000 claims description 19
150000004965 peroxy acids Chemical class 0.000 claims description 16
229940088598 enzyme Drugs 0.000 claims description 11
102000035195 Peptidases Human genes 0.000 claims description 10
108091005804 Peptidases Proteins 0.000 claims description 10
125000000217 alkyl group Chemical group 0.000 claims description 9
125000000129 anionic group Chemical group 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 7
239000003446 ligand Substances 0.000 claims description 6
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 claims description 6
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000002736 nonionic surfactant Substances 0.000 claims description 5
150000001340 alkali metals Chemical class 0.000 claims description 4
125000002091 cationic group Chemical group 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
150000004967 organic peroxy acids Chemical class 0.000 claims description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
230000002366 lipolytic effect Effects 0.000 claims description 3
230000003647 oxidation Effects 0.000 claims description 3
238000007254 oxidation reaction Methods 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
150000004973 alkali metal peroxides Chemical class 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
239000002280 amphoteric surfactant Substances 0.000 claims description 2
239000003945 anionic surfactant Substances 0.000 claims description 2
239000003093 cationic surfactant Substances 0.000 claims description 2
150000002500 ions Chemical class 0.000 claims description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
150000002894 organic compounds Chemical class 0.000 claims description 2
150000001451 organic peroxides Chemical class 0.000 claims description 2
UYXFOIMFLBVYDL-UHFFFAOYSA-N 1,2,4,7-tetramethyl-1,4,7-triazonane Chemical compound CC1CN(C)CCN(C)CCN1C UYXFOIMFLBVYDL-UHFFFAOYSA-N 0.000 claims 1
229910001914 chlorine tetroxide Inorganic materials 0.000 claims 1
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims 1
238000005406 washing Methods 0.000 abstract description 14
238000004061 bleaching Methods 0.000 abstract description 8
239000000047 product Substances 0.000 description 16
239000000463 material Substances 0.000 description 15
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 14
239000008187 granular material Substances 0.000 description 14
229910052708 sodium Inorganic materials 0.000 description 14
239000011734 sodium Substances 0.000 description 14
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 10
239000000344 soap Substances 0.000 description 10
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
239000002585 base Substances 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
239000010457 zeolite Substances 0.000 description 7
229910021536 Zeolite Inorganic materials 0.000 description 6
239000002253 acid Substances 0.000 description 6
229910000029 sodium carbonate Inorganic materials 0.000 description 6
238000012360 testing method Methods 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 5
239000011575 calcium Substances 0.000 description 5
239000007795 chemical reaction product Substances 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
229910052938 sodium sulfate Inorganic materials 0.000 description 5
235000011152 sodium sulphate Nutrition 0.000 description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
239000004365 Protease Substances 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 4
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
229910052791 calcium Inorganic materials 0.000 description 4
239000001768 carboxy methyl cellulose Substances 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000000034 method Methods 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 4
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 4
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
229910052911 sodium silicate Inorganic materials 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
229910016887 MnIV Inorganic materials 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
108010056079 Subtilisins Proteins 0.000 description 3
102000005158 Subtilisins Human genes 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
229910000323 aluminium silicate Inorganic materials 0.000 description 3
239000002518 antifoaming agent Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
235000019864 coconut oil Nutrition 0.000 description 3
239000003240 coconut oil Substances 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000004744 fabric Substances 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
238000009472 formulation Methods 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
108010020132 microbial serine proteinases Proteins 0.000 description 3
239000002304 perfume Substances 0.000 description 3
230000002797 proteolythic effect Effects 0.000 description 3
125000001453 quaternary ammonium group Chemical group 0.000 description 3
229960001922 sodium perborate Drugs 0.000 description 3
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 2
BPSYZMLXRKCSJY-UHFFFAOYSA-N 1,3,2-dioxaphosphepan-2-ium 2-oxide Chemical compound O=[P+]1OCCCCO1 BPSYZMLXRKCSJY-UHFFFAOYSA-N 0.000 description 2
102000005575 Cellulases Human genes 0.000 description 2
108010084185 Cellulases Proteins 0.000 description 2
239000004150 EU approved colour Substances 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
244000269722 Thea sinensis Species 0.000 description 2
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 2
239000011149 active material Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
235000006708 antioxidants Nutrition 0.000 description 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
239000011976 maleic acid Substances 0.000 description 2
YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical class OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
102000004169 proteins and genes Human genes 0.000 description 2
108090000623 proteins and genes Proteins 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000003352 sequestering agent Substances 0.000 description 2
239000001509 sodium citrate Substances 0.000 description 2
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
229940045872 sodium percarbonate Drugs 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
239000003760 tallow Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
LPLXQXYZLABPRN-VLGUWGOYSA-N (2R,3S,4S,5R)-3,4,5-trihexadecyl-2,3,4,5-tetrahydroxy-2-(hydroxymethyl)-1-phenyldocosane-1,6-dione Chemical compound C(C1=CC=CC=C1)(=O)[C@@]([C@]([C@@]([C@](C(=O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CO LPLXQXYZLABPRN-VLGUWGOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
FNZXYRPYOMKZHY-UHFFFAOYSA-N 2-hexanoyloxybenzenesulfonic acid Chemical compound CCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O FNZXYRPYOMKZHY-UHFFFAOYSA-N 0.000 description 1
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
UTMYFCFWEQRTOM-UHFFFAOYSA-N 3-(carboxymethylperoxy)-3-oxopropanoic acid Chemical compound OC(=O)COOC(=O)CC(O)=O UTMYFCFWEQRTOM-UHFFFAOYSA-N 0.000 description 1
GNSKZCHHQSPRNM-UHFFFAOYSA-N 3-carbonoperoxoyltridecanoic acid Chemical compound CCCCCCCCCCC(CC(O)=O)C(=O)OO GNSKZCHHQSPRNM-UHFFFAOYSA-N 0.000 description 1
LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 1
FCZZQVBGZFNATF-UHFFFAOYSA-N 6-(octylamino)-6-oxohexaneperoxoic acid Chemical compound CCCCCCCCNC(=O)CCCCC(=O)OO FCZZQVBGZFNATF-UHFFFAOYSA-N 0.000 description 1
TVEXGJYMHHTVKP-UHFFFAOYSA-N 6-oxabicyclo[3.2.1]oct-3-en-7-one Chemical group C1C2C(=O)OC1C=CC2 TVEXGJYMHHTVKP-UHFFFAOYSA-N 0.000 description 1
102000004400 Aminopeptidases Human genes 0.000 description 1
108090000915 Aminopeptidases Proteins 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
241000193830 Bacillus <bacterium> Species 0.000 description 1
241000194108 Bacillus licheniformis Species 0.000 description 1
235000014469 Bacillus subtilis Nutrition 0.000 description 1
108010004032 Bromelains Proteins 0.000 description 1
FYJQFTDDXICKAM-UHFFFAOYSA-N CC[Na].OC(OC(C=C1)=CC=C1S(O)(=O)=O)=O.Cl Chemical compound CC[Na].OC(OC(C=C1)=CC=C1S(O)(=O)=O)=O.Cl FYJQFTDDXICKAM-UHFFFAOYSA-N 0.000 description 1
229910021532 Calcite Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
102000000496 Carboxypeptidases A Human genes 0.000 description 1
108010080937 Carboxypeptidases A Proteins 0.000 description 1
108090000317 Chymotrypsin Proteins 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
108060005980 Collagenase Proteins 0.000 description 1
102000029816 Collagenase Human genes 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 description 1
102000004882 Lipase Human genes 0.000 description 1
108090001060 Lipase Proteins 0.000 description 1
239000004367 Lipase Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
108010067372 Pancreatic elastase Proteins 0.000 description 1
102000016387 Pancreatic elastase Human genes 0.000 description 1
108090000526 Papain Proteins 0.000 description 1
108090000284 Pepsin A Proteins 0.000 description 1
102000057297 Pepsin A Human genes 0.000 description 1
229930182556 Polyacetal Natural products 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
239000004614 Process Aid Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
PCKSUVDVOPIZBJ-UHFFFAOYSA-N S(=O)(=O)(O)C1=CC=C(C=C1)C(=O)O.C(CC)[Na] Chemical compound S(=O)(=O)(O)C1=CC=C(C=C1)C(=O)O.C(CC)[Na] PCKSUVDVOPIZBJ-UHFFFAOYSA-N 0.000 description 1
240000004808 Saccharomyces cerevisiae Species 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
108090000631 Trypsin Proteins 0.000 description 1
102000004142 Trypsin Human genes 0.000 description 1
OFQGYBUACFYNQF-UHFFFAOYSA-L [Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-].[Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-] Chemical compound [Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-].[Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-] OFQGYBUACFYNQF-UHFFFAOYSA-L 0.000 description 1
239000012190 activator Substances 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
230000003625 amylolytic effect Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000001580 bacterial effect Effects 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
229960002376 chymotrypsin Drugs 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
229960002424 collagenase Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
150000004696 coordination complex Chemical class 0.000 description 1
230000001461 cytolytic effect Effects 0.000 description 1
RMKNCYHVESPYFD-UHFFFAOYSA-N decan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCC[NH3+] RMKNCYHVESPYFD-UHFFFAOYSA-N 0.000 description 1
UNWDCFHEVIWFCW-UHFFFAOYSA-N decanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCC(=O)OO UNWDCFHEVIWFCW-UHFFFAOYSA-N 0.000 description 1
BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
229960001484 edetic acid Drugs 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
239000008233 hard water Substances 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229940045996 isethionic acid Drugs 0.000 description 1
108010059345 keratinase Proteins 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
150000004668 long chain fatty acids Chemical class 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000012856 packing Methods 0.000 description 1
229940055729 papain Drugs 0.000 description 1
235000019834 papain Nutrition 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
229940111202 pepsin Drugs 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
125000005342 perphosphate group Chemical group 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
VVTMNCICAIKIRN-UHFFFAOYSA-N phenyl benzoate;sodium Chemical compound [Na].C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 VVTMNCICAIKIRN-UHFFFAOYSA-N 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920001983 poloxamer Polymers 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
235000019419 proteases Nutrition 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
235000012217 sodium aluminium silicate Nutrition 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000004289 sodium hydrogen sulphite Substances 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000010186 staining Methods 0.000 description 1
125000005156 substituted alkylene group Chemical group 0.000 description 1
125000005650 substituted phenylene group Chemical group 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
230000007704 transition Effects 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
239000012588 trypsin Substances 0.000 description 1
229960001322 trypsin Drugs 0.000 description 1
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

CA002065927A 1991-04-17 1992-04-13 Compositions de detergent en poudre concentre Expired - Fee Related CA2065927C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB919108136A GB9108136D0 (en)	1991-04-17	1991-04-17	Concentrated detergent powder compositions
GB9108136.4		1991-04-17

Publications (2)

Publication Number	Publication Date
CA2065927A1 CA2065927A1 (fr)	1992-10-18
CA2065927C true CA2065927C (fr)	1996-12-17

Family

ID=10693404

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002065927A Expired - Fee Related CA2065927C (fr)	1991-04-17	1992-04-13	Compositions de detergent en poudre concentre

Country Status (16)

Country	Link
US (1)	US5227084A (fr)
EP (1)	EP0509787B1 (fr)
JP (1)	JPH0768558B2 (fr)
KR (1)	KR960001020B1 (fr)
AU (1)	AU649803B2 (fr)
BR (1)	BR9201436A (fr)
CA (1)	CA2065927C (fr)
DE (1)	DE69201323T2 (fr)
ES (1)	ES2068003T3 (fr)
GB (1)	GB9108136D0 (fr)
ID (1)	ID1012B (fr)
MY (1)	MY107213A (fr)
NO (1)	NO921512L (fr)
TR (1)	TR25735A (fr)
TW (1)	TW232707B (fr)
ZA (1)	ZA922766B (fr)

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1991
- 1991-04-17 GB GB919108136A patent/GB9108136D0/en active Pending
1992
- 1992-04-13 CA CA002065927A patent/CA2065927C/fr not_active Expired - Fee Related
- 1992-04-14 AU AU14885/92A patent/AU649803B2/en not_active Ceased
- 1992-04-15 MY MYPI92000644A patent/MY107213A/en unknown
- 1992-04-15 DE DE69201323T patent/DE69201323T2/de not_active Expired - Fee Related
- 1992-04-15 ES ES92303385T patent/ES2068003T3/es not_active Expired - Lifetime
- 1992-04-15 NO NO92921512A patent/NO921512L/no unknown
- 1992-04-15 ZA ZA922766A patent/ZA922766B/xx unknown
- 1992-04-15 EP EP92303385A patent/EP0509787B1/fr not_active Expired - Lifetime
- 1992-04-16 ID IDP271592A patent/ID1012B/id unknown
- 1992-04-16 US US07/869,587 patent/US5227084A/en not_active Expired - Fee Related
- 1992-04-16 BR BR929201436A patent/BR9201436A/pt not_active Application Discontinuation
- 1992-04-16 TR TR92/0379A patent/TR25735A/xx unknown
- 1992-04-17 KR KR1019920006466A patent/KR960001020B1/ko not_active Expired - Fee Related
- 1992-04-17 JP JP4098279A patent/JPH0768558B2/ja not_active Expired - Lifetime
- 1992-05-18 TW TW081103846A patent/TW232707B/zh active

Also Published As

Publication number	Publication date
AU1488592A (en)	1992-10-22
US5227084A (en)	1993-07-13
TW232707B (fr)	1994-10-21
JPH0768558B2 (ja)	1995-07-26
AU649803B2 (en)	1994-06-02
BR9201436A (pt)	1992-12-01
KR960001020B1 (ko)	1996-01-17
DE69201323T2 (de)	1995-06-08
EP0509787A2 (fr)	1992-10-21
JPH05112799A (ja)	1993-05-07
GB9108136D0 (en)	1991-06-05
TR25735A (tr)	1993-09-01
DE69201323D1 (de)	1995-03-16
ZA922766B (en)	1993-10-15
EP0509787B1 (fr)	1995-02-01
NO921512L (no)	1992-10-19
NO921512D0 (no)	1992-04-15
KR920019921A (ko)	1992-11-20
ID1012B (id)	1993-11-18
ES2068003T3 (es)	1995-04-01
CA2065927A1 (fr)	1992-10-18
MY107213A (en)	1995-10-31
EP0509787A3 (fr)	1992-12-09

Legal Events

Date	Code	Title	Description
1993-03-01	EEER	Examination request
1998-04-14	MKLA	Lapsed

Publication	Publication Date	Title
US5227084A (en)	1993-07-13	Concentrated detergent powder compositions
EP0549271B1 (fr)	1997-10-08	Activateur de blanchiment comprenant un composé du manganèse et un ligand organique
US5580485A (en)	1996-12-03	Bleach activation
AU661522B2 (en)	1995-07-27	Detergent bleach compositions
CA2083658C (fr)	1996-06-25	Catalyseur au manganese
US5244594A (en)	1993-09-14	Bleach activation multinuclear manganese-based coordination complexes
CA2085720A1 (fr)	1993-06-21	Activation de blanchiment
AU749526B2 (en)	2002-06-27	Detergent bleaching composition
EP0909809B1 (fr)	2004-11-24	Activation de blanchiment
WO1996006154A1 (fr)	1996-02-29	Composition de blanchiment detergente
ZA200103295B (en)	2002-06-26	Bleach and oxidation catalyst
WO1996006157A1 (fr)	1996-02-29	Composition detergente de blanchiment
US6432901B2 (en)	2002-08-13	Bleach catalysts
US20200231910A1 (en)	2020-07-23	Bleach or detergent composition
EP0337274B1 (fr)	1994-11-30	Compositions détergentes pour tissus
US5002687A (en)	1991-03-26	Fabric washing compositions
AU613209B2 (en)	1991-07-25	Bleaching detergent compositions
AU733805B2 (en)	2001-05-24	Bleach activation
WO2003014280A1 (fr)	2003-02-20	Compositions de blanchiment
EP0588622A1 (fr)	1994-03-23	Composition de blanchissage